| Common Name: | PHENOLPHTHALEIN, 1% IN 95% ETHANOL |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 1/23/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 5EER5, 9DUK1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
PHENOLPHTHALEIN, 1% IN 95% ETHANOL
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 12/17/2013
REVISION DATE: 01/23/2018
SUPERSEDES: 06/13/2014
VERSION: 2.1
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: PHENOLPHTHALEIN, 1% IN 95% ETHANOL
PRODUCT CODE: LC18220
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK
BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM
WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAMMABLE LIQUIDS CATEGORY 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
ACUTE TOXICITY (ORAL) CATEGORY 4:
H302: HARMFUL IF SWALLOWED
SKIN CORROSION/IRRITATION CATEGORY 2:
H315: CAUSES SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A:
H319: CAUSES SERIOUS EYE IRRITATION
CARCINOGENICITY CATEGORY 2:
H351: SUSPECTED OF CAUSING CANCER (ORAL)
REPRODUCTIVE TOXICITY CATEGORY 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD (ORAL)
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 1:
H370:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE)
(ORAL, DERMAL)
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3:
H335: MAY CAUSE RESPIRATORY IRRITATION
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H302: HARMFUL IF SWALLOWED
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
H351: SUSPECTED OF CAUSING CANCER (ORAL)
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD (ORAL)
H370:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE) (ORAL,
DERMAL)
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241:
USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE MIST, VAPORS, SPRAY.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P330: IF SWALLOWED, RINSE MOUTH
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P370+P378:
IN CASE OF FIRE:
USE CARBON DIOXIDE (CO2), POWDER, ALCOHOL-RESISTANT FOAM TO EXTINGUISH
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P235: KEEP COOL.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
ETHANOL (CAS-NO.): 64-17-5 89.1 FLAM. LIQ. 2, H225
CARC. 1A, H350
REPR. 2, H361
METHANOL (CAS-NO.): 67-56-1 4.95 FLAM. LIQ. 2, H225
ACUTE TOX. 3 (ORAL), H301
ACUTE TOX. 3 (DERMAL),
H311
ACUTE TOX. 3 (INHALATION),
H331
STOT SE 1, H370
ISOPROPYL ALCOHOL (CAS-NO.): 67-63-0 4.95 FLAM. LIQ. 2, H225
(2-PROPANOL) EYE IRRIT. 2A, H319
STOT SE 3, H335
PHENOLPHTHALEIN, (CAS-NO.): 77-09-8 1 CARC. 2, H351
ACS
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SUSPECTED OF CAUSING
CANCER (ORAL).
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD (INGESTION). CAUSES
DAMAGE TO ORGANS.
SYMPTOMS/EFFECTS AFTER INHALATION: MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD: FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
SAFETY GLASSES. PROTECTIVE CLOTHING. GLOVES. COMBINED GAS/DUST MASK WITH
FILTER TYPE A/P3.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. AVOID BREATHING MIST, SPRAY.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH
AS SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. USE ONLY NON-SPARKING
TOOLS. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL
SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE ONLY OUTDOORS OR IN
A WELL-VENTILATED AREA. DO NOT BREATHE MIST, VAPORS, SPRAY.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED SKIN
THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM:
HEAT SOURCES, IGNITION SOURCES, INCOMPATIBLE MATERIALS. KEEP CONTAINER
TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS: STRONG BASES. STRONG ACIDS. STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
PHENOLPHTHALEIN, ACS (77-09-8): NOT APPLICABLE
METHANOL (67-56-1):
ACGIH:
ACGIH TWA (PPM):
200 PPM (METHANOL; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT 8 H;
TLV - ADOPTED VALUE)
ACGIH:
ACGIH STEL (PPM):
250 PPM (METHANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 260 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 200 PPM
IDLH:
US IDLH (PPM): 6000 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 250 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 200 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 325 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 250 PPM
NIOSH:
REMARK (NIOSH): SKIN
ETHANOL (64-17-5):
ACGIH:
ACGIH STEL (PPM):
1000 PPM (ETHANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 1900 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 1000 PPM
IDLH:
US IDLH (PPM): 3300 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 1900 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 1000 PPM
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
ACGIH:
ACGIH TWA (PPM):
200 PPM (2-PROPANOL; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT 8 H;
TLV - ADOPTED VALUE)
ACGIH:
ACGIH STEL (PPM):
400 PPM (2-PROPANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 980 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 400 PPM
IDLH:
US IDLH (PPM): 2000 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 980 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 400 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 1225 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 500 PPM
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST
VENTILATION.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
GAS MASK.
GLOVES.
SAFETY GLASSES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
WHERE EXPOSURE THROUGH INHALATION MAY OCCUR FROM USE, RESPIRATORY
PROTECTION EQUIPMENT IS RECOMMENDED. GAS MASK
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): FLAMMABLE LIQUID AND VAPOR.
VAPOR PRESSURE: 59 HPA
VAPOR PRESSURE AT 50 DEG. C: 300 HPA
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 0.95 G/ML
SOLUBILITY: SOLUBLE IN WATER. SOLUBLE IN METHANOL. SOLUBLE IN ACETONE.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: 363 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: 2.9 CST
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS:
3.3 - 19 VOL %
67 - 290 G/M3
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 99%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY:
FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
MAY REACT VIOLENTLY WITH OXIDANTS.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
OVERHEATING. HEAT. SPARKS.
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS. STRONG BASES. STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
FUME. CARBON MONOXIDE. CARBON DIOXIDE. MAY RELEASE FLAMMABLE GASES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE:
INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY:
ORAL: HARMFUL IF SWALLOWED.
PHENOLPHTHALEIN, 1% IN 95% ETHANOL:
ATE US (ORAL): 500 MG/KG BODY WEIGHT
METHANOL (67-56-1):
LD50 ORAL RAT:
>5000 MG/KG (RAT; BASF TEST; LITERATURE STUDY; 1187-2769 MG/KG BODYWEIGHT;
RAT; WEIGHT OF EVIDENCE)
LD50 DERMAL RABBIT: 15800 MG/KG (RABBIT; LITERATURE STUDY)
LC50 INHALATION RAT (MG/L): 85 MG/L/4H (RAT; LITERATURE STUDY)
LC50 INHALATION RAT (PPM): 64000 PPM/4H (RAT; LITERATURE STUDY)
ETHANOL (64-17-5):
LD50 ORAL RAT:
10740 MG/KG (RAT; EXPERIMENTAL VALUE, RAT; EXPERIMENTAL VALUE)
LD50 DERMAL RABBIT: >16000 MG/KG (RABBIT; LITERATURE STUDY)
ATE US (ORAL): 10740 MG/KG BODY WEIGHT
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LD50 DERMAL RABBIT:
12870 MG/KG (RABBIT; EXPERIMENTAL VALUE; EQUIVALENT OR SIMILAR TO OECD 402;
16.4; RABBIT)
LC50 INHALATION RAT (MG/L): 73 MG/L/4H (RAT)
ATE US (ORAL): 5045 MG/KG BODY WEIGHT
ATE US (DERMAL): 12870 MG/KG BODY WEIGHT
ATE US (VAPORS): 73 MG/L/4H
ATE US (DUST, MIST): 73 MG/L/4H
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER (ORAL).
PHENOLPHTHALEIN, ACS (77-09-8):
IARC GROUP: 2B - POSSIBLY CARCINOGENIC TO HUMANS
ETHANOL (64-17-5):
IARC GROUP: 1 - CARCINOGENIC TO HUMANS
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD (ORAL).
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE)
(ORAL, DERMAL). MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. HARMFUL
IF SWALLOWED.
SYMPTOMS/EFFECTS AFTER INHALATION: MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
PHENOLPHTHALEIN, ACS (77-09-8):
EC50 DAPHNIA 1:
>100 MG/L (EC50; OECD 202: DAPHNIA SP. ACUTE IMMOBILISATION TEST; 48 H;
DAPHNIA MAGNA; STATIC SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
THRESHOLD LIMIT ALGAE 1:
8.9 MG/L (EC50; OECD 201: ALGA, GROWTH INHIBITION TEST; 72 H; DESMODESMUS
SUBSPICATUS; STATIC SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
METHANOL (67-56-1):
LC50 FISH 1:
15400 MG/L (LC50; EPA 660/3 - 75/009; 96 H; LEPOMIS MACROCHIRUS;
FLOW-THROUGH SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
EC50 DAPHNIA 1:
>10000 MG/L (EC50; DIN 38412-11; 48 H; DAPHNIA MAGNA; STATIC SYSTEM;
FRESH WATER; EXPERIMENTAL VALUE)
LC50 FISH 2: 10800 MG/L (LC50; 96 H; SALMO GAIRDNERI)
ETHANOL (64-17-5):
LC50 FISH 1:
14200 MG/L (LC50; US EPA; 96 H; PIMEPHALES PROMELAS; FLOW-THROUGH SYSTEM;
FRESH WATER; EXPERIMENTAL VALUE)
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LC50 FISH 2:
9640 MG/L (LC50; OECD 203: FISH, ACUTE TOXICITY TEST; 96 H; PIMEPHALES
PROMELAS; FLOW-THROUGH SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
EC50 DAPHNIA 2: 13299 MG/L (EC50; OTHER; 48 H; DAPHNIA MAGNA)
THRESHOLD LIMIT ALGAE 1:
>1000 MG/L (EC50; UBA; 72 H; SCENEDESMUS SUBSPICATUS)
12.2. PERSISTENCE AND DEGRADABILITY:
PHENOLPHTHALEIN, 1% IN 95% ETHANOL:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
PHENOLPHTHALEIN, ACS (77-09-8):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. NO TEST DATA ON MOBILITY OF THE SUBSTANCE
AVAILABLE. PHOTODEGRADATION IN THE AIR.
METHANOL (67-56-1):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. HIGHLY MOBILE
IN SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.6 - 1.12 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.42 G O2/G SUBSTANCE
THOD: 1.5 G O2/G SUBSTANCE
BOD (% OF THOD): 0.8 (LITERATURE STUDY)
ETHANOL (64-17-5):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. HIGHLY MOBILE
IN SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.8 - 0.967 G O2/G SUBSTANCE
ETHANOL (64-17-5):
CHEMICAL OXYGEN DERRIAND (COD): 1.7 G O2/G SUBSTANCE
THOD: 2.1 G O2/G SUBSTANCE
BOD (% OF THOD): 0.43
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. BIODEGRADABLE
IN THE SOIL UNDER ANAEROBIC CONDITIONS. NO TEST DATA ON MOBILITY OF THE
SUBSTANCE AVAILABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): 1.19 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.23 G O2/G SUBSTANCE
THOD: 2.4 G O2/G SUBSTANCE
12.3. BIOACCUMULATIVE POTENTIAL:
PHENOLPHTHALEIN, 1% IN 95% ETHANOL:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
PHENOLPHTHALEIN, ACS (77-09-8):
LOG POW: 2.41 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
METHANOL (67-56-1):
BCF FISH 1: <10 (BCF; 72 H; LEUCISCUS IDUS)
LOG POW: -0.77 (EXPERIMENTAL VALUE; OTHER)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
ETHANOL (64-17-5):
BCF FISH 1:
1 (BCF; OTHER; 72 H; CYPRINUS CARPIO; STATIC SYSTEM; FRESH WATER;
READ-ACROSS)
LOG POW: -0.31 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LOG POW: 0.05 (WEIGHT OF EVIDENCE APPROACH; OTHER; 25 DEG. C)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
12.4. MOBILITY IN SOIL:
METHANOL (67-56-1):
SURFACE TENSION: 0.023 N/M (20 DEG. C)
LOG KOC: KOC, PCKOCWIN V1.66; 1; CALCULATED VALUE
ETHANOL (64-17-5):
SURFACE TENSION: 0.022 N/M (20 DEG. C)
LOG KOC: KOC,PCKOCWIN V1.66; 1; READ-ACROSS
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
SURFACE TENSION: 0.021 N/M (25 DEG. C)
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1170 ETHANOL SOLUTIONS, 3, II
UN-NO.(DOT): UN1170
PROPER SHIPPING NAME (DOT): ETHANOL SOLUTIONS
TRANSPORT HAZARD CLASS(ES) (DOT):
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SPECIAL PROVISIONS (49 CFR 172.102):
24 - ALCOHOLIC BEVERAGES CONTAINING MORE THAN 70 PERCENT ALCOHOL BY VOLUME
MUST BE TRANSPORTED AS MATERIALS IN PACKING GROUP II. ALCOHOLIC BEVERAGES
CONTAINING MORE THAN 24 PERCENT BUT NOT MORE THAN 70 PERCENT ALCOHOL BY
VOLUME MUST BE TRANSPORTED AS MATERIALS IN PACKING GROUP III.
IB2 - AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE
(31HZ1).
ADDITIONAL REQUIREMENT:
ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C
(1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED.
T4 - 2.65 178.274(D)(2) NORMAL.... 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING:
DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE:
TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS THE
TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 4B;150
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL(49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
PHENOLPHTHALEIN, 1% IN 95% ETHANOL:
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR
TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA)
OF 1986 AND 40 CFR PART 372.
PHENOLPHTHALEIN, ACS CAS-NO.: 77-09-8 1%
METHANOL CAS-NO.: 67-56-1 4.95%
ISOPROPYL ALCOHOL (2-PROPANOL) CAS-NO.: 67-63-0 4.95%
METHANOL (67-56-1):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
15.2. INTERNATIONAL REGULATIONS:
CANADA:
PHENOLPHTHALEIN, ACS (77-09-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
METHANOL (67-56-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
PHENOLPHTHALEIN, ACS (77-09-8):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
ETHANOL (64-17-5):
LISTED ON IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
15.3. US STATE REGULATIONS:
THIS PRODUCT CAN EXPOSE YOU TO PHENOLPHTHALEIN, ACS, WHICH IS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CANCER, AND METHANOL, WHICH IS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
FOR MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
PHENOLPHTHALEIN, ACS (77-09-8):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: YES
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANT RISK LEVEL (NSRL):
METHANOL (67-56-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANT RISK LEVEL (NSRL):
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 01/23/2018
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H301: TOXIC IF SWALLOWED
H302: HARMFUL IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION
H331: TOXIC IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H350: MAY CAUSE CANCER
H351: SUSPECTED OF CAUSING CANCER
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H370: CAUSES DAMAGE TO ORGANS
NFPA HEALTH HAZARD 3 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SERIOUS OR PERMANENT INJURY.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER
ALMOST ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 3 SERIOUS HAZARD - MAJOR INJURY LIKELY UNLESS PROMPT
ACTION IS TAKEN AND MEDICAL TREATMENT IS GIVEN
FLAMMABILITY 3 SERIOUS HAZARD - MATERIALS CAPABLE OF IGNITION UNDER
ALMOST ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73 F AND
BOILING POINTS ABOVE 100 F. AS WELL AS LIQUIDS WITH
FLASH POINTS BETWEEN 73 F AND 100 F. (CLASSES
IB & IC)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION H
H - SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, VAPOR RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)