| Common Name: | GIEMSA STAIN SOLUTION |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 2/17/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8XMV7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
GIEMSA STAIN SOLUTION
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 02/17/2015
VERSION: 1.0
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME: GIEMSA STAIN SOLUTION
PRODUCT CODE: LC14840
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
FLAM. LIQ. 2: H225
ACUTE TOX. 3 (ORAL): H301
ACUTE TOX. 3 (DERMAL): H311
ACUTE TOX. 4 (INHALATION: DUST, MIST): H332
STOT SE 1: H370
FULL TEXT OF H-PHRASES: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS06: SKULLS AND CROSSBONES
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H301+H311: TOXIC IF SWALLOWED OR IN CONTACT WITH SKIN
H332: HARMFUL IF INHALED
H370: CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE)
PRECAUTIONARY STATEMENTS (GHS-US):
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P260: DO NOT BREATHE MIST, VAPORS, SPRAY
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
P280: WEAR PROTECTIVE GLOVES, EYE PROTECTION
P301+P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
P312: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL
P330: IF SWALLOWED, RINSE MOUTH
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % CLASSIFICATION (GHS-US)
GLYCERIN (CAS NO) 56-81-5 60.98 NOT CLASSIFIED
METHANOL (CAS NO) 67-56-1 38.28 FLAM. LIQ. 2, H225
ACUTE TOX. 3 (ORAL), H301
ACUTE TOX. 3 (DERMAL), H311
ACUTE TOX. 3 (INHALATION), H331
STOT SE 1, H370
GIEMSA STAIN (CAS NO) 51811-82-6 0.74 EYE IRRIT. 2A, H319
FULL TEXT OF H-PHRASES: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE). CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER/DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE SKIN WITH WATER/SHOWER. REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED
CLOTHING. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. RINSE
CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. OBTAIN MEDICAL ATTENTION IF
PAIN, BLINKING OR REDNESS PERSIST.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. IMMEDIATELY CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES: CAUSES DAMAGE TO ORGANS.
SYMPTOMS/INJURIES AFTER INHALATION:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION. HARMFUL IF INHALED.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
REPEATED EXPOSURE TO THIS MATERIAL CAN RESULT IN ABSORPTION THROUGH SKIN
CAUSING SIGNIFICANT HEALTH HAZARD. TOXIC IN CONTACT WITH SKIN. MAY STAIN
THE SKIN.
SYMPTOMS/INJURIES AFTER EYE CONTACT: MILD EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
TOXIC IF SWALLOWED. SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL
RESULT IN SERIOUS HEALTH HAZARD.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: SAFETY GLASSES. GLOVES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. AVOID BREATHING MIST, SPRAY.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING.
USE ONLY NON-SPARKING TOOLS. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA. DO NOT BREATHE MIST, VAPORS, SPRAY.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED SKIN
THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: HEAT SOURCES., IGNITION SOURCES, INCOMPATIBLE MATERIALS. KEEP IN
FIREPROOF PLACE. KEEP CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
7.3. SPECIFIC END USE(S): NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
GIEMSA STAIN SOLUTION:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
GIEMSA STAIN (51811-82-6):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
METHANOL (67-56-1):
ACGIH:
ACGIH TWA (PPM): 200 PPM
OSHA:
OSHA PEL (TWA) (MG/M3): 260 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 200 PPM
GLYCERIN (56-81-5):
ACGIH:
ACGIH TWA (MG/M3): 10 MG/M3 MIST
GLYCERIN (56-81-5):
OSHA:
OSHA PEL (TWA) (MG/M3): 5 MG/M3 RESPIRABLE
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. ENSURE ADEQUATE VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT: AVOID ALL UNNECESSARY EXPOSURE.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
RESPIRATORY PROTECTION:
WHERE EXPOSURE THROUGH INHALATION MAY OCCUR FROM USE, RESPIRATORY
PROTECTION EQUIPMENT IS RECOMMENDED.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: PURPLE
ODOR: NONE.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 1.03 G/ML
SOLUBILITY:
SOLUBLE IN GLYCEROL. SOLUBLE IN METHANOL. SOLUBLE IN WATER.
WATER:
SOLUBILITY IN WATER OF COMPONENT(S) OF THE MIXTURE:
METHANOL:
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY:
HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
HYDROGEN BROMIDE, BROMINE. CARBON MONOXIDE. CARBON DIOXIDE. HYDROGEN
CHLORIDE. SULFUR COMPOUNDS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
ORAL: TOXIC IF SWALLOWED.
DERMAL: TOXIC IN CONTACT WITH SKIN.
INHALATION: DUST, MIST HARMFUL IF INHALED.
GIEMSA STAIN SOLUTION:
ATE US (ORAL):
261.233 MG/KG BODY WEIGHT
ATE US (DERMAL):
783.699 MG/KG BODY WEIGHT
ATE US (DUST, MIST): 1.306 MG/L/4H
METHANOL (67-56-1):
LD50 ORAL RAT:
>5000 MG/KG (RAT; BASF TEST; LITERATURE STUDY; 1187-2769 MG/KG BODYWEIGHT;
RAT; WEIGHT OF EVIDENCE)
LD50 DERMAL RABBIT: 15800 MG/KG (RABBIT; LITERATURE STUDY)
LC50 INHALATION RAT (MG/L): 85 MG/L/4H (RAT; LITERATURE STUDY)
LC50 INHALATION RAT (PPM): 64000 PPM/4H (RAT; LITERATURE STUDY)
ATE US (ORAL): 100.000 MG/KG BODY WEIGHT
ATE US (DERMAL): 300.000 MG/KG BODY WEIGHT
ATE US (GASES): 700.000 PPMV/4H
ATE US (VAPORS): 3.000 MG/L/4H
ATE US (DUST, MIST): 0.500 MG/L/4H
GLYCERIN (56-81-5):
LD50 ORAL RAT: 12600 MG/KG
LD50 DERMAL RAT: 21900 MG/KG
ATE US (ORAL): 12600.000 MG/KG BODY WEIGHT
ATE US (DERMAL): 21900.000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE).
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. HARMFUL
IF INHALED. TOXIC IF SWALLOWED. TOXIC IN CONTACT WITH SKIN.
SYMPTOMS/INJURIES AFTER INHALATION:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION. HARMFUL IF INHALED.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
REPEATED EXPOSURE TO THIS MATERIAL CAN RESULT IN ABSORPTION THROUGH SKIN
CAUSING SIGNIFICANT HEALTH HAZARD. TOXIC IN CONTACT WITH SKIN. MAY STAIN
THE SKIN.
SYMPTOMS/INJURIES AFTER EYE CONTACT: MILD EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
TOXIC IF SWALLOWED. SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL
RESULT IN SERIOUS HEALTH HAZARD.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
METHANOL (67-56-1):
LC50 FISH 1: 15400 MG/L (96 H; LEPOMIS MACROCHIRUS; LETHAL)
EC50 DAPHNIA 1: >10000 MG/L (48 H; DAPHNIA MAGNA; LETHAL)
LC50 FISH 2: 10800 MG/L 96 H; SALMO GAIRDNERI (ONCORHYNCHUS MYKISS)
EC50 DAPHNIA 2: 24500 MG/L (48 H; DAPHNIA MAGNA)
THRESHOLD LIMIT OTHER AQUATIC ORGANISMS 1:
6600 MG/L (16 H; PSEUDOMONAS PUTIDA)
THRESHOLD LIMIT ALGAE 1: 530 MG/L (192 H; MICROCYSTIS AERUGINOSA)
THRESHOLD LIMIT ALGAE 2: 8000 MG/L (168 H; SCENEDESMUS QUADRICAUDA)
GLYCERIN (56-81-5):
LC50 FISH: 1 64 - 72 G/L
12.2. PERSISTENCE AND DEGRADABILITY:
GIEMSA STAIN SOLUTION:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
GIEMSA STAIN (51811-82-6):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
METHANOL (67-56-1):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.6 - 1.12 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.42 G O2/G SUBSTANCE
THOD: 1.5 G O2/G SUBSTANCE
BOD (% OF THOD): 0.8% THOD
GLYCERIN (56-81-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
GIEMSA STAIN SOLUTION:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
GIEMSA STAIN (51811-82-6):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
METHANOL (67-56-1):
BCF FISH 1: <10 (LEUCISCUS IDUS)
LOG POW: -0.77 (EXPERIMENTAL VALUE; OTHER)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
GLYCERIN (56-81-5):
LOG POW: 0
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
METHANOL (67-56-1):
SURFACE TENSION: 0.023 N/M (20 DEG. C)
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON OZONE LAYER:
EFFECT ON THE GLOBAL WARMING:
NO KNOWN ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS:
AVOID RELEASE TO THE ENVIRONMENT. HAZARDOUS WASTE DUE TO TOXICITY.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN1993 FLAMMABLE LIQUIDS, N.O.S. (METHANOL), 3, III
UN-NO.(DOT): UN1993
PROPER SHIPPING NAME (DOT): FLAMMABLE LIQUIDS, N.O.S.
DEPARTMENT OF TRANSPORTATION (DOT) HAZARD CLASSES:
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
FLAMMABLE LIQUID CLASS/DIVISION 3.1, 3.2, 3.3
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
PACKING GROUP (DOT): III - MINOR DANGER
DOT SPECIAL PROVISIONS (49 CFR 172.102):
B1 - IF THE MATERIAL HAS A FLASH POINT AT OR ABOVE 38 C (100 F) AND BELOW
93 C (200 F), THEN THE BULK PACKAGING REQUIREMENTS OF 173.241 OF THIS
SUBCHAPTER ARE APPLICABLE. IF THE MATERIAL HAS A FLASH POINT OF LESS THAN
38 C (100 F), THEN THE BULK PACKAGING REQUIREMENTS OF 173.242 OF THIS
SUBCHAPTER ARE APPLICABLE.
B52 - NOTWITHSTANDING THE PROVISIONS OF 173.24B OF THIS SUBCHAPTER,
NON-RECLOSING PRESSURE RELIEF DEVICES ARE AUTHORIZED ON DOT 57 PORTABLE
TANKS.
IB3 - AUTHORIZED IBCS: METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND
31H2); COMPOSITE (31HZ1 AND 31HA2, 31HB2, 31HN2, 31HD2 AND 31HH2).
ADDITIONAL REQUIREMENT: ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR
EQUAL TO 110 KPA AT 50 C (1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT
131 F) ARE AUTHORIZED, EXCEPT FOR UN2672 (ALSO SEE SPECIAL PROVISION IP8 IN
TABLE 2 FOR UN2672).
T4 - 2.65 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
TP29 - A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 1.5 BAR (150.0
KPA) MAY BE USED PROVIDED THE CALCULATED TEST PRESSURE IS 1.5 BAR OR LESS
BASED ON THE MAWP OF THE HAZARDOUS MATERIALS, AS DEFINED IN 178.275 OF THIS
SUBCHAPTER, WHERE THE TEST PRESSURE IS 1.5 TIMES THE MAWP.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 150
DOT PACKAGING NON BULK (49 CFR 173.XXX): 203
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 60 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 220 L
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
ADR: NO ADDITIONAL INFORMATION AVAILABLE
TRANSPORT BY SEA: NO ADDITIONAL INFORMATION AVAILABLE
AIR TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
GIEMSA STAIN SOLUTION:
SARA SECTION 311/312 HAZARD CLASSES:
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
GIEMSA STAIN (51811-82-6):
SARA SECTION 311/312 HAZARD CLASSES: IMMEDIATE (ACUTE) HEALTH HAZARD
METHANOL (67-56-1):
LISTED ON UNITED STATES SARA SECTION 313
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
15.2. INTERNATIONAL REGULATIONS:
CANADA:
GIEMSA STAIN SOLUTION:
WHMIS CLASSIFICATION:
CLASS B DIVISION 3 - COMBUSTIBLE LIQUID
CLASS D DIVISION 1 SUBDIVISION B - TOXIC MATERIAL CAUSING IMMEDIATE AND
SERIOUS TOXIC EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
GIEMSA STAIN (51811-82-6):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
METHANOL (67-56-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS B DIVISION 2 - FLAMMABLE LIQUID
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
GLYCERIN (56-81-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC [DSD] OR 1999/45/EC [DPD]:
NOT CLASSIFIED
15.2.2. NATIONAL REGULATIONS:
GIEMSA STAIN (51811-82-6):
NOT LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
METHANOL (67-56-1):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
GLYCERIN (56-81-5):
NOT LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT CONTAINS, OR MAY CONTAIN, TRACE
QUANTITIES OF A SUBSTANCE(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND/OR REPRODUCTIVE TOXICITY
METHANOL (67-56-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANCE RISK LEVEL (NSRL): 23000 (MICRO)G/DAY
| SECTION 16: OTHER INFORMATION | |
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES:
SEE SECTION 16:
ACUTE TOX. 3 (DERMAL): ACUTE TOXICITY (DERMAL) CATEGORY 3
ACUTE TOX. 3 (INHALATION): ACUTE TOXICITY (INHALATION) CATEGORY 3
ACUTE TOX. 3 (ORAL): ACUTE TOXICITY (ORAL) CATEGORY 3
ACUTE TOX. 4 (INHALATION: DUST, MIST):
ACUTE TOXICITY (INHALATION: DUST, MIST) CATEGORY 4
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A
FLAM. LIQ. 2: FLAMMABLE LIQUIDS CATEGORY 2
STOT SE 1: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 1
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H301: TOXIC IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H319: CAUSES SERIOUS EYE IRRITATION
H331: TOXIC IF INHALED
H332: HARMFUL IF INHALED
H370: CAUSES DAMAGE TO ORGANS
NFPA HEALTH HAZARD 2 - INTENSE OR CONTINUED EXPOSURE COULD CAUSE TEMPORARY
INCAPACITATION OR POSSIBLE RESIDUAL INJURY UNLESS
PROMPT MEDICAL ATTENTION IS GIVEN.
NFPA FIRE HAZARD 2 - MUST BE MODERATELY HEATED OR EXPOSED TO RELATIVELY
HIGH TEMPERATURE BEFORE IGNITION CAN OCCUR.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
HMIS III RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 2 MODERATE HAZARD
PHYSICAL 0 MINIMAL HAZARD
PERSONAL PROTECTION G
SDS US (GHS HAZCOM 2012)
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)