| Common Name: | COBALTOUS CHLORIDE, HEXAHYDRATE |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 9/7/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8GA84 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
COBALTOUS CHLORIDE, HEXAHYDRATE
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
ISSUE DATE: 03/20/2014
REVISION DATE: 09/07/2021
SUPERSEDES: 04/05/2017
VERSION: 1.3
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: SUBSTANCE
SUBSTANCE NAME: COBALTOUS CHLORIDE, HEXAHYDRATE
CAS-NO.: 7791-13-1
PRODUCT CODE: LC13190
FORMULA: COCl2.6H2O
SYNONYMS: COBALT DICHLORIDE, HEXAHYDRATE
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM, INC.
1010 JACKSON'S POINTE CT.
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR +1-703-741-5970
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS US CLASSIFICATION:
ACUTE TOXICITY (ORAL) CATEGORY 4:
H302: HARMFUL IF SWALLOWED
RESPIRATORY SENSITIZATION, CATEGORY 1:
H334:
MAY CAUSE AN ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF
INHALED
SKIN SENSITIZATION, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
GERM CELL MUTAGENICITY CATEGORY 2:
H341: SUSPECTED OF CAUSING GENETIC DEFECTS
CARCINOGENICITY CATEGORY 1B:
H350: MAY CAUSE CANCER
REPRODUCTIVE TOXICITY CATEGORY 1B:
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1:
H400: VERY TOXIC TO AQUATIC LIFE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 1:
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS US LABELING:
HAZARD PICTOGRAMS (GHS US):
EXCLAMATION MARK
HEALTH HAZARD
ENVIRONMENT
SIGNAL WORD (GHS US): DANGER
HAZARD STATEMENTS (GHS US):
H302: HARMFUL IF SWALLOWED
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H334:
MAY CAUSE AN ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF
INHALED
H341: SUSPECTED OF CAUSING GENETIC DEFECTS
H350: MAY CAUSE CANCER
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS (GHS US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P261: AVOID BREATHING DUST.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P272:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION.
P284: WEAR RESPIRATORY PROTECTION.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P304+P341:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P330: IF SWALLOWED, RINSE MOUTH
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P391: COLLECT SPILLAGE.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES:
SUBSTANCE TYPE: MONO-CONSTITUENT
NAME PRODUCT IDENTIFIER % GHS US CLASSIFICATION
COBALTOUS CHLORIDE, (CAS-NO.) 7791-13-1 100 ACUTE TOX. 4 (ORAL),
HEXAHYDRATE H302
(MAIN CONSTITUENT) RESP. SENS. 1, H334
SKIN SENS. 1, H317
MUTA. 2, H341
CARC. 1B, H350
REPR. 1B, H360
AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
3.2. MIXTURES: NOT APPLICABLE
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL: CHECK THE VITAL FUNCTIONS.
UNCONSCIOUS: MAINTAIN ADEQUATE AIRWAY AND RESPIRATION.
RESPIRATORY ARREST: ARTIFICIAL RESPIRATION OR OXYGEN.
CARDIAC ARREST: PERFORM RESUSCITATION.
VICTIM CONSCIOUS WITH LABORED BREATHING: HALF-SEATED.
VICTIM IN SHOCK: ON HIS BACK WITH LEGS SLIGHTLY RAISED.
VOMITING:
PREVENT ASPHYXIA/ASPIRATION PNEUMONIA. PREVENT COOLING BY COVERING THE
VICTIM (NO WARMING UP). KEEP WATCHING THE VICTIM. GIVE PSYCHOLOGICAL AID.
KEEP THE VICTIM CALM, AVOID PHYSICAL STRAIN.
DEPENDING ON THE VICTIM'S CONDITION: DOCTOR/HOSPITAL.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE THE VICTIM INTO FRESH AIR. RESPIRATORY PROBLEMS:
CONSULT A DOCTOR/MEDICAL SERVICE.
FIRST-AID MEASURES AFTER SKIN CONTACT:
WASH IMMEDIATELY WITH LOTS OF WATER. SOAP MAY BE USED. DO NOT APPLY
(CHEMICAL) NEUTRALIZING AGENTS WITHOUT MEDICAL ADVICE. TAKE VICTIM TO A
DOCTOR IF IRRITATION PERSISTS.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE WITH WATER. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO.
CONTINUE RINSING. DO NOT APPLY (CHEMICAL) NEUTRALIZING AGENTS WITHOUT
MEDICAL ADVICE.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH WITH WATER. DO NOT APPLY (CHEMICAL) NEUTRALIZING AGENTS WITHOUT
MEDICAL ADVICE.
IMMEDIATELY AFTER INGESTION:
GIVE LOTS OF WATER TO DRINK. CALL POISON INFORMATION CENTRE
(WWW.BIG.BE/ANTIGIF.HTM). CONSULT A DOCTOR/MEDICAL SERVICE IF YOU FEEL
UNWELL.
INGESTION OF LARGE QUANTITIES: IMMEDIATELY TO HOSPITAL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
HARMFUL IF SWALLOWED. NOT IRRITANT TO SKIN. PRACTICALLY NON-TOXIC IN
CONTACT WITH SKIN (LD50 SKIN >2000 MG/KG).
SYMPTOMS/EFFECTS AFTER INHALATION:
AFTER INHALATION OF DUST: COUGHING. RESPIRATORY DIFFICULTIES.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: NO EFFECTS KNOWN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: NO EFFECTS KNOWN.
SYMPTOMS/EFFECTS AFTER INGESTION:
NAUSEA. DILATION OF THE BLOOD VESSELS. RED SKIN. LOW ARTERIAL PRESSURE.
AFTER ABSORPTION OF LARGE QUANTITIES:
BLUE/GREY DISCOLORATION OF THE SKIN. UNCONTROLLABLE BLEEDING TENDENCY.
DISTURBANCES OF CONSCIOUSNESS.
CHRONIC SYMPTOMS:
SKIN RASH/INFLAMMATION. RESPIRATORY DIFFICULTIES. CARDIAC AND BLOOD
CIRCULATION EFFECTS. RINGING IN THE EARS. AUDITORY DISTURBANCES. THYROID
ENLARGEMENT/AFFECTION.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
ADAPT EXTINGUISHING MEDIA TO THE ENVIRONMENT FOR SURROUNDING FIRES.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD: DIRECT FIRE HAZARD. NON COMBUSTIBLE.
HAZARDOUS DECOMPOSITION PRODUCTS IN CASE OF FIRE:
ON BURNING:
RELEASE OF TOXIC AND CORROSIVE GASES/VAPORS (CHLORINE, HYDROGEN CHLORIDE,
COBALT OXIDES).
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
PRECAUTIONARY MEASURES FIRE:
EXPOSURE TO FIRE/HEAT: KEEP UPWIND.
EXPOSURE TO FIRE/HEAT: CONSIDER EVACUATION.
EXPOSURE TO FIRE/HEAT: HAVE NEIGHBORHOOD CLOSE DOORS AND WINDOWS.
FIREFIGHTING INSTRUCTIONS:
COOL TANKS/DRUMS WITH WATER SPRAY/REMOVE THEM INTO SAFETY. DILUTE TOXIC
GASES WITH WATER SPRAY. TAKE ACCOUNT OF TOXIC/CORROSIVE PRECIPITATION
WATER. TAKE ACCOUNT OF TOXIC FIRE-FIGHTING WATER. USE WATER MODERATELY AND
IF POSSIBLE COLLECT OR CONTAIN IT.
PROTECTION DURING FIREFIGHTING: HEAT/FIRE EXPOSURE:
SELF-CONTAINED BREATHING APPARATUS (EN 136 + EN 137).
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
GLOVES (EN 374). PROTECTIVE CLOTHING (EN 14605 OR EN 13034).
DUST CLOUD PRODUCTION:
SELF-CONTAINED BREATHING APPARATUS (EN 136 + EN 137).
EMERGENCY PROCEDURES:
MARK THE DANGER AREA. PREVENT DUST CLOUD FORMATION. NO NAKED FLAMES. WASH
CONTAMINATED CLOTHES.
MEASURES IN CASE OF DUST RELEASE:
IN CASE OF DUST PRODUCTION:
KEEP UPWIND. DUST PRODUCTION: HAVE NEIGHBORHOOD CLOSE DOORS AND WINDOWS.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. DO NOT BREATHE DUST.
EMERGENCY PROCEDURES:
STOP RELEASE. VENTILATE AREA. IF A MAJOR SPILL OCCURS, ALL PERSONNEL SHOULD
BE IMMEDIATELY EVACUATED AND THE AREA VENTILATED.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT SOIL AND WATER POLLUTION. PREVENT SPREADING IN SEWERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. PLUG THE LEAK,
CUT OFF THE SUPPLY. DAM UP THE SOLID SPILL. KNOCK DOWN/DILUTE DUST CLOUD
WITH WATER SPRAY.
METHODS FOR CLEANING UP:
STOP DUST CLOUD BY COVERING WITH SAND/EARTH. SCOOP SOLID SPILL INTO CLOSING
CONTAINERS. CAREFULLY COLLECT THE SPILL/LEFTOVERS. CLEAN CONTAMINATED
SURFACES WITH AN EXCESS OF WATER. TAKE COLLECTED SPILL TO
MANUFACTURER/COMPETENT AUTHORITY. WASH CLOTHING AND EQUIPMENT AFTER
HANDLING.
6.4. REFERENCE TO OTHER SECTIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
AVOID RAISING DUST. KEEP AWAY FROM NAKED FLAMES/HEAT. MEASURE THE
CONCENTRATION IN THE AIR REGULARLY. CARRY OPERATIONS IN THE OPEN/UNDER
LOCAL EXHAUST/VENTILATION OR WITH RESPIRATORY PROTECTION. COMPLY WITH THE
LEGAL REQUIREMENTS. REMOVE CONTAMINATED CLOTHING IMMEDIATELY. CLEAN
CONTAMINATED CLOTHING. THOROUGHLY CLEAN/DRY THE INSTALLATION BEFORE USE. DO
NOT DISCHARGE THE WASTE INTO THE DRAIN. KEEP CONTAINER TIGHTLY CLOSED.
HYGIENE MEASURES:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS.
HEAT-IGNITION: KEEP SUBSTANCE AWAY FROM: HEAT SOURCES.
PROHIBITIONS ON MIXED STORAGE:
KEEP SUBSTANCE AWAY FROM: OXIDIZING AGENTS. WATER/MOISTURE.
STORAGE AREA:
STORE IN A DRY AREA. STORE AT AMBIENT TEMPERATURE. KEEP CONTAINER IN A
WELL-VENTILATED PLACE. KEEP LOCKED UP. UNAUTHORIZED PERSONS ARE NOT
ADMITTED. MEET THE LEGAL REQUIREMENTS.
SPECIAL RULES ON PACKAGING:
SPECIAL REQUIREMENTS:
CLOSING. WATERTIGHT. DRY. CORRECTLY LABELED. MEET THE LEGAL REQUIREMENTS.
SECURE FRAGILE PACKAGINGS IN SOLID CONTAINERS.
PACKAGING MATERIALS:
SUITABLE MATERIAL: CARDBOARD. SYNTHETIC MATERIAL. GLASS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
COBALTOUS CHLORIDE, HEXAHYDRATE (7791-13-1):
USA - ACGIH - OCCUPATIONAL EXPOSURE LIMITS:
ACGIH OEL TWA: 0.02 MG/M3 (INHALABLE FRACTION)
USA - OSHA - OCCUPATIONAL EXPOSURE LIMITS:
OSHA PEL (TWA) [1]: 0.1 MG/M3
USA - IDLH - OCCUPATIONAL EXPOSURE LIMITS:
IDLH: 20 MG/M3
USA - NIOSH - OCCUPATIONAL EXPOSURE LIMITS:
NIOSH REL (TWA): 0.05 MG/M3
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE. ENSURE ADEQUATE VENTILATION.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
GAS MASK. GLOVES. SAFETY GLASSES. CHEMICAL RESISTANT APRON.
MATERIALS FOR PROTECTIVE CLOTHING:
GIVE GOOD RESISTANCE: BUTYL RUBBER. PVC
HAND PROTECTION: GLOVES
EYE PROTECTION:
FACE SHIELD (EN 166). IN CASE OF DUST PRODUCTION: PROTECTIVE GOGGLES (EN
166)
SKIN AND BODY PROTECTION: PROTECTIVE CLOTHING (EN 14605 OR EN 13034).
IN CASE OF DUST PRODUCTION: HEAD/NECK PROTECTION.
IN CASE OF DUST PRODUCTION: DUSTPROOF CLOTHING (EN 13982)
RESPIRATORY PROTECTION:
DUST PRODUCTION: DUST MASK WITH FILTER TYPE P3.
HIGH DUST PRODUCTION: SELF-CONTAINED BREATHING APPARATUS (EN 136 + EN 137)
PERSONAL PROTECTIVE EQUIPMENT SYMBOL(S):
FULL-FACE RESPIRATOR
GLOVES
SAFETY GLASSES
APRON
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
APPEARANCE: CRYSTALLINE SOLID. CRYSTALLINE POWDER.
COLOR: ROSE TO RED
ODOR: MILD ODOR IRRITATING/PUNGENT ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 7 (AQUEOUS SOLUTION, 58.5%, 20 DEG. C, OECD 105: WATER SOLUBILITY)
MELTING POINT: 735 DEG. C (ANHYDROUS FORM)
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 1049 DEG. C (1013 HPA, ANHYDROUS FORM)
FLASH POINT: NOT APPLICABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: <0.01 HPA (20 DEG. C, ANHYDROUS FORM)
RELATIVE VAPOR DENSITY AT 20 DEG. C: NOT APPLICABLE
RELATIVE DENSITY: 1.92 (20 DEG. C)
DENSITY: 3360 KG/M3 (25 DEG. C, ANHYDROUS FORM)
MOLECULAR MASS: 237.93 G/MOL
SOLUBILITY:
SOLUBLE IN WATER. SOLUBLE IN ETHANOL. SOLUBLE IN ACETONE. SOLUBLE IN
METHANOL. SOLUBLE IN ACETIC ACID. SOLUBLE IN GLYCEROL.
WATER: 5806 G/100 ML (20 DEG. C, OECD 105:
WATER SOLUBILITY, ANHYDROUS FORM)
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
NO DATA AVAILABLE VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: NOT APPLICABLE (INORGANIC)
OTHER PROPERTIES: HYGROSCOPIC. NEUTRAL REACTION.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY: HYGROSCOPIC.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS. MOISTURE.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY (ORAL): HARMFUL IF SWALLOWED.
ACUTE TOXICITY (DERMAL): NOT CLASSIFIED
ACUTE TOXICITY (INHALATION): NOT CLASSIFIED
COBALTOUS CHLORIDE, HEXAHYDRATE (7791-13-1):
LD50 ORAL RAT:
537 MG/KG BODY WEIGHT (EQUIVALENT OR SIMILAR TO OECD 401, RAT, MALE /
FEMALE, EXPERIMENTAL VALUE, HYDRATE FORM, ORAL, 10 DAY(S))
LD50 DERMAL RAT:
>2000 MG/KG (OECD 402: ACUTE DERMAL TOXICITY, 24 H, RAT, MALE / FEMALE,
EXPERIMENTAL VALUE, DERMAL, 14 DAY(S))
ATE US (ORAL): 537 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: 7 (AQUEOUS SOLUTION, 58.5%, 20 DEG. C, OECD 105: WATER SOLUBILITY)
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: 7 (AQUEOUS SOLUTION, 58.5%, 20 DEG. C, OECD 105: WATER SOLUBILITY)
RESPIRATORY OR SKIN SENSITIZATION:
MAY CAUSE AN ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF
INHALED. MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: SUSPECTED OF CAUSING GENETIC DEFECTS.
CARCINOGENICITY: MAY CAUSE CANCER.
REPRODUCTIVE TOXICITY: MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
STOT-SINGLE EXPOSURE: NOT CLASSIFIED
STOT-REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
LIKELY ROUTES OF EXPOSURE: SKIN AND EYE CONTACT. INHALATION.
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
HARMFUL IF SWALLOWED. NOT IRRITANT TO SKIN. PRACTICALLY NON-TOXIC IN
CONTACT WITH SKIN (LD50 SKIN > 2000 MG/KG).
SYMPTOMS/EFFECTS AFTER INHALATION:
AFTER INHALATION OF DUST: COUGHING. RESPIRATORY DIFFICULTIES.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: NO EFFECTS KNOWN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: NO EFFECTS KNOWN.
SYMPTOMS/EFFECTS AFTER INGESTION:
NAUSEA. DILATION OF THE BLOOD VESSELS. RED SKIN. LOW ARTERIAL PRESSURE.
AFTER ABSORPTION OF LARGE QUANTITIES:
BLUE/GREY DISCOLORATION OF THE SKIN. UNCONTROLLABLE BLEEDING
TENDENCY. DISTURBANCES OF CONSCIOUSNESS.
CHRONIC SYMPTOMS:
SKIN RASH/INFLAMMATION. RESPIRATORY DIFFICULTIES. CARDIAC AND BLOOD
CIRCULATION EFFECTS. RINGING IN THE EARS. AUDITORY DISTURBANCES. THYROID
ENLARGEMENT/AFFECTION.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL: DANGEROUS FOR THE ENVIRONMENT.
ECOLOGY - AIR:
NOT INCLUDED IN THE LIST OF SUBSTANCES WHICH MAY CONTRIBUTE TO THE
GREENHOUSE EFFECT (IPCC).
NOT INCLUDED IN THE LIST OF FLUORINATED GREENHOUSE GASES (REGULATION (EU)
NO 517/2014). NOT CLASSIFIED AS DANGEROUS FOR THE OZONE LAYER (REGULATION
(EC) NO 1005/2009).
ECOLOGY - WATER:
TOXIC TO CRUSTACEA. TOXIC TO FISHES. INHIBITION OF ACTIVATED SLUDGE. VERY
TOXIC TO ALGAE. COBALTOUS CHLORIDE, HEXAHYDRATE (7791-13-1)
LC50 FISH 1:
1.512 MG/L (ASTM, 96 H, ONCORHYNCHUS MYKISS, FLOW-THROUGH SYSTEM, FRESH
WATER, EXPERIMENTAL VALUE, ANHYDROUS FORM)
EC50 DAPHNIA 1:
5.89 MG/L (OECD 202: DAPHNIA SP. ACUTE IMMOBILIZATION TEST, 48 H, DAPHNIA
MAGNA, STATIC SYSTEM, FRESH WATER, READ-ACROSS, LOCOMOTOR EFFECT)
ERC50 (ALGAE):
144 (MICRO)G/L (OECD 201: ALGA, GROWTH INHIBITION TEST, 72 H,
PSEUDOKIRCHNERIELLA SUBCAPITATA, STATIC SYSTEM, FRESH WATER, EXPERIMENTAL
VALUE, ANHYDROUS FORM)
12.2. PERSISTENCE AND DEGRADABILITY:
COBALTOUS CHLORIDE, HEXAHYDRATE (7791-13-1):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY IN SOIL: NOT APPLICABLE.
BIODEGRADABILITY: NOT APPLICABLE.
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE (INORGANIC)
THOD: NOT APPLICABLE (INORGANIC)
12.3. BIOACCUMULATIVE POTENTIAL:
COBALTOUS CHLORIDE, HEXAHYDRATE (7791-13-1):
BCF FISH 1:
4.6 (56 DAY(S), ONCORHYNCHUS MYKISS, SEMI-STATIC SYSTEM, FRESH WATER,
READ-ACROSS, FRESH WEIGHT)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
12.4. MOBILITY IN SOIL:
COBALTOUS CHLORIDE, HEXAHYDRATE (7791-13-1):
ECOLOGY - SOIL:
NO (TEST)DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE. TOXIC TO FLORA.
12.5. OTHER ADVERSE EFFECTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DO NOT DISCHARGE INTO DRAINS OR THE ENVIRONMENT. REMOVE WASTE IN ACCORDANCE
WITH LOCAL AND/OR NATIONAL REGULATIONS. HAZARDOUS WASTE SHALL NOT BE MIXED
TOGETHER WITH OTHER WASTE. DIFFERENT TYPES OF HAZARDOUS WASTE SHALL NOT BE
MIXED TOGETHER IF THIS MAY ENTAIL A RISK OF POLLUTION OR CREATE PROBLEMS
FOR THE FURTHER MANAGEMENT OF THE WASTE. HAZARDOUS WASTE SHALL BE MANAGED
RESPONSIBLY. ALL ENTITIES THAT STORE, TRANSPORT OR HANDLE HAZARDOUS WASTE
SHALL TAKE THE NECESSARY MEASURES TO PREVENT RISKS OF POLLUTION OR DAMAGE
TO PEOPLE OR ANIMALS. RECYCLE/REUSE. REMOVE TO AN AUTHORIZED DUMP (CLASS
I). PRECIPITATE/MAKE INSOLUBLE.
ADDITIONAL INFORMATION:
HAZARDOUS WASTE ACCORDING TO DIRECTIVE 2008/98/EC, AS AMENDED BY REGULATION
(EU) NO 1357/2014 AND REGULATION (EU) NO 2017/997.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S., 8, III
UN-NO.(DOT): UN3260
PROPER SHIPPING NAME (DOT): CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
TRANSPORT HAZARD CLASS(ES) (DOT):
8 - CLASS 8 - CORROSIVE MATERIAL 49 CFR 173.136
PACKING GROUP (DOT): III - MINOR DANGER
HAZARD LABELS (DOT): 8 - CORROSIVE
CORROSIVE, CLASS/DIVISION 8
DANGEROUS FOR THE ENVIRONMENT: YES
MARINE POLLUTANT: YES
ENVIRONMENT
DOT PACKAGING NON BULK (49 CFR 173.XXX): 213
DOT PACKAGING BULK (49 CFR 173.XXX): 240
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB8 - AUTHORIZED IBCS: METAL (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B AND
31N); RIGID PLASTICS (11H1, 11H2, 21H1, 21H2, 31H1 AND 31H2); COMPOSITE
(11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 AND 31HZ2); FIBERBOARD (11G); WOODEN
(11C, 11D AND 11F); FLEXIBLE (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2,
13L3, 13L4, 13M1 OR 13M2).
IP3 - FLEXIBLE IBCS MUST BE SIFT-PROOF AND WATER-RESISTANT OR MUST BE
FITTED WITH A SIFT-PROOF AND WATER-RESISTANT LINER.
T1 - 1.5 178.274(D)(2) NORMAL............. 178.275(D)(2)
TP33 - THE PORTABLE TANK INSTRUCTION ASSIGNED FOR THIS SUBSTANCE APPLIES
FOR GRANULAR AND POWDERED SOLIDS AND FOR SOLIDS WHICH ARE FILLED AND
DISCHARGED AT TEMPERATURES ABOVE THEIR MELTING POINT WHICH ARE COOLED AND
TRANSPORTED AS A SOLID MASS. SOLID SUBSTANCES TRANSPORTED OR OFFERED FOR
TRANSPORT ABOVE THEIR MELTING POINT ARE AUTHORIZED FOR TRANSPORTATION IN
PORTABLE TANKS CONFORMING TO THE PROVISIONS OF PORTABLE TANK INSTRUCTION T4
FOR SOLID SUBSTANCES OF PACKING GROUP III OR T7 FOR SOLID SUBSTANCES OF
PACKING GROUP II, UNLESS A TANK WITH MORE STRINGENT REQUIREMENTS FOR
MINIMUM SHELL THICKNESS, MAXIMUM ALLOWABLE WORKING PRESSURE,
PRESSURE-RELIEF DEVICES OR BOTTOM OUTLETS ARE ASSIGNED IN WHICH CASE THE
MORE STRINGENT TANK INSTRUCTION AND SPECIAL PROVISIONS SHALL APPLY. FILLING
LIMITS MUST BE IN ACCORDANCE WITH PORTABLE TANK SPECIAL PROVISION TP3.
SOLIDS MEETING THE DEFINITION OF AN ELEVATED TEMPERATURE MATERIAL MUST BE
TRANSPORTED IN ACCORDANCE WITH THE APPLICABLE REQUIREMENTS OF THIS
SUBCHAPTER.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 154
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 25 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 100 KG
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
COBALTOUS CHLORIDE, HEXAHYDRATE (7791-13-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SARA SECTION 311/312 HAZARD CLASSES:
HEALTH HAZARD - ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
HEALTH HAZARD - CARCINOGENICITY
HEALTH HAZARD - RESPIRATORY OR SKIN SENSITIZATION
HEALTH HAZARD - GERM CELL MUTAGENICITY
HEALTH HAZARD - REPRODUCTIVE TOXICITY
ALL COMPONENTS OF THIS PRODUCT ARE LISTED AS ACTIVE, OR EXCLUDED FROM
LISTING, ON THE UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC
SUBSTANCES CONTROL ACT (TSCA) INVENTORY
COBALTOUS CHLORIDE, HEXAHYDRATE CAS-NO. 7791-13-1 100%
15.2. INTERNATIONAL REGULATIONS:
CANADA:
COBALTOUS CHLORIDE, HEXAHYDRATE (7791-13-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR
REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS:
REVISION DATE: 09/07/2021
FULL TEXT OF H - AND EUH-STATEMENTS: SEE SECTION 16:
H302: HARMFUL IF SWALLOWED
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H334:
MAY CAUSE AN ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF
INHALED
H341: SUSPECTED OF CAUSING GENETIC DEFECTS
H350: MAY CAUSE CANCER
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD
H400: VERY TOXIC TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN UNDER TYPICAL FIRE
CONDITIONS, INCLUDING INTRINSICALLY NONCOMBUSTIBLE
MATERIALS SUCH AS CONCRETE, STONE, AND SAND.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 0 MINIMAL HAZARD - MATERIALS THAT WILL NOT BURN
PERSONAL PROTECTION F
F - SAFETY GLASSES, GLOVES, SYNTHETIC APRON, DUST
RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)