| Common Name: | METHYL RED-METHYLENE BLUE |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 1/3/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8GFP2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
METHYL RED-METHYLENE BLUE
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 04/09/2015
REVISION DATE: 01/03/2018
SUPERSEDES: 09/25/2015
VERSION: 1.2
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: METHYL RED-METHYLENE BLUE
PRODUCT CODE: LC17170
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAMMABLE LIQUIDS CATEGORY 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
CARCINOGENICITY CATEGORY 1A:
H350: MAY CAUSE CANCER
REPRODUCTIVE TOXICITY CATEGORY 2:
H361: SUSPECTED OF DAMAGING THE UNBORN CHILD (ORAL)
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 1:
H370:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE, LIVER,
KIDNEYS)
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H350: MAY CAUSE CANCER
H361: SUSPECTED OF DAMAGING THE UNBORN CHILD (ORAL)
H370:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE, LIVER,
KIDNEYS)
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P260: DO NOT BREATHE MIST, VAPORS, SPRAY
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
P280: WEAR PROTECTIVE GLOVES, EYE PROTECTION
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
P370+P378:
IN CASE OF FIRE:
USE ALCOHOL RESISTANT FOAM, CARBON DIOXIDE (CO2), EXTINGUISHING POWDER TO
EXTINGUISH
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
ETHANOL (CAS-NO.) 64-17-5 89.88 FLAM. LIQ. 2, H225
CARC. 1A, H350
REPR. 2, H361
METHANOL (CAS-NO.) 67-56-1 4.96 FLAM. LIQ. 2, H225
ACUTE TOX. 3 (ORAL), H301
ACUTE TOX. 3 (DERMAL), H311
ACUTE TOX. 3 (INHALATION),
H331
STOT SE 1, H370
ISOPROPYL ALCOHOL (CAS-NO.) 67-63-0 4.96 FLAM. LIQ. 2, H225
(2-PROPANOL) EYE IRRIT. 2A, H319
STOT SE 3, H335
METHYL RED, (CAS-NO.) 845-10-3 0.13 NOT CLASSIFIED
SODIUM SALT, ACS
METHYLENE BLUE (CAS-NO.) 61-73-4 0.07 ACUTE TOX. 4 (ORAL), H302
AQUATIC ACUTE 2, H401
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF EXPOSED OR
CONCERNED: GET MEDICAL ADVICE/ATTENTION. CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE SKIN WITH WATER/SHOWER. REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED
CLOTHING.
FIRST-AID MEASURES AFTER EYE CONTACT:
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. RINSE
CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. OBTAIN MEDICAL ATTENTION IF
PAIN, BLINKING OR REDNESS PERSISTS.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CAUSES DAMAGE TO
ORGANS.
SYMPTOMS/EFFECTS AFTER INHALATION: DIZZINESS. HEADACHE.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
MAY STAIN THE SKIN. VISUAL DISTURBANCES.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD. BLINDNESS. VISUAL DISTURBANCES. VOMITING. NAUSEA. DIZZINESS.
DRUNKENNESS. CENTRAL NERVOUS SYSTEM DEPRESSION.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD: HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
SAFETY GLASSES. PROTECTIVE CLOTHING. GLOVES. COMBINED GAS/DUST MASK WITH
FILTER TYPE A/P3.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. AVOID BREATHING MIST, SPRAY.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING.
USE ONLY NON-SPARKING TOOLS. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT
HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT
BREATHE MIST, VAPORS, SPRAY.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED SKIN
THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: HEAT SOURCES, IGNITION SOURCES, INCOMPATIBLE MATERIALS. KEEP IN
FIREPROOF PLACE. KEEP CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS: STRONG BASES. STRONG ACIDS. STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
METHYLENE BLUE (61-73-4): NOT APPLICABLE
ETHANOL (64-17-5):
ACGIH:
ACGIH STEL (PPM):
1000 PPM (ETHANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 1900 MG/M3
ETHANOL (64-17-5):
OSHA:
OSHA PEL (TWA) (PPM): 1000 PPM
IDLH:
US IDLH (PPM): 3300 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 1900 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 1000 PPM
METHANOL (67-56-1):
ACGIH:
ACGIH TWA (PPM):
200 PPM (METHANOL; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT 8 H; TLV -
ADOPTED VALUE)
ACGIH:
ACGIH STEL (PPM):
250 PPM (METHANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 260 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 200 PPM
IDLH:
US IDLH (PPM): 6000 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 250 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 200 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 325 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 250 PPM
NIOSH:
REMARK (NIOSH): SKIN
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
ACGIH:
ACGIH TWA (PPM):
200 PPM (2-PROPANOL; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT 8 H; TLV -
ADOPTED VALUE)
ACGIH:
ACGIH STEL (PPM):
400 PPM (2-PROPANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 980 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 400 PPM
IDLH:
US IDLH (PPM): 2000 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 980 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 400 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 1225 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 500 PPM
METHYL RED, SODIUM SALT, ACS (845-10-3): NOT APPLICABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT: GLOVES. PROTECTIVE CLOTHING. SAFETY GLASSES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
SKIN AND BODY PROTECTION: CHEMICAL RESISTANT APRON
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NOT REQUIRED IN NORMAL CONDITIONS
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: DARK GREEN
ODOR: ALCOHOL ODOR
ODOR THRESHOLD:
100 PPM
188 MG/M3
PH: NO DATA AVAILABLE
MELTING POINT: -115 DEG. C
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 78 DEG. C
FLASH POINT: 13 DEG. C
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): 2.4
RELATIVE EVAPORATION RATE (ETHER=1): 8.3
FLAMMABILITY (SOLID, GAS): HIGHLY FLAMMABLE LIQUID AND VAPOR.
VAPOR PRESSURE: 59 HPA
VAPOR PRESSURE AT 50 DEG. C: 300 HPA
RELATIVE VAPOR DENSITY AT 20 DEG. C: 1.6
RELATIVE DENSITY: 0.79
SOLUBILITY:
SOLUBLE IN WATER. SOLUBLE IN METHANOL. SOLUBLE IN ISOPROPANOL. SOLUBLE IN
ETHANOL.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: 363 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: 0.0012 PA.S (20 DEG. C)
EXPLOSION LIMITS: 3.3 - 19 VOL %
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY:
HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS. STRONG BASES. STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. MAY RELEASE FLAMMABLE GASES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
METHYLENE BLUE (61-73-4):
LD50 ORAL RAT: 1180 MG/KG (RAT)
ATE US (ORAL): 1180 MG/KG BODY WEIGHT
ETHANOL (64-17-5):
LD50 ORAL RAT:
10740 MG/KG (RAT; EXPERIMENTAL VALUE, RAT; EXPERIMENTAL VALUE)
LD50 DERMAL RABBIT: >16000 MG/KG (RABBIT; LITERATURE STUDY)
ATE US (ORAL): 10740 MG/KG BODY WEIGHT
METHANOL (67-56-1):
LD50 ORAL RAT:
>5000 MG/KG (RAT; BASF TEST; LITERATURE STUDY; 1187-2769 MG/KG BODYWEIGHT;
RAT; WEIGHT OF EVIDENCE)
LD50 DERMAL RABBIT: 15800 MG/KG (RABBIT; LITERATURE STUDY)
LC50 INHALATION RAT (MG/L): 85 MG/L/4H (RAT; LITERATURE STUDY)
LC50 INHALATION RAT (PPM): 64000 PPM/4H (RAT; LITERATURE STUDY)
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LD50 DERMAL RABBIT:
12870 MG/KG (RABBIT; EXPERIMENTAL VALUE; EQUIVALENT OR SIMILAR TO OECD 402;
16.4; RABBIT)
LC50 INHALATION RAT (MG/L): 73 MG/L/4H (RAT)
ATE US (ORAL): 5045 MG/KG BODY WEIGHT
ATE US (DERMAL): 12870 MG/KG BODY WEIGHT
ATE US (VAPORS): 73 MG/L/4H
ATE US (DUST, MIST): 73 MG/L/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: MAY CAUSE CANCER.
ETHANOL (64-17-5):
IARC GROUP: 1 - CARCINOGENIC TO HUMANS
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING THE UNBORN CHILD (ORAL).
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE, LIVER,
KIDNEYS).
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS: HARMFUL IF SWALLOWED.
SYMPTOMS/EFFECTS AFTER INHALATION: DIZZINESS. HEADACHE.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
MAY STAIN THE SKIN. VISUAL DISTURBANCES.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD. BLINDNESS. VISUAL DISTURBANCES. VOMITING. NAUSEA. DIZZINESS.
DRUNKENNESS. CENTRAL NERVOUS SYSTEM DEPRESSION.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
METHYLENE BLUE (61-73-4):
EC50 DAPHNIA 1: 2.26 MG/L (EC50; 48 H)
LC50 FISH 2: 18 MG/L (LC50; 96 H)
ETHANOL (64-17-5):
LC50 FISH 1:
14200 MG/L (LC50; US EPA; 96 H; PIMEPHALES PROMELAS; FLOW-THROUGH SYSTEM;
FRESH WATER; EXPERIMENTAL VALUE)
METHANOL (67-56-1):
LC50 FISH 1:
15400 MG/L (LC50; EPA 660/3 - 75/009; 96 H; LEPOMIS MACROCHIRUS;
FLOW-THROUGH SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
EC50 DAPHNIA 1:
>10000 MG/L (EC50; DIN 38412-11; 48 H; DAPHNIA MAGNA; STATIC SYSTEM; FRESH
WATER; EXPERIMENTAL VALUE)
LC50 FISH 2: 10800 MG/L (LC50; 96 H; SALMO GAIRDNERI)
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LC50 FISH 2:
9640 MG/L (LC50; OECD 203: FISH, ACUTE TOXICITY TEST; 96 H; PIMEPHALES
PROMELAS; FLOW-THROUGH SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
EC50 DAPHNIA 2: 13299 MG/L (EC50; OTHER; 48 H; DAPHNIA MAGNA)
THRESHOLD LIMIT ALGAE 1:
>1000 MG/L (EC50; UBA; 72 H; SCENEDESMUS SUBSPICATUS)
12.2. PERSISTENCE AND DEGRADABILITY:
METHYL RED-METHYLENE BLUE:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
METHYLENE BLUE (61-73-4):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY IN WATER: NO DATA AVAILABLE. PHOTODEGRADATION IN THE AIR.
ETHANOL (64-17-5):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. HIGHLY MOBILE IN
SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.8 - 0.967 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.7 G O2/G SUBSTANCE
THOD: 2.1 G O2/G SUBSTANCE
BOD (% OF THOD): 0.43
METHANOL (67-56-1):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. HIGHLY MOBILE IN
SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.6 - 1.12 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.42 G O2/G SUBSTANCE
THOD: 1.5 G O2/G SUBSTANCE
BOD (% OF THOD): 0.8 (LITERATURE STUDY)
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN
THE SOIL UNDER ANAEROBIC CONDITIONS. NO TEST DATA ON MOBILITY OF THE
SUBSTANCE AVAILABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): 1.19 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.23 G O2/G SUBSTANCE
THOD: 2.4 G O2/G SUBSTANCE
METHYL RED, SODIUM SALT, ACS (845-10-3):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
METHYL RED-METHYLENE BLUE:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
METHYLENE BLUE (61-73-4):
LOG POW: 5.85 (ESTIMATED VALUE)
METHYLENE BLUE (61-73-4):
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
ETHANOL (64-17-5):
BCF FISH 1:
1 (BCF; OTHER; 72 H; CYPRINUS CARPIO; STATIC SYSTEM; FRESH WATER;
READ-ACROSS)
LOG POW: -0.31 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
METHANOL (67-56-1):
BCF FISH 1: <10 (BCF; 72 H; LEUCISCUS IDUS)
LOG POW: -0.77 (EXPERIMENTAL VALUE; OTHER)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LOG POW: 0.05 (WEIGHT OF EVIDENCE APPROACH; OTHER; 25 DEG. C)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
METHYL RED, SODIUM SALT, ACS (845-10-3):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
ETHANOL (64-17-5):
SURFACE TENSION: 0.022 N/M (20 DEG. C)
LOG KOC: KOC, PCKOCWIN V1.66; 1; READ-ACROSS
METHANOL (67-56-1):
SURFACE TENSION: 0.023 N/M (20 DEG. C)
LOG KOC: KOC, PCKOCWIN V1.66; 1; CALCULATED VALUE
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
SURFACE TENSION: 0.021 N/M (25 DEG. C)
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1170 ETHANOL SOLUTIONS, 3, II
UN-NO.(DOT): UN1170
PROPER SHIPPING NAME (DOT): ETHANOL SOLUTIONS
TRANSPORT HAZARD CLASS(ES) (DOT):
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SPECIAL PROVISIONS (49 CFR 172.102):
24 - ALCOHOLIC BEVERAGES CONTAINING MORE THAN 70 PERCENT ALCOHOL BY VOLUME
MUST BE TRANSPORTED AS MATERIALS IN PACKING GROUP II. ALCOHOLIC BEVERAGES
CONTAINING MORE THAN 24 PERCENT BUT NOT MORE THAN 70 PERCENT ALCOHOL BY
VOLUME MUST BE TRANSPORTED AS MATERIALS IN PACKING GROUP III.
IB2 - AUTHORIZED IBCS: METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND
31H2); COMPOSITE (31HZ1). ADDITIONAL REQUIREMENT: ONLY LIQUIDS WITH A VAPOR
PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C (1.1 BAR AT 122 F), OR 130
KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED.
T4 - 2.65 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 4B; 150
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
METHYL RED-METHYLENE BLUE:
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
METHANOL CAS-NO. 67-56-1 4.96%
ISOPROPYL ALCOHOL (2-PROPANOL) CAS-NO. 67-63-0 4.96%
METHANOL (67-56-1):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
15.2. INTERNATIONAL REGULATIONS:
CANADA:
METHYLENE BLUE (61-73-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
METHANOL (67-56-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
METHYL RED, SODIUM SALT, ACS (845-10-3):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
METHYLENE BLUE (61-73-4):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
ETHANOL (64-17-5):
LISTED ON IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
METHYL RED, SODIUM SALT, ACS (845-10-3):
NOT LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT CONTAINS, OR MAY CONTAIN, TRACE
QUANTITIES OF A SUBSTANCE(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, DEVELOPMENTAL AND/OR REPRODUCTIVE HARM
METHANOL (67-56-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANT RISK LEVEL (NSRL):
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 01/03/2018
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H301: TOXIC IF SWALLOWED
H302: HARMFUL IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H319: CAUSES SERIOUS EYE IRRITATION
H331: TOXIC IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H350: MAY CAUSE CANCER
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H370: CAUSES DAMAGE TO ORGANS
H401: TOXIC TO AQUATIC LIFE
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
* - CHRONIC (LONG-TERM) HEALTH EFFECTS MAY RESULT FROM
REPEATED OVEREXPOSURE
FLAMMABILITY 3 SERIOUS HAZARD - MATERIALS CAPABLE OF IGNITION UNDER
ALMOST ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73 F AND
BOILING POINTS ABOVE 100 F. AS WELL AS LIQUIDS WITH
FLASH POINTS BETWEEN 73 F AND 100 F. (CLASSES IB &
IC)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION H
H - SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, VAPOR
RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
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