| Common Name: | POTASSIUM PERMANGANATE |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 2/13/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 9AR48 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
POTASSIUM PERMANGANATE
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 02/04/2014
REVISION DATE: 02/13/2018
SUPERSEDES: 02/13/2018
VERSION: 1.1
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: SUBSTANCE
SUBSTANCE NAME: POTASSIUM PERMANGANATE
CAS-NO.: 7722-64-7
PRODUCT CODE: LC19850
FORMULA: KMNO4
SYNONYMS: PERMANGANATE OF POTASH / POTASSIUM SALT PERMANGANIC ACID
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE:
OXIDANT
BLEACHING AGENT
REAGENT
DISINFECTANT
DEODORIZER
ALGICIDE
DYESTUFF/PIGMENT: COMPONENT
MEDICINE
LABORATORY CHEMICAL
FOOD INDUSTRY: ADDITIVE
INSECTICIDE
GERMICIDE
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
OXIDIZING SOLIDS CATEGORY 2:
H272: MAY INTENSIFY FIRE; OXIDIZER
ACUTE TOXICITY (ORAL) CATEGORY 4:
H302: HARMFUL IF SWALLOWED
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1:
H400: VERY TOXIC TO AQUATIC LIFE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 1:
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS03: FLAME OVER CIRCLE
GHS07: EXCLAMATION MARK
GHS09: ENVIRONMENT
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H272: MAY INTENSIFY FIRE; OXIDIZER
H302: HARMFUL IF SWALLOWED
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS (GHS-US):
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING.
P220: KEEP/STORE AWAY FROM CLOTHING, COMBUSTIBLE MATERIALS
P221: TAKE ANY PRECAUTION TO AVOID MIXING WITH COMBUSTIBLES
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P330: IF SWALLOWED, RINSE MOUTH
P391: COLLECT SPILLAGE.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES:
SUBSTANCE TYPE: MONO-CONSTITUENT
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
POTASSIUM PERMANGANATE (CAS-NO.) 7722-64-7 100 OX. SOL. 2, H272
(MAIN CONSTITUENT) ACUTE TOX. 4 (ORAL), H302
AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
3.2. MIXTURES: NOT APPLICABLE
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
CHECK THE VITAL FUNCTIONS. UNCONSCIOUS: MAINTAIN ADEQUATE AIRWAY AND
RESPIRATION.
RESPIRATORY ARREST: ARTIFICIAL RESPIRATION OR OXYGEN.
CARDIAC ARREST: PERFORM RESUSCITATION.
VICTIM CONSCIOUS WITH LABORED BREATHING: HALF-SEATED.
VICTIM IN SHOCK: ON HIS BACK WITH LEGS SLIGHTLY RAISED.
VOMITING:
PREVENT ASPHYXIA/ASPIRATION PNEUMONIA. PREVENT COOLING BY COVERING THE
VICTIM (NO WARMING UP). KEEP WATCHING THE VICTIM. GIVE PSYCHOLOGICAL AID.
KEEP THE VICTIM CALM, AVOID PHYSICAL STRAIN.
DEPENDING ON THE VICTIM'S CONDITION: DOCTOR/HOSPITAL.
FIRST-AID MEASURES AFTER INHALATION: REMOVE THE VICTIM INTO FRESH AIR.
RESPIRATORY PROBLEMS: CONSULT A DOCTOR/MEDICAL SERVICE.
FIRST-AID MEASURES AFTER SKIN CONTACT:
WASH IMMEDIATELY WITH LOTS OF WATER (15 MINUTES)/SHOWER. DO NOT APPLY
(CHEMICAL) NEUTRALIZING AGENTS. REMOVE CLOTHING WHILE WASHING. DO NOT
REMOVE CLOTHING IF IT STICKS TO THE SKIN. COVER WOUNDS WITH STERILE
BANDAGE. CONSULT A DOCTOR/MEDICAL SERVICE.
IF BURNED SURFACE >10%: TAKE VICTIM TO HOSPITAL.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER FOR 15 MINUTES. DO NOT APPLY
NEUTRALIZING AGENTS. TAKE VICTIM TO AN OPHTHALMOLOGIST.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH WITH WATER. IMMEDIATELY AFTER INGESTION: GIVE LOTS OF WATER TO
DRINK. DO NOT INDUCE VOMITING. IMMEDIATELY CONSULT A DOCTOR/MEDICAL
SERVICE. CALL POISON INFORMATION CENTRE (WWW.BIG.BE/ANTIGIF.HTM). TAKE THE
CONTAINER/VOMIT TO THE DOCTOR/HOSPITAL.
INGESTION OF LARGE QUANTITIES: IMMEDIATELY TO HOSPITAL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS AFTER INHALATION:
AFTER INHALATION OF DUST:
DRY/SORE THROAT. COUGHING. IRRITATION OF THE RESPIRATORY TRACT. IRRITATION
OF THE NASAL MUCOUS MEMBRANES.
EXPOSURE TO HIGH CONCENTRATIONS: RESPIRATORY DIFFICULTIES.
FOLLOWING SYMPTOMS MAY APPEAR LATER: RISK OF LUNG EDEMA.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
TINGLING/IRRITATION OF THE SKIN. MAY STAIN THE SKIN.
ON CONTINUOUS EXPOSURE/CONTACT: CAUSTIC BURNS/CORROSION OF THE SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
CORROSION OF THE EYE TISSUE. INFLAMMATION/DAMAGE OF THE EYE TISSUE.
ON CONTINUOUS EXPOSURE/CONTACT: PERMANENT EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
NAUSEA. VOMITING. DIARRHOEA. IRRITATION OF THE GASTRIC/INTESTINAL MUCOSA.
AFTER ABSORPTION OF LARGE QUANTITIES:
POSSIBLE ESOPHAGEAL PERFORATION. SHOCK. SLOWING HEART ACTION. LOW ARTERIAL
PRESSURE. POSSIBLE LARYNGEAL SPASM/OEDEMA. RESPIRATORY DIFFICULTIES.
CHRONIC SYMPTOMS:
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
RESPIRATORY DIFFICULTIES. IMPAIRMENT OF THE NERVOUS SYSTEM. MOVEMENT
DISTURBANCES. COORDINATION DISORDERS. MYASTHENIA. TREMOR. PARALYSIS.
CRAMPS/UNCONTROLLED MUSCULAR CONTRACTIONS. IMPAIRED MEMORY. EMOTIONAL
INSTABILITY.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA: ADAPT EXTINGUISHING MEDIA TO THE ENVIRONMENT.
PREFERABLY: QUANTITIES OF WATER.
UNSUITABLE EXTINGUISHING MEDIA: NO UNSUITABLE EXTINGUISHING MEDIA KNOWN.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD:
DIRECT FIRE HAZARD. NON COMBUSTIBLE. INDIRECT FIRE HAZARD. PROMOTES
COMBUSTION.
REACTIONS INVOLVING A FIRE HAZARD: SEE "REACTIVITY HAZARD".
EXPLOSION HAZARD: INDIRECT EXPLOSION HAZARD.
REACTIONS WITH EXPLOSION HAZARDS: SEE "REACTIVITY HAZARD".
REACTIVITY:
DECOMPOSES ON EXPOSURE TO TEMPERATURE RISE:
OXIDATION WHICH INCREASES FIRE HAZARD.
REACTS WITH COMBUSTIBLE MATERIALS: RISK OF SPONTANEOUS IGNITION.
VIOLENT TO EXPLOSIVE REACTION WITH (SOME) ACIDS:
RELEASE OF TOXIC AND CORROSIVE GASES/VAPORS.
REACTS VIOLENTLY WITH MANY COMPOUNDS E.G.:
WITH ORGANIC MATERIAL AND WITH (STRONG) REDUCERS. WITH (SOME) METALS. WITH
(INCREASED) RISK OF FIRE/EXPLOSION.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
PRECAUTIONARY MEASURES FIRE:
EXPOSURE TO FIRE/HEAT: KEEP UPWIND.
EXPOSURE TO FIRE/HEAT: CONSIDER EVACUATION.
FIREFIGHTING INSTRUCTIONS:
COOL TANKS/DRUMS WITH WATER SPRAY/REMOVE THEM INTO SAFETY. DO NOT MOVE THE
LOAD IF EXPOSED TO HEAT. TAKE ACCOUNT OF ENVIRONMENTALLY HAZARDOUS
FIREFIGHTING WATER. USE WATER MODERATELY AND IF POSSIBLE COLLECT OR CONTAIN
IT.
PROTECTION DURING FIREFIGHTING:
HEAT/FIRE EXPOSURE: COMPRESSED AIR/OXYGEN APPARATUS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: GLOVES. FACE-SHIELD. PROTECTIVE CLOTHING.
DUST CLOUD PRODUCTION: COMPRESSED AIR/OXYGEN APPARATUS.
DUST CLOUD PRODUCTION: DUST-TIGHT SUIT.
REACTIVITY HAZARD: COMPRESSED AIR/OXYGEN APPARATUS.
REACTIVITY HAZARD:
GAS-TIGHT SUIT. SEE "MATERIAL-HANDLING" TO SELECT PROTECTIVE CLOTHING.
EMERGENCY PROCEDURES:
MARK THE DANGER AREA. PREVENT DUST CLOUD FORMATION. NO NAKED FLAMES. KEEP
CONTAINERS CLOSED. WASH CONTAMINATED CLOTHES.
IN CASE OF HAZARDOUS REACTIONS: KEEP UPWIND.
IN CASE OF REACTIVITY HAZARD: CONSIDER EVACUATION.
MEASURES IN CASE OF DUST RELEASE:
IN CASE OF DUST PRODUCTION: KEEP UPWIND.
DUST PRODUCTION: HAVE NEIGHBORHOOD CLOSE DOORS AND WINDOWS.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. DO NOT BREATHE DUST.
EMERGENCY PROCEDURES:
IF A MAJOR SPILL OCCURS, ALL PERSONNEL SHOULD BE IMMEDIATELY EVACUATED AND
THE AREA VENTILATED. STOP RELEASE. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT SOIL AND WATER POLLUTION. PREVENT SPREADING IN SEWERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. CONSULT
"MATERIAL-HANDLING" TO SELECT MATERIAL OF CONTAINERS. PLUG THE LEAK, CUT
OFF THE SUPPLY. DAM UP THE SOLID SPILL. KNOCK DOWN/DILUTE DUST CLOUD WITH
WATER SPRAY.
IF REACTING:
DILUTE TOXIC GAS/VAPOUR WITH WATER SPRAY. TAKE ACCOUNT OF TOXIC/CORROSIVE
PRECIPITATION WATER.
METHODS FOR CLEANING UP:
STOP DUST CLOUD BY COVERING WITH SAND/EARTH. SCOOP SOLID SPILL INTO CLOSING
CONTAINERS. CAREFULLY COLLECT THE SPILL/LEFTOVERS. SPILL MUST NOT RETURN IN
ITS ORIGINAL CONTAINER. SEE "MATERIAL-HANDLING" FOR SUITABLE CONTAINER
MATERIALS. CLEAN CONTAMINATED SURFACES WITH AN EXCESS OF WATER. WASH
CLOTHING AND EQUIPMENT AFTER HANDLING.
6.4. REFERENCE TO OTHER SECTIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
COMPLY WITH THE LEGAL REQUIREMENTS. REMOVE CONTAMINATED CLOTHING
IMMEDIATELY. CLEAN CONTAMINATED CLOTHING. KEEP THE SUBSTANCE FREE FROM
CONTAMINATION. USE CORROSION PROOF EQUIPMENT. THOROUGHLY CLEAN/DRY THE
INSTALLATION BEFORE USE. DO NOT DISCHARGE THE WASTE INTO THE DRAIN. AVOID
RAISING DUST. KEEP AWAY FROM NAKED FLAMES/HEAT. OBSERVE VERY STRICT HYGIENE
- AVOID CONTACT. KEEP CONTAINER TIGHTLY CLOSED. MEASURE THE CONCENTRATION
IN THE AIR REGULARLY. CARRY OPERATIONS IN THE OPEN/UNDER LOCAL
EXHAUST/VENTILATION OR WITH RESPIRATORY PROTECTION.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
HEAT-IGNITION: KEEP SUBSTANCE
AWAY FROM: HEAT SOURCES.
PROHIBITIONS ON MIXED STORAGE:
KEEP SUBSTANCE AWAY FROM:
COMBUSTIBLE MATERIALS. REDUCING AGENTS. STRONG ACIDS. METAL POWDERS.
CELLULOSIC MATERIALS. ORGANIC MATERIALS. ALCOHOLS. PEROXIDES.
STORAGE AREA:
STORE AT AMBIENT TEMPERATURE. KEEP OUT OF DIRECT SUNLIGHT. STORE IN A DRY
AREA. FIREPROOF STOREROOM. UNAUTHORIZED PERSONS ARE NOT ADMITTED. KEEP ONLY
IN THE ORIGINAL CONTAINER. STORE ONLY IN A LIMITED QUANTITY. MEET THE LEGAL
REQUIREMENTS.
SPECIAL RULES ON PACKAGING:
SPECIAL REQUIREMENTS:
CLOSING. CLEAN. CORRECTLY LABELED. MEET THE LEGAL REQUIREMENTS. SECURE
FRAGILE PACKAGINGS IN SOLID CONTAINERS.
PACKAGING MATERIALS:
SUITABLE MATERIAL: STEEL. ALUMINIUM. GLASS. STONEWARE/PORCELAIN.
MATERIAL TO AVOID: WOOD. CELLULOSIC MATERIAL.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
POTASSIUM PERMANGANATE (7722-64-7):
ACGIH:
ACGIH TWA (MG/M3):
0.1 MG/M3 (MANGANESE, INORGANIC COMPOUNDS, AS Mn; USA; TIME-WEIGHTED
AVERAGE EXPOSURE LIMIT 8 H; TLV - ADOPTED VALUE; INHALABLE FRACTION)
OSHA:
OSHA PEL (CEILING) (MG/M3): 5 MG/M3 AS Mn
IDLH:
US IDLH (MG/M3): 500 MG/M3 AS Mn
NIOSH:
NIOSH REL (TWA) (MG/M3): 1 MG/M3 AS Mn
NIOSH:
NIOSH REL (CEILING) (MG/M3): 3 MG/M3 AS Mn
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT: GLOVES. SAFETY GLASSES.
DUST PRODUCTION: DUST MASK WITH FILTER TYPE P3.
MATERIALS FOR PROTECTIVE CLOTHING:
GIVE EXCELLENT RESISTANCE: POLYETHYLENE.
GIVE GOOD RESISTANCE: BUTYL RUBBER. PVC. POLYETHYLENE/ETHYLENEVINYLALCOHOL
HAND PROTECTION: GLOVES
EYE PROTECTION: FACE SHIELD.
IN CASE OF DUST PRODUCTION: PROTECTIVE GOGGLES
SKIN AND BODY PROTECTION: PROTECTIVE CLOTHING.
IN CASE OF DUST PRODUCTION: HEAD/NECK PROTECTION.
IN CASE OF DUST PRODUCTION: DUSTPROOF CLOTHING
RESPIRATORY PROTECTION:
DUST PRODUCTION: DUST MASK WITH FILTER TYPE P3.
HIGH DUST PRODUCTION: SELF-CONTAINED BREATHING APPARATUS
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
APPEARANCE: CRYSTALLINE SOLID. CRYSTALLINE POWDER.
COLOR: DARK VIOLET-BROWN
ODOR: ODORLESS
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 7.0 - 8.5 (1.6 %)
PH SOLUTION: 1.6 %
MELTING POINT: >240 DEG. C
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: NOT APPLICABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: <0.1 HPA (20 DEG. C)
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: 2.7
SPECIFIC GRAVITY / DENSITY: 2700 KG/M3
MOLECULAR MASS: 158.03 G/MOL
SOLUBILITY:
MODERATELY SOLUBLE IN WATER. SUBSTANCE SINKS IN WATER. SOLUBLE IN ETHANOL.
SOLUBLE IN METHANOL. SOLUBLE IN ACETONE. SOLUBLE IN ACETIC ACID. SOLUBLE IN
SULFURIC ACID. SOLUBLE IN PYRIDINE.
WATER: 6.4 G/100 ML
LOG POW: -1.73 (ESTIMATED VALUE)
AUTO-IGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: >240 DEG. C
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: MAY INTENSIFY FIRE; OXIDIZER.
9.2. OTHER INFORMATION:
MINIMUM IGNITION ENERGY: NOT APPLICABLE
SADT: NOT APPLICABLE
VOC CONTENT: NOT APPLICABLE
OTHER PROPERTIES: OPAQUE. SUBSTANCE HAS BASIC REACTION.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
DECOMPOSES ON EXPOSURE TO TEMPERATURE RISE:
OXIDATION WHICH INCREASES FIRE HAZARD.
REACTS WITH COMBUSTIBLE MATERIALS: RISK OF SPONTANEOUS IGNITION.
VIOLENT TO EXPLOSIVE REACTION WITH (SOME) ACIDS:
RELEASE OF TOXIC AND CORROSIVE GASES/VAPORS.
REACTS VIOLENTLY WITH MANY COMPOUNDS E.G.:
WITH ORGANIC MATERIAL AND WITH (STRONG) REDUCERS. WITH (SOME) METALS. WITH
(INCREASED) RISK OF FIRE/EXPLOSION.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS EXOTHERMICALLY WITH COMBUSTIBLE MATERIALS: (INCREASED) RISK OF FIRE.
10.4. CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS.
10.5. INCOMPATIBLE MATERIALS:
STRONG REDUCING AGENTS. ORGANIC COMPOUNDS. COMBUSTIBLE MATERIALS. METALS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: MANGANESE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: SKIN AND EYE CONTACT; INHALATION
ACUTE TOXICITY:
ORAL: HARMFUL IF SWALLOWED.
POTASSIUM PERMANGANATE (7722-64-7):
LD50 ORAL RAT: 1090 MG/KG (RAT)
ATE US (ORAL): 1090 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: 7.0 - 8.5 (1.6 %)
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: 7.0 - 8.5 (1.6 %)
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/EFFECTS AFTER INHALATION:
AFTER INHALATION OF DUST: DRY/SORE THROAT. COUGHING.
IRRITATION OF THE RESPIRATORY TRACT. IRRITATION OF THE NASAL MUCOUS
MEMBRANES.
EXPOSURE TO HIGH CONCENTRATIONS: RESPIRATORY DIFFICULTIES.
FOLLOWING SYMPTOMS MAY APPEAR LATER: RISK OF LUNG EDEMA.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
TINGLING/IRRITATION OF THE SKIN. MAY STAIN THE SKIN.
ON CONTINUOUS EXPOSURE/CONTACT: CAUSTIC BURNS/CORROSION OF THE SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
CORROSION OF THE EYE TISSUE. INFLAMMATION/DAMAGE OF THE EYE TISSUE.
ON CONTINUOUS EXPOSURE/CONTACT: PERMANENT EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
NAUSEA. VOMITING. DIARRHOEA. IRRITATION OF THE GASTRIC/INTESTINAL MUCOSA.
AFTER ABSORPTION OF LARGE QUANTITIES:
POSSIBLE ESOPHAGEAL PERFORATION. SHOCK. SLOWING HEART ACTION. LOW ARTERIAL
PRESSURE. POSSIBLE LARYNGEAL SPASM/OEDEMA. RESPIRATORY DIFFICULTIES.
CHRONIC SYMPTOMS:
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
RESPIRATORY DIFFICULTIES. IMPAIRMENT OF THE NERVOUS SYSTEM. MOVEMENT
DISTURBANCES. COORDINATION DISORDERS. MYASTHENIA. TREMOR. PARALYSIS.
CRAMPS/UNCONTROLLED MUSCULAR CONTRACTIONS. IMPAIRED MEMORY. EMOTIONAL
INSTABILITY.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL: DANGEROUS FOR THE ENVIRONMENT.
ECOLOGY - AIR:
NOT CLASSIFIED AS DANGEROUS FOR THE OZONE LAYER (REGULATION (EC) NO
1005/2009). TA-LUFT KLASSE 5.2.2/III.
ECOLOGY - WATER:
SEVERE WATER POLLUTANT (SURFACE WATER). GROUND WATER POLLUTANT. TOXIC TO
FISHES. VERY TOXIC TO INVERTEBRATES (DAPHNIA).
POTASSIUM PERMANGANATE (7722-64-7):
EC50 DAPHNIA: 1 0.235 MG/L (EC50; 24 H)
LC50 FISH 2: 1.22 MG/L (LC50; 96 H)
THRESHOLD LIMIT ALGAE 1: 10 MG/L (EC50; 4 H)
12.2. PERSISTENCE AND DEGRADABILITY:
POTASSIUM PERMANGANATE (7722-64-7):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY: NOT APPLICABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
POTASSIUM PERMANGANATE (7722-64-7):
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
12.3. BIOACCUMULATIVE POTENTIAL:
POTASSIUM PERMANGANATE (7722-64-7):
LOG POW: -1.73 (ESTIMATED VALUE)
BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION: NOT APPLICABLE.
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
REMOVE WASTE IN ACCORDANCE WITH LOCAL AND/OR NATIONAL REGULATIONS.
HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER WITH OTHER WASTE. DIFFERENT
TYPES OF HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER IF THIS MAY ENTAIL A
RISK OF POLLUTION OR CREATE PROBLEMS FOR THE FURTHER MANAGEMENT OF THE
WASTE. HAZARDOUS WASTE SHALL BE MANAGED RESPONSIBLY. ALL ENTITIES THAT
STORE, TRANSPORT OR HANDLE HAZARDOUS WASTE SHALL TAKE THE NECESSARY
MEASURES TO PREVENT RISKS OF POLLUTION OR DAMAGE TO PEOPLE OR ANIMALS.
RECYCLE/REUSE. IMMOBILIZE THE TOXIC OR HARMFUL COMPONENTS. REMOVE TO AN
AUTHORIZED DUMP (CLASS I).
ADDITIONAL INFORMATION:
LWCA (THE NETHERLANDS):
KGA CATEGORY 06. HAZARDOUS WASTE ACCORDING TO DIRECTIVE 2008/98/EC.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1490 POTASSIUM PERMANGANATE, 5.1, II
UN-NO.(DOT): UN1490
PROPER SHIPPING NAME (DOT): POTASSIUM PERMANGANATE
TRANSPORT HAZARD CLASS(ES) (DOT): 5.1 - CLASS 5.1 - OXIDIZER 49 CFR 173.128
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 5.1 - OXIDIZER
DANGEROUS FOR THE ENVIRONMENT: YES
MARINE POLLUTANT: YES
ENVIRONMENT
DOT PACKAGING NON BULK (49 CFR 173.XXX): 212
DOT PACKAGING BULK (49 CFR 173.XXX): 240
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB8 - AUTHORIZED IBCS:
METAL (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B AND 31N); RIGID PLASTICS
(11H1, 11H2, 21H1, 21H2, 31H1 AND 31H2); COMPOSITE (11HZ1, 11HZ2, 21HZ1,
21HZ2, 31HZ1 AND 31HZ2); FIBERBOARD (11G); WOODEN (11C, 11D AND 11F);
FLEXIBLE (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 OR
13M2).
IP2:
WHEN IBCS OTHER THAN METAL OR RIGID PLASTICS IBCS ARE USED, THEY MUST BE
OFFERED FOR TRANSPORTATION IN A CLOSED FREIGHT CONTAINER OR A CLOSED
TRANSPORT VEHICLE.
IP4:
FLEXIBLE, FIBERBOARD OR WOODEN IBCS MUST BE SIFT-PROOF AND WATER-RESISTANT
OR BE FITTED WITH A SIFT-PROOF AND WATER-RESISTANT LINER.
T3: 2.65 178.274(D)(2) NORMAL............. 178.275(D)(2)
TP33:
THE PORTABLE TANK INSTRUCTION ASSIGNED FOR THIS SUBSTANCE APPLIES FOR
GRANULAR AND POWDERED SOLIDS AND FOR SOLIDS WHICH ARE FILLED AND DISCHARGED
AT TEMPERATURES ABOVE THEIR MELTING POINT WHICH ARE COOLED AND TRANSPORTED
AS A SOLID MASS. SOLID SUBSTANCES TRANSPORTED OR OFFERED FOR TRANSPORT
ABOVE THEIR MELTING POINT ARE AUTHORIZED FOR TRANSPORTATION IN PORTABLE
TANKS CONFORMING TO THE PROVISIONS OF PORTABLE TANK INSTRUCTION T4 FOR
SOLID SUBSTANCES OF PACKING GROUP III OR T7 FOR SOLID SUBSTANCES OF PACKING
GROUP II, UNLESS A TANK WITH MORE STRINGENT REQUIREMENTS FOR MINIMUM SHELL
THICKNESS, MAXIMUM ALLOWABLE WORKING PRESSURE, PRESSURE-RELIEF DEVICES OR
BOTTOM OUTLETS ARE ASSIGNED IN WHICH CASE THE MORE STRINGENT TANK
INSTRUCTION AND SPECIAL PROVISIONS SHALL APPLY. FILLING LIMITS MUST BE IN
ACCORDANCE WITH PORTABLE TANK SPECIAL PROVISION TP3. SOLIDS MEETING THE
DEFINITION OF AN ELEVATED TEMPERATURE MATERIAL MUST BE TRANSPORTED IN
ACCORDANCE WITH THE APPLICABLE REQUIREMENTS OF THIS SUBCHAPTER.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 152
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 25 KG
DOT VESSEL STOWAGE LOCATION:
D - THE MATERIAL MUST BE STOWED "ON DECK ONLY" ON A CARGO VESSEL AND ON A
PASSENGER VESSEL CARRYING A NUMBER OF PASSENGERS LIMITED TO NOT MORE THAN
THE LARGER OF 25 PASSENGERS OR ONE PASSENGER PER EACH 3 M OF OVERALL VESSEL
LENGTH, BUT THE MATERIAL IS PROHIBITED ON PASSENGER VESSELS IN WHICH THE
LIMITING NUMBER OF PASSENGERS IS EXCEEDED.
DOT VESSEL STOWAGE OTHER:
56 - STOW "SEPARATED FROM" AMMONIUM COMPOUNDS, 58 - STOW "SEPARATED FROM"
CYANIDES
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
POTASSIUM PERMANGANATE (7722-64-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313:
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 100 LB
SARA SECTION 311/312 HAZARD CLASSES: REACTIVE HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
POTASSIUM PERMANGANATE CAS-NO. 7722-64-7 100%
15.2. INTERNATIONAL REGULATIONS:
CANADA:
POTASSIUM PERMANGANATE (7722-64-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
POTASSIUM PERMANGANATE (7722-64-7):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 02/13/2018
FULL TEXT OF H-PHRASES: SEE SECTION 16
H272: MAY INTENSIFY FIRE; OXIDIZER
H302: HARMFUL IF SWALLOWED
H400: VERY TOXIC TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
NFPA HEALTH HAZARD 1 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SIGNIFICANT IRRITATION.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN UNDER TYPICAL DIRE
CONDITIONS, INCLUDING INTRINSICALLY NONCOMBUSTIBLE
MATERIALS SUCH AS CONCRETE, STONE, AND SAND.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
NFPA SPECIFIC HAZARD OX - MATERIALS THAT POSSES OXIDIZING PROPERTIES.
HAZARD RATING:
HEALTH 1 SLIGHT HAZARD - IRRITATION OR MINOR REVERSIBLE INJURY
POSSIBLE
FLAMMABILITY 0 MINIMAL HAZARD - MATERIALS THAT WILL NOT BURN
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION F
F - SAFETY GLASSES, GLOVES, SYNTHETIC APRON, DUST
RESPIRATOR
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