| Common Name: | METHYL ORANGE, SODIUM SALT, ACS |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 3/13/2019 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8GF68 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
METHYL ORANGE, SODIUM SALT, ACS
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 01/15/2014
REVISION DATE: 03/13/2019
SUPERSEDES: 12/12/2017
VERSION: 1.4
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: SUBSTANCE
SUBSTANCE NAME: METHYL ORANGE, SODIUM SALT, ACS
CAS-NO.: 547-58-0
PRODUCT CODE: LC16980
FORMULA: C14H14N3NaO3S
SYNONYMS:
4-DIMETHYLAMINOAZOBENZENE-4'-SULFONIC ACID SODIUM SALT / ACID ORANGE 52 /
BETA-HELIANTHIN / DIMETHYLANILINE ORANGE / ENIAMETHYL ORANGE / GOLD ORANGE
/ METHYL ORANGE B / METHYL ORANGE, SODIUM SALT / ORANGE 3 /
P-((DIMETHYLAMINO)PHENYL)AZO)BENZENE SULFONIC ACID SODIUM SALT / PORRIER'S
ORANGE III / P-SULFOBENZENEAZODIMETHYLANILINE SODIUM SALT / SODIUM
4-(4-DIMETHYLAMINOPHENYLAZO)BENZENESULFONATE / TROPAEOLINE D
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE:
LABORATORY CHEMICAL TEXTILE: DYESTUFF DYESTUFF
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM, INC.
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR +1-703-741-5970
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
ACUTE TOXICITY (ORAL) CATEGORY 3:
H301: TOXIC IF SWALLOWED
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS US LABELING:
HAZARD PICTOGRAMS (GHS US):
GHS06: SKULLS AND CROSSBONES
SIGNAL WORD (GHS US): DANGER
HAZARD STATEMENTS (GHS US):
H301: TOXIC IF SWALLOWED
PRECAUTIONARY STATEMENTS (GHS US):
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
P301+P330+P331 - IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: COMBUSTIBLE DUST.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES:
SUBSTANCE TYPE: MONO-CONSTITUENT
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
METHYL ORANGE, (CAS-NO.) 547-58-0 100 ACUTE TOX. 3 (ORAL), H301
SODIUM SALT, ACS
(MAIN CONSTITUENT)
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
3.2. MIXTURES: NOT APPLICABLE
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL: CHECK THE VITAL FUNCTIONS.
UNCONSCIOUS: MAINTAIN ADEQUATE AIRWAY AND RESPIRATION.
RESPIRATORY ARREST: ARTIFICIAL RESPIRATION OR OXYGEN.
CARDIAC ARREST: PERFORM RESUSCITATION.
VICTIM CONSCIOUS WITH LABORED BREATHING: HALF-SEATED.
VICTIM IN SHOCK: ON HIS BACK WITH LEGS SLIGHTLY RAISED.
VOMITING:
PREVENT ASPHYXIA/ASPIRATION PNEUMONIA. PREVENT COOLING BY COVERING THE
VICTIM (NO WARMING UP). KEEP WATCHING THE VICTIM. GIVE PSYCHOLOGICAL AID.
KEEP THE VICTIM CALM, AVOID PHYSICAL STRAIN.
DEPENDING ON THE VICTIM'S CONDITION: DOCTOR/HOSPITAL.
FIRST-AID MEASURES AFTER INHALATION: REMOVE THE VICTIM INTO FRESH AIR.
RESPIRATORY PROBLEMS: CONSULT A DOCTOR/MEDICAL SERVICE.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE WITH WATER. SOAP MAY BE USED. DO NOT APPLY (CHEMICAL) NEUTRALIZING
AGENTS. TAKE VICTIM TO A DOCTOR IF IRRITATION PERSISTS.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE WITH WATER. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO.
CONTINUE RINSING. DO NOT APPLY NEUTRALIZING AGENTS. TAKE VICTIM TO AN
OPHTHALMOLOGIST IF IRRITATION PERSISTS.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH WITH WATER. GIVE NOTHING TO DRINK.
VICTIM IS FULLY CONSCIOUS:
IMMEDIATELY INDUCE VOMITING. IMMEDIATELY CONSULT A DOCTOR/MEDICAL SERVICE.
CALL POISON INFORMATION CENTRE (WWW.BIG.BE/ANTIGIF.HTM).
INGESTION OF LARGE QUANTITIES: IMMEDIATELY TO HOSPITAL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS AFTER INHALATION:
AFTER INHALATION OF DUST: COUGHING.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: MAY STAIN THE SKIN. SLIGHT IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: SLIGHT IRRITATION.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
QUICK-ACTING ABC POWDER EXTINGUISHER. CLASS A FOAM EXTINGUISHER. WATER
(QUICK-ACTING EXTINGUISHER, REEL). WATER. CLASS A FOAM.
UNSUITABLE EXTINGUISHING MEDIA:
QUICK-ACTING BC POWDER EXTINGUISHER. QUICK-ACTING CO2 EXTINGUISHER.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD: DIRECT FIRE HAZARD. NON-FLAMMABLE.
IN FINELY DIVIDED STATE:
INCREASED FIRE HAZARD. INDIRECT FIRE HAZARD. HEATING INCREASES THE FIRE
HAZARD.
EXPLOSION HAZARD:
DIRECT EXPLOSION HAZARD. FINE DUST IS EXPLOSIVE WITH AIR. INDIRECT
EXPLOSION HAZARD. DUST CLOUD CAN BE IGNITED BY A SPARK.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
PRECAUTIONARY MEASURES FIRE:
EXPOSURE TO FIRE/HEAT: KEEP UPWIND.
EXPOSURE TO FIRE/HEAT: CONSIDER EVACUATION.
EXPOSURE TO FIRE/HEAT: HAVE NEIGHBORHOOD CLOSE DOORS AND WINDOWS.
FIREFIGHTING INSTRUCTIONS:
DILUTE TOXIC GASES WITH WATER SPRAY. TAKE ACCOUNT OF TOXIC FIRE-FIGHTING
WATER. USE WATER MODERATELY AND IF POSSIBLE COLLECT OR CONTAIN IT.
PROTECTION DURING FIREFIGHTING:
HEAT/FIRE EXPOSURE: COMPRESSED AIR/OXYGEN APPARATUS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: GLOVES. PROTECTIVE CLOTHING.
DUST CLOUD PRODUCTION: COMPRESSED AIR/OXYGEN APPARATUS.
EMERGENCY PROCEDURES:
MARK THE DANGER AREA. PREVENT DUST CLOUD FORMATION. NO NAKED FLAMES. WASH
CONTAMINATED CLOTHES.
MEASURES IN CASE OF DUST RELEASE:
IN CASE OF DUST PRODUCTION: KEEP UPWIND.
DUST PRODUCTION: HAVE NEIGHBORHOOD CLOSE DOORS AND WINDOWS.
IN CASE OF DUST PRODUCTION: STOP ENGINES AND NO SMOKING.
IN CASE OF DUST PRODUCTION: NO NAKED FLAMES OR SPARKS.
DUST: SPARK-/EXPLOSION PROOF APPLIANCES/LIGHTING EQUIPMENT.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
DO NOT BREATHE DUST. EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: STOP RELEASE. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT SOIL AND WATER POLLUTION. PREVENT SPREADING IN SEWERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. PLUG THE LEAK,
CUT OFF THE SUPPLY. DAM UP THE SOLID SPILL. KNOCK DOWN/DILUTE DUST CLOUD
WITH WATER SPRAY. TAKE ACCOUNT OF TOXIC/CORROSIVE PRECIPITATION WATER.
POWDERED FORM: NO COMPRESSED AIR FOR PUMPING OVER SPILLS.
METHODS FOR CLEANING UP:
STOP DUST CLOUD BY COVERING WITH SAND/EARTH. SCOOP SOLID SPILL INTO CLOSING
CONTAINERS. CAREFULLY COLLECT THE SPILL/LEFTOVERS.
POWDERED:
DO NOT USE COMPRESSED AIR FOR PUMPING OVER SPILLS. CLEAN CONTAMINATED
SURFACES WITH AN EXCESS OF WATER. TAKE COLLECTED SPILL TO
MANUFACTURER/COMPETENT AUTHORITY. WASH CLOTHING AND EQUIPMENT AFTER
HANDLING.
6.4. REFERENCE TO OTHER SECTIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
PULVERIZATION RAPIDLY INCREASES TOXIC CONCENTRATION.
PRECAUTIONS FOR SAFE HANDLING:
AVOID RAISING DUST. KEEP AWAY FROM NAKED FLAMES/HEAT.
IN FINELY DIVIDED STATE: USE SPARK-/EXPLOSION PROOF APPLIANCES.
FINELY DIVIDED:
KEEP AWAY FROM IGNITION SOURCES/SPARKS. CARRY OPERATIONS IN THE OPEN/UNDER
LOCAL EXHAUST/VENTILATION OR WITH RESPIRATORY PROTECTION. COMPLY WITH THE
LEGAL REQUIREMENTS. CLEAN CONTAMINATED CLOTHING. DO NOT DISCHARGE THE WASTE
INTO THE DRAIN.
POWDERED FORM:
NO COMPRESSED AIR FOR PUMPING OVER. KEEP CONTAINER TIGHTLY CLOSED.
HYGIENE MEASURES: OBSERVE STRICT HYGIENE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE TEMPERATURE: 5 - 30 DEG. C
HEAT-IGNITION: KEEP SUBSTANCE AWAY FROM: HEAT SOURCES. IGNITION SOURCES.
PROHIBITIONS ON MIXED STORAGE:
KEEP SUBSTANCE AWAY FROM: OXIDIZING AGENTS.
STORAGE AREA:
STORE IN A DRY AREA. KEEP CONTAINER IN A WELL-VENTILATED PLACE. KEEP LOCKED
UP. UNAUTHORIZED PERSONS ARE NOT ADMITTED. MEET THE LEGAL REQUIREMENTS.
SPECIAL RULES ON PACKAGING:
SPECIAL REQUIREMENTS:
CLOSING. CORRECTLY LABELED. MEET THE LEGAL REQUIREMENTS. SECURE FRAGILE
PACKAGINGS IN SOLID CONTAINERS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS: NO ADDITIONAL INFORMATION AVAILABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
GLOVES. SAFETY GLASSES.
DUST PRODUCTION: DUST MASK WITH FILTER TYPE P3.
MATERIALS FOR PROTECTIVE CLOTHING:
GIVE GOOD RESISTANCE: NEOPRENE. NITRILE RUBBER
HAND PROTECTION: GLOVES
EYE PROTECTION: SAFETY GLASSES.
IN CASE OF DUST PRODUCTION: PROTECTIVE GOGGLES
SKIN AND BODY PROTECTION: PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
DUST PRODUCTION: DUST MASK WITH FILTER TYPE P3
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
APPEARANCE:
CRYSTALLINE SOLID. POWDER. SCALES.
ORANGE-YELLOW
ODORLESS
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 6.5 (0.5 %)
MELTING POINT: >300 DEG. C
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: <0.1 HPA (20 DEG. C)
RELATIVE VAPOR DENSITY AT 20 DEG. C: NOT APPLICABLE
RELATIVE DENSITY: 1
SPECIFIC GRAVITY / DENSITY: 1000 KG/M3
MOLECULAR MASS: 327.34 G/MOL
SOLUBILITY: INSOLUBLE IN WATER.
WATER: 0.02 G/100 ML (25 DEG. C)
ETHANOL: 0.1 G/100 ML
LOG POW: -0.66 (ESTIMATED VALUE)
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 0 %
OTHER PROPERTIES: BASIC REACTION.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
NO ADDITIONAL INFORMATION AVAILABLE
10.4. CONDITIONS TO AVOID: NO ADDITIONAL INFORMATION AVAILABLE
10.5. INCOMPATIBLE MATERIALS: NO ADDITIONAL INFORMATION AVAILABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
METHYL ORANGE, SODIUM SALT, ACS (547-58-0):
LD50 ORAL RAT: 60 MG/KG (RAT, ORAL)
ATE US (ORAL): 60 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: 6.5 (0.5 %)
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: 6.5 (0.5 %)
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
TOXIC IF SWALLOWED. SLIGHTLY IRRITANT TO SKIN. SLIGHTLY IRRITANT TO EYES.
SYMPTOMS/EFFECTS AFTER INHALATION:
AFTER INHALATION OF DUST: COUGHING.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: MAY STAIN THE SKIN. SLIGHT IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: SLIGHT IRRITATION.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL:
NOT CLASSIFIED AS DANGEROUS FOR THE ENVIRONMENT ACCORDING TO THE CRITERIA
OF REGULATION (EC) NO 1272/2008.
ECOLOGY - AIR:
NOT CLASSIFIED AS DANGEROUS FOR THE OZONE LAYER (REGULATION (EC) NO
1005/2009).
ECOLOGY - WATER:
SEVERE WATER POLLUTANT (SURFACE WATER). NO DATA AVAILABLE ON ECOTOXICITY.
12.2. PERSISTENCE AND DEGRADABILITY:
METHYL ORANGE, SODIUM SALT, ACS (547-58-0):
PERSISTENCE AND DEGRADABILITY:
NON DEGRADABLE IN THE SOIL. NOT READILY BIODEGRADABLE IN WATER.
12.3. BIOACCUMULATIVE POTENTIAL:
METHYL ORANGE, SODIUM SALT, ACS (547-58-0):
LOG POW: -0.66 (ESTIMATED VALUE)
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DO NOT DISCHARGE INTO DRAINS OR THE ENVIRONMENT. REMOVE WASTE IN ACCORDANCE
WITH LOCAL AND/OR NATIONAL REGULATIONS. HAZARDOUS WASTE SHALL NOT BE MIXED
TOGETHER WITH OTHER WASTE. DIFFERENT TYPES OF HAZARDOUS WASTE SHALL NOT BE
MIXED TOGETHER IF THIS MAY ENTAIL A RISK OF POLLUTION OR CREATE PROBLEMS
FOR THE FURTHER MANAGEMENT OF THE WASTE. HAZARDOUS WASTE SHALL BE MANAGED
RESPONSIBLY. ALL ENTITIES THAT STORE, TRANSPORT OR HANDLE HAZARDOUS WASTE
SHALL TAKE THE NECESSARY MEASURES TO PREVENT RISKS OF POLLUTION OR DAMAGE
TO PEOPLE OR ANIMALS. REMOVE TO AN AUTHORIZED INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND A FLUE GAS SCRUBBER WITH ENERGY RECOVERY. DISSOLVE OR MIX
WITH A COMBUSTIBLE SOLVENT.
ADDITIONAL INFORMATION:
HAZARDOUS WASTE ACCORDING TO DIRECTIVE 2008/98/EC, AS AMENDED BY REGULATION
(EU) NO 1357/2014 AND REGULATION (EU) NO 2017/997.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN2811 TOXIC SOLIDS, ORGANIC, N.O.S., 6.1, III
UN-NO.(DOT): UN2811
PROPER SHIPPING NAME (DOT): TOXIC SOLIDS, ORGANIC, N.O.S.
TRANSPORT HAZARD CLASS(ES) (DOT):
6.1 - CLASS 6.1 - POISONOUS MATERIALS 49 CFR 173.132
PACKING GROUP (DOT): III - MINOR DANGER
HAZARD LABELS (DOT): 6.1 - POISON
DOT PACKAGING NON BULK (49 CFR 173.XXX): 213
DOT PACKAGING BULK (49 CFR 173.XXX): 240
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB8 - AUTHORIZED IBCS:
METAL (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B AND 31N); RIGID PLASTICS
(11H1, 11H2, 21H1, 21H2, 31H1 AND 31H2); COMPOSITE (11HZ1, 11HZ2, 21HZ1,
21HZ2, 31HZ1 AND 31HZ2); FIBERBOARD (11G); WOODEN (11C, 11D AND 11F);
FLEXIBLE (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 OR
13M2). IP3 - FLEXIBLE IBCS MUST BE SIFT-PROOF AND WATER-RESISTANT OR MUST
BE FITTED WITH A SIFT-PROOF AND WATER-RESISTANT LINER.
T1: 1.5 178.274(D)(2) NORMAL............. 178.275(D)(2)
TP33:
THE PORTABLE TANK INSTRUCTION ASSIGNED FOR THIS SUBSTANCE APPLIES FOR
GRANULAR AND POWDERED SOLIDS AND FOR SOLIDS WHICH ARE FILLED AND DISCHARGED
AT TEMPERATURES ABOVE THEIR MELTING POINT WHICH ARE COOLED AND TRANSPORTED
AS A SOLID MASS. SOLID SUBSTANCES TRANSPORTED OR OFFERED FOR TRANSPORT
ABOVE THEIR MELTING POINT ARE AUTHORIZED FOR TRANSPORTATION IN PORTABLE
TANKS CONFORMING TO THE PROVISIONS OF PORTABLE TANK INSTRUCTION T4 FOR
SOLID SUBSTANCES OF PACKING GROUP III OR T7 FOR SOLID SUBSTANCES OF PACKING
GROUP II, UNLESS A TANK WITH MORE STRINGENT REQUIREMENTS FOR MINIMUM SHELL
THICKNESS, MAXIMUM ALLOWABLE WORKING PRESSURE, PRESSURE-RELIEF DEVICES OR
BOTTOM OUTLETS ARE ASSIGNED IN WHICH CASE THE MORE STRINGENT TANK
INSTRUCTION AND SPECIAL PROVISIONS SHALL APPLY. FILLING LIMITS MUST BE IN
ACCORDANCE WITH PORTABLE TANK SPECIAL PROVISION TP3. SOLIDS MEETING THE
DEFINITION OF AN ELEVATED TEMPERATURE MATERIAL MUST BE TRANSPORTED IN
ACCORDANCE WITH THE APPLICABLE REQUIREMENTS OF THIS SUBCHAPTER.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 153
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 100 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 200 KG
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
TRANSPORTATION OF DANGEROUS GOODS:
TRANSPORT DOCUMENT DESCRIPTION:
UN2811 TOXIC SOLID, ORGANIC, N.O.S. (METHYL ORANGE, SODIUM SALT), 6.1, II
UN-NO. (TDG): UN2811
PROPER SHIPPING NAME (TRANSPORTATION OF DANGEROUS GOODS):
TOXIC SOLID, ORGANIC, N.O.S.
TDG PRIMARY HAZARD CLASSES: 6.1 - CLASS 6.1 - TOXIC SUBSTANCES
PACKING GROUP: II - MEDIUM DANGER
TDG SPECIAL PROVISIONS:
16 - (1) THE TECHNICAL NAME OF AT LEAST ONE OF THE MOST DANGEROUS
SUBSTANCES THAT PREDOMINANTLY CONTRIBUTES TO THE HAZARD OR HAZARDS POSED BY
THE DANGEROUS GOODS MUST BE SHOWN, IN PARENTHESES, ON THE SHIPPING DOCUMENT
FOLLOWING THE SHIPPING NAME IN ACCORDANCE WITH CLAUSE 3.5(1)(C)(II)(A) OF
PART 3 (DOCUMENTATION). THE TECHNICAL NAME MUST ALSO BE SHOWN, IN
PARENTHESES, ON A SMALL MEANS OF CONTAINMENT OR ON A TAG FOLLOWING THE
SHIPPING NAME IN ACCORDANCE WITH SUBSECTIONS 4.11(2) AND (3) OF PART 4
(DANGEROUS GOODS SAFETY MARKS). (2) DESPITE SUBSECTION (1), THE TECHNICAL
NAME FOR THE FOLLOWING DANGEROUS GOODS IS NOT REQUIRED TO BE SHOWN ON A
SHIPPING DOCUMENT OR ON A SMALL MEANS OF CONTAINMENT WHEN CANADIAN LAW FOR
DOMESTIC TRANSPORT OR AN INTERNATIONAL CONVENTION FOR INTERNATIONAL
TRANSPORT PROHIBITS THE DISCLOSURE OF THE TECHNICAL NAME: (A)UN1544,
ALKALOID SALTS, SOLID, N.O.S. OR ALKALOIDS, SOLID, N.O.S; (B)UN1851,
MEDICINE, LIQUID, TOXIC, N.O.S; (C)UN3140, ALKALOID SALTS, LIQUID, N.O.S.
OR ALKALOIDS, LIQUID, N.O.S; (D)UN3248, MEDICINE, LIQUID, FLAMMABLE, TOXIC,
N.O.S; OR (E)UN3249, MEDICINE, SOLID, TOXIC, N.O.S. AN EXAMPLE IN CANADA IS
THE "FOOD AND DRUGS ACT". (3) DESPITE SUBSECTION (1), THE TECHNICAL
NAME FOR THE FOLLOWING DANGEROUS GOODS IS NOT REQUIRED TO BE SHOWN ON A
SMALL MEANS OF CONTAINMENT: (A)UN2814, INFECTIOUS SUBSTANCE, AFFECTING
HUMANS; OR (B)UN2900, INFECTIOUS SUBSTANCE, AFFECTING ANIMALS. SOR/2014-306
EXPLOSIVE LIMIT AND LIMITED QUANTITY INDEX: 0.5 KG
PASSENGER CARRYING ROAD VEHICLE OR PASSENGER CARRYING RAILWAY VEHICLE
INDEX: 25 KG
TRANSPORT BY SEA:
TRANSPORT DOCUMENT DESCRIPTION (IMDG):
UN 2811 TOXIC SOLID, ORGANIC, N.O.S. (METHYL ORANGE, SODIUM SALT), 6.1, II
UN-NO. (IMDG): 2811
PROPER SHIPPING NAME (IMDG): TOXIC SOLID, ORGANIC, N.O.S.
CLASS (IMDG): 6.1 - TOXIC SUBSTANCES
PACKING GROUP (IMDG): II - SUBSTANCES PRESENTING MEDIUM DANGER
EMS-NO. (1): F-A
EMS-NO. (2): S-A
AIR TRANSPORT:
TRANSPORT DOCUMENT DESCRIPTION (IATA):
UN 2811 TOXIC SOLID, ORGANIC, N.O.S. (METHYL ORANGE, SODIUM SALT), 6.1, II
UN-NO. (IATA): 2811
PROPER SHIPPING NAME (IATA): TOXIC SOLID, ORGANIC, N.O.S.
CLASS (IATA): 6.1 - TOXIC SUBSTANCES
PACKING GROUP (IATA): II - MEDIUM DANGER
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
METHYL ORANGE, SODIUM SALT, ACS (547-58-0):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SARA SECTION 311/312 HAZARD CLASSES:
HEALTH HAZARD - ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
METHYL ORANGE, SODIUM SALT, ACS (547-58-0):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
NOT LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 03/13/2019
FULL TEXT OF H-PHRASES: SEE SECTION 16:
H301: TOXIC IF SWALLOWED
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 1 - MATERIALS THAT MUST BE PREHEATED BEFORE IGNITION
CAN OCCUR.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 1 SLIGHT HAZARD - MATERIALS THAT MUST BE PREHEATED
BEFORE IGNITION WILL OCCUR. INCLUDES LIQUIDS, SOLIDS
AND SEMI SOLIDS HAVING A FLASH POINT ABOVE 200 F.
(CLASS IIIB)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION E
E - SAFETY GLASSES, GLOVES, DUST RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)