| Common Name: | HYDRAZINE STANDARD, 1000PPM |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 10/10/2017 |
| SDS Format: | No Format Specified |
| Item Number(s): | 9FJT5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
HYDRAZINE STANDARD, 1000PPM
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 11/23/1997
REVISION DATE: 10/10/2017
SUPERSEDES: 10/10/2017
VERSION: 1.3
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: HYDRAZINE STANDARD, 1000PPM
PRODUCT CODE: LC14930
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION SKIN SENSITIZATION, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
CARCINOGENICITY CATEGORY 1B:
H350: MAY CAUSE CANCER
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 3:
H402: HARMFUL TO AQUATIC LIFE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 3:
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H350: MAY CAUSE CANCER
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P261: AVOID BREATHING MIST, SPRAY, VAPORS
P272: CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
P273: AVOID RELEASE TO THE ENVIRONMENT
P280: WEAR PROTECTIVE GLOVES, EYE PROTECTION
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
WATER (CAS-NO.) 7732-18-5 99.17 NOT CLASSIFIED
HYDROCHLORIC ACID, (CAS-NO.) 7647-01-0 0.5 ACUTE TOX. 4 (ORAL), H302
37% W/W SKIN CORR. 1B, H314
EYE DAM. 1, H318
STOT SE 3, H335
AQUATIC ACUTE 3, H402
HYDRAZINE (CAS-NO.) 5341-61-7 0.33 CARC. 1B, H350
DIHYDROCHLORIDE ACUTE TOX. 3 (INHALATION),
H331
ACUTE TOX. 3 (DERMAL), H311
ACUTE TOX. 3 (ORAL), H301
SKIN SENS. 1, H317
AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ALLOW VICTIM TO BREATHE FRESH AIR. ALLOW THE VICTIM TO REST.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE AFFECTED CLOTHING AND WASH ALL EXPOSED SKIN AREA WITH MILD SOAP AND
WATER, FOLLOWED BY WARM WATER RINSE. WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER. OBTAIN MEDICAL ATTENTION IF PAIN,
BLINKING OR REDNESS PERSISTS.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS: MAY CAUSE CANCER.
SYMPTOMS/EFFECTS AFTER INHALATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
BLISTERS. RED SKIN. SKIN RASH/INFLAMMATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION: NAUSEA. VOMITING. DIARRHOEA.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD: NOT FLAMMABLE.
EXPLOSION HAZARD: NOT APPLICABLE.
REACTIVITY: NONE.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
WEAR CHEMICALLY PROTECTIVE GLOVES, LAB COAT OR APRON TO PREVENT PROLONGED
OR REPEATED SKIN CONTACT.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. AVOID BREATHING MIST, VAPORS,
SPRAY. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL
SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
HYGIENE MEASURES:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: INCOMPATIBLE MATERIALS. KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: CYANIDES. NITRATES. SULFITES. FORMALDEHYDE.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
HYDRAZINE DIHYDROCHLORIDE (5341-61-7): NOT APPLICABLE
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
ACGIH:
ACGIH CEILING (MG/M3): 2.98 MG/M3
ACGIH:
ACGIH CEILING (PPM): 2 PPM
OSHA:
OSHA PEL (CEILING) (MG/M3): 7 MG/M3
OSHA:
OSHA PEL (CEILING) (PPM): 5 PPM
IDLH:
US IDLH (PPM): 50 PPM
NIOSH:
NIOSH REL (CEILING) (MG/M3): 7 MG/M3
NIOSH:
NIOSH REL (CEILING) (PPM): 5 PPM
WATER (7732-18-5): NOT APPLICABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT: GLOVES. SAFETY GLASSES.
MATERIALS FOR PROTECTIVE CLOTHING:
BUTYL RUBBER. LATEX GLOVES. NEOPRENE. NITRILE RUBBER
HAND PROTECTION: WEAR PROTECTIVE GLOVES
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NOT REQUIRED IN NORMAL CONDITIONS
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR, COLORLESS LIQUID.
COLOR: COLORLESS
ODOR: ODORLESS
ODOR THRESHOLD: NO DATA AVAILABLE
PH: </=4
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 1 G/ML
SOLUBILITY: SOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE.
OXIDIZING PROPERTIES: NONE.
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NONE.
10.2. CHEMICAL STABILITY: NOT ESTABLISHED.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS: NITRATES. SULFITES. FORMALDEHYDE. CYANIDES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
NITROGEN OXIDES. GASEOUS AMMONIA. HYDROGEN CHLORIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
HYDRAZINE DIHYDROCHLORIDE (5341-61-7):
ATE US (ORAL): 100 MG/KG BODY WEIGHT
ATE US (DERMAL): 300 MG/KG BODY WEIGHT
ATE US (DUST, MIST): 0.5 MG/L/4H
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LD50 ORAL RAT: 700 MG/KG
LD50 DERMAL RABBIT: 5010 MG/KG
ATE US (ORAL): 700 MG/KG BODY WEIGHT
ATE US (DERMAL): 5010 MG/KG BODY WEIGHT
WATER (7732-18-5):
LD50 ORAL RAT: >/=90000 MG/KG
ATE US (ORAL): 90000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: </=4
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: </=4
RESPIRATORY OR SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET
CARCINOGENICITY: MAY CAUSE CANCER.
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/EFFECTS AFTER INHALATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
BLISTERS. RED SKIN. SKIN RASH/INFLAMMATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION: NAUSEA. VOMITING. DIARRHOEA.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LC50 FISH 1: 282 MG/L (LC50; 96 H)
EC50 DAPHNIA 1: <56 MG/L (EC50; 72 H)
12.2. PERSISTENCE AND DEGRADABILITY:
HYDRAZINE STANDARD, 1000PPM:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
HYDRAZINE DIHYDROCHLORIDE (5341-61-7):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY: NOT APPLICABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY:
NOT APPLICABLE. NO TEST DATA ON MOBILITY OF THE COMPONENTS AVAILABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
HYDRAZINE STANDARD, 1000PPM:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LOG POW: 0.25 (QSAR)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
ECOLOGY - SOIL MAY BE HARMFUL TO PLANT GROWTH, BLOOMING AND FRUIT
FORMATION.
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1789 HYDROCHLORIC ACID (SOLUTION), 8, III
UN-NO.(DOT): UN1789
PROPER SHIPPING NAME (DOT): HYDROCHLORIC ACID SOLUTION
TRANSPORT HAZARD CLASS(ES) (DOT):
8 - CLASS 8 - CORROSIVE MATERIAL 49 CFR 173.136
PACKING GROUP (DOT): III - MINOR DANGER
HAZARD LABELS (DOT): 8 - CORROSIVE
DOT PACKAGING NON BULK (49 CFR 173.XXX): 203
DOT PACKAGING BULK (49 CFR 173.XXX): 241
DOT SPECIAL PROVISIONS (49 CFR 172.102):
A3 - FOR COMBINATION PACKAGING, IF GLASS INNER PACKAGING (INCLUDING
AMPOULES) ARE USED, THEY MUST BE PACKED WITH ABSORBENT MATERIAL IN TIGHTLY
CLOSED METAL RECEPTACLES BEFORE PACKING IN OUTER PACKAGING.
IB3 - AUTHORIZED IBCS: METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND
31H2); COMPOSITE (31HZ1 AND 31HA2, 31HB2, 31HN2, 31HD2 AND 31HH2).
ADDITIONAL REQUIREMENT: ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR
EQUAL TO 110 KPA AT 50 C (1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT
131 F) ARE AUTHORIZED, EXCEPT FOR UN2672 (ALSO SEE SPECIAL PROVISION IP8 IN
TABLE 2 FOR UN2672).
T4 - 2.65 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
TP12 - THIS MATERIAL IS CONSIDERED HIGHLY CORROSIVE TO STEEL.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 154
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
C - THE MATERIAL MUST BE STOWED "ON DECK ONLY" ON A CARGO VESSEL AND ON A
PASSENGER VESSEL.
DOT VESSEL STOWAGE OTHER:
8 - GLASS CARBOYS NOT PERMITTED ON PASSENGER VESSELS
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
HYDROCHLORIC ACID, 37% W/W CAS-NO. 7647-01-0 0.5%
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
EPA TSCA REGULATORY FLAG:
T - T - INDICATES A SUBSTANCE THAT IS THE SUBJECT OF A SECTION 4 TEST RULE
UNDER TSCA.
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ): 500 LB
SARA SECTION 311/312 HAZARD CLASSES: IMMEDIATE (ACUTE) HEALTH HAZARD
15.2. INTERNATIONAL REGULATIONS:
CANADA:
HYDRAZINE DIHYDROCHLORIDE (5341-61-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
HYDRAZINE DIHYDROCHLORIDE (5341-61-7):
NOT LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR
REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 10/10/2017
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16:
H301: TOXIC IF SWALLOWED
H302: HARMFUL IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H318: CAUSES SERIOUS EYE DAMAGE
H331: TOXIC IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H350: MAY CAUSE CANCER
H400: VERY TOXIC TO AQUATIC LIFE
H402: HARMFUL TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN UNDER TYPICAL DIRE
CONDITIONS, INCLUDING INTRINSICALLY NONCOMBUSTIBLE
MATERIALS SUCH AS CONCRETE, STONE, AND SAND.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 0 MINIMAL HAZARD - MATERIALS THAT WILL NOT BURN
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION C
C - SAFETY GLASSES, GLOVES, SYNTHETIC APRON
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)