| Common Name: | DIMETHYLGLYOXIME, 1% ALCOHOLIC |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 1/28/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8RX83 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
DIMETHYLGLYOXIME, 1% ALCOHOLIC
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
ISSUE DATE: 12/31/2014
REVISION DATE: 01/28/2021
SUPERSEDES: 05/03/2017
VERSION: 2.0
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: DIMETHYLGLYOXIME, 1% ALCOHOLIC
PRODUCT CODE: LC13600
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE:
FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM, INC.
1010 JACKSON'S POINTE CT.
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR +1-703-741-5970
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS US CLASSIFICATION:
FLAMMABLE LIQUIDS CATEGORY 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
ACUTE TOXICITY (ORAL) CATEGORY 4:
H302: HARMFUL IF SWALLOWED
SKIN CORROSION/IRRITATION CATEGORY 2:
H315: CAUSES SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A:
H319: CAUSES SERIOUS EYE IRRITATION
REPRODUCTIVE TOXICITY CATEGORY 2:
H361: SUSPECTED OF DAMAGING THE UNBORN CHILD. (ORAL)
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 1:
H370:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE, LIVER,
KIDNEYS)
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3, RESPIRATORY
TRACT IRRITATION:
H335: MAY CAUSE RESPIRATORY IRRITATION
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS US LABELING:
HAZARD PICTOGRAMS (GHS US):
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD (GHS US): DANGER
HAZARD STATEMENTS (GHS US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H302: HARMFUL IF SWALLOWED
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
H361: SUSPECTED OF DAMAGING THE UNBORN CHILD. (ORAL)
H370:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE, LIVER,
KIDNEYS)
PRECAUTIONARY STATEMENTS (GHS US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT, HOT SURFACES, OPEN FLAMES, SPARKS. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL, LIGHTING, VENTILATING EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE MIST, VAPORS, SPRAY.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR EYE PROTECTION, FACE PROTECTION, PROTECTIVE CLOTHING, PROTECTIVE
GLOVES.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P330: IF SWALLOWED, RINSE MOUTH
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P370+P378:
IN CASE OF FIRE:
USE CARBON DIOXIDE (CO2), POWDER, ALCOHOL-RESISTANT FOAM TO EXTINGUISH
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS US CLASSIFICATION
ETHANOL (CAS-NO.) 64-17-5 89.1 FLAM. LIQ. 2, H225
ISOPROPYL ALCOHOL (CAS-NO.) 67-63-0 4.95 FLAM. LIQ. 2, H225
(2-PROPANOL) EYE IRRIT. 2A, H319
STOT SE 3, H335
METHANOL (CAS-NO.) 67-56-1 4.95 FLAM. LIQ. 2, H225
ACUTE TOX. 3 (ORAL), H301
ACUTE TOX. 3 (DERMAL), H311
ACUTE TOX. 3 (INHALATION),
H331
STOT SE 1, H370
DIMETHYLGLYOXIME, (CAS-NO.) 95-45-4 1 FLAM. SOL. 2, H228
ACS ACUTE TOX. 3 (ORAL), H301
COMB. DUST
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
CHECK THE VITAL FUNCTIONS. UNCONSCIOUS: MAINTAIN ADEQUATE AIRWAY AND
RESPIRATION. RESPIRATORY ARREST: ARTIFICIAL RESPIRATION OR OXYGEN. CARDIAC
ARREST: PERFORM RESUSCITATION. VICTIM CONSCIOUS WITH LABORED BREATHING:
HALF-SEATED. VICTIM IN SHOCK: ON HIS BACK WITH LEGS SLIGHTLY RAISED.
VOMITING: PREVENT ASPHYXIA/ASPIRATION PNEUMONIA. PREVENT COOLING BY
COVERING THE VICTIM (NO WARMING UP). KEEP WATCHING THE VICTIM. GIVE
PSYCHOLOGICAL AID. KEEP THE VICTIM CALM, AVOID PHYSICAL STRAIN. DEPENDING
ON THE VICTIM'S CONDITION: DOCTOR/HOSPITAL. NEVER GIVE ALCOHOL TO DRINK.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF EXPOSED OR
CONCERNED: GET MEDICAL ADVICE/ATTENTION. CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INHALATION: REMOVE VICTIM TO FRESH AIR AND KEEP AT
REST IN A POSITION COMFORTABLE FOR BREATHING. CALL A POISON CENTER OR
DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE SKIN WITH WATER/SHOWER. REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED
CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSE. IF SKIN IRRITATION
OCCURS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. DO NOT APPLY NEUTRALIZING
AGENTS. TAKE VICTIM TO AN OPHTHALMOLOGIST IF IRRITATION PERSISTS. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
FIRST-AID MEASURES AFTER INGESTION:
INGESTION OF LARGE QUANTITIES:
IMMEDIATELY TO HOSPITAL. RINSE MOUTH. DO NOT INDUCE VOMITING. CALL A
POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS: HARMFUL IF SWALLOWED.
SYMPTOMS/EFFECTS:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CAUSES DAMAGE TO
ORGANS.
SYMPTOMS/EFFECTS AFTER INHALATION:
EXPOSURE TO HIGH CONCENTRATIONS:
DRY/SORE THROAT. COUGHING. IRRITATION OF THE RESPIRATORY TRACT. IRRITATION
OF THE NASAL MUCOUS MEMBRANES. RESPIRATORY DIFFICULTIES. CENTRAL NERVOUS
SYSTEM DEPRESSION. SYMPTOMS SIMILAR TO THOSE LISTED UNDER INGESTION. MAY
CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
REDNESS OF THE EYE TISSUE. LACRIMATION. ON CONTINUOUS EXPOSURE/CONTACT:
IRRITATION OF THE EYE TISSUE.
SYMPTOMS/EFFECTS AFTER INGESTION:
AFTER ABSORPTION OF LARGE QUANTITIES:
RISK OF ASPIRATION PNEUMONIA. RED SKIN. BODY TEMPERATURE RISE. DAMP/CLAMMY
SKIN. EXCITED/RESTLESS. ACCELERATED HEART ACTION. CENTRAL NERVOUS SYSTEM
DEPRESSION. DIZZINESS. NARCOSIS. HEADACHE. DRUNKENNESS. NAUSEA. VOMITING.
DISTURBED MOTOR RESPONSE. COORDINATION DISORDERS. VISUAL DISTURBANCES.
IMPAIRED CONCENTRATION. DELUSIONS. DISTURBED SENSATION OF PAIN.
DISTURBANCES OF HEART RATE. DISTURBANCES OF CONSCIOUSNESS. TREMOR.
CRAMPS/UNCONTROLLED MUSCULAR CONTRACTIONS. DILATED PUPILS. SWALLOWING A
SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH HAZARD.
CHRONIC SYMPTOMS:
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
DRY SKIN. GASTROINTESTINAL COMPLAINTS. ENLARGEMENT/AFFECTION OF THE LIVER.
CHANGE IN THE HAEMOGRAMME/BLOOD COMPOSITION. CARDIAC AND BLOOD CIRCULATION
EFFECTS. HIGH ARTERIAL PRESSURE. IMPAIRMENT OF THE NERVOUS SYSTEM.
BEHAVIORAL DISTURBANCES. MENTAL CONFUSION. DISTURBED TACTILE SENSIBILITY.
TREMOR. AFFECTION OF THE BONE MARROW. AFFECTION OF THE ENDOCRINE SYSTEM.
WEAKENING OF THE IMMUNE SYSTEM.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY. ALCOHOL-RESISTANT FOAM. BC POWDER. CARBON DIOXIDE. FOAM. DRY
POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA:
SOLID WATER JET INEFFECTIVE AS EXTINGUISHING MEDIUM. DO NOT USE A HEAVY
WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD:
DIRECT FIRE HAZARD. HIGHLY FLAMMABLE. GAS/VAPOR FLAMMABLE WITH AIR WITHIN
EXPLOSION LIMITS. INDIRECT FIRE HAZARD. MAY BE IGNITED BY SPARKS. GAS/VAPOR
SPREADS AT FLOOR LEVEL: IGNITION HAZARD. REACTIONS INVOLVING A FIRE HAZARD:
SEE "REACTIVITY HAZARD". HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD:
DIRECT EXPLOSION HAZARD. GAS/VAPOUR EXPLOSIVE WITH AIR WITHIN EXPLOSION
LIMITS. INDIRECT EXPLOSION HAZARD. MAY BE IGNITED BY SPARKS. REACTIONS
WITH EXPLOSION HAZARDS: SEE "REACTIVITY HAZARD". MAY FORM
FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
HAZARDOUS DECOMPOSITION PRODUCTS IN CASE OF FIRE:
UPON COMBUSTION: CO AND CO2 ARE FORMED.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
COOL TANKS/DRUMS WITH WATER SPRAY/REMOVE THEM INTO SAFETY. DO NOT MOVE THE
LOAD IF EXPOSED TO HEAT. USE WATER SPRAY OR FOG FOR COOLING EXPOSED
CONTAINERS. EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT
FIRE-FIGHTING WATER FROM ENTERING ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
HEAT/FIRE EXPOSURE: COMPRESSED AIR/OXYGEN APPARATUS. DO NOT ENTER FIRE AREA
WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: GLOVES. PROTECTIVE GOGGLES. PROTECTIVE CLOTHING.
EMERGENCY PROCEDURES:
KEEP UPWIND. MARK THE DANGER AREA. CONSIDER EVACUATION. SEAL OFF LOW-LYING
AREAS. CLOSE DOORS AND WINDOWS OF ADJACENT PREMISES. STOP ENGINES AND NO
SMOKING. NO NAKED FLAMES OR SPARKS. SPARK- AND EXPLOSION-PROOF APPLIANCES
AND LIGHTING EQUIPMENT. KEEP CONTAINERS CLOSED. WASH CONTAMINATED CLOTHES.
EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. AVOID BREATHING MIST, VAPORS,
SPRAY.
EMERGENCY PROCEDURES:
IF A MAJOR SPILL OCCURS, ALL PERSONNEL SHOULD BE IMMEDIATELY EVACUATED AND
THE AREA VENTILATED. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT SPREADING IN SEWERS. PREVENT ENTRY TO SEWERS AND PUBLIC WATERS.
NOTIFY AUTHORITIES IF LIQUID ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. CONSULT
"MATERIAL-HANDLING" TO SELECT MATERIAL OF CONTAINERS. PLUG THE LEAK, CUT
OFF THE SUPPLY. DAM UP THE LIQUID SPILL. TRY TO REDUCE EVAPORATION. MEASURE
THE CONCENTRATION OF THE EXPLOSIVE GAS-AIR MIXTURE. DILUTE/DISPERSE
COMBUSTIBLE GAS/VAPOUR WITH WATER CURTAIN. PROVIDE EQUIPMENT/RECEPTACLES
WITH EARTHING. DO NOT USE COMPRESSED AIR FOR PUMPING OVER SPILLS.
METHODS FOR CLEANING UP:
SMALL QUANTITIES OF LIQUID SPILL:
TAKE UP IN NON-COMBUSTIBLE ABSORBENT MATERIAL AND SHOVEL INTO CONTAINER FOR
DISPOSAL. WASH AWAY NEUTRALIZED PRODUCT WITH PLENTIFUL WATER.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
COMPLY WITH THE LEGAL REQUIREMENTS. REMOVE CONTAMINATED CLOTHING
IMMEDIATELY. CLEAN CONTAMINATED CLOTHING. HANDLE UNCLEANED EMPTY CONTAINERS
AS FULL ONES. THOROUGHLY CLEAN/DRY THE INSTALLATION BEFORE USE. DO NOT
DISCHARGE THE WASTE INTO THE DRAIN. DO NOT USE COMPRESSED AIR FOR PUMPING
OVER. USE SPARK-/EXPLOSION PROOF APPLIANCES AND LIGHTING SYSTEM. TAKE
PRECAUTIONS AGAINST ELECTROSTATIC CHARGES. KEEP AWAY FROM NAKED
FLAMES/HEAT. KEEP AWAY FROM IGNITION SOURCES/SPARKS. OBSERVE NORMAL HYGIENE
STANDARDS. KEEP CONTAINER TIGHTLY CLOSED. MEASURE THE CONCENTRATION IN THE
AIR REGULARLY. WORK UNDER LOCAL EXHAUST/VENTILATION. WASH HANDS AND OTHER
EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING
AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN PROCESS AREA TO PREVENT
FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING. USE ONLY NON-SPARKING
TOOLS. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL
SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA. DO NOT BREATHE MIST, VAPORS, SPRAY.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED SKIN
THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
STORAGE CONDITIONS:
KEEP COOL. KEEP IN FIREPROOF PLACE. KEEP CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS. STRONG BASES. STRONG ACIDS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
HEAT-IGNITION:
KEEP SUBSTANCE AWAY FROM: HEAT SOURCES. IGNITION SOURCES. PROHIBITIONS ON
MIXED STORAGE: KEEP SUBSTANCE AWAY FROM: OXIDIZING AGENTS. STRONG ACIDS.
WATER/MOISTURE.
STORAGE AREA:
KEEP OUT OF DIRECT SUNLIGHT. STORE IN A DRY AREA. VENTILATION AT FLOOR
LEVEL. FIREPROOF STOREROOM. PROVIDE FOR AN AUTOMATIC SPRINKLER SYSTEM.
PROVIDE FOR A TUB TO COLLECT SPILLS. PROVIDE THE TANK WITH EARTHING. MEET
THE LEGAL REQUIREMENTS.
SPECIAL RULES ON PACKAGING:
SPECIAL REQUIREMENTS:
CLOSING. DRY. CLEAN. CORRECTLY LABELED. MEET THE LEGAL
REQUIREMENTS. SECURE FRAGILE PACKAGINGS IN SOLID CONTAINERS.
PACKAGING MATERIALS:
SUITABLE MATERIAL:
STAINLESS STEEL. ALUMINIUM. IRON. COPPER. NICKEL. SYNTHETIC MATERIAL.
GLASS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
DIMETHYLGLYOXIME, 1% ALCOHOLIC:
USA - ACGIH - OCCUPATIONAL EXPOSURE LIMITS:
ACGIH STEL (PPM): 1000 PPM
USA - OSHA - OCCUPATIONAL EXPOSURE LIMITS:
OSHA PEL (TWA) [1]: 1900 MG/M3
OSHA PEL (TWA) [2]: 1000 PPM
USA - IDLH - OCCUPATIONAL EXPOSURE LIMITS:
IDLH [PPM]: 3300 PPM
USA - NIOSH - OCCUPATIONAL EXPOSURE LIMITS:
NIOSH REL (TWA): 1900 MG/M3
NIOSH REL TWA [PPM]: 1000 PPM
ETHANOL (64-17-5):
USA - ACGIH - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: ETHANOL
ACGIH STEL (PPM): 1000 PPM
REMARK (ACGIH):
TLV(R*) BASIS:
URT IRR. NOTATIONS:
A3 (CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS)
REGULATORY REFERENCE: ACGIH 2020
USA - OSHA - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: ETHYL ALCOHOL (ETHANOL)
OSHA PEL (TWA) [1]: 1900 MG/M3
OSHA PEL (TWA) [2]: 1000 PPM
REGULATORY REFERENCE (US-OSHA): OSHA ANNOTATED TABLE Z-1
USA - IDLH - OCCUPATIONAL EXPOSURE LIMITS:
IDLH [PPM]: 3300 PPM
USA - NIOSH - OCCUPATIONAL EXPOSURE LIMITS:
NIOSH REL (TWA): 1900 MG/M3
NIOSH REL TWA [PPM]: 1000 PPM
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
USA - ACGIH - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: 2-PROPANOL
ACGIH OEL TWA [PPM]: 200 PPM
ACGIH STEL (PPM): 400 PPM
REMARK:
(ACGIH) TLV(R*) BASIS:
EYE & URT IRR; CNS IMPAIR. NOTATIONS: A4 (NOT CLASSIFIABLE AS A HUMAN
CARCINOGEN); BEI
REGULATORY REFERENCE: ACGIH 2020
USA - ACGIH - BIOLOGICAL EXPOSURE INDICES:
LOCAL NAME: 2-PROPANOL
BIOLOGICAL EXPOSURE INDICES (BEI):
40 MG/L PARAMETER: ACETONE - MEDIUM: URINE - SAMPLING TIME: END OF SHIFT AT
END OF WORKWEEK - NOTATIONS: B, NS
REGULATORY REFERENCE: ACGIH 2020
USA - OSHA - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: ISOPROPYL ALCOHOL
OSHA PEL (TWA) [1]: 980 MG/M3
OSHA PEL (TWA) [2]: 400 PPM
REGULATORY REFERENCE (US-OSHA): OSHA ANNOTATED TABLE Z-1
USA - IDLH - OCCUPATIONAL EXPOSURE LIMITS:
IDLH [PPM]: 2000 PPM
USA - NIOSH - OCCUPATIONAL EXPOSURE LIMITS:
NIOSH REL (TWA): 980 MG/M3
NIOSH REL TWA [PPM]: 400 PPM
NIOSH REL (STEL): 1225 MG/M3
NIOSH REL STEL [PPM]: 500 PPM
METHANOL (67-56-1):
USA - ACGIH - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: METHANOL
ACGIH OEL TWA [PPM]: 200 PPM
ACGIH STEL (PPM): 250 PPM
REMARK (ACGIH):
TLV(R*) BASIS:
HEADACHE; EYE DAM; DIZZINESS; NAUSEA. NOTATIONS: SKIN; BEI
REGULATORY REFERENCE ACGIH 2020
USA - ACGIH - BIOLOGICAL EXPOSURE INDICES:
LOCAL NAME: METHANOL
BIOLOGICAL EXPOSURE INDICES (BEI):
15 MG/L PARAMETER: METHANOL - MEDIUM: URINE - SAMPLING TIME: END OF SHIFT -
NOTATIONS: B, NS
REGULATORY REFERENCE: ACGIH 2020
USA - OSHA - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: METHYL ALCOHOL
OSHA PEL (TWA) [1]: 260 MG/M3
OSHA PEL (TWA) [2]: 200 PPM
REGULATORY REFERENCE (US-OSHA): OSHA ANNOTATED TABLE Z-1
USA - IDLH - OCCUPATIONAL EXPOSURE LIMITS:
IDLH [PPM]: 6000 PPM
USA - NIOSH - OCCUPATIONAL EXPOSURE LIMITS:
NIOSH REL (TWA): 250 MG/M3
NIOSH REL TWA [PPM]: 200 PPM
NIOSH REL (STEL): 325 MG/M3
NIOSH REL STEL [PPM]: 250 PPM
REMARK (NIOSH): SKIN
DIMETHYLGLYOXIME, ACS (95-45-4): NO ADDITIONAL INFORMATION AVAILABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST
VENTILATION.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
HIGH GAS/VAPOR CONCENTRATION:
GAS MASK WITH FILTER TYPE A. GLOVES. SAFETY GLASSES. CHEMICAL RESISTANT
APRON.
MATERIALS FOR PROTECTIVE CLOTHING:
GIVE EXCELLENT RESISTANCE:
BUTYL RUBBER. VITON. GIVE GOOD RESISTANCE: NEOPRENE. TETRAFLUOROETHYLENE.
GIVE LESS RESISTANCE: NITRILE RUBBER. POLYETHYLENE. GIVE POOR RESISTANCE:
NATURAL RUBBER. PVA. PVC
HAND PROTECTION: GLOVES. WEAR PROTECTIVE GLOVES.
EYE PROTECTION: SAFETY GLASSES. CHEMICAL GOGGLES OR SAFETY GLASSES
SKIN AND BODY PROTECTION:
PROTECTIVE CLOTHING. WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
WEAR GAS MASK WITH FILTER TYPE A IF CONC. IN AIR > EXPOSURE LIMIT
PERSONAL PROTECTIVE EQUIPMENT SYMBOL(S):
GLOVES
SAFETY GLASSES
APRON
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: ALCOHOL ODOR PLEASANT ODOR
ODOR THRESHOLD:
100 PPM
188 MG/M3
PH: 7 (789 G/L, 20 DEG. C)
MELTING POINT: -115 DEG. C
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 78 DEG. C
CRITICAL TEMPERATURE: 243 DEG. C
CRITICAL PRESSURE: 63840 HPA
FLASH POINT: 13 DEG. C
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): 2.4
RELATIVE EVAPORATION RATE (ETHER=1): 8.3
FLAMMABILITY (SOLID, GAS): HIGHLY FLAMMABLE LIQUID AND VAPOR.
VAPOR PRESSURE: 59 HPA
VAPOR PRESSURE AT 50 DEG. C: 300 HPA
RELATIVE VAPOR DENSITY AT 20 DEG. C: 1.6
RELATIVE DENSITY: 0.79
RELATIVE DENSITY OF SATURATED GAS/AIR MIXTURE: 1.04
DENSITY: 790 KG/M3
SOLUBILITY: SOLUBLE IN ETHER. SOLUBLE IN ACETONE. SOLUBLE IN METHANOL.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: 363 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: 1.6 MM2/S (20 DEG. C)
VISCOSITY, DYNAMIC: 20 DEG. C
EXPLOSION LIMITS:
3.3 - 19 VOL %
67 - 290 G/M3
LOWER EXPLOSIVE LIMIT (LEL): 2.5 VOL % (ASTM E681: FLAMMABILITY (GASES))
UPPER EXPLOSIVE LIMIT (UEL): 13.5 VOL % (ASTM E681: FLAMMABILITY (GASES))
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
SPECIFIC CONDUCTIVITY: 130000 PS/M
SATURATION CONCENTRATION: 112 G/M3
VOC CONTENT: 100%
OTHER PROPERTIES:
GAS/VAPOUR HEAVIER THAN AIR AT 20 DEG. C. CLEAR. HYGROSCOPIC. VOLATILE.
NEUTRAL REACTION.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
UPON COMBUSTION:
CO AND CO2 ARE FORMED. REACTS VIOLENTLY WITH MANY COMPOUNDS E.G.: WITH
(STRONG) OXIDIZERS: (INCREASED) RISK OF FIRE/EXPLOSION. VIOLENT TO
EXPLOSIVE REACTION WITH (SOME) ACIDS.
10.2. CHEMICAL STABILITY:
HYGROSCOPIC. HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY FORM
FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS VIOLENTLY WITH COMBUSTIBLE MATERIALS: RISK OF SPONTANEOUS IGNITION.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS. STRONG ACIDS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. MAY RELEASE FLAMMABLE GASES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY (ORAL): HARMFUL IF SWALLOWED.
ACUTE TOXICITY (DERMAL): NOT CLASSIFIED
ACUTE TOXICITY (INHALATION): NOT CLASSIFIED
DIMETHYLGLYOXIME, 1% ALCOHOLIC:
LC50 INHALATION - RAT:
125 MG/L AIR (EQUIVALENT OR SIMILAR TO OECD 403, 4 H, RAT, MALE / FEMALE,
EXPERIMENTAL VALUE, INHALATION (VAPORS), 14 DAY(S))
ATE US (ORAL): 1680.672 MG/KG BODY WEIGHT
ETHANOL (64-17-5):
LD50 ORAL RAT:
10740 MG/KG (RAT; EXPERIMENTAL VALUE, RAT; EXPERIMENTAL VALUE)
LD50 DERMAL RABBIT:
>15800 MG/KG BODY WEIGHT (RABBIT, EXPERIMENTAL VALUE, DERMAL)
LC50 INHALATION - RAT:
125 MG/L AIR (EQUIVALENT OR SIMILAR TO OECD 403, 4 H, RAT, MALE / FEMALE,
EXPERIMENTAL VALUE, INHALATION (VAPORS), 14 DAY(S))
ATE US (ORAL): 10740 MG/KG BODY WEIGHT
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LD50 ORAL RAT:
5840 MG/KG BODY WEIGHT (EQUIVALENT OR SIMILAR TO OECD 401, RAT,
EXPERIMENTAL VALUE, ORAL, 14 DAY(S))
LD50 DERMAL RABBIT:
12882 MG/KG BODY WEIGHT (EQUIVALENT OR SIMILAR TO OECD 402, 24 H, RABBIT,
EXPERIMENTAL VALUE, CONVERTED VALUE, DERMAL, 14 DAY(S))
LC50 INHALATION - RAT [PPM]:
>10000 PPM (EQUIVALENT OR SIMILAR TO OECD 403, 6 H, RAT, MALE / FEMALE,
EXPERIMENTAL VALUE, INHALATION (VAPORS), 14 DAY(S))
ATE US (ORAL): 5840 MG/KG BODY WEIGHT
ATE US (DERMAL): 12882 MG/KG BODY WEIGHT
METHANOL (67-56-1):
LD50 ORAL RAT:
1187 - 2769 MG/KG BODY WEIGHT (BASF TEST, RAT, MALE / FEMALE, EXPERIMENTAL
VALUE, AQUEOUS SOLUTION, ORAL, 7 DAY(S))
LC50 INHALATION - RAT:
128 MG/L AIR (BASF TEST, 4 H, RAT, MALE / FEMALE, EXPERIMENTAL VALUE,
INHALATION (VAPORS))
ATE US (ORAL): 100 MG/KG BODY WEIGHT
ATE US (DERMAL): 300 MG/KG BODY WEIGHT
ATE US (GASES): 700 PPMV/4H
ATE US (VAPORS): 3 MG/L/4H
ATE US (DUST, MIST): 0.5 MG/L/4H
DIMETHYLGLYOXIME, ACS (95-45-4):
ATE US (ORAL): 100 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
PH: 7 (789 G/L, 20 DEG. C)
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
PH: 7 (789 G/L, 20 DEG. C)
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING THE UNBORN CHILD. (ORAL).
STOT-SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE, LIVER,
KIDNEYS). MAY CAUSE RESPIRATORY IRRITATION.
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
STOT-SINGLE EXPOSURE: MAY CAUSE RESPIRATORY IRRITATION.
METHANOL (67-56-1):
STOT-SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS (LIVER, KIDNEYS, CENTRAL NERVOUS SYSTEM, OPTIC
NERVE) (DERMAL, ORAL).
STOT-REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
VISCOSITY, KINEMATIC: 1.6 MM2/S (20 DEG. C)
LIKELY ROUTES OF EXPOSURE: INHALATION. SKIN AND EYE CONTACT.
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS: HARMFUL IF SWALLOWED.
SYMPTOMS/EFFECTS:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CAUSES DAMAGE TO
ORGANS.
SYMPTOMS/EFFECTS AFTER INHALATION:
EXPOSURE TO HIGH CONCENTRATIONS:
DRY/SORE THROAT. COUGHING. IRRITATION OF THE RESPIRATORY TRACT. IRRITATION
OF THE NASAL MUCOUS MEMBRANES. RESPIRATORY DIFFICULTIES. CENTRAL NERVOUS
SYSTEM DEPRESSION. SYMPTOMS SIMILAR TO THOSE LISTED UNDER INGESTION. MAY
CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
REDNESS OF THE EYE TISSUE. LACRIMATION. ON CONTINUOUS EXPOSURE/CONTACT:
IRRITATION OF THE EYE TISSUE.
SYMPTOMS/EFFECTS AFTER INGESTION:
AFTER ABSORPTION OF LARGE QUANTITIES:
RISK OF ASPIRATION PNEUMONIA. RED SKIN. BODY TEMPERATURE RISE. DAMP/CLAMMY
SKIN. EXCITED/RESTLESS. ACCELERATED HEART ACTION. CENTRAL NERVOUS SYSTEM
DEPRESSION. DIZZINESS. NARCOSIS. HEADACHE. DRUNKENNESS. NAUSEA. VOMITING.
DISTURBED MOTOR RESPONSE. COORDINATION DISORDERS. VISUAL DISTURBANCES.
IMPAIRED CONCENTRATION. DELUSIONS. DISTURBED SENSATION OF PAIN.
DISTURBANCES OF HEART RATE. DISTURBANCES OF CONSCIOUSNESS. TREMOR.
CRAMPS/UNCONTROLLED MUSCULAR CONTRACTIONS. DILATED PUPILS. SWALLOWING A
SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH HAZARD.
CHRONIC SYMPTOMS:
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
DRY SKIN. GASTROINTESTINAL COMPLAINTS. ENLARGEMENT/AFFECTION OF THE LIVER.
CHANGE IN THE HAEMOGRAMME/BLOOD COMPOSITION. CARDIAC AND BLOOD CIRCULATION
EFFECTS. HIGH ARTERIAL PRESSURE. IMPAIRMENT OF THE NERVOUS SYSTEM.
BEHAVIORAL DISTURBANCES. MENTAL CONFUSION. DISTURBED TACTILE SENSIBILITY.
TREMOR. AFFECTION OF THE BONE MARROW. AFFECTION OF THE ENDOCRINE SYSTEM.
WEAKENING OF THE IMMUNE SYSTEM.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL:
CLASSIFICATION CONCERNING THE ENVIRONMENT: NOT APPLICABLE.
ECOLOGY - AIR:
NOT CLASSIFIED AS DANGEROUS FOR THE OZONE LAYER (REGULATION (EC) NO
1005/2009). NOT INCLUDED IN THE LIST OF SUBSTANCES WHICH MAY CONTRIBUTE TO
THE GREENHOUSE EFFECT (REGULATION (EC) NO 842/2006). TA-LUFT KLASSE 5.2.5.
ECOLOGY - WATER:
NOT HARMFUL TO CRUSTACEA. NOT HARMFUL TO FISHES. NO INHIBITION OF ACTIVATED
SLUDGE. SLIGHTLY HARMFUL TO ALGAE. NOT HARMFUL TO BACTERIA. HARMFUL TO
PLANKTON.
ETHANOL (64-17-5):
LC50 FISH 1:
15300 MG/L (US EPA, 96 H, PIMEPHALES PROMELAS, FLOW-THROUGH SYSTEM, FRESH
WATER, EXPERIMENTAL VALUE, LETHAL)
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LC50 FISH 1:
9640 - 10000 MG/L (EQUIVALENT OR SIMILAR TO OECD 203, 96 H, PIMEPHALES
PROMELAS, FLOW-THROUGH SYSTEM, FRESH WATER, EXPERIMENTAL VALUE, LETHAL)
METHANOL (67-56-1):
LC50 FISH 1:
15400 MG/L (EPA 660/3 - 75/009, 96 H, LEPOMIS MACROCHIRUS, FLOW-THROUGH
SYSTEM, FRESH WATER, EXPERIMENTAL VALUE, LETHAL)
EC50 DAPHNIA 1:
18260 MG/L (OECD 202: DAPHNIA SP. ACUTE IMMOBILIZATION TEST, 96 H, DAPHNIA
MAGNA, SEMI-STATIC SYSTEM, FRESH WATER, EXPERIMENTAL VALUE, LOCOMOTOR
EFFECT)
12.2. PERSISTENCE AND DEGRADABILITY:
DIMETHYLGLYOXIME, 1% ALCOHOLIC:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
ETHANOL (64-17-5):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABLE IN THE SOIL. READILY BIODEGRADABLE IN WATER.
ETHANOL (64-17-5):
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.8 - 0.967 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.7 G O2/G SUBSTANCE
THOD: 2.1 G O2/G SUBSTANCE
BOD (% OF THOD): 0.43
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN THE SOIL UNDER ANAEROBIC
CONDITIONS. READILY BIODEGRADABLE IN WATER.
BIOCHEMICAL OXYGEN DEMAND (BOD): 1.19 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.23 G O2/G SUBSTANCE
THOD: 2.4 G O2/G SUBSTANCE
METHANOL (67-56-1):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN THE SOIL. READILY BIODEGRADABLE IN WATER.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.6 - 1.12 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.42 G O2/G SUBSTANCE
THOD: 1.5 G O2/G SUBSTANCE
DIMETHYLGLYOXIME, ACS (95-45-4):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY IN WATER: NO DATA AVAILABLE. NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
DIMETHYLGLYOXIME, 1% ALCOHOLIC:
BCF FISH 1:
1 (OTHER, 72 H, CYPRINUS CARPIO, STATIC SYSTEM, FRESH WATER, READ-ACROSS)
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
ETHANOL (64-17-5):
BCF FISH 1:
1 (OTHER, 72 H, CYPRINUS CARPIO, STATIC SYSTEM, FRESH WATER, READ-ACROSS)
LOG POW: -0.31 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LOG POW: 0.05 (WEIGHT OF EVIDENCE APPROACH, 25 DEG. C)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
METHANOL (67-56-1):
BCF FISH 1:
1 - 4.5 (72 H, CYPRINUS CARPIO, STATIC SYSTEM, FRESH WATER, EXPERIMENTAL
VALUE)
LOG POW: -0.77 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
DIMETHYLGLYOXIME, ACS (95-45-4):
LOG POW: -2.16 - -0.29 (CALCULATED)
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
12.4. MOBILITY IN SOIL:
DIMETHYLGLYOXIME, 1% ALCOHOLIC:
SURFACE TENSION: 0.022 N/M 20 DEG. C
LOG KOC: 0.2 (LOG KOC, EXPERIMENTAL VALUE)
ECOLOGY - SOIL: HIGHLY MOBILE IN SOIL.
ETHANOL (64-17-5):
SURFACE TENSION: 22.31 MN/M (20 DEG. C, 100%)
LOG KOC: 0.2 (LOG KOC, EXPERIMENTAL VALUE)
ECOLOGY - SOIL: HIGHLY MOBILE IN SOIL.
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
SURFACE TENSION: NO DATA AVAILABLE (TEST NOT PERFORMED)
ECOLOGY - SOIL: HIGHLY MOBILE IN SOIL.
METHANOL (67-56-1):
SURFACE TENSION: NO DATA AVAILABLE IN THE LITERATURE
LOG KOC: -0.89 - -0.21 (LOG KOC, CALCULATED VALUE)
ECOLOGY - SOIL: HIGHLY MOBILE IN SOIL.
DIMETHYLGLYOXIME, ACS (95-45-4):
ECOLOGY - SOIL: NO (TEST)DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE.
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
REMOVE WASTE IN ACCORDANCE WITH LOCAL AND/OR NATIONAL REGULATIONS.
HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER WITH OTHER WASTE. DIFFERENT
TYPES OF HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER IF THIS MAY ENTAIL A
RISK OF POLLUTION OR CREATE PROBLEMS FOR THE FURTHER MANAGEMENT OF THE
WASTE. HAZARDOUS WASTE SHALL BE MANAGED RESPONSIBLY. ALL ENTITIES THAT
STORE, TRANSPORT OR HANDLE HAZARDOUS WASTE SHALL TAKE THE NECESSARY
MEASURES TO PREVENT RISKS OF POLLUTION OR DAMAGE TO PEOPLE OR ANIMALS.
RECYCLE BY DISTILLATION. REMOVE TO AN AUTHORIZED WASTE INCINERATOR FOR
SOLVENTS WITH ENERGY RECOVERY. DO NOT DISCHARGE INTO SURFACE WATER. MAY BE
DISCHARGED TO WASTEWATER TREATMENT INSTALLATION. DISPOSE IN A SAFE MANNER
IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
LWCA (THE NETHERLANDS):
KGA CATEGORY 03. HAZARDOUS WASTE ACCORDING TO DIRECTIVE 2008/98/EC. HANDLE
EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1170 ETHANOL SOLUTIONS, 3, II
UN-NO.(DOT): UN1170
PROPER SHIPPING NAME (DOT): ETHANOL SOLUTIONS
TRANSPORT HAZARD CLASS(ES) (DOT):
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SPECIAL PROVISIONS (49 CFR 172.102):
24 - ALCOHOLIC BEVERAGES CONTAINING MORE THAN 70 PERCENT ALCOHOL BY VOLUME
MUST BE TRANSPORTED AS MATERIALS IN PACKING GROUP II. ALCOHOLIC BEVERAGES
CONTAINING MORE THAN 24 PERCENT BUT NOT MORE THAN 70 PERCENT ALCOHOL BY
VOLUME MUST BE TRANSPORTED AS MATERIALS IN PACKING GROUP III.
IB2 - AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE
(31HZ1). ADDITIONAL REQUIREMENT: ONLY LIQUIDS WITH A VAPOR PRESSURE LESS
THAN OR EQUAL TO 110
KPA AT 50 C (1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE
AUTHORIZED.
T4 - 2.65 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 4B;150
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
TRANSPORT BY SEA (IMDG):
UN-NO. (IMDG): 1170
PROPER SHIPPING NAME (IMDG): ETHANOL (ETHYL ALCOHOL)
CLASS (IMDG): 3 - FLAMMABLE LIQUIDS
PACKING GROUP (IMDG): II - SUBSTANCES PRESENTING MEDIUM DANGER
EMS-NO. (1): F-E
EMS-NO. (2): S-D
AIR TRANSPORT (IATA/ICAO):
UN-NO. (IATA): 1170
PROPER SHIPPING NAME (IATA): ETHANOL
CLASS (IATA): 3 - FLAMMABLE LIQUIDS
PACKING GROUP (IATA): II - MEDIUM DANGER
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
DIMETHYLGLYOXIME, 1% ALCOHOLIC:
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD - FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARD - ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
HEALTH HAZARD - SKIN CORROSION OR IRRITATION
HEALTH HAZARD - SERIOUS EYE DAMAGE OR EYE IRRITATION
HEALTH HAZARD - REPRODUCTIVE TOXICITY
HEALTH HAZARD - SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED
EXPOSURE)
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
ISOPROPYL ALCOHOL (2-PROPANOL) CAS-NO. 67-63-0 4.95%
METHANOL CAS-NO. 67-56-1 4.95%
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD - FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARD - SERIOUS EYE DAMAGE OR EYE IRRITATION
HEALTH HAZARD - SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED
EXPOSURE)
METHANOL (67-56-1):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD - FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARD - ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
HEALTH HAZARD - SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED
EXPOSURE)
DIMETHYLGLYOXIME, ACS (95-45-4):
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD - FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARD - ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
15.2. INTERNATIONAL REGULATIONS:
CANADA:
METHANOL (67-56-1): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
DIMETHYLGLYOXIME, ACS (95-45-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
ETHANOL (64-17-5):
LISTED ON IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
15.3. US STATE REGULATIONS:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO METHANOL, WHICH IS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR MORE
INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
| SECTION 16: OTHER INFORMATION | |
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS:
REVISION DATE: 01/28/2021
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H228: FLAMMABLE SOLID
H301: TOXIC IF SWALLOWED
H302: HARMFUL IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION
H331: TOXIC IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H370: CAUSES DAMAGE TO ORGANS
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
* - CHRONIC (LONG-TERM) HEALTH EFFECTS MAY RESULT FROM
REPEATED OVEREXPOSURE
FLAMMABILITY 3 SERIOUS HAZARD - MATERIALS CAPABLE OF IGNITION UNDER
ALMOST ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73 F AND
BOILING POINTS ABOVE 100 F. AS WELL AS LIQUIDS WITH
FLASH POINTS BETWEEN 73 F AND 100 F. (CLASSES IB &
IC)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION H
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