| Common Name: | COPPER SULFATE-HYDROCHLORIC ACID |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 5/3/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 9AP29 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
COPPER SULFATE-HYDROCHLORIC ACID
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 11/24/2014
REVISION DATE: 05/03/2017
SUPERSEDES: 11/24/2014
VERSION: 1.1
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: COPPER SULFATE-HYDROCHLORIC ACID
PRODUCT CODE: LC13450
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000, 1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
ACUTE TOXICITY (ORAL) CATEGORY 4:
H302: HARMFUL IF SWALLOWED
SKIN CORROSION/IRRITATION CATEGORY 1B:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 2:
H401: TOXIC TO AQUATIC LIFE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 2:
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
FULL TEXT OF H STATEMENTS : SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS05: CORROSION
GHS07: EXCLAMATION MARK
GHS09: ENVIRONMENT
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H302: HARMFUL IF SWALLOWED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS (GHS-US):
P260: DO NOT BREATHE MIST, VAPORS, SPRAY
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
P273: AVOID RELEASE TO THE ENVIRONMENT
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE
P391: COLLECT SPILLAGE
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
WATER (CAS NO) 7732-18-5 77.4 NOT CLASSIFIED
COPPER (II) SULFATE, (CAS NO) 7758-99-8 17.8 ACUTE TOX. 3 (ORAL), H301
PENTAHYDRATE AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
HYDROCHLORIC ACID, (CAS NO) 7647-01-0 4.8 ACUTE TOX. 4 (ORAL), H302
37% W/W SKIN CORR. 1B, H314
EYE DAM. 1, H318
STOT SE 3, H335
AQUATIC ACUTE 3, H402
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/INJURIES: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/INJURIES AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS
HEALTH HAZARD.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
TREAT SYMPTOMATICALLY. OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
REACTIVITY:
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPORS.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
SAFETY GLASSES. GLOVES. PROTECTIVE CLOTHING. FACE-SHIELD.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. DO NOT BREATHE MIST, VAPORS,
SPRAY.
HYGIENE MEASURES:
WASH CONTAMINATED CLOTHING BEFORE REUSE. DO NOT EAT, DRINK OR SMOKE WHEN
USING THIS PRODUCT. WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES: COMPLY WITH APPLICABLE REGULATIONS.
STORAGE CONDITIONS: KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: STRONG REDUCING AGENTS. STRONG BASES. STRONG ACIDS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8): NOT APPLICABLE
WATER (7732-18-5): NOT APPLICABLE
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
ACGIH:
ACGIH CEILING (MG/M3): 2.98 MG/M3
ACGIH:
ACGIH CEILING (PPM): 2 PPM
OSHA:
OSHA PEL (CEILING) (MG/M3): 7 MG/M3
OSHA:
OSHA PEL (CEILING) (PPM): 5 PPM
IDLH:
US IDLH (PPM): 50 PPM
NIOSH:
NIOSH REL (CEILING) (MG/M3): 7 MG/M3
NIOSH:
NIOSH REL (CEILING) (PPM): 5 PPM
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST
VENTILATION.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
FACE SHIELD. GLOVES. SAFETY GLASSES. PROTECTIVE CLOTHING.
HAND PROTECTION: WEAR PROTECTIVE GLOVES
EYE PROTECTION: CHEMICAL GOGGLES OR FACE SHIELD
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NOT REQUIRED IN NORMAL CONDITIONS
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: BLUE
ODOR: NONE.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C : NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 1.1 G/ML
SOLUBILITY: SOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE.
OXIDIZING PROPERTIES: NO DATA AVAILABLE.
9.2. OTHER INFORMATION:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPORS.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS: STRONG REDUCING AGENTS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SULFUR COMPOUNDS. COPPER. HYDROGEN CHLORIDE.
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPORS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: SKIN AND EYE CONTACT
ACUTE TOXICITY:
ORAL: HARMFUL IF SWALLOWED.
COPPER SULFATE-HYDROCHLORIC ACID:
ATE US (ORAL): 1510.791 MG/KG BODY WEIGHT
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
LD50 ORAL RAT:
300 MG/KG (RAT; OECD 401: ACUTE ORAL TOXICITY; EXPERIMENTAL VALUE;
482 MG/KG BODYWEIGHT; RAT)
LD50 DERMAL RABBIT:
>2000 MG/KG (RABBIT; LITERATURE STUDY; OECD 402: ACUTE DERMAL TOXICITY)
ATE US (ORAL): 300.000 MG/KG BODY WEIGHT
WATER (7732-18-5):
LD50 ORAL RAT: >/= 90000 MG/KG
ATE US (ORAL): 90000.000 MG/KG BODY WEIGHT
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LD50 ORAL RAT: 700 MG/KG
LD50 DERMAL RABBIT: 5010 MG/KG
ATE US (ORAL): 700.000 MG/KG BODY WEIGHT
ATE US (DERMAL): 5010.000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. HARMFUL
IF SWALLOWED.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/INJURIES AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - WATER:
TOXIC TO AQUATIC LIFE. TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
THRESHOLD LIMIT ALGAE 2:
0.368 MG/L (ERC50; OECD 201: ALGA, GROWTH INHIBITION TEST; 72 H;
PSEUDOKIRCHNERIELLA SUBCAPITATA; STATIC SYSTEM; FRESH WATER; READ-ACROSS)
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LC50 FISH 1: 282 MG/L (LC50; 96 H)
EC50 DAPHNIA 1: <56 MG/L (EC50; 72 H)
12.2. PERSISTENCE AND DEGRADABILITY:
COPPER SULFATE-HYDROCHLORIC ACID:
PERSISTENCE AND DEGRADABILITY:
NOT READILY BIODEGRADABLE. MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
ENVIRONMENT.
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY:
NOT APPLICABLE. NO TEST DATA ON MOBILITY OF THE COMPONENTS AVAILABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
12.3. BIOACCUMULATIVE POTENTIAL:
COPPER SULFATE-HYDROCHLORIC ACID:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
BIOACCUMULATIVE POTENTIAL: BIOACCUMABLE. NOT ESTABLISHED.
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LOG POW: 0.25 (QSAR)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
12.4. MOBILITY IN SOIL:
COPPER SULFATE-HYDROCHLORIC ACID:
ECOLOGY - SOIL:
MAY BE HARMFUL TO PLANT GROWTH, BLOOMING AND FRUIT FORMATION.
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
ECOLOGY - SOIL: TOXIC TO FLORA.
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
ECOLOGY - SOIL:
MAY BE HARMFUL TO PLANT GROWTH, BLOOMING AND FRUIT FORMATION.
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1789 HYDROCHLORIC ACID, 8, II
UN-NO.(DOT): UN1789
PROPER SHIPPING NAME (DOT): HYDROCHLORIC ACID
TRANSPORT HAZARD CLASS(ES) (DOT):
8 - CLASS 8 - CORROSIVE MATERIAL 49 CFR 173.136
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 8 - CORROSIVE
DANGEROUS FOR THE ENVIRONMENT: YES
MARINE POLLUTANT: YES
ENVIRONMENT
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SPECIAL PROVISIONS (49 CFR 172.102):
A3 - FOR COMBINATION PACKAGING, IF GLASS INNER PACKAGING (INCLUDING
AMPOULES) ARE USED, THEY MUST BE PACKED WITH ABSORBENT MATERIAL IN
TIGHTLY CLOSED METAL RECEPTACLES BEFORE PACKING IN OUTER PACKAGING.
A6 - FOR COMBINATION PACKAGING, IF PLASTIC INNER PACKAGING ARE USED,
THEY MUST BE PACKED IN TIGHTLY CLOSED METAL RECEPTACLES BEFORE PACKING
IN OUTER PACKAGING.
B3 - MC 300, MC 301, MC 302, MC 303, MC 305, AND MC 306 AND DOT 406 CARGO
TANKS AND DOT 57 PORTABLE TANKS ARE NOT AUTHORIZED.
B15 - PACKAGING MUST BE PROTECTED WITH NON-METALLIC LININGS IMPERVIOUS TO
THE LADING OR HAVE A SUITABLE CORROSION ALLOWANCE.
IB2 - AUTHORIZED IBCS: METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND
31H2); COMPOSITE (31HZ1). ADDITIONAL REQUIREMENT: ONLY LIQUIDS WITH A
VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C (1.1 BAR AT 122 F),
OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED.
N41 - METAL CONSTRUCTION MATERIALS ARE NOT AUTHORIZED FOR ANY PART OF A
ACKAGING WHICH IS NORMALLY IN CONTACT WITH THE HAZARDOUS MATERIAL.
T8 - 4 178.274(D)(2) NORMAL............. PROHIBITED
TP2 - A. THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF
FILLING DETERMINED BY THE FOLLOWING: (IMAGE) WHERE: TR IS THE MAXIMUM MEAN
BULK TEMPERATURE DURING TRANSPORT, TF IS THE TEMPERATURE IN DEGREES
CELSIUS OF THE LIQUID DURING FILLING, AND A IS THE MEAN COEFFICIENT OF
CUBICAL EXPANSION OF THE LIQUID BETWEEN THE MEAN TEMPERATURE OF THE LIQUID
DURING FILLING (TF) AND THE MAXIMUM MEAN BULK TEMPERATURE DURING
TRANSPORTATION (TR) BOTH IN DEGREES CELSIUS. B. FOR LIQUIDS TRANSPORTED
UNDER AMBIENT CONDITIONS MAY BE CALCULATED USING THE FORMULA: (IMAGE)
WHERE: D15 AND D50 ARE THE DENSITIES (IN UNITS OF MASS PER UNIT VOLUME) OF
THE LIQUID AT 15 C (59 F) AND 50 C (122 F), RESPECTIVELY.
TP12 - THIS MATERIAL IS CONSIDERED HIGHLY CORROSIVE TO STEEL.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 154
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 1 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 30 L
DOT VESSEL STOWAGE LOCATION:
C - THE MATERIAL MUST BE STOWED "ON DECK ONLY" ON A CARGO VESSEL AND ON
A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
COPPER SULFATE-HYDROCHLORIC ACID:
SARA SECTION 311/312 HAZARD CLASSES: IMMEDIATE (ACUTE) HEALTH HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON
THE UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL
ACT (TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
COPPER (II) SULFATE, PENTAHYDRATE CAS NO 7758-99-8 17.8%
HYDROCHLORIC ACID, 37% W/W CAS NO 7647-01-0 4.8%
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 10 LB
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
EPA TSCA REGULATORY FLAG:
T - T - INDICATES A SUBSTANCE THAT IS THE SUBJECT OF A SECTION 4 TEST
RULE UNDER TSCA.
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ): 500 LB
SARA SECTION 311/312 HAZARD CLASSES: IMMEDIATE (ACUTE) HEALTH HAZARD
15.2. INTERNATIONAL REGULATIONS:
CANADA:
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
COPPER (II) SULFATE, PENTAHYDRATE (7758-99-8):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR
REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 05/03/2017
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16
H301: TOXIC IF SWALLOWED
H302: HARMFUL IF SWALLOWED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H318: CAUSES SERIOUS EYE DAMAGE
H335: MAY CAUSE RESPIRATORY IRRITATION
H400: VERY TOXIC TO AQUATIC LIFE
H401: TOXIC TO AQUATIC LIFE
H402: HARMFUL TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
NFPA HEALTH HAZARD 3 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SERIOUS OR PERMANENT INJURY.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN UNDER TYPICAL DIRE
CONDITIONS, INCLUDING INTRINSICALLY NONCOMBUSTIBLE
MATERIALS SUCH AS CONCRETE, STONE, AND SAND.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HMIS III RATING:
HEALTH 3 SERIOUS HAZARD - MAJOR INJURY LIKELY UNLESS PROMPT
ACTION IS TAKEN AND MEDICAL TREATMENT IS GIVEN
FLAMMABILITY 0 MINIMAL HAZARD - MATERIALS THAT WILL NOT BURN
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION B
B - SAFETY GLASSES, GLOVES
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS
BELIEVED TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND
LABCHEM INC ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS
SDS. THE USER MUST DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS
APPLICATION.
EN (ENGLISH US)