| Common Name: | HYDROCHLORIC ACID, 0.1N (0.1M) IN ISOPROPANOL |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 10/11/2017 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8FYH1, 9GT44 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
HYDROCHLORIC ACID, 0.1N (0.1M) IN ISOPROPANOL
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 09/09/2013
REVISION DATE: 10/11/2017
SUPERSEDES: 09/22/2015
VERSION: 1.3
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: HYDROCHLORIC ACID, 0.1N (0.1M) IN ISOPROPANOL
PRODUCT CODE: LC15400
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR +1-703-741-5970
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAMMABLE LIQUIDS CATEGORY 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A:
H319: CAUSES SERIOUS EYE IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3:
H335: MAY CAUSE RESPIRATORY IRRITATION
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS07: EXCLAMATION MARK
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
PRECAUTIONARY STATEMENTS (GHS-US):
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P261: AVOID BREATHING MIST, VAPORS, SPRAY.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P370+P378:
IN CASE OF FIRE:
USE CARBON DIOXIDE (CO2), POWDER, ALCOHOL-RESISTANT FOAM TO EXTINGUISH
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
ISOPROPYL ALCOHOL (CAS-NO.) 67-63-0 99.64 FLAM. LIQ. 2, H225
(2-PROPANOL) EYE IRRIT. 2A, H319
STOT SE 3, H335
HYDROCHLORIC ACID, (CAS-NO.) 7647-01-0 0.36 ACUTE TOX. 4 (ORAL), H302
37% W/W SKIN CORR. 1B, H314
EYE DAM. 1, H318
STOT SE 3, H335
AQUATIC ACUTE 3, H402
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE). CALL A POISON
CENTER/DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. REMOVE
VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
CALL A POISON CENTER/DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE SKIN WITH WATER/SHOWER. REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED
CLOTHING.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
CALL A POISON CENTER/DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS AFTER INHALATION:
MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: DRY SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. EYE IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION: NAUSEA. VOMITING. HEADACHE. DIZZINESS.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
TREAT SYMPTOMATICALLY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD: HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
REACTIVITY: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION. DO NOT ATTEMPT TO TAKE ACTION WITHOUT SUITABLE
PROTECTIVE EQUIPMENT. SELF-CONTAINED BREATHING APPARATUS. COMPLETE
PROTECTIVE CLOTHING.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: SAFETY GLASSES. GLOVES. PROTECTIVE CLOTHING.
EMERGENCY PROCEDURES:
VENTILATE SPILLAGE AREA. EVACUATE UNNECESSARY PERSONNEL. NO OPEN FLAMES, NO
SPARKS, AND NO SMOKING. AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
AVOID CONTACT WITH SKIN AND EYES.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
DO NOT ATTEMPT TO TAKE ACTION WITHOUT SUITABLE PROTECTIVE EQUIPMENT. EQUIP
CLEANUP CREW WITH PROPER PROTECTION. AVOID BREATHING MIST, SPRAY. FOR
FURTHER INFORMATION REFER TO SECTION 8: "EXPOSURE CONTROLS/PERSONAL
PROTECTION".
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. PREVENT ENTRY TO SEWERS AND PUBLIC
WATERS. NOTIFY AUTHORITIES IF LIQUID ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
TAKE UP LIQUID SPILL INTO ABSORBENT MATERIAL. SOAK UP SPILLS WITH INERT
SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS SOON AS POSSIBLE. COLLECT
SPILLAGE. STORE AWAY FROM OTHER MATERIALS. NOTIFY AUTHORITIES IF PRODUCT
ENTERS SEWERS OR PUBLIC WATERS.
OTHER INFORMATION:
DISPOSE OF MATERIALS OR SOLID RESIDUES AT AN AUTHORIZED SITE.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION. FOR FURTHER
INFORMATION REFER TO SECTION 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING.
USE ONLY NON-SPARKING TOOLS. AVOID BREATHING MIST, VAPORS, SPRAY. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA. KEEP AWAY FROM HEAT, HOT SURFACES,
SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING. GROUND/BOND
CONTAINER AND RECEIVING EQUIPMENT. TAKE PRECAUTIONARY MEASURES AGAINST
STATIC DISCHARGE. FLAMMABLE VAPORS MAY ACCUMULATE IN THE CONTAINER. USE
EXPLOSION-PROOF EQUIPMENT. WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID
CONTACT WITH SKIN AND EYES.
HYGIENE MEASURES:
WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE
WHEN USING THIS PRODUCT. ALWAYS WASH HANDS AFTER HANDLING THE PRODUCT.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: DIRECT SUNLIGHT, HEAT SOURCES, IGNITION SOURCES, INCOMPATIBLE
MATERIALS. KEEP IN FIREPROOF PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN
A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
INCOMPATIBLE PRODUCTS: STRONG BASES. METALS. STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
ACGIH:
ACGIH CEILING (MG/M3): 2.98 MG/M3
ACGIH:
ACGIH CEILING (PPM): 2 PPM
OSHA:
OSHA PEL (CEILING) (MG/M3): 7 MG/M3
OSHA:
OSHA PEL (CEILING) (PPM): 5 PPM
IDLH:
US IDLH (PPM): 50 PPM
NIOSH:
NIOSH REL (CEILING) (MG/M3): 7 MG/M3
NIOSH:
NIOSH REL (CEILING) (PPM): 5 PPM
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
ACGIH:
ACGIH TWA (PPM): 200 PPM
ACGIH:
ACGIH STEL (PPM): 400 PPM
OSHA:
OSHA PEL (TWA) (MG/M3): 980 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 400 PPM
IDLH:
US IDLH (PPM): 2000 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 980 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 400 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 1225 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 500 PPM
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE.
ENVIRONMENTAL EXPOSURE CONTROLS: AVOID RELEASE TO THE ENVIRONMENT.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
SAFETY GLASSES. GLOVES. PROTECTIVE CLOTHING. HIGH GAS/VAPOR CONCENTRATION:
GAS MASK WITH FILTER TYPE A.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES. SAFETY GLASSES
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
HIGH GAS/VAPOUR CONCENTRATION: GAS MASK WITH FILTER TYPE A
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR, COLORLESS LIQUID.
COLOR: COLORLESS
ODOR: STUFFY ODOR ALCOHOL ODOR
ODOR THRESHOLD:
3 - 610 PPM
8 - 1499 MG/M3
PH: NO DATA AVAILABLE
MELTING POINT: NOT APPLICABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 82 DEG. C
CRITICAL TEMPERATURE: 235 DEG. C
FLASH POINT: 12 DEG. C
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): 2.3
FLAMMABILITY (SOLID, GAS): HIGHLY FLAMMABLE LIQUID AND VAPOR.
VAPOR PRESSURE: 44 HPA
VAPOR PRESSURE AT 50 DEG. C: 229 HPA
RELATIVE VAPOR DENSITY AT 20 DEG. C: 2.1
RELATIVE DENSITY: 0.79
RELATIVE DENSITY OF SATURATED GAS/AIR MIXTURE: 1.05
SPECIFIC GRAVITY / DENSITY: 785 KG/M3
SOLUBILITY:
SOLUBLE IN WATER. SOLUBLE IN ETHANOL. SOLUBLE IN ETHER. SOLUBLE IN ACETONE.
SOLUBLE IN OILS/FATS. SOLUBLE IN CHLOROFORM.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: 399 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: 2.5316 MM2/S
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: 2 - 13 VOL %
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE.
OXIDIZING PROPERTIES: NONE.
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
10.2. CHEMICAL STABILITY:
HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
CAN FORM EXPLOSIVE MIXTURE WITH AIR.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME. AVOID
CONTACT WITH HOT SURFACES. HEAT. NO FLAMES, NO SPARKS. ELIMINATE ALL
SOURCES OF IGNITION.
10.5. INCOMPATIBLE MATERIALS:
STRONG OXIDIZERS. STRONG BASES. METALS. HALOGENS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
HYDROGEN CHLORIDE. CARBON MONOXIDE. CARBON DIOXIDE. MAY RELEASE FLAMMABLE
GASES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LD50 ORAL RAT: 700 MG/KG
LD50 DERMAL RABBIT: 5010 MG/KG
ATE US (ORAL): 700 MG/KG BODY WEIGHT
ATE US (DERMAL): 5010 MG/KG BODY WEIGHT
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LD50 ORAL RAT:
5840 MG/KG BODY WEIGHT (EQUIVALENT OR SIMILAR TO OECD 401, RAT,
EXPERIMENTAL VALUE)
LD50 DERMAL RABBIT:
16400 ML/KG (EQUIVALENT OR SIMILAR TO OECD 402, 24 H, RABBIT, EXPERIMENTAL
VALUE)
LC50 INHALATION RAT (PPM):
>10000 PPM (EQUIVALENT OR SIMILAR TO OECD 403, 6 H, RAT, MALE/FEMALE,
EXPERIMENTAL VALUE)
ATE US (ORAL): 5045 MG/KG BODY WEIGHT
ATE US (DERMAL): 12870 MG/KG BODY WEIGHT
ATE US (VAPORS): 73 MG/L/4H
ATE US (DUST, MIST): 73 MG/L/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/EFFECTS AFTER INHALATION:
MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: DRY SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. EYE IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION: NAUSEA. VOMITING. HEADACHE. DIZZINESS.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL:
THE PRODUCT IS NOT CONSIDERED HARMFUL TO AQUATIC ORGANISMS OR TO CAUSE
LONG-TERM ADVERSE EFFECTS IN THE ENVIRONMENT.
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LC50 FISH 1: 282 MG/L (96 H, GAMBUSIA AFFINIS)
EC50 DAPHNIA 1: <56 MG/L (72 H, DAPHNIA MAGNA)
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LC50 FISH 1:
9640 - 10000 MG/L (EQUIVALENT OR SIMILAR TO OECD 203, 96 H, PIMEPHALES
PROMELAS, FLOW-THROUGH SYSTEM, FRESH WATER, EXPERIMENTAL VALUE)
12.2. PERSISTENCE AND DEGRADABILITY:
HYDROCHLORIC ACID, 0.1N (0.1M) IN ISOPROPANOL:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY: NOT APPLICABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
BOD (% OF THOD): NOT APPLICABLE
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN THE SOIL UNDER ANAEROBIC
CONDITIONS. READILY BIODEGRADABLE IN WATER.
BIOCHEMICAL OXYGEN DEMAND (BOD): 1.19 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.23 G O2/G SUBSTANCE
THOD: 2.4 G O2/G SUBSTANCE
12.3. BIOACCUMULATIVE POTENTIAL:
HYDROCHLORIC ACID, 0.1N (0.1M) IN ISOPROPANOL:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
LOG POW: 0.25 (QSAR)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LOG POW: 0.05 (WEIGHT OF EVIDENCE APPROACH, 25 DEG. C)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
12.4. MOBILITY IN SOIL:
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
ECOLOGY - SOIL:
NO (TEST)DATA ON MOBILITY OF THE COMPONENTS AVAILABLE. MAY BE HARMFUL TO
PLANT GROWTH, BLOOMING AND FRUIT FORMATION.
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
SURFACE TENSION: 0.021 N/M (25 DEG. C)
ECOLOGY - SOIL: NO (TEST)DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE.
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE TREATMENT METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LICENSED COLLECTOR'S
SORTING INSTRUCTIONS.
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
FLAMMABLE VAPORS MAY ACCUMULATE IN THE CONTAINER.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN1993 FLAMMABLE LIQUIDS, N.O.S. (ISOPROPYL ALCOHOL), 3, II
UN-NO.(DOT): UN1993
PROPER SHIPPING NAME (DOT): FLAMMABLE LIQUIDS, N.O.S.
TRANSPORT HAZARD CLASS(ES) (DOT):
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB2 - AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE
(31HZ1). ADDITIONAL REQUIREMENT: ONLY LIQUIDS WITH A VAPOR PRESSURE LESS
THAN OR EQUAL TO 110 KPA AT 50 C (1.1 BAR AT 122 F), OR 130 KPA AT 55 C
(1.3 BAR AT 131 F) ARE AUTHORIZED.
T7 - 4 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING:
DEGREE OF FILLING = 97 / 1 + A (TR - TF) WHERE: TR IS THE MAXIMUM MEAN BULK
TEMPERATURE DURING TRANSPORT, AND TF IS THE TEMPERATURE IN DEGREES CELSIUS
OF THE LIQUID DURING FILLING.
TP8 - A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 1.5 BAR (150 KPA)
MAY BE USED WHEN THE FLASH POINT OF THE HAZARDOUS MATERIAL TRANSPORTED IS
GREATER THAN 0 C (32 F).
TP28 - A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 2.65 BAR (265 KPA)
MAY BE USED PROVIDED THE CALCULATED TEST PRESSURE IS 2.65 BAR OR LESS BASED
ON THE MAWP OF THE HAZARDOUS MATERIAL, AS DEFINED IN 178.275 OF THIS
SUBCHAPTER, WHERE THE TEST PRESSURE IS 1.5 TIMES THE MAWP.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 150
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
B - (I) THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO
VESSEL AND ON A PASSENGER VESSEL CARRYING A NUMBER OF PASSENGERS LIMITED TO
NOT MORE THAN THE LARGER OF 25 PASSENGERS, OR ONE PASSENGER PER EACH 3 M OF
OVERALL VESSEL LENGTH; AND (II) "ON DECK ONLY" ON PASSENGER VESSELS IN
WHICH THE NUMBER OF PASSENGERS SPECIFIED IN PARAGRAPH (K)(2)(I) OF THIS
SECTION IS EXCEEDED.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
HYDROCHLORIC ACID, 0.1N (0.1M) IN ISOPROPANOL:
SARA SECTION 311/312 HAZARD CLASSES: FIRE HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
HYDROCHLORIC ACID, 37% W/W CAS-NO. 7647-01-0 0.36%
ISOPROPYL ALCOHOL (2-PROPANOL) CAS-NO. 67-63-0 99.64%
HYDROCHLORIC ACID, 37% W/W (7647-01-0):
EPA TSCA REGULATORY FLAG:
T - T - INDICATES A SUBSTANCE THAT IS THE SUBJECT OF A SECTION 4 TEST RULE
UNDER TSCA.
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ): 500 LB
SARA SECTION 311/312 HAZARD CLASSES:
HEALTH HAZARD - ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
HEALTH HAZARD - SKIN CORROSION OR IRRITATION
HEALTH HAZARD - SERIOUS EYE DAMAGE OR EYE IRRITATION
HEALTH HAZARD - SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED
EXPOSURE)
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD - FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARD - SERIOUS EYE DAMAGE OR EYE IRRITATION
HEALTH HAZARD - SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED
EXPOSURE)
15.2. INTERNATIONAL REGULATIONS:
CANADA: NO ADDITIONAL INFORMATION AVAILABLE
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR
REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 10/11/2017
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H302: HARMFUL IF SWALLOWED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H318: CAUSES SERIOUS EYE DAMAGE
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
H402: HARMFUL TO AQUATIC LIFE
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 3 SERIOUS HAZARD - MATERIALS CAPABLE OF IGNITION UNDER
ALMOST ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73 F AND
BOILING POINTS ABOVE 100 F. AS WELL AS LIQUIDS WITH
FLASH POINTS BETWEEN 73 F AND 100 F. (CLASSES IB &
IC)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION H
H - SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, VAPOR
RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
05/15/2018
EN (ENGLISH US)