| Common Name: | WATER HARDNESS BUFFER (WITH MAGNESIUM) |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 12/28/2016 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8XNC2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
WATER HARDNESS BUFFER (WITH MAGNESIUM)
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 11/25/2013
REVISION DATE: 12/28/2016
SUPERSEDES: 09/29/2015
VERSION: 1.2
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: WATER HARDNESS BUFFER (WITH MAGNESIUM)
PRODUCT CODE: LC26810
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
SKIN CORROSION/IRRITATION CATEGORY 1C: H314
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 2: H401
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS05: CORROSION
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H401: TOXIC TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS (GHS-US):
P260: DO NOT BREATHE MIST, GAS, VAPORS, SPRAY
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING
P273: AVOID RELEASE TO THE ENVIRONMENT
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
WATER (CAS NO) 7732-18-5 76.7 NOT CLASSIFIED
AMMONIUM HYDROXIDE, (CAS NO) 1336-21-6 16 ACUTE TOX. 4 (ORAL), H302
ACS ACUTE TOX. 4
(INHALATION:VAPOR), H332
SKIN CORR. 1C, H314
EYE DAM. 1, H318
AQUATIC ACUTE 1, H400
AMMONIUM CHLORIDE (CAS NO) 12125-02-9 6.8 ACUTE TOX. 4 (ORAL), H302
EDTA, MAGNESIUM (CAS NO) 14402-88-1 0.5 NOT CLASSIFIED
DISODIUM SALT
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ALLOW VICTIM TO BREATHE FRESH AIR. ALLOW THE VICTIM TO REST. REMOVE VICTIM
TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. IMMEDIATELY CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SYMPTOMS/INJURIES AFTER INHALATION: MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: BURNS.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE BURNS.
SYMPTOMS/INJURIES AFTER INGESTION:
BURNS OR IRRITATION OF THE LININGS OF THE MOUTH, THROAT, AND
GASTROINTESTINAL TRACT.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: TREAT SYMPTOMATICALLY.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
REACTIVITY:
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPORS.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
PROTECTIVE GOGGLES. GLOVES. COMBINED GAS/DUST MASK WITH FILTER TYPE K/P2.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. DO NOT BREATHE MIST, VAPORS,
SPRAY.
HYGIENE MEASURES:
WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES: COMPLY WITH APPLICABLE REGULATIONS.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM : INCOMPATIBLE MATERIALS, HEAT SOURCES. KEEP CONTAINER CLOSED WHEN NOT
IN USE.
INCOMPATIBLE PRODUCTS:
STRONG OXIDIZERS. STRONG ACIDS. SILVER NITRATE. ACID CHLORIDES.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
AMMONIUM CHLORIDE (12125-02-9):
ACGIH:
ACGIH TWA (MG/M3):
10 MG/M3 (AMMONIUM CHLORIDE FUME; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT
8 H; TLV - ADOPTED VALUE)
ACGIH:
ACGIH STEL (MG/M3):
20 MG/M3 (AMMONIUM CHLORIDE FUME; USA; SHORT TIME VALUE; TLV - ADOPTED
VALUE)
NIOSH:
NIOSH REL (TWA) (MG/M3): 10 MG/M3
NIOSH:
NIOSH REL (STEL) (MG/M3): 20 MG/M3
AMMONIUM HYDROXIDE, ACS (1336-21-6):
ACGIH:
ACGIH TWA (MG/M3): 17 MG/M3
ACGIH:
ACGIH STEL (MG/M3): 24 MG/M3
OSHA:
OSHA PEL (TWA) (MG/M3): 35 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 50 PPM
IDLH:
US IDLH (PPM): 300 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 18 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 25 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 27 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 35 PPM
EDTA, MAGNESIUM DISODIUM SALT (14402-88-1): NOT APPLICABLE
WATER (7732-18-5): NOT APPLICABLE
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND
LOCAL EXHAUST VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT: SAFETY GLASSES. GLOVES.
HIGH GAS/VAPOR CONCENTRATION: GAS MASK WITH FILTER TYPE K.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR FACE SHIELD.
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
GAS MASK WITH FILTER TYPE K AT CONC. IN AIR > EXPOSURE LIMIT.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 0.96 G/ML
SOLUBILITY: NO DATA AVAILABLE
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 0%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPORS.
10.2. CHEMICAL STABILITY: NOT ESTABLISHED.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS. STRONG OXIDIZERS. SILVER NITRATE. ACID CHLORIDES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
FUME. CARBON MONOXIDE. CARBON DIOXIDE.
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPORS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
AMMONIUM CHLORIDE (12125-02-9)
LD50 ORAL RAT: 1650 MG/KG (RAT; LITERATURE STUDY)
ATE US (ORAL): 1650.000 MG/KG BODY WEIGHT
AMMONIUM HYDROXIDE, ACS (1336-21-6):
LD50 ORAL RAT: 350 MG/KG
ATE US (ORAL): 350.000 MG/KG BODY WEIGHT
ATE US (VAPORS): 10.714 MG/L/4H
WATER (7732-18-5):
LD50 ORAL RAT: >/=90000 MG/KG
ATE US (ORAL): 90000.000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/INJURIES AFTER INHALATION: MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: BURNS.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE BURNS.
SYMPTOMS/INJURIES AFTER INGESTION:
BURNS OR IRRITATION OF THE LININGS OF THE MOUTH, THROAT, AND
GASTROINTESTINAL TRACT.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - WATER: TOXIC TO AQUATIC LIFE.
AMMONIUM CHLORIDE (12125-02-9):
EC50 DAPHNIA 1: 161 MG/L (EC50; 48 H)
THRESHOLD LIMIT ALGAE 2: <70 MG/L (EC50; 240 H)
AMMONIUM HYDROXIDE, ACS (1336-21-6):
LC50 FISH 1: 0.16 - 1.1 MG/L (LC50; 96 H)
EC50 DAPHNIA 1: 2.08 MG/L (LC50; 48 H)
12.2. PERSISTENCE AND DEGRADABILITY:
WATER HARDNESS BUFFER (WITH MAGNESIUM):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
AMMONIUM CHLORIDE (12125-02-9):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE IN WATER.
AMMONIUM HYDROXIDE, ACS (1336-21-6):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. OZONATION IN WATER. BIODEGRADABLE IN THE
SOIL. NO TEST DATA ON MOBILITY OF THE COMPONENTS AVAILABLE. OZONATION IN
THE AIR.
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
WATER HARDNESS BUFFER (WITH MAGNESIUM):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
AMMONIUM CHLORIDE (12125-02-9):
LOG POW: -4.37 (ESTIMATED VALUE)
BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION: NOT APPLICABLE.
AMMONIUM HYDROXIDE, ACS (1336-21-6):
LOG POW: -1.3
BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION: NOT APPLICABLE.
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN2672 AMMONIA SOLUTIONS (RELATIVE DENSITY BETWEEN 0.880 AND 0.957 AT 15
DEGREES C IN WATER, WITH MORE THAN 10 PERCENT BUT NOT MORE THAN 35 PERCENT
AMMONIA), 8, III
UN-NO.(DOT): UN2672
PROPER SHIPPING NAME (DOT): AMMONIA SOLUTIONS
RELATIVE DENSITY BETWEEN 0.880 AND 0.957 AT 15 DEGREES C IN WATER, WITH
MORE THAN 10 PERCENT BUT NOT MORE THAN 35 PERCENT AMMONIA
TRANSPORT HAZARD CLASS(ES) (DOT):
8 - CLASS 8 - CORROSIVE MATERIAL 49 CFR 173.136
PACKING GROUP (DOT): III - MINOR DANGER
HAZARD LABELS (DOT): 8 - CORROSIVE
DOT PACKAGING NON BULK (49 CFR 173.XXX): 203
DOT PACKAGING BULK (49 CFR 173.XXX): 241
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB3 - AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE (31HZ1
AND 31HA2, 31HB2, 31HN2, 31HD2 AND 31HH2).
ADDITIONAL REQUIREMENT:
ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C
(1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED,
EXCEPT FOR UN2672 (ALSO SEE SPECIAL PROVISION IP8 IN TABLE 2 FOR UN2672).
IP8:
AMMONIA SOLUTIONS MAY BE TRANSPORTED IN RIGID OR COMPOSITE PLASTIC IBCS
(31H1, 31H2 AND 31HZ1) THAT HAVE SUCCESSFULLY PASSED, WITHOUT LEAKAGE OR
PERMANENT DEFORMATION, THE HYDROSTATIC TEST SPECIFIED IN 178.814 OF THIS
SUBCHAPTER AT A TEST PRESSURE THAT IS NOT LESS THAN 1.5 TIMES THE VAPOR
PRESSURE OF THE CONTENTS AT 55 C (131 F).
T7: 4 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1:
THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 154
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
A:
THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL AND
ON A PASSENGER VESSEL.
DOT VESSEL STOWAGE OTHER:
40 - STOW "CLEAR OF LIVING QUARTERS", 52 - STOW "SEPARATED FROM" ACIDS, 85
- UNDER DECK STOWAGE MUST BE IN MECHANICALLY VENTILATED SPACE
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
WATER HARDNESS BUFFER (WITH MAGNESIUM):
SARA SECTION 311/312 HAZARD CLASSES: IMMEDIATE (ACUTE) HEALTH HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
AMMONIUM HYDROXIDE, ACS CAS NO 1336-21-6 16%
AMMONIUM CHLORIDE (12125-02-9):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
AMMONIUM HYDROXIDE, ACS (1336-21-6):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 1000 LB
15.2. INTERNATIONAL REGULATIONS:
CANADA:
WATER HARDNESS BUFFER (WITH MAGNESIUM):
WHMIS CLASSIFICATION: CLASS E - CORROSIVE MATERIAL
AMMONIUM CHLORIDE (12125-02-9):
WHMIS CLASSIFICATION:
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
AMMONIUM HYDROXIDE, ACS (1336-21-6):
WHMIS CLASSIFICATION: CLASS E - CORROSIVE MATERIAL
WATER (7732-18-5):
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 12/28/2016
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16:
H302: HARMFUL IF SWALLOWED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H318: CAUSES SERIOUS EYE DAMAGE
H332: HARMFUL IF INHALED
H400: VERY TOXIC TO AQUATIC LIFE
H401: TOXIC TO AQUATIC LIFE
NFPA HEALTH HAZARD 3 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SERIOUS OR PERMANENT INJURY.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN UNDER TYPICAL DIRE
CONDITIONS, INCLUDING INTRINSICALLY NONCOMBUSTIBLE
MATERIALS SUCH AS CONCRETE, STONE, AND SAND.
NFPA REACTIVITY 1 - MATERIALS THAT IN THEMSELVES ARE NORMALLY STABLE BUT
CAN BECOME UNSTABLE AT ELEVATED TEMPERATURES AND
PRESSURES.
HMIS III RATING:
HEALTH 3 SERIOUS HAZARD - MAJOR INJURY LIKELY UNLESS PROMPT
ACTION IS TAKEN AND MEDICAL TREATMENT IS GIVEN
FLAMMABILITY 0 MINIMAL HAZARD - MATERIALS THAT WILL NOT BURN
PHYSICAL 1 SLIGHT HAZARD - MATERIALS THAT ARE NORMALLY STABLE
BUT CAN BECOME UNSTABLE (SELF-REACT) AT HIGH
TEMPERATURES AND PRESSURES. MATERIALS MAY REACT
NON-VIOLENTLY WITH WATER OR UNDERGO HAZARDOUS
POLYMERIZATION IN THE ABSENCE OF INHIBITORS.
PERSONAL PROTECTION G
G - SAFETY GLASSES, GLOVES, VAPOR RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
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