| Common Name: | MORPHOLINE |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 1/9/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8GF69 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
MORPHOLINE
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 05/13/2014
REVISION DATE: 01/09/2018
SUPERSEDES: 01/09/2018
VERSION: 1.2
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: SUBSTANCE
SUBSTANCE NAME: MORPHOLINE
CHEMICAL NAME: MORPHOLINE
CAS-NO.: 110-91-8
PRODUCT CODE: LC17440
FORMULA: C4H9NO
SYNONYMS: TETRAHYDRO-2H-1,4-OXAZINE / 1-OXA-4-AZACYCLOHEXANE
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAMMABLE LIQUIDS CATEGORY 3:
H226: FLAMMABLE LIQUID AND VAPOR
ACUTE TOXICITY (ORAL) CATEGORY 4:
H302: HARMFUL IF SWALLOWED
ACUTE TOXICITY (DERMAL) CATEGORY 3:
H311: TOXIC IN CONTACT WITH SKIN
SKIN CORROSION/IRRITATION CATEGORY 1A:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 3:
H402: HARMFUL TO AQUATIC LIFE
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS05: CORROSION
GHS06: SKULLS AND CROSSBONES
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H226: FLAMMABLE LIQUID AND VAPOR
H302: HARMFUL IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H402: HARMFUL TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS (GHS-US):
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P260: DO NOT BREATHE MIST, VAPORS, SPRAY
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
P273: AVOID RELEASE TO THE ENVIRONMENT
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE
P370+P378:
IN CASE OF FIRE:
USE ALCOHOL RESISTANT FOAM, CARBON DIOXIDE (CO2), SAND TO EXTINGUISH
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES:
SUBSTANCE TYPE: MONO-CONSTITUENT
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
MORPHOLINE (CAS-NO.) 110-91-8 100 FLAM. LIQ. 3, H226
(MAIN CONSTITUENT) ACUTE TOX. 4 (ORAL), H302
ACUTE TOX. 3 (DERMAL), H311
SKIN CORR. 1A, H314
EYE DAM. 1, H318
AQUATIC ACUTE 3, H402
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
3.2. MIXTURES: NOT APPLICABLE
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. IMMEDIATELY CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
REPEATED EXPOSURE TO THIS MATERIAL CAN RESULT IN ABSORPTION THROUGH SKIN
CAUSING SIGNIFICANT HEALTH HAZARD. TOXIC IN CONTACT WITH SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD: FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
REACTIVITY: THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPORS.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
SAFETY GLASSES. GLOVES. PROTECTIVE CLOTHING. FACE-SHIELD.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP: SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR
DIATOMACEOUS EARTH AS SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM
OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. USE ONLY NON-SPARKING
TOOLS. DO NOT BREATHE MIST, VAPORS, SPRAY. AVOID CONTACT DURING
PREGNANCY/WHILE NURSING.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED SKIN
THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT. COMPLY WITH APPLICABLE
REGULATIONS.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: HEAT SOURCES, IGNITION SOURCES, INCOMPATIBLE MATERIALS. KEEP
CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
MORPHOLINE (110-91-8):
ACGIH:
ACGIH TWA (MG/M3): 71 MG/M3
MORPHOLINE (110-91-8):
ACGIH:
ACGIH TWA (PPM): 20 PPM
OSHA:
OSHA PEL (TWA) (MG/M3): 70 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 20 PPM
IDLH:
US IDLH (PPM): 1400 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 70 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 20 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 105 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 30 PPM
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
GLOVES. SAFETY GLASSES. PROTECTIVE CLOTHING.
HAND PROTECTION: WEAR PROTECTIVE GLOVES
EYE PROTECTION: CHEMICAL GOGGLES OR FACE SHIELD
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NOT REQUIRED IN NORMAL CONDITIONS
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: STRONG
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: -5 DEG. C
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 128 DEG. C
FLASH POINT: 32 DEG. C
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): FLAMMABLE LIQUID AND VAPOR.
VAPOR PRESSURE: 11 MBAR
RELATIVE VAPOR DENSITY AT 20 DEG. C: 3 AIR = 1
RELATIVE DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 0.99 G/CM3
MOLECULAR MASS: 87.12 G/MOL
SOLUBILITY:
MISCIBLE WITH WATER. SOLUBLE IN ACETONE. SOLUBLE IN ETHER. SOLUBLE IN
ETHANOL. SOLUBLE IN METHANOL.
LOG POW: -2.55
AUTO-IGNITION TEMPERATURE: 255 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: 2.23 CP
EXPLOSION LIMITS: 2 - 11.2 VOL %
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPORS.
10.2. CHEMICAL STABILITY:
FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
OVERHEATING. HEAT. SPARKS.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
NITROGEN OXIDES. CARBON MONOXIDE. CARBON DIOXIDE. MAY RELEASE FLAMMABLE
GASES.
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPORS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY:
ORAL: HARMFUL IF SWALLOWED.
DERMAL: TOXIC IN CONTACT WITH SKIN.
MORPHOLINE (110-91-8):
LD50 ORAL RAT: 1050 MG/KG
LD50 DERMAL RABBIT: 310 MG/KG
ATE US (ORAL): 1050 MG/KG BODY WEIGHT
ATE US (DERMAL): 310 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. HARMFUL
IF SWALLOWED. TOXIC IN CONTACT WITH SKIN.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
REPEATED EXPOSURE TO THIS MATERIAL CAN RESULT IN ABSORPTION THROUGH SKIN
CAUSING SIGNIFICANT HEALTH HAZARD. TOXIC IN CONTACT WITH SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - WATER: HARMFUL TO AQUATIC LIFE.
MORPHOLINE (110-91-8):
LC50 FISH 1: 350 MG/L
EC50 DAPHNIA 1: 100 MG/L
EC50 OTHER AQUATIC ORGANISMS 1: 28 MG/L 96 HR. ALGAE
LC50 FISH 2: 375 - 460 MG/L
12.2. PERSISTENCE AND DEGRADABILITY:
MORPHOLINE (110-91-8):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
MORPHOLINE (110-91-8):
LOG POW: -2.55
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS:
HAZARDOUS WASTE DUE TO TOXICITY. AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN2054 MORPHOLINE, 8, I
UN-NO.(DOT): UN2054
PROPER SHIPPING NAME (DOT): MORPHOLINE
TRANSPORT HAZARD CLASS(ES) (DOT):
8 - CLASS 8 - CORROSIVE MATERIAL 49 CFR 173.136
PACKING GROUP (DOT): I - GREAT DANGER
HAZARD LABELS (DOT):
8 - CORROSIVE
3 - FLAMMABLE LIQUID
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
DOT PACKAGING NON BULK (49 CFR 173.XXX): 201
DOT PACKAGING BULK (49 CFR 173.XXX): 243
DOT SPECIAL PROVISIONS (49 CFR 172.102):
A6 - FOR COMBINATION PACKAGING, IF PLASTIC INNER PACKAGING ARE USED, THEY
MUST BE PACKED IN TIGHTLY CLOSED METAL RECEPTACLES BEFORE PACKING IN OUTER
PACKAGING.
T10 - 4 6 MM PROHIBITED 178.275(G)(3).
TP2 - A. THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF
FILLING DETERMINED BY THE FOLLOWING: (IMAGE) WHERE: TR IS THE MAXIMUM MEAN
BULK TEMPERATURE DURING TRANSPORT, TF IS THE TEMPERATURE IN DEGREES CELSIUS
OF THE LIQUID DURING FILLING, AND A IS THE MEAN COEFFICIENT OF CUBICAL
EXPANSION OF THE LIQUID BETWEEN THE MEAN TEMPERATURE OF THE LIQUID DURING
FILLING (TF) AND THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORTATION
(TR) BOTH IN DEGREES CELSIUS. B. FOR LIQUIDS TRANSPORTED UNDER AMBIENT
CONDITIONS MAY BE CALCULATED USING THE FORMULA: (IMAGE) WHERE: D15 AND D50
ARE THE DENSITIES (IN UNITS OF MASS PER UNIT VOLUME) OF THE LIQUID AT 15 C
(59 F) AND 50 C (122 F), RESPECTIVELY.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): NONE
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 0.5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 2.5 L
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
MORPHOLINE (110-91-8):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
MORPHOLINE (110-91-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
MORPHOLINE (110-91-8):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 01/09/2018
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16:
H226: FLAMMABLE LIQUID AND VAPOR
H302: HARMFUL IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H318: CAUSES SERIOUS EYE DAMAGE
H402: HARMFUL TO AQUATIC LIFE
NFPA HEALTH HAZARD 3 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SERIOUS OR PERMANENT INJURY.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 1 - MATERIALS THAT IN THEMSELVES ARE NORMALLY STABLE BUT
CAN BECOME UNSTABLE AT ELEVATED TEMPERATURES AND
PRESSURES.
HAZARD RATING:
HEALTH 3 SERIOUS HAZARD - MAJOR INJURY LIKELY UNLESS PROMPT
ACTION IS TAKEN AND MEDICAL TREATMENT IS GIVEN
FLAMMABILITY 3 SERIOUS HAZARD - MATERIALS CAPABLE OF IGNITION UNDER
ALMOST ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73 F AND
BOILING POINTS ABOVE 100 F. AS WELL AS LIQUIDS WITH
FLASH POINTS BETWEEN 73 F AND 100 F.
(CLASSES IB & IC)
PHYSICAL 1 SLIGHT HAZARD - MATERIALS THAT ARE NORMALLY STABLE
BUT CAN BECOME UNSTABLE (SELF-REACT) AT HIGH
TEMPERATURES AND PRESSURES. MATERIALS MAY REACT
NON-VIOLENTLY WITH WATER OR UNDERGO HAZARDOUS
POLYMERIZATION IN THE ABSENCE OF INHIBITORS.
PERSONAL PROTECTION H
H - SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, VAPOR
RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)