| Common Name: | COPPER SULFATE, 10% W/V |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 5/3/2017 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8PXF4, 9TN92 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
COPPER SULFATE, 10% W/V
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 02/24/2014
REVISION DATE: 05/03/2017
SUPERSEDES: 09/14/2015
VERSION: 1.2
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: COPPER SULFATE, 10% W/V
PRODUCT CODE: LC13440
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 2:
H401: TOXIC TO AQUATIC LIFE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 2:
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS09: ENVIRONMENT
HAZARD STATEMENTS (GHS-US):
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS (GHS-US):
P273: AVOID RELEASE TO THE ENVIRONMENT
P391: COLLECT SPILLAGE
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
WATER (CAS NO) 7732-18-5 90 NOT CLASSIFIED
COPPER (II) SULFATE, (CAS NO) 7758-99-8 10 ACUTE TOX. 3 (ORAL), H301
PENTAHYDRATE AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ALLOW VICTIM TO BREATHE FRESH AIR. ALLOW THE VICTIM TO REST.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE AFFECTED CLOTHING AND WASH ALL EXPOSED SKIN AREA WITH MILD SOAP AND
WATER, FOLLOWED BY WARM WATER RINSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER. OBTAIN MEDICAL ATTENTION IF PAIN,
BLINKING OR REDNESS PERSISTS.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/INJURIES:
NOT EXPECTED TO PRESENT A SIGNIFICANT HAZARD UNDER ANTICIPATED CONDITIONS
OF NORMAL USE.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
NO ADDITIONAL INFORMATION AVAILABLE
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: SAFETY GLASSES. GLOVES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR.
HYGIENE MEASURES: WASH CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS: KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: STRONG REDUCING AGENTS. STRONG BASES. STRONG ACIDS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8): NOT APPLICABLE
WATER (7732-18-5): NOT APPLICABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST
VENTILATION.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT: SAFETY GLASSES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NOT REQUIRED IN NORMAL CONDITIONS
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: BLUE
ODOR: NONE.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY: SOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE.
OXIDIZING PROPERTIES: NO DATA AVAILABLE.
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS: STRONG REDUCING AGENTS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: SULFUR COMPOUNDS. COPPER.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
COPPER SULFATE, 10% W/V:
LD50 ORAL RAT: 3000 MG/KG
ATE US (ORAL): 3000.000 MG/KG BODY WEIGHT
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
LD50 ORAL RAT:
300 MG/KG (RAT; OECD 401: ACUTE ORAL TOXICITY; EXPERIMENTAL VALUE; 482
MG/KG BODYWEIGHT; RAT)
LD50 DERMAL RABBIT:
>2000 MG/KG (RABBIT; LITERATURE STUDY; OECD 402: ACUTE DERMAL TOXICITY)
ATE US (ORAL): 300.000 MG/KG BODY WEIGHT
WATER (7732-18-5):
LD50 ORAL RAT: >/=90000 MG/KG
ATE US (ORAL): 90000.000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - WATER:
TOXIC TO AQUATIC LIFE. TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
THRESHOLD LIMIT ALGAE 2:
0.368 MG/L (ERC50; OECD 201: ALGA, GROWTH INHIBITION TEST; 72 H;
PSEUDOKIRCHNERIELLA SUBCAPITATA; STATIC SYSTEM; FRESH WATER; READ-ACROSS)
12.2. PERSISTENCE AND DEGRADABILITY:
COPPER SULFATE, 10% W/V:
PERSISTENCE AND DEGRADABILITY:
NOT READILY BIODEGRADABLE. MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
ENVIRONMENT.
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
COPPER SULFATE, 10% W/V:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
BIOACCUMULATIVE POTENTIAL BIOACCUMABLE.: NOT ESTABLISHED.
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
COPPER SULFATE, 10% W/V:
ECOLOGY - SOIL:
MAY BE HARMFUL TO PLANT GROWTH, BLOOMING AND FRUIT FORMATION.
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
ECOLOGY - SOIL: TOXIC TO FLORA.
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT: NOT REGULATED
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
COPPER (II) SULFATE, PENTAHYDRATE CAS NO 7758-99-8 10%
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 10 LB
15.2. INTERNATIONAL REGULATIONS:
CANADA:
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR
REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 05/03/2017
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES:
SEE SECTION 16:
H301: TOXIC IF SWALLOWED
H400: VERY TOXIC TO AQUATIC LIFE
H401: TOXIC TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN UNDER TYPICAL DIRE
CONDITIONS, INCLUDING INTRINSICALLY NONCOMBUSTIBLE
MATERIALS SUCH AS CONCRETE, STONE, AND SAND.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HMIS III RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 0 MINIMAL HAZARD - MATERIALS THAT WILL NOT BURN
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION B
B - SAFETY GLASSES, GLOVES
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)