| Common Name: | PHENOLPHTHALEIN, 1% IN 60% ISOPROPANOL |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 1/23/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8GCX8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
PHENOLPHTHALEIN, 1% IN 60% ISOPROPANOL
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 12/17/2013
REVISION DATE: 01/23/2018
SUPERSEDES: 01/23/2018
VERSION: 2.1
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION
PRODUCT FORM: MIXTURES
PRODUCT NAME: PHENOLPHTHALEIN, 1% IN 60% ISOPROPANOL
PRODUCT CODE: LC18210
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAMMABLE LIQUIDS CATEGORY 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A:
H319: CAUSES SERIOUS EYE IRRITATION
CARCINOGENICITY CATEGORY 2:
H351: SUSPECTED OF CAUSING CANCER
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3:
H335: MAY CAUSE RESPIRATORY IRRITATION
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
H351: SUSPECTED OF CAUSING CANCER
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT, HOT SURFACES, OPEN FLAMES, SPARKS. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL, LIGHTING, VENTILATING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P261: AVOID BREATHING MIST, SPRAY, VAPORS.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR EYE PROTECTION, FACE PROTECTION, PROTECTIVE CLOTHING, PROTECTIVE
GLOVES.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P337+P313 - IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P370+P378:
IN CASE OF FIRE:
USE DRY CHEMICAL POWDER, ALCOHOL-RESISTANT FOAM, CARBON DIOXIDE (CO2) TO
EXTINGUISH
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
ISOPROPYL ALCOHOL (CAS-NO.) 67-63-0 60 FLAM. LIQ. 2, H225
(2-PROPANOL) EYE IRRIT. 2A, H319
STOT SE 3, H335
WATER (CAS-NO.) 7732-18-5 39 NOT CLASSIFIED
PHENOLPHTHALEIN, ACS (CAS-NO.) 77-09-8 1 CARC. 2, H351
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL: CHECK THE VITAL FUNCTIONS.
UNCONSCIOUS: MAINTAIN ADEQUATE AIRWAY AND RESPIRATION.
RESPIRATORY ARREST: ARTIFICIAL RESPIRATION OR OXYGEN.
CARDIAC ARREST: PERFORM RESUSCITATION.
VICTIM CONSCIOUS WITH LABORED BREATHING: HALF-SEATED.
VICTIM IN SHOCK: ON HIS BACK WITH LEGS SLIGHTLY RAISED.
VOMITING:
PREVENT ASPHYXIA/ASPIRATION PNEUMONIA. PREVENT COOLING BY COVERING THE
VICTIM (NO WARMING UP). KEEP WATCHING THE VICTIM. GIVE PSYCHOLOGICAL AID.
KEEP THE VICTIM CALM, AVOID PHYSICAL STRAIN.
DEPENDING ON THE VICTIM'S CONDITION:
DOCTOR/HOSPITAL. NEVER GIVE ALCOHOL TO DRINK. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE
LABEL WHERE POSSIBLE). SUSPECTED OF CAUSING CANCER.
FIRST-AID MEASURES AFTER INHALATION: REMOVE THE VICTIM INTO FRESH AIR.
RESPIRATORY PROBLEMS:
CONSULT A DOCTOR/MEDICAL SERVICE. REMOVE VICTIM TO FRESH AIR AND KEEP AT
REST IN A POSITION COMFORTABLE FOR BREATHING. CALL A POISON CENTER OR
DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE WITH WATER. SOAP MAY BE USED. DO NOT APPLY (CHEMICAL) NEUTRALIZING
AGENTS. TAKE VICTIM TO A DOCTOR IF IRRITATION PERSISTS. RINSE SKIN WITH
WATER/SHOWER. REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. RINSE IMMEDIATELY WITH
PLENTY OF WATER. DO NOT APPLY NEUTRALIZING AGENTS. TAKE VICTIM TO AN
OPHTHALMOLOGIST IF IRRITATION PERSISTS. REMOVE CONTACT LENSES, IF PRESENT
AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INGESTION: RINSE MOUTH WITH WATER.
IMMEDIATELY AFTER INGESTION:
GIVE LOTS OF WATER TO DRINK. DO NOT INDUCE VOMITING. GIVE ACTIVATED
CHARCOAL. CALL POISON INFORMATION CENTRE (WWW.BIG.BE/ANTIGIF.HTM). CONSULT
A DOCTOR/MEDICAL SERVICE IF YOU FEEL UNWELL.
INGESTION OF LARGE QUANTITIES: IMMEDIATELY TO HOSPITAL.
DOCTOR:
GASTRIC LAVAGE. RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY
MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS AFTER INHALATION:
EXPOSURE TO HIGH CONCENTRATIONS:
COUGHING. DRY/SORE THROAT. CENTRAL NERVOUS SYSTEM DEPRESSION. DIZZINESS.
HEADACHE. NARCOSIS. MAY CAUSE DROWSINESS OR DIZZINESS.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: DRY SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
IRRITATION OF THE EYE TISSUE. CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION:
AFTER ABSORPTION OF LARGE QUANTITIES:
CENTRAL NERVOUS SYSTEM DEPRESSION. HEADACHE. DILATION OF THE BLOOD VESSELS.
LOW ARTERIAL PRESSURE. NAUSEA. VOMITING. ABDOMINAL PAIN. DISTURBED MOTOR
RESPONSE. DISTURBANCES OF CONSCIOUSNESS.
FOLLOWING SYMPTOMS MAY APPEAR LATER:
BODY TEMPERATURE FALL. SLOWING RESPIRATION.
CHRONIC SYMPTOMS:
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
RED SKIN. DRY SKIN. ITCHING. CRACKING OF THE SKIN. SKIN RASH/INFLAMMATION.
IMPAIRED MEMORY.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY. POLYVALENT FOAM. ALCOHOL-RESISTANT FOAM. BC POWDER. CARBON
DIOXIDE. FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA:
SOLID WATER JET INEFFECTIVE AS EXTINGUISHING MEDIUM. DO NOT USE A HEAVY
WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD:
DIRECT FIRE HAZARD. HIGHLY FLAMMABLE. GAS/VAPOR FLAMMABLE WITH AIR WITHIN
EXPLOSION LIMITS. INDIRECT FIRE HAZARD. MAY BE IGNITED BY SPARKS.
GAS/VAPOR SPREADS AT FLOOR LEVEL:
IGNITION HAZARD. HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD:
DIRECT EXPLOSION HAZARD. GAS/VAPOUR EXPLOSIVE WITH AIR WITHIN EXPLOSION
LIMITS.
INDIRECT EXPLOSION HAZARD. MAY BE IGNITED BY SPARKS. REACTIONS WITH
EXPLOSION HAZARDS: SEE "REACTIVITY HAZARD". MAY FORM FLAMMABLE/EXPLOSIVE
VAPOR-AIR MIXTURE.
REACTIVITY: VIOLENT TO EXPLOSIVE REACTION WITH (STRONG) OXIDIZERS.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
COOL TANKS/DRUMS WITH WATER SPRAY/REMOVE THEM INTO SAFETY. DO NOT MOVE THE
LOAD IF EXPOSED TO HEAT. USE WATER SPRAY OR FOG FOR COOLING EXPOSED
CONTAINERS. EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT
FIRE-FIGHTING WATER FROM ENTERING ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
HEAT/FIRE EXPOSURE:
COMPRESSED AIR/OXYGEN APPARATUS. DO NOT ENTER FIRE AREA WITHOUT PROPER
PROTECTIVE EQUIPMENT, INCLUDING RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: GLOVES. PROTECTIVE GOGGLES. PROTECTIVE CLOTHING.
LARGE SPILLS/IN ENCLOSED SPACES: COMPRESSED AIR APPARATUS.
EMERGENCY PROCEDURES:
KEEP UPWIND. MARK THE DANGER AREA. CONSIDER EVACUATION. SEAL OFF LOW-LYING
AREAS. CLOSE DOORS AND WINDOWS OF ADJACENT PREMISES. STOP ENGINES AND NO
SMOKING. NO NAKED FLAMES OR SPARKS. SPARK- AND EXPLOSION-PROOF APPLIANCES
AND LIGHTING EQUIPMENT. KEEP CONTAINERS CLOSED. WASH CONTAMINATED CLOTHES.
EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. AVOID BREATHING MIST, SPRAY.
EMERGENCY PROCEDURES: STOP LEAK IF SAFE TO DO SO. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT SPREADING IN SEWERS. PREVENT ENTRY TO SEWERS AND PUBLIC WATERS.
NOTIFY AUTHORITIES IF LIQUID ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. CONSULT
"MATERIAL-HANDLING" TO SELECT MATERIAL OF CONTAINERS. PLUG THE LEAK, CUT
OFF THE SUPPLY. DAM UP THE LIQUID SPILL. TRY TO REDUCE EVAPORATION. MEASURE
THE CONCENTRATION OF THE EXPLOSIVE GAS-AIR MIXTURE. DILUTE/DISPERSE
COMBUSTIBLE GAS/VAPOUR WITH WATER CURTAIN. PROVIDE EQUIPMENT/RECEPTACLES
WITH EARTHING. DO NOT USE COMPRESSED AIR FOR PUMPING OVER SPILLS.
METHODS FOR CLEANING UP:
TAKE UP LIQUID SPILL INTO ABSORBENT MATERIAL, E.G.:
DRY SAND/EARTH/VERMICULITE OR POWDERED LIMESTONE. SCOOP ABSORBED SUBSTANCE
INTO CLOSING CONTAINERS. SEE "MATERIAL-HANDLING" FOR SUITABLE CONTAINER
MATERIALS. DAMAGED/COOLED TANKS MUST BE EMPTIED. DO NOT USE COMPRESSED AIR
FOR PUMPING OVER SPILLS. CAREFULLY COLLECT THE SPILL/LEFTOVERS. CLEAN
CONTAMINATED SURFACES WITH AN EXCESS OF WATER. TAKE COLLECTED SPILL TO
MANUFACTURER/COMPETENT AUTHORITY. WASH CLOTHING AND EQUIPMENT AFTER
HANDLING. SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS
EARTH AS SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER
MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
COMPLY WITH THE LEGAL REQUIREMENTS. REMOVE CONTAMINATED CLOTHING
IMMEDIATELY. CLEAN CONTAMINATED CLOTHING. HANDLE UNCLEANED EMPTY CONTAINERS
AS FULL ONES. THOROUGHLY CLEAN/DRY THE INSTALLATION BEFORE USE. DO NOT
DISCHARGE THE WASTE INTO THE DRAIN. DO NOT USE COMPRESSED AIR FOR PUMPING
OVER. USE SPARK-/EXPLOSION PROOF APPLIANCES AND LIGHTING SYSTEM. TAKE
PRECAUTIONS AGAINST ELECTROSTATIC CHARGES. KEEP AWAY FROM NAKED
FLAMES/HEAT. KEEP AWAY FROM IGNITION SOURCES/SPARKS. OBSERVE NORMAL HYGIENE
STANDARDS. KEEP CONTAINER TIGHTLY CLOSED. MEASURE THE CONCENTRATION IN THE
AIR REGULARLY. WORK UNDER LOCAL EXHAUST/VENTILATION. WASH HANDS AND OTHER
EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING
AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN PROCESS AREA TO PREVENT
FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING. USE ONLY NON-SPARKING
TOOLS. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL
SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING MIST,
VAPORS, SPRAY. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: HEAT SOURCES, IGNITION SOURCES, INCOMPATIBLE MATERIALS. KEEP IN
FIREPROOF PLACE. KEEP CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS:
OXIDIZING AGENT. SILVER NITRATE. SODIUM HYPOCHLORITE. STRONG BASES. STRONG
ACIDS.
INCOMPATIBLE MATERIALS: DIRECT SUNLIGHT. HEAT SOURCES. SOURCES OF IGNITION.
HEAT-IGNITION:
KEEP SUBSTANCE AWAY FROM: HEAT SOURCES. IGNITION SOURCES.
PROHIBITIONS ON MIXED STORAGE:
KEEP SUBSTANCE AWAY FROM:
OXIDIZING AGENTS. STRONG ACIDS. (STRONG) BASES. AMINES. HALOGENS.
STORAGE AREA:
STORE IN A COOL AREA. STORE IN A DRY AREA. VENTILATION AT FLOOR LEVEL.
FIREPROOF STOREROOM. PROVIDE FOR AN AUTOMATIC SPRINKLER SYSTEM. PROVIDE FOR
A TUB TO COLLECT SPILLS. PROVIDE THE TANK WITH EARTHING. MAY BE STORED
UNDER NITROGEN. MEET THE LEGAL REQUIREMENTS.
SPECIAL RULES ON PACKAGING:
SPECIAL REQUIREMENTS:
CLOSING. WITH PRESSURE RELIEF VALVE. DRY. CLEAN. CORRECTLY LABELED. MEET
THE LEGAL REQUIREMENTS. SECURE FRAGILE PACKAGINGS IN SOLID CONTAINERS.
PACKAGING MATERIALS:
SUITABLE MATERIAL:
STAINLESS STEEL. MONEL STEEL. CARBON STEEL. COPPER. NICKEL. BRONZE. GLASS.
TEFLON. POLYETHYLENE. POLYPROPYLENE. ZINC.
MATERIAL TO AVOID: STEEL WITH RUBBER INNER LINING. ALUMINIUM.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
ACGIH:
ACGIH TWA (PPM):
200 PPM (2-PROPANOL; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT 8 H; TLV -
ADOPTED VALUE)
ACGIH:
ACGIH STEL (PPM):
400 PPM (2-PROPANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 980 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 400 PPM
IDLH:
US IDLH (PPM): 2000 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 980 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 400 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 1225 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 500 PPM
WATER (7732-18-5): NOT APPLICABLE
PHENOLPHTHALEIN, ACS (77-09-8): NOT APPLICABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST
VENTILATION.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT: GAS MASK. GLOVES. SAFETY GLASSES.
MATERIALS FOR PROTECTIVE CLOTHING:
GIVE EXCELLENT RESISTANCE:
BUTYL RUBBER. NITRILE RUBBER. VITON. POLYETHYLENE/ETHYLENEVINYLALCOHOL.
GIVE GOOD RESISTANCE: NEOPRENE.
GIVE LESS RESISTANCE: PVC. NEOPRENE/NATURAL RUBBER.
GIVE POOR RESISTANCE: NATURAL RUBBER. POLYETHYLENE. PVA
HAND PROTECTION: GLOVES. WEAR PROTECTIVE GLOVES.
EYE PROTECTION: SAFETY GLASSES. CHEMICAL GOGGLES OR SAFETY GLASSES
SKIN AND BODY PROTECTION: PROTECTIVE CLOTHING
RESPIRATORY PROTECTION: GAS MASK
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: LIQUID.
COLOR: COLORLESS
ODOR: ALCOHOL ODOR STUFFY ODOR MILD ODOR
ODOR THRESHOLD:
3 - 610 PPM
8 - 1499 MG/M3
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): HIGHLY FLAMMABLE LIQUID AND VAPOR.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: 2.1
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY:
SOLUBLE IN WATER. SOLUBLE IN ETHANOL. SOLUBLE IN ETHER. SOLUBLE IN ACETONE.
ETHANOL: COMPLETE
ETHER: COMPLETE
ACETONE: SOLUBLE
LOG POW: 0.05 (EXPERIMENTAL VALUE)
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: (25 DEG. C)
VISCOSITY, DYNAMIC: (25 DEG. C)
EXPLOSION LIMITS:
2 - 13 VOL%
50 - 335 G/M3
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
OTHER PROPERTIES:
GAS/VAPOUR HEAVIER THAN AIR AT 20 DEG. C. CLEAR. VOLATILE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
VIOLENT TO EXPLOSIVE REACTION WITH (STRONG) OXIDIZERS.
10.2. CHEMICAL STABILITY:
HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
MAY REACT VIOLENTLY WITH OXIDANTS.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. HEAT. HIGH TEMPERATURE. INCOMPATIBLE MATERIALS. OPEN
FLAME. SPARKS. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS. STRONG ACIDS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON DIOXIDE. CARBON MONOXIDE. FUME. MAY RELEASE FLAMMABLE GASES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LD50 DERMAL RABBIT:
12870 MG/KG (RABBIT; EXPERIMENTAL VALUE; EQUIVALENT OR SIMILAR TO OECD 402;
16.4; RABBIT)
LC50 INHALATION RAT (MG/L): 73 MG/L/4H (RAT)
ATE US (ORAL): 5045 MG/KG BODY WEIGHT
ATE US (DERMAL): 12870 MG/KG BODY WEIGHT
ATE US (VAPORS): 73 MG/L/4H
ATE US (DUST, MIST): 73 MG/L/4H
WATER (7732-18-5):
LD50 ORAL RAT: >/=90000 MG/KG
ATE US (ORAL): 90000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER.
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
IARC GROUP: 3 - NOT CLASSIFIABLE
PHENOLPHTHALEIN, ACS (77-09-8):
IARC GROUP: 2B - POSSIBLY CARCINOGENIC TO HUMANS
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/EFFECTS AFTER INHALATION:
EXPOSURE TO HIGH CONCENTRATIONS:
COUGHING. DRY/SORE THROAT. CENTRAL NERVOUS SYSTEM DEPRESSION. DIZZINESS.
HEADACHE. NARCOSIS. MAY CAUSE DROWSINESS OR DIZZINESS.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: DRY SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
IRRITATION OF THE EYE TISSUE. CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION:
AFTER ABSORPTION OF LARGE QUANTITIES:
CENTRAL NERVOUS SYSTEM DEPRESSION. HEADACHE. DILATION OF THE BLOOD VESSELS.
LOW ARTERIAL PRESSURE. NAUSEA. VOMITING. ABDOMINAL PAIN. DISTURBED MOTOR
RESPONSE. DISTURBANCES OF CONSCIOUSNESS.
FOLLOWING SYMPTOMS MAY APPEAR LATER:
BODY TEMPERATURE FALL. SLOWING RESPIRATION.
CHRONIC SYMPTOMS:
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
RED SKIN. DRY SKIN. ITCHING. CRACKING OF THE SKIN. SKIN RASH/INFLAMMATION.
IMPAIRED MEMORY.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL:
CLASSIFICATION CONCERNING THE ENVIRONMENT: NOT APPLICABLE.
ECOLOGY - AIR: TA-LUFT KLASSE 5.2.5.
ECOLOGY - WATER:
GROUND WATER POLLUTANT. NOT HARMFUL TO FISHES (LC50(96H) >1000 MG/L). NOT
HARMFUL TO INVERTEBRATES (DAPHNIA). NOT HARMFUL TO ALGAE (EC50 (72H) >1000
MG/L). INHIBITION OF ACTIVATED SLUDGE.
PHENOLPHTHALEIN, 1% IN 60% ISOPROPANOL:
THRESHOLD LIMIT ALGAE 1:
>1000 MG/L (EC50; UBA; 72 H; SCENEDESMUS SUBSPICATUS)
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LC50 FISH 2:
9640 MG/L (LC50; OECD 203: FISH, ACUTE TOXICITY TEST; 96 H; PIMEPHALES
PROMELAS; FLOW-THROUGH SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
EC50 DAPHNIA 2: 13299 MG/L (EC50; OTHER; 48 H; DAPHNIA MAGNA)
THRESHOLD LIMIT ALGAE 1:
>1000 MG/L (EC50; UBA; 72 H; SCENEDESMUS SUBSPICATUS)
PHENOLPHTHALEIN, ACS (77-09-8):
EC50 DAPHNIA 1:
>100 MG/L (EC50; OECD 202: DAPHNIA SP. ACUTE IMMOBILIZATION TEST; 48 H;
DAPHNIA MAGNA; STATIC SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
THRESHOLD LIMIT ALGAE 1:
8.9 MG/L (EC50; OECD 201: ALGA, GROWTH INHIBITION TEST; 72 H; DESMODESMUS
SUBSPICATUS; STATIC SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
12.2. PERSISTENCE AND DEGRADABILITY:
PHENOLPHTHALEIN, 1% IN 60% ISOPROPANOL:
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN
THE SOIL UNDER ANAEROBIC CONDITIONS. NO TEST DATA ON MOBILITY OF THE
SUBSTANCE AVAILABLE. NOT ESTABLISHED.
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN
THE SOIL UNDER ANAEROBIC CONDITIONS. NO TEST DATA ON MOBILITY OF THE
SUBSTANCE AVAILABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): 1.19 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.23 G O2/G SUBSTANCE
THOD: 2.4 G O2/G SUBSTANCE
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
PHENOLPHTHALEIN, ACS (77-09-8):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. NO TEST DATA ON MOBILITY OF THE SUBSTANCE
AVAILABLE. PHOTODEGRADATION IN THE AIR.
12.3. BIOACCUMULATIVE POTENTIAL:
PHENOLPHTHALEIN, 1% IN 60% ISOPROPANOL:
LOG POW: 0.05 (EXPERIMENTAL VALUE)
PHENOLPHTHALEIN, 1% IN 60% ISOPROPANOL:
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LOG POW: 0.05 (WEIGHT OF EVIDENCE APPROACH; OTHER; 25 DEG. C)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
PHENOLPHTHALEIN, ACS (77-09-8):
LOG POW: 2.41 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL:
LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
12.4. MOBILITY IN SOIL:
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
SURFACE TENSION: 0.021 N/M (25 DEG. C)
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
REMOVE WASTE IN ACCORDANCE WITH LOCAL AND/OR NATIONAL REGULATIONS.
HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER WITH OTHER WASTE. DIFFERENT
TYPES OF HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER IF THIS MAY ENTAIL A
RISK OF POLLUTION OR CREATE PROBLEMS FOR THE FURTHER MANAGEMENT OF THE
WASTE. HAZARDOUS WASTE SHALL BE MANAGED RESPONSIBLY. ALL ENTITIES THAT
STORE, TRANSPORT OR HANDLE HAZARDOUS WASTE SHALL TAKE THE NECESSARY
MEASURES TO PREVENT RISKS OF POLLUTION OR DAMAGE TO PEOPLE OR ANIMALS.
RECYCLE BY DISTILLATION. REMOVE TO AN AUTHORIZED WASTE INCINERATOR FOR
SOLVENTS WITH ENERGY RECOVERY. DO NOT DISCHARGE INTO SURFACE WATER. OBTAIN
THE CONSENT OF POLLUTION CONTROL AUTHORITIES BEFORE DISCHARGING TO
WASTEWATER TREATMENT PLANTS. DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH
LOCAL/NATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
LWCA (THE NETHERLANDS):
KGA CATEGORY 03. HAZARDOUS WASTE ACCORDING TO DIRECTIVE 2008/98/EC. HANDLE
EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1219 ISOPROPANOL, 3, II
UN-NO.(DOT): UN1219
PROPER SHIPPING NAME (DOT): ISOPROPANOL
TRANSPORT HAZARD CLASS(ES) (DOT):
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB2 - AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE
(31HZ1).
ADDITIONAL REQUIREMENT:
ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C
(1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED.
T4 - 2.65 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 4B; 150
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
B - (I) THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO
VESSEL AND ON A PASSENGER VESSEL CARRYING A NUMBER OF PASSENGERS LIMITED TO
NOT MORE THAN THE LARGER OF 25 PASSENGERS, OR ONE PASSENGER PER EACH 3 M OF
OVERALL VESSEL LENGTH; AND (II) "ON DECK ONLY" ON PASSENGER VESSELS IN
WHICH THE NUMBER OF PASSENGERS SPECIFIED IN PARAGRAPH (K)(2)(I) OF THIS
SECTION IS EXCEEDED.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
PHENOLPHTHALEIN, 1% IN 60% ISOPROPANOL:
SARA SECTION 311/312 HAZARD CLASSES: FIRE HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
ISOPROPYL ALCOHOL (2-PROPANOL) CAS-NO. 67-63-0 60%
PHENOLPHTHALEIN, ACS CAS-NO. 77-09-8 1%
15.2. INTERNATIONAL REGULATIONS:
CANADA: NO ADDITIONAL INFORMATION AVAILABLE
PHENOLPHTHALEIN, ACS (77-09-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
PHENOLPHTHALEIN, ACS (77-09-8):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
THIS PRODUCT CAN EXPOSE YOU TO PHENOLPHTHALEIN, ACS, WHICH IS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CANCER. FOR MORE INFORMATION GO TO
WWW.P65WARNINGS.CA.GOV.
PHENOLPHTHALEIN, ACS (77-09-8):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: YES
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANT RISK LEVEL (NSRL):
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 01/23/2018
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
H351: SUSPECTED OF CAUSING CANCER
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 3 SERIOUS HAZARD - MATERIALS CAPABLE OF IGNITION UNDER
ALMOST ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73 F AND
BOILING POINTS ABOVE 100 F. AS WELL AS LIQUIDS WITH
FLASH POINTS BETWEEN 73 F AND 100 F. (CLASSES IB &
IC)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION H
H - SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, VAPOR
RESPIRATOR
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ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
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