| Common Name: | SODIUM HYPOCHLORITE, 5% W/V |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 11/14/2013 |
| SDS Format: | No Format Specified |
| Item Number(s): | 9CZ26 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
SODIUM HYPOCHLORITE, 5% W/V
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 11/14/2013
VERSION: 1.0
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE |  |
COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME: SODIUM HYPOCHLORITE, 5% W/V
CAS NO: 7681-52-9
PRODUCT CODE: LC24630
FORMULA: NaOCl
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
SKIN IRRIT. 2: H315
EYE DAM. 1: H318
AQUATIC ACUTE 2: H401
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS05: CORROSION
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H315: CAUSES SKIN IRRITATION
H318: CAUSES SERIOUS EYE DAMAGE
H401: TOXIC TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS (GHS-US):
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING
P273: AVOID RELEASE TO THE ENVIRONMENT
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION
P302/P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER
P305/P351/P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
P332/P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
P362: TAKE OFF CONTAMINATED CLOTHING
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
FULL TEXT OF H-PHRASES: SEE SECTION 16
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
WATER (CAS NO) 7732-18-5 95 NOT CLASSIFIED
SODIUM HYPOCHLORITE (CAS NO) 7681-52-9 5 UNST. EXPL, H200
OX. SOL. 2, H272
SKIN CORR. 1B, H314
STOT SE 3, H335
AQUATIC ACUTE 1, H400
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ASSURE FRESH AIR BREATHING. ALLOW THE VICTIM TO REST.
FIRST-AID MEASURES AFTER SKIN CONTACT:
WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO ADDITIONAL INFORMATION AVAILABLE
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. AVOID (REJECT) FIRE-FIGHTING WATER TO
ENTER ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: SAFETY GLASSES. PROTECTIVE CLOTHING. GLOVES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOUR.
HYGIENE MEASURES: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: INCOMPATIBLE MATERIALS. KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS:
STRONG REDUCING AGENTS. COMBUSTIBLE MATERIALS. ALUMINIUM. METALS. AMMONIA.
STRONG ACIDS.
INCOMPATIBLE PRODUCTS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
7.3. SPECIFIC END USE(S): NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND
LOCAL EXHAUST VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT: AVOID ALL UNNECESSARY EXPOSURE.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION: WEAR APPROPRIATE MASK.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: YELLOW LIQUID.
COLOR: YELLOW.
ODOR: CHLORINE-LIKE.
ODOR THRESHOLD: 0.3 PPM
PH: 11.3
RELATIVE EVAPORATION RATE (BUTYLACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
SELF IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOUR PRESSURE: 12 MMHg
RELATIVE VAPOUR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY: SOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 0%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS VIOLENTLY WITH ACIDS. MAY REACT VIOLENTLY WITH REDUCING AGENTS.
CONTACT WITH ACIDS LIBERATES TOXIC GAS.
10.4. CONDITIONS TO AVOID:
INCOMPATIBLE MATERIALS. DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW
TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS:
STRONG REDUCING AGENTS. WATER. ZINC. METALS. ALUMINIUM. AMMONIA. STRONG
ACIDS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
HYDROGEN CHLORIDE. CHLORINE. PHOSGENE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
WATER (7732-18-5):
LD50 ORAL RAT: >/=90000 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
PH: 11.3
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
PH: 11.3
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
SODIUM HYPOCHLORITE (7681-52-9):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - WATER: TOXIC TO AQUATIC LIFE.
SODIUM HYPOCHLORITE, 5% W/V (7681-52-9):
LC50 FISHES 1: 4.7 MG/L
SODIUM HYPOCHLORITE (7681-52-9):
LC50 FISHES 1: 0.026 MG/L (96 H; ONCORHYNCHUS KISUTCH; CHLORINE)
EC50 DAPHNIA 1: 2.1 MG/L (96 H; DAPHNIA MAGNA)
EC50 OTHER AQUATIC ORGANISMS 1:
0.2 MG/L (24 H; SKELETONEMA COSTATUM; BIOMASS)
LC50 FISH 2: 0.19 MG/L (96 H; PIMEPHALES PROMELAS)
THRESHOLD LIMIT ALGAE 1: 0.84 MG/L (24 H; CHLOROPHYTA; BIOMASS)
12.2. PERSISTENCE AND DEGRADABILITY:
SODIUM HYPOCHLORITE, 5% W/V (7681-52-9):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
SODIUM HYPOCHLORITE (7681-52-9):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY: NOT APPLICABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
BOD (% OF THOD): NOT APPLICABLE
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
SODIUM HYPOCHLORITE, 5% W/V (7681-52-9):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
SODIUM HYPOCHLORITE (7681-52-9):
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT:
NO DANGEROUS GOOD IN SENSE OF TRANSPORT REGULATIONS
ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
ADR: TRANSPORT DOCUMENT DESCRIPTION
TRANSPORT BY SEA: NO ADDITIONAL INFORMATION AVAILABLE
AIR TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
SODIUM HYPOCHLORITE, 5% W/V (7681-52-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 100 LB
SODIUM HYPOCHLORITE (7681-52-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 100 LB
WATER (7732-18-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
SODIUM HYPOCHLORITE, 5% W/V (7681-52-9):
WHMIS CLASSIFICATION: CLASS E - CORROSIVE MATERIAL
WATER (7732-18-5):
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR 1999/45/EC:
C; R34
R31
N; R50
FULL TEXT OF R-PHRASES: SEE SECTION 16
15.2.2. NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 16: OTHER INFORMATION | |
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16:
AQUATIC ACUTE 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD, CATEGORY 1
AQUATIC ACUTE 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD, CATEGORY 2
EYE DAM. 1: SERIOUS EYE DAMAGE/EYE IRRITATION, CATEGORY 1
OX. SOL. 2: OXIDIZING SOLIDS, CATEGORY 2
SKIN CORR. 1B: SKIN CORROSION/IRRITATION, CATEGORY 1B
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, CATEGORY 2
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3, RESPIRATORY
TRACT IRRITATION
UNST. EXPL: EXPLOSIVES, UNSTABLE EXPLOSIVES
H200: UNSTABLE EXPLOSIVES
H272: MAY INTENSIFY FIRE; OXIDIZER
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H315: CAUSES SKIN IRRITATION
H318: CAUSES SERIOUS EYE DAMAGE
H335: MAY CAUSE RESPIRATORY IRRITATION
H400: VERY TOXIC TO AQUATIC LIFE
H401: TOXIC TO AQUATIC LIFE
NFPA HEALTH HAZARD 3 - SHORT EXPOSURE COULD CAUSE SERIOUS TEMPORARY OR
RESIDUAL INJURY EVEN THOUGH PROMPT MEDICAL ATTENTION
WAS GIVEN.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN.
NFPA REACTIVITY 1 - NORMALLY STABLE, BUT CAN BECOME UNSTABLE AT ELEVATED
TEMPERATURES AND PRESSURES OR MAY REACT WITH WATER
WITH SOME RELEASE OF ENERGY, BUT NOT VIOLENTLY.
HMIS III RATING:
HEALTH 3 SERIOUS HAZARD - MAJOR INJURY LIKELY UNLESS PROMPT
ACTION IS TAKEN AND MEDICAL TREATMENT IS GIVEN
FLAMMABILITY 0 MINIMAL HAZARD
PHYSICAL 1 SLIGHT HAZARD
PERSONAL PROTECTION H
SDS US (GHS HAZCOM 2012)
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
11/19/2013
EN (ENGLISH)