| Common Name: | WATER HARDNESS BUFFER, ODORLESS |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 9/30/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 9AR65 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
WATER HARDNESS BUFFER, ODORLESS
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
ISSUE DATE: 5/11/2015
REVISION DATE: 9/30/2021
SUPERSEDES: 9/14/2021
VERSION: 2.0
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: WATER HARDNESS BUFFER, ODORLESS
PRODUCT CODE: LC26800
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM, INC.
1010 JACKSON'S POINTE CT.
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR +1-703-741-5970
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS US CLASSIFICATION:
ACUTE TOXICITY (INHALATION: DUST, MIST) CATEGORY 4:
H332: HARMFUL IF INHALED
SKIN CORROSION/IRRITATION CATEGORY 1:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 3:
H402: HARMFUL TO AQUATIC LIFE
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS US LABELING:
HAZARD PICTOGRAMS (GHS US):
CORROSION
EXCLAMATION MARK
SIGNAL WORD (GHS US): DANGER
HAZARD STATEMENTS (GHS US):
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H332: HARMFUL IF INHALED
H402: HARMFUL TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS (GHS US):
P260: DO NOT BREATHE MIST.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280: WEAR PROTECTIVE GLOVES, EYE PROTECTION.
P301+P330+P331
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS US CLASSIFICATION
WATER CAS-NO.: 7732-18-5 64 NOT CLASSIFIED
ETHANOLAMINE CAS-NO.: 141-43-5 30 FLAM. LIQ. 4, H227
ACUTE TOX. 4 (ORAL), H302
ACUTE TOX. 3 (DERMAL), H311
ACUTE TOX. 4 (INHALATION),
H332
SKIN CORR. 1C, H314
EYE DAM. 1, H318
AQUATIC ACUTE 3, H402
HYDROCHLORIC ACID, CAS-NO.: 7647-01-0 5.5 ACUTE TOX. 4 (ORAL), H302
37% W/W SKIN CORR. 1B, H314
EYE DAM. 1, H318
STOT SE 3, H335
EDTA, MAGNESIUM CAS-NO.: 14402-88-1 0.5 NOT CLASSIFIED
DISODIUM SALT
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ALLOW AFFECTED PERSON TO BREATHE FRESH AIR. ALLOW THE VICTIM TO REST.
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE AFFECTED CLOTHING AND WASH ALL EXPOSED SKIN AREA WITH MILD SOAP AND
WATER, FOLLOWED BY WARM WATER RINSE. GET IMMEDIATE MEDICAL
ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. HARMFUL
IF INHALED.
SYMPTOMS/EFFECTS AFTER INHALATION:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION. HARMFUL IF INHALED.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSTIC BURNS/CORROSION OF THE SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
BURNS OR IRRITATION OF THE LININGS OF THE MOUTH, THROAT, AND
GASTROINTESTINAL TRACT.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
TREAT SYMPTOMATICALLY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD: COULD BURN BUT DO NOT IGNITE READILY.
EXPLOSION HAZARD: NO DIRECT EXPLOSION HAZARD.
REACTIVITY IN CASE OF FIRE:
REACTS WITH (SOME) ACIDS: RELEASE OF TOXIC/COMBUSTIBLE GASES/VAPORS.
HAZARDOUS DECOMPOSITION PRODUCTS IN CASE OF FIRE:
AMMONIA. CARBON DIOXIDE. CARBON MONOXIDE. HYDROGEN CHLORIDE.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
CLEAN UP ANY SPILLS AS SOON AS POSSIBLE, USING AN ABSORBENT MATERIAL TO
COLLECT IT.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: SAFETY GLASSES. GLOVES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA. AVOID BREATHING MIST.
HYGIENE MEASURES: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS: KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS. STRONG ACIDS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
WATER HARDNESS BUFFER, ODORLESS: NO ADDITIONAL INFORMATION AVAILABLE
ETHANOLAMINE (141-43-5):
USA - ACGIH - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: ETHANOLAMINE
ACGIH:
OEL TWA [PPM]: 3 PPM
ACGIH:
STEL (PPM): 6 PPM
REMARK (ACGIH):
TLV(R*) BASIS: EYE & SKIN IRR
REGULATORY REFERENCE: ACGIH 2021
USA - OSHA - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: ETHANOLAMINE
OSHA PEL (TWA) [1]: 6 MG/M3
OSHA PEL (TWA) [2]: 3 PPM
REGULATORY REFERENCE (US-OSHA): OSHA ANNOTATED TABLE Z-1
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
USA - ACGIH - OCCUPATIONAL EXPOSURE LIMITS:
ACGIH CEILING (MG/M3): 2.98 MG/M3
ACGIH CEILING (PPM): 2 PPM
USA - OSHA - OCCUPATIONAL EXPOSURE LIMITS:
OSHA PEL (CEILING): 7 MG/M3
OSHA PEL C [PPM]: 5 PPM
USA - IDLH - OCCUPATIONAL EXPOSURE LIMITS:
IDLH [PPM]: 50 PPM
USA - NIOSH - OCCUPATIONAL EXPOSURE LIMITS:
NIOSH REL (CEILING): 7 MG/M3
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
NIOSH REL C [PPM]: 5 PPM
EDTA, MAGNESIUM DISODIUM SALT (14402-88-1):
NO ADDITIONAL INFORMATION AVAILABLE
WATER (7732-18-5): NO ADDITIONAL INFORMATION AVAILABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
GLOVES. SAFETY GLASSES. DUST/AEROSOL MASK WITH FILTER TYPE P1. CHEMICAL
RESISTANT APRON.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
RESPIRATORY PROTECTION:
HIGH GAS/VAPOUR CONCENTRATION: FULL FACE MASK WITH FILTER TYPE A
PERSONAL PROTECTIVE EQUIPMENT SYMBOL(S):
GLOVES
SAFETY GLASSES
FULL-FACE RESPIRATOR
APRON
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: MILD
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 12
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY: NO DATA AVAILABLE
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS. NOT ESTABLISHED.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS. STRONG ACIDS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
NITROGEN OXIDES. CARBON MONOXIDE. CARBON DIOXIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY (ORAL): NOT CLASSIFIED
ACUTE TOXICITY (DERMAL): NOT CLASSIFIED
ACUTE TOXICITY (INHALATION): HARMFUL IF INHALED.
WATER HARDNESS BUFFER, ODORLESS:
ATE US (DUST, MIST): 5 MG/L/4H
ETHANOLAMINE (141-43-5):
LD50 ORAL RAT: 1720 MG/KG
LD50 DERMAL RABBIT: 1000 MG/KG
ATE US (ORAL): 1720 MG/KG BODY WEIGHT
ATE US (DERMAL): 1000 MG/KG BODY WEIGHT
ATE US (GASES): 4500 PPMV/4H
ATE US (VAPORS): 11 MG/L/4H
ETHANOLAMINE (141-43-5):
ATE US (DUST, MIST): 1.5 MG/L/4H
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LD50 ORAL RAT: 700 MG/KG
LD50 DERMAL RABBIT: 5010 MG/KG
ATE US (ORAL): 700 MG/KG BODY WEIGHT
ATE US (DERMAL): 5010 MG/KG BODY WEIGHT
WATER (7732-18-5):
LD50 ORAL RAT: >/=90000 MG/KG
ATE US (ORAL): 90000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: CAUSES SEVERE SKIN BURNS.
PH: 12
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
PH: 12
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
STOT-SINGLE EXPOSURE: NOT CLASSIFIED
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
STOT-SINGLE EXPOSURE: MAY CAUSE RESPIRATORY IRRITATION.
STOT-REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
LIKELY ROUTES OF EXPOSURE: INHALATION. SKIN AND EYE CONTACT.
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. HARMFUL
IF INHALED.
SYMPTOMS/EFFECTS AFTER INHALATION:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION. HARMFUL IF INHALED.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSTIC BURNS/CORROSION OF THE SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
BURNS OR IRRITATION OF THE LININGS OF THE MOUTH, THROAT, AND
GASTROINTESTINAL TRACT.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - WATER: HARMFUL TO AQUATIC LIFE.
ETHANOLAMINE (141-43-5):
LC50 FISH 1: 150 MG/L 96 H
EC50 DAPHNIA 1: 65 MG/L 48 H
EC50 OTHER AQUATIC ORGANISMS 1: 15 MG/L 72 H
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LC50 FISH 1: 282 MG/L (96 H, GAMBUSIA AFFINIS, PURE SUBSTANCE)
EC50 DAPHNIA 1: <56 MG/L (72 H, DAPHNIA MAGNA, PURE SUBSTANCE)
12.2. PERSISTENCE AND DEGRADABILITY:
WATER HARDNESS BUFFER, ODORLESS:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY: NOT APPLICABLE.
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
BOD (% OF THOD): NOT APPLICABLE
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
WATER HARDNESS BUFFER, ODORLESS:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
ETHANOLAMINE (141-43-5):
LOG POW: -1.91
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LOG POW: 0.25 (QSAR)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
ECOLOGY - SOIL:
NO (TEST)DATA ON MOBILITY OF THE COMPONENT(S) AVAILABLE. MAY BE HARMFUL TO
PLANT GROWTH, BLOOMING AND FRUIT FORMATION.
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
14.1. UN NUMBER:
DOT NA NO: UN1760
UN-NO. (IMDG): 1760
UN-NO. (IATA): 1760
14.2. UN PROPER SHIPPING NAME:
PROPER SHIPPING NAME (DOT): CORROSIVE LIQUIDS, N.O.S.
PROPER SHIPPING NAME (TDG): CORROSIVE LIQUID, N.O.S.
PROPER SHIPPING NAME (IMDG): CORROSIVE LIQUID, N.O.S.
PROPER SHIPPING NAME (IATA): CORROSIVE LIQUID, N.O.S.
14.3. TRANSPORT HAZARD CLASS(ES):
DOT:
TRANSPORT HAZARD CLASS(ES) (DOT): 8
HAZARD LABELS (DOT): 8
IMDG: CLASS 8 - CORROSIVE
TRANSPORT HAZARD CLASS(ES) (IMDG): 8
HAZARD LABELS (IMDG): 8
IATA: CLASS 8, CORROSIVES
TRANSPORT HAZARD CLASS(ES) (IATA): 8
HAZARD LABELS (IATA): 8
14.4. PACKING GROUP:
PACKING GROUP (DOT): III
PACKING GROUP (IMDG): III
PACKING GROUP (IATA): III
14.5. ENVIRONMENTAL HAZARDS:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
14.6. SPECIAL PRECAUTIONS FOR USER:
DOT:
UN-NO.(DOT): UN1760
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB3 - AUTHORIZED IBCS: METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND
31H2); COMPOSITE (31HZ1 AND 31HA2, 31HB2, 31HN2, 31HD2 AND 31HH2).
ADDITIONAL REQUIREMENT: ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR
EQUAL TO 110 KPA AT 50 C (1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT
131 F) ARE AUTHORIZED, EXCEPT FOR UN2672 (ALSO SEE SPECIAL PROVISION IP8 IN
TABLE 2 FOR UN2672).
T7 - 4 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
TP28 - A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 2.65 BAR (265 KPA)
MAY BE USED PROVIDED THE CALCULATED TEST PRESSURE IS 2.65 BAR OR LESS BASED
ON THE MAWP OF THE HAZARDOUS MATERIAL, AS DEFINED IN 178.275 OF THIS
SUBCHAPTER, WHERE THE TEST PRESSURE IS 1.5 TIMES THE MAWP.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 154
DOT PACKAGING NON BULK (49 CFR 173.XXX): 203
DOT PACKAGING BULK (49 CFR 173.XXX): 241
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
DOT VESSEL STOWAGE OTHER: 40 - STOW "CLEAR OF LIVING QUARTERS"
IMDG:
SPECIAL PROVISION (IMDG): 223, 274
LIMITED QUANTITIES (IMDG): 5 L
EXCEPTED QUANTITIES (IMDG): E1
PACKING INSTRUCTIONS (IMDG): P001, LP01
IBC PACKING INSTRUCTIONS (IMDG): IBC03
TANK INSTRUCTIONS (IMDG): T7
TANK SPECIAL PROVISIONS (IMDG): TP1, TP28
EMS-NO. (FIRE): F-A - FIRE SCHEDULE ALFA - GENERAL FIRE SCHEDULE
EMS-NO. (SPILLAGE): S-B - SPILLAGE SCHEDULE BRAVO - CORROSIVE SUBSTANCES
STOWAGE CATEGORY (IMDG): A
PROPERTIES AND OBSERVATIONS (IMDG):
CAUSES BURNS TO SKIN, EYES AND MUCOUS MEMBRANES.
IATA:
PCA EXCEPTED QUANTITIES (IATA): E1
PCA LIMITED QUANTITIES (IATA): Y841
PCA LIMITED QUANTITY MAX NET QUANTITY (IATA): 1L
PCA PACKING INSTRUCTIONS (IATA): 852
PCA MAX NET QUANTITY (IATA): 5L
CAO PACKING INSTRUCTIONS (IATA): 856
CAO MAX NET QUANTITY (IATA): 60L
SPECIAL PROVISION (IATA): A3, A803
ERG CODE (IATA): 8L
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE: NOT APPLICABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
WATER HARDNESS BUFFER, ODORLESS:
SARA SECTION 311/312 HAZARD CLASSES:
HEALTH HAZARD - ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
HEALTH HAZARD - SKIN CORROSION OR IRRITATION
HEALTH HAZARD - SERIOUS EYE DAMAGE OR EYE IRRITATION
ALL COMPONENTS OF THIS PRODUCT ARE PRESENT AND LISTED AS ACTIVE ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
HYDROCHLORIC ACID, 37% W/W CAS-NO. 7647-01-0 5.5%
ETHANOLAMINE (141-43-5):
SARA SECTION 311/312 HAZARD CLASSES: IMMEDIATE (ACUTE) HEALTH HAZARD
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ): 500 LB
SARA SECTION 311/312 HAZARD CLASSES:
HEALTH HAZARD - ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
HEALTH HAZARD - SKIN CORROSION OR IRRITATION
HEALTH HAZARD - SERIOUS EYE DAMAGE OR EYE IRRITATION
HEALTH HAZARD - SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED
EXPOSURE)
15.2. INTERNATIONAL REGULATIONS:
CANADA:
ETHANOLAMINE (141-43-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WATER (7732-18-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR
REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS:
REVISION DATE: 09/30/2021
OTHER INFORMATION: NONE.
FULL TEXT OF H - AND EUH-STATEMENTS: SEE SECTION 16
H227: COMBUSTIBLE LIQUID
H302: HARMFUL IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H318: CAUSES SERIOUS EYE DAMAGE
H332: HARMFUL IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H402: HARMFUL TO AQUATIC LIFE
NFPA HEALTH HAZARD 3 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SERIOUS OR PERMANENT INJURY.
NFPA FIRE HAZARD 1 - MATERIALS THAT MUST BE PREHEATED BEFORE IGNITION CAN
OCCUR.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 3 SERIOUS HAZARD - MAJOR INJURY LIKELY UNLESS PROMPT
ACTION IS TAKEN AND MEDICAL TREATMENT IS GIVEN
FLAMMABILITY 1 SLIGHT HAZARD - MATERIALS THAT MUST BE PREHEATED
BEFORE IGNITION WILL OCCUR. INCLUDES LIQUIDS, SOLIDS
AND SEMI SOLIDS HAVING A FLASH POINT ABOVE 200 F.
(CLASS IIIB)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION F - SAFETY GLASSES, GLOVES, SYNTHETIC APRON, DUST
RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
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EN (ENGLISH US)