| Common Name: | TITRATION SOLVENT |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 1/16/2017 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8RXT9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
TITRATION SOLVENT
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 01/13/2014
REVISION DATE: 01/16/2017
SUPERSEDES: 10/23/2015
VERSION: 1.2
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: TITRATION SOLVENT
PRODUCT CODE: LC26140
SYNONYMS: TAN SOLVENT
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAMMABLE LIQUIDS CATEGORY 2: H225
ACUTE TOXICITY (ORAL) CATEGORY 4: H302
SKIN CORROSION/IRRITATION CATEGORY 2: H315
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A: H319
REPRODUCTIVE TOXICITY CATEGORY 2: H361
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3: H336
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) CATEGORY 2: H373
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 3: H402
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H302: HARMFUL IF SWALLOWED
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H373:
MAY CAUSE DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, BONE MARROW, LIVER,
KIDNEYS) THROUGH PROLONGED OR REPEATED EXPOSURE (ORAL, INHALATION)
H402: HARMFUL TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P260: DO NOT BREATHE MIST, VAPORS, SPRAY
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
P273: AVOID RELEASE TO THE ENVIRONMENT
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION
P303/P361/P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P305/P351/P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
P235: KEEP COOL
P301/P330/P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
P332/P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
P337/P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE
P370/P378:
IN CASE OF FIRE:
USE CARBON DIOXIDE (CO2), POWDER, ALCOHOL-RESISTANT FOAM TO EXTINGUISH
P403/P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
TOLUENE (CAS NO) 108-88-3 50 FLAM. LIQ. 2, H225
SKIN IRRIT. 2, H315
REPR. 2, H361
STOT SE 3, H336
STOT RE 2, H373
ASP. TOX. 1, H304
AQUATIC ACUTE 3, H402
ISOPROPYL ALCOHOL (CAS NO) 67-63-0 49.5 FLAM. LIQ. 2, H225
(2-PROPANOL) EYE IRRIT. 2A, H319
STOT SE 3, H335
WATER (CAS NO) 7732-18-5 0.5 NOT CLASSIFIED
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF EXPOSED OR
CONCERNED: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE SKIN WITH WATER/SHOWER. REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED
CLOTHING. WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CAUSES DAMAGE TO
ORGANS.
SYMPTOMS/INJURIES AFTER INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
COMBINED GAS/DUST MASK WITH FILTER TYPE A/P3. SAFETY GLASSES. PROTECTIVE
CLOTHING. GLOVES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. DO NOT BREATHE GAS, FUMES, VAPOR
OR SPRAY.
EMERGENCY PROCEDURES:
VENTILATE AREA. STOP LEAK IF SAFE TO DO SO. IF A MAJOR SPILL OCCURS, ALL
PERSONNEL SHOULD BE IMMEDIATELY EVACUATED AND THE AREA VENTILATED.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING.
USE ONLY NON-SPARKING TOOLS. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT
HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID
BREATHING MIST, VAPORS, SPRAY. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED SKIN
THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: HEAT SOURCES, IGNITION SOURCES, INCOMPATIBLE MATERIALS. KEEP IN
FIREPROOF PLACE. KEEP CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS:
STRONG OXIDIZERS. STRONG ACIDS. ACID ANHYDRIDES. HALOGENS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
TOLUENE (108-88-3):
ACGIH:
ACGIH TWA (PPM):
20 PPM (TOLUENE; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT 8 H; TLV -
ADOPTED VALUE)
OSHA: OSHA PEL (TWA) (PPM): 200 PPM
OSHA:
OSHA PEL (STEL) (PPM): 500 PPM 10-MIN PEAK PER 8 HOUR SHIFT
OSHA:
OSHA PEL (CEILING) (PPM): 300 PPM
IDLH:
US IDLH (PPM): 500 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 375 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 100 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 560 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 150 PPM
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
ACGIH:
ACGIH TWA (PPM):
200 PPM (2-PROPANOL; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT 8 H; TLV -
ADOPTED VALUE)
ACGIH:
ACGIH STEL (PPM):
400 PPM (2-PROPANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 980 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 400 PPM
IDLH:
US IDLH (PPM): 2000 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 980 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 400 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 1225 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 500 PPM
WATER (7732-18-5): NOT APPLICABLE
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. ENSURE ADEQUATE VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT:
SAFETY GLASSES. GLOVES. PROTECTIVE CLOTHING. HIGH GAS/VAPOR CONCENTRATION:
GAS MASK WITH FILTER TYPE A.
MATERIALS FOR PROTECTIVE CLOTHING:
GIVE GOOD RESISTANCE: PVA.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
WHERE EXPOSURE THROUGH INHALATION MAY OCCUR FROM USE, RESPIRATORY
PROTECTION EQUIPMENT IS RECOMMENDED.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): HIGHLY FLAMMABLE LIQUID AND VAPOR.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: 0.82
SOLUBILITY: POORLY SOLUBLE IN WATER. SOLUBLE IN TOLUENE.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: 425 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: 1.1 - 12 VOL %
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY:
HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS VIGOROUSLY WITH STRONG OXIDIZERS AND ACIDS.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS. STRONG OXIDIZERS. ACID ANHYDRIDES. HALOGENS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
FUME. CARBON MONOXIDE. CARBON DIOXIDE. MAY RELEASE FLAMMABLE GASES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: ORAL: HARMFUL IF SWALLOWED.
TITRATION SOLVENT:
LD50 ORAL RAT: 1114 MG/KG
ATE US (ORAL): 1114.000 MG/KG BODY WEIGHT
TOLUENE (108-88-3):
LD50 ORAL RAT:
>2000 MG/KG (RAT; EQUIVALENT OR SIMILAR TO OECD 401; LITERATURE STUDY; 5580
MG/KG BODYWEIGHT; RAT; EXPERIMENTAL VALUE)
LD50 DERMAL RABBIT:
12223 MG/KG (RABBIT; LITERATURE STUDY; OTHER; >5000 MG/KG BODYWEIGHT;
RABBIT; EXPERIMENTAL VALUE)
LC50 INHALATION RAT (MG/L): >20 MG/L/4H (RAT; LITERATURE STUDY)
TOLUENE (108-88-3):
ATE US (DERMAL): 12223.000 MG/KG BODY WEIGHT
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LD50 DERMAL RABBIT:
12870 MG/KG (RABBIT; EXPERIMENTAL VALUE; EQUIVALENT OR SIMILAR TO OECD 402;
16.4; RABBIT)
LC50 INHALATION RAT (MG/L): 73 MG/L/4H (RAT)
ATE US (ORAL): 5045.000 MG/KG BODY WEIGHT
ATE US (DERMAL): 12870.000 MG/KG BODY WEIGHT
ATE US (VAPORS): 73.000 MG/L/4H
ATE US (DUST, MIST): 73.000 MG/L/4H
WATER (7732-18-5):
LD50 ORAL RAT: >/=90000 MG/KG
ATE US (ORAL): 90000.000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
TOLUENE (108-88-3):
IARC GROUP: 3 - NOT CLASSIFIABLE
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS OR DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, BONE MARROW, LIVER,
KIDNEYS) THROUGH PROLONGED OR REPEATED EXPOSURE (ORAL, INHALATION).
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. HARMFUL
IF SWALLOWED.
SYMPTOMS/INJURIES AFTER INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - WATER: HARMFUL TO AQUATIC LIFE.
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LC50 FISH 2:
9640 MG/L (LC50; OECD 203: FISH, ACUTE TOXICITY TEST; 96 H; PIMEPHALES
PROMELAS; FLOW-THROUGH SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
EC50 DAPHNIA 2: 13299 MG/L (EC50; OTHER; 48 H; DAPHNIA MAGNA)
THRESHOLD LIMIT ALGAE 1:
>1000 MG/L (EC50; UBA; 72 H; SCENEDESMUS SUBSPICATUS)
12.2. PERSISTENCE AND DEGRADABILITY:
TITRATION SOLVENT:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
TOLUENE (108-88-3):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. LOW POTENTIAL
FOR ADSORPTION IN SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 2.15 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.52 G O2/G SUBSTANCE
THOD: 3.13 G O2/G SUBSTANCE
TOLUENE (108-88-3):
BOD (% OF THOD): 0.69
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN
THE SOIL UNDER ANAEROBIC CONDITIONS. NO TEST DATA ON MOBILITY OF THE
SUBSTANCE AVAILABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): 1.19 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.23 G O2/G SUBSTANCE
THOD: 2.4 G O2/G SUBSTANCE
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
TITRATION SOLVENT:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
TOLUENE (108-88-3):
BCF FISH: 2 90 (BCF; 72 H; LEUCISCUS IDUS; STATIC SYSTEM; FRESH WATER)
LOG POW: 2.73 (EXPERIMENTAL VALUE; OTHER; 20 DEG. C)
BIOACCUMULATIVE POTENTIAL:
LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LOG POW: 0.05 (WEIGHT OF EVIDENCE APPROACH; OTHER; 25 DEG. C)
BIOACCUMULATIVE POTENTIAL:
LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
TOLUENE (108-88-3):
SURFACE TENSION: 0.03 N/M (20 DEG. C)
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
SURFACE TENSION: 0.021 N/M (25 DEG. C)
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1993 FLAMMABLE LIQUIDS, N.O.S., 3, II
UN-NO.(DOT): UN1993
PROPER SHIPPING NAME (DOT): FLAMMABLE LIQUIDS, N.O.S.
TRANSPORT HAZARD CLASS(ES) (DOT):
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB2 - AUTHORIZED IBCS: METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND
31H2); COMPOSITE (31HZ1). ADDITIONAL REQUIREMENT: ONLY LIQUIDS WITH A VAPOR
PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C (1.1 BAR AT 122 F), OR 130
KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED.
T7 - 4 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 / A (TR - TF)
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
TP8 - A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 1.5 BAR (150 KPA)
MAY BE USED WHEN THE FLASH POINT OF THE HAZARDOUS MATERIAL TRANSPORTED IS
GREATER THAN 0 C (32 F).
TP28 - A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 2.65 BAR (265 KPA)
MAY BE USED PROVIDED THE CALCULATED TEST PRESSURE IS 2.65 BAR OR LESS BASED
ON THE MAWP OF THE HAZARDOUS MATERIAL, AS DEFINED IN 178.275 OF THIS
SUBCHAPTER, WHERE THE TEST PRESSURE IS 1.5 TIMES THE MAWP.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 150
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
B - (I) THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO
VESSEL AND ON A PASSENGER VESSEL CARRYING A NUMBER OF PASSENGERS LIMITED TO
NOT MORE THAN THE LARGER OF 25 PASSENGERS, OR ONE PASSENGER PER EACH 3 M OF
OVERALL VESSEL LENGTH; AND (II) "ON DECK ONLY" ON PASSENGER VESSELS IN
WHICH THE NUMBER OF PASSENGERS SPECIFIED IN PARAGRAPH (K)(2)(I) OF THIS
SECTION IS EXCEEDED.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
TITRATION SOLVENT:
SARA SECTION 311/312 HAZARD CLASSES:
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
TOLUENE CAS NO 108-88-3 50%
ISOPROPYL ALCOHOL (2-PROPANOL) CAS NO 67-63-0 49.5%
TOLUENE (108-88-3):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 1000 LB
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
15.2. INTERNATIONAL REGULATIONS:
CANADA:
TITRATION SOLVENT:
WHMIS CLASSIFICATION:
CLASS B DIVISION 2 - FLAMMABLE LIQUID
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
TOLUENE (108-88-3): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS B DIVISION 2 - FLAMMABLE LIQUID
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
WHMIS CLASSIFICATION:
CLASS B DIVISION 2 - FLAMMABLE LIQUID
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
WATER (7732-18-5):
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
TOLUENE (108-88-3):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT CONTAINS, OR MAY CONTAIN, TRACE
QUANTITIES OF A SUBSTANCE(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, DEVELOPMENTAL AND/OR REPRODUCTIVE HARM
TOLUENE (108-88-3):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANT RISK LEVEL (NSRL): 7000 (MICRO)G/DAY
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 01/16/2017
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H302: HARMFUL IF SWALLOWED
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
H402: HARMFUL TO AQUATIC LIFE
NFPA HEALTH HAZARD 3 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SERIOUS OR PERMANENT INJURY.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HMIS III RATING:
HEALTH 3 SERIOUS HAZARD - MAJOR INJURY LIKELY UNLESS PROMPT
ACTION IS TAKEN AND MEDICAL TREATMENT IS GIVEN
FLAMMABILITY 3 SERIOUS HAZARD - MATERIALS CAPABLE OF IGNITION UNDER
ALMOST ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73 F AND
BOILING POINTS ABOVE 100 F. AS WELL AS LIQUIDS WITH
FLASH POINTS BETWEEN 73 F AND 100 F. (CLASSES IB &
IC)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION H
H - SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, VAPOR
RESPIRATOR
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