| Common Name: | FORMALDEHYDE, 10% V/V, BUFFERED |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 6/28/2017 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8G181, 9FJT1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
FORMALDEHYDE, 10% V/V, BUFFERED
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 12/13/2013
REVISION DATE: 06/28/2017
SUPERSEDES: 09/17/2015
VERSION: 2.0
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: FORMALDEHYDE, 10% V/V, BUFFERED
PRODUCT CODE: LC14670
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
SKIN CORROSION/IRRITATION CATEGORY 2:
H315: CAUSES SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE
SKIN SENSITIZATION, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
CARCINOGENICITY CATEGORY 1A:
H350: MAY CAUSE CANCER (INHALATION)
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 3:
H402: HARMFUL TO AQUATIC LIFE
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS05: CORROSION
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H315: CAUSES SKIN IRRITATION
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H318: CAUSES SERIOUS EYE DAMAGE
H350: MAY CAUSE CANCER (INHALATION)
H402: HARMFUL TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING
P272: CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
P273: AVOID RELEASE TO THE ENVIRONMENT
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
WATER (CAS-NO.) 7732-18-5 95 NOT CLASSIFIED
FORMALDEHYDE, (CAS-NO.) 50-00-0 3.7 FLAM. LIQ. 3, H226
37% W/W ACUTE TOX. 4 (ORAL), H302
ACUTE TOX. 4 (DERMAL), H312
ACUTE TOX. 2 (INHALATION:
VAPOUR), H330
SKIN CORR. 1C, H314
EYE DAM. 1, H318
CARC. 1A, H350
STOT SE 1, H370
AQUATIC ACUTE 2, H401
METHANOL (CAS-NO.) 67-56-1 0.5 FLAM. LIQ. 2, H225
ACUTE TOX. 3 (ORAL), H301
ACUTE TOX. 3 (DERMAL), H311
ACUTE TOX. 3 (INHALATION), H331
STOT SE 1, H370
PHOSPHORIC (CAS-NO.) 7664-38-2 0.5 SKIN CORR. 1B, H314
ACID, 85% W/W EYE DAM. 1, H318
SODIUM HYDROXIDE (CAS-NO.) 1310-73-2 0.3 ACUTE TOX. 4 (DERMAL), H312
SKIN CORR. 1A, H314
EYE DAM. 1, H318
AQUATIC ACUTE 3, H402
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ALLOW VICTIM TO BREATHE FRESH AIR. ALLOW THE VICTIM TO REST.
FIRST-AID MEASURES AFTER SKIN CONTACT:
WASH SKIN WITH PLENTY OF WATER. WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS AFTER INHALATION:
MAY CAUSE AN ALLERGIC SKIN REACTION. MAY CAUSE CANCER BY INHALATION.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
NAUSEA. VOMITING. DIARRHOEA. BURNS OR IRRITATION OF THE LININGS OF THE
MOUTH, THROAT, AND GASTROINTESTINAL TRACT.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
NO ADDITIONAL INFORMATION AVAILABLE
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
SAFETY GLASSES. PROTECTIVE CLOTHING. GLOVES. COMBINED GAS/DUST MASK WITH
FILTER TYPE A/P3.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. AVOID BREATHING GAS, MIST,
VAPORS, SPRAY. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL
ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
HYGIENE MEASURES:
WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING
SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: HEAT SOURCES. KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS. STRONG BASES. STRONG ACIDS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
FORMALDEHYDE, 37% W/W (50-00-0):
ACGIH:
ACGIH CEILING (MG/M3): 0.37 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 0.75 PPM
OSHA:
OSHA PEL (STEL) (PPM): 2 PPM
IDLH:
US IDLH (PPM): 20 PPM
NIOSH:
NIOSH REL (TWA) (PPM): 0.016 PPM
NIOSH:
NIOSH REL (CEILING) (PPM): 0.1 PPM 15 MIN.
METHANOL (67-56-1):
ACGIH:
ACGIH TWA (PPM):
200 PPM (METHANOL; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT 8 H; TLV -
ADOPTED VALUE)
ACGIH:
ACGIH STEL (PPM):
250 PPM (METHANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 260 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 200 PPM
IDLH:
US IDLH (PPM): 6000 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 250 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 200 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 325 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 250 PPM
NIOSH:
REMARK (NIOSH): SKIN
SODIUM HYDROXIDE (1310-73-2):
ACGIH:
ACGIH CEILING (MG/M3):
2 MG/M3 (SODIUM HYDROXIDE; USA; MOMENTARY VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 2 MG/M3
IDLH:
US IDLH (MG/M3): 10 MG/M3
NIOSH:
NIOSH REL (CEILING) (MG/M3): 2 MG/M3
PHOSPHORIC ACID, 85% W/W (7664-38-2):
OSHA:
OSHA PEL (TWA) (MG/M3): 1 MG/M3
IDLH:
US IDLH (MG/M3): 1000 MG/M3
NIOSH:
NIOSH REL (TWA) (MG/M3): 1 MG/M3
NIOSH:
NIOSH REL (STEL) (MG/M3): 3 MG/M3
WATER (7732-18-5): NOT APPLICABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND
LOCAL EXHAUST VENTILATION.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
SAFETY GLASSES. GLOVES. PROTECTIVE CLOTHING. GAS MASK AT CONCENTRATION IN
THE AIR > TLV.
HAND PROTECTION: WEAR PROTECTIVE GLOVES
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION: WEAR APPROPRIATE MASK
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 7
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY: SOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE.
OXIDIZING PROPERTIES: NO DATA AVAILABLE.
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS:
STRONG OXIDIZERS. STRONG ACIDS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
PHOSPHORUS OXIDES. CARBON MONOXIDE. CARBON DIOXIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
FORMALDEHYDE, 37% W/W (50-00-0):
LD50 ORAL RAT: 500 MG/KG
ATE US (ORAL): 500 MG/KG BODY WEIGHT
ATE US (DERMAL): 2000 MG/KG BODY WEIGHT
ATE US (VAPORS): 0.578 MG/L/4H
METHANOL (67-56-1):
LD50 ORAL RAT:
>5000 MG/KG (RAT; BASF TEST; LITERATURE STUDY; 1187-2769 MG/KG BODYWEIGHT;
RAT; WEIGHT OF EVIDENCE)
LD50 DERMAL RABBIT: 15800 MG/KG (RABBIT; LITERATURE STUDY)
METHANOL (67-56-1):
LC50 INHALATION RAT (MG/L): 85 MG/L/4H (RAT; LITERATURE STUDY)
LC50 INHALATION RAT (PPM): 64000 PPM/4H (RAT; LITERATURE STUDY)
SODIUM HYDROXIDE (1310-73-2):
ATE US (DERMAL): 1350 MG/KG BODY WEIGHT
WATER (7732-18-5):
LD50 ORAL RAT: >/=90000 MG/KG
ATE US (ORAL): 90000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
PH: 7
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
PH: 7
RESPIRATORY OR SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: MAY CAUSE CANCER (INHALATION).
FORMALDEHYDE, 37% W/W (50-00-0):
IARC GROUP: 1 - CARCINOGENIC TO HUMANS
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/EFFECTS AFTER INHALATION:
MAY CAUSE AN ALLERGIC SKIN REACTION. MAY CAUSE CANCER BY INHALATION.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
NAUSEA. VOMITING. DIARRHOEA. BURNS OR IRRITATION OF THE LININGS OF THE
MOUTH, THROAT, AND GASTROINTESTINAL TRACT.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - WATER: HARMFUL TO AQUATIC LIFE.
FORMALDEHYDE, 10% V/V, BUFFERED:
EC50 DAPHNIA 1: 54 MG/L
FORMALDEHYDE, 37% W/W (50-00-0):
LC50 FISH 1: 41 MG/L (LC50; 96 H)
EC50 DAPHNIA 1: 14.7 MG/L (EC50; 24 H)
EC50 DAPHNIA 2: 2 MG/L
THRESHOLD LIMIT ALGAE 1: 2.5 MG/L (EC0; 192 H)
METHANOL (67-56-1):
LC50 FISH 1:
15400 MG/L (LC50; EPA 660/3 - 75/009; 96 H; LEPOMIS MACROCHIRUS;
FLOW-THROUGH SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
EC50 DAPHNIA 1:
>10000 MG/L (EC50; DIN 38412-11; 48 H; DAPHNIA MAGNA; STATIC SYSTEM; FRESH
WATER; EXPERIMENTAL VALUE)
LC50 FISH 2: 10800 MG/L (LC50; 96 H; SALMO GAIRDNERI)
SODIUM HYDROXIDE (1310-73-2):
LC50 FISH 1:
45.4 MG/L (LC50; OTHER; 96 H; SALMO GAIRDNERI; STATIC SYSTEM; FRESH WATER;
EXPERIMENTAL VALUE)
PHOSPHORIC ACID, 85% W/W (7664-38-2):
LC50 FISH 1: 138 MG/L (LC50)
12.2. PERSISTENCE AND DEGRADABILITY:
FORMALDEHYDE, 10% V/V, BUFFERED :
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
FORMALDEHYDE, 37% W/W (50-00-0):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE IN WATER.
BIODEGRADABILITY IN SOIL:
NO DATA AVAILABLE. NO TEST DATA ON MOBILITY OF THE COMPONENTS AVAILABLE.
PHOTODEGRADATION IN THE AIR.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.64 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.06 G O2/G SUBSTANCE
THOD: 1.068 G O2/G SUBSTANCE
BOD (% OF THOD): 0.6 (5 DAYS; LITERATURE STUDY)
METHANOL (67-56-1):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. HIGHLY MOBILE IN
SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.6 - 1.12 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.42 G O2/G SUBSTANCE
THOD: 1.5 G O2/G SUBSTANCE
BOD (% OF THOD): 0.8 (LITERATURE STUDY)
SODIUM HYDROXIDE (1310-73-2):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY:
NOT APPLICABLE. NO TEST DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
PHOSPHORIC ACID, 85% W/W (7664-38-2):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY:
NOT APPLICABLE. NO TEST DATA ON MOBILITY OF THE COMPONENTS AVAILABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
FORMALDEHYDE, 10% V/V, BUFFERED:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
FORMALDEHYDE, 37% W/W (50-00-0):
LOG POW: -0.78 - 0.0
BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION: NOT APPLICABLE.
METHANOL (67-56-1):
BCF FISH 1: <10 (BCF; 72 H; LEUCISCUS IDUS)
LOG POW: -0.77 (EXPERIMENTAL VALUE; OTHER)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
SODIUM HYDROXIDE (1310-73-2):
BIOACCUMULATIVE POTENTIAL: NO BIOACCUMULATION DATA AVAILABLE.
PHOSPHORIC ACID, 85% W/W (7664-38-2):
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
FORMALDEHYDE, 37% W/W (50-00-0):
ECOLOGY - SOIL: TOXIC TO FLORA.
METHANOL (67-56-1):
SURFACE TENSION: 0.023 N/M (20 DEG. C)
LOG KOC: KOC, PCKOCWIN V1.66; 1; CALCULATED VALUE
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT: NOT REGULATED
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
FORMALDEHYDE, 10% V/V, BUFFERED:
SARA SECTION 311/312 HAZARD CLASSES:
HEALTH HAZARD - CARCINOGENICITY
HEALTH HAZARD - RESPIRATORY OR SKIN SENSITIZATION
HEALTH HAZARD - SERIOUS EYE DAMAGE OR EYE IRRITATION
HEALTH HAZARD - SKIN CORROSION OR IRRITATION
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
METHANOL CAS-NO. 67-56-1 0.5%
FORMALDEHYDE, 37% W/W (50-00-0):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 100 LB
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
SARA SECTION 313 - EMISSION REPORTING: 0.1%
METHANOL (67-56-1):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
SODIUM HYDROXIDE (1310-73-2):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 1000 LB
SARA SECTION 311/312 HAZARD CLASSES: IMMEDIATE (ACUTE) HEALTH HAZARD
PHOSPHORIC ACID, 85% W/W (7664-38-2):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
15.2. INTERNATIONAL REGULATIONS:
CANADA:
FORMALDEHYDE, 37% W/W (50-00-0):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
METHANOL (67-56-1): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
SODIUM HYDROXIDE (1310-73-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
PHOSPHORIC ACID, 85% W/W (7664-38-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
FORMALDEHYDE, 37% W/W (50-00-0):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT CONTAINS, OR MAY CONTAIN, TRACE
QUANTITIES OF A SUBSTANCE(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, DEVELOPMENTAL AND/OR REPRODUCTIVE HARM
FORMALDEHYDE, 37% W/W (50-00-0):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: YES
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANT RISK LEVEL (NSRL): 40 (MICRO)G/DAY
METHANOL (67-56-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANT RISK LEVEL (NSRL):
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 06/28/2017
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H226: FLAMMABLE LIQUID AND VAPOR
H301: TOXIC IF SWALLOWED
H302: HARMFUL IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H312: HARMFUL IN CONTACT WITH SKIN
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H315: CAUSES SKIN IRRITATION
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H318: CAUSES SERIOUS EYE DAMAGE
H330: FATAL IF INHALED
H331: TOXIC IF INHALED
H350: MAY CAUSE CANCER
H370: CAUSES DAMAGE TO ORGANS
H401: TOXIC TO AQUATIC LIFE
H402: HARMFUL TO AQUATIC LIFE
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 1 - MATERIALS THAT MUST BE PREHEATED BEFORE IGNITION CAN
OCCUR.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
* - CHRONIC (LONG-TERM) HEALTH EFFECTS MAY RESULT FROM
REPEATED OVEREXPOSURE
FLAMMABILITY 1 SLIGHT HAZARD - MATERIALS THAT MUST BE PREHEATED
BEFORE IGNITION WILL OCCUR. INCLUDES LIQUIDS, SOLIDS
AND SEMI SOLIDS HAVING A FLASH POINT ABOVE 200 F.
(CLASS IIIB)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION H
H - SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, VAPOR
RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)