| Common Name: | METHANOL, 50% V/V (1+1) |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 5/14/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 8GET6, 9GUT6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
METHANOL, 50% V/V (1+1)
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 04/07/2015
REVISION DATE: 05/14/2018
SUPERSEDES: 09/24/2015
VERSION: 1.2
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION
PRODUCT FORM: MIXTURES
PRODUCT NAME: METHANOL, 50% V/V (1+1)
PRODUCT CODE: LC16830
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR +1 -703-741 -5970
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAMMABLE LIQUIDS CATEGORY 3:
H226: FLAMMABLE LIQUID AND VAPOUR
ACUTE TOXICITY (ORAL) CATEGORY 3:
H301: TOXIC IF SWALLOWED
ACUTE TOXICITY (DERMAL) CATEGORY 3:
H311: TOXIC IN CONTACT WITH SKIN
ACUTE TOXICITY (INHALATION: DUST,MIST) CATEGORY 4:
H332: HARMFUL IF INHALED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 1:
H370: CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE)
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS06: SKULLS AND CROSSBONES
GHS08: HEALTH HAZAR
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H226: FLAMMABLE LIQUID AND VAPOUR
H301+H311: TOXIC IF SWALLOWED OR IN CONTACT WITH SKIN
H332: HARMFUL IF INHALED
H370: CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE)
PRECAUTIONARY STATEMENTS (GHS-US):
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE MIST, VAPORS, SPRAY.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION.
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P370+P378:
IN CASE OF FIRE:
USE ALCOHOL RESISTANT FOAM, SAND, EXTINGUISHING POWDER TO EXTINGUISH
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
WATER (CAS-NO.) 7732-18-5 55.5 NOT CLASSIFIED
METHANOL (CAS-NO.) 67-56-1 44.5 FLAM. LIQ. 2, H225
ACUTE TOX. 3 (ORAL), H301
ACUTE TOX. 3 (DERMAL), H311
ACUTE TOX. 3 (INHALATION), H331
STOT SE 1, H370
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE). CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. RINSE
CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. OBTAIN MEDICAL ATTENTION IF
PAIN, BLINKING OR REDNESS PERSISTS.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. IMMEDIATELY CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS: CAUSES DAMAGE TO ORGANS (OPTIC NERVE).
SYMPTOMS/EFFECTS AFTER INHALATION:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION. HARMFUL IF INHALED.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
REPEATED EXPOSURE TO THIS MATERIAL CAN RESULT IN ABSORPTION THROUGH SKIN
CAUSING SIGNIFICANT HEALTH HAZARD. TOXIC IN CONTACT WITH SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION:
TOXIC IF SWALLOWED. SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL
RESULT IN SERIOUS HEALTH HAZARD.
CHRONIC SYMPTOMS: BLURRED VISION. VISUAL DISTURBANCES.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
HOSPITALIZE AT ONCE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD: FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
SAFETY GLASSES. PROTECTIVE CLOTHING. GLOVES. FACE-SHIELD. COMBINED GAS/DUST
MASK WITH FILTER TYPE A/P3.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. AVOID BREATHING
DUST/FUME/GAS/MIST/VAPORS/SPRAY.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLINNG AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. USE ONLY NON-SPARKING
TOOLS. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. DO NOT BREATHE MIST,
VAPORS, SPRAY.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED SKIN
THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM:
HEAT SOURCES, IGNITION SOURCES, INCOMPATIBLE MATERIALS. KEEP CONTAINER
TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS: STRONG BASES. STRONG ACIDS. STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS
METHANOL (67-56-1):
ACGIH:
ACGIH TWA (PPM): 200 PPM
ACGIH:
ACGIH STEL (PPM): 250 PPM
OSHA:
OSHA PEL (TWA) (MG/M3): 260 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 200 PPM
IDLH:
US IDLH (PPM): 6000 PPM
NIOSH:
NIOSH REL (TWA) (MG/MG3): 250 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 200 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 325 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 250 PPM
NIOSH:
REMARK (NIOSH): SKIN
WATER (7732-18-5): NOT APPLICABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE. ENSURE ADEQUATE VENTILATION. MATERIAL SHOULD BE
HANDLED IN A LABORATORY HOOD WHENEVER POSSIBLE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT: GAS MASK. GLOVES. SAFETY GLASSES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
SKIN AND BODY PROTECTION: CHEMICAL RESISTANT APRON
RESPIRATORY PROTECTION:
WHERE EXPOSURE THROUGH INHALATION MAY OCCUR FROM USE, RESPIRATORY
PROTECTION EQUIPMENT IS RECOMMENDED. GAS MASK
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: 27 DEG. C
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): FLAMMABLE LIQUID AND VAPOR.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: 0.93
SOLUBILITY: SOLUBLE IN METHANOL. SOLUBLE IN WATER. SOLUBLE IN ETHANOL.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: 1.96 CST
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY:
FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS VIGOROUSLY WITH STRONG OXIDIZERS AND ACIDS.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
OVERHEATING. HEAT. SPARKS.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS. STRONG BASES. STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. MAY RELEASE FLAMMABLE GASES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE:
INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
METHANOL, 50% V/V (1+1):
ATE US (ORAL): 224.719 MG/KG BODY WEIGHT
ATE US (DERMAL): 674.157 MG/KG BODY WEIGHT
ATE US (DUST, MIST): 1.124 MG/L/4H
METHANOL (67-56-1):
LD50 ORAL RAT:
1187 - 2769 MG/KG BODY WEIGHT (BASF TEST, RAT, MALE/FEMALE, WEIGHT OF
EVIDENCE)
LD50 DERMAL RABBIT:
17100 MG/KG (RABBIT, INCONCLUSIVE, INSUFFICIENT DATA)
LC50 INHALATION RAT (MG/L):
128.2 MG/L AIR (BASF TEST, 4 H, RAT, MALE/FEMALE, WEIGHT OF EVIDENCE)
ATE US (ORAL): 100 MG/KG BODY WEIGHT
ATE US (DERMAL): 300 MG/KG BODY WEIGHT
ATE US (GASES): 700 PPMV/4H
ATE US (VAPORS): 3 MG/L/4H
ATE US (DUST, MIST): 0.5 MG/L/4H
WATER (7732-18-5):
LD50 ORAL RAT: >/=90000 MG/KG
ATE US (ORAL): 90000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE).
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. HARMFUL
IF INHALED. TOXIC IF SWALLOWED. TOXIC IN CONTACT WITH SKIN.
SYMPTOMS/EFFECTS AFTER INHALATION:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION. HARMFUL IF INHALED.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
REPEATED EXPOSURE TO THIS MATERIAL CAN RESULT IN ABSORPTION THROUGH SKIN
CAUSING SIGNIFICANT HEALTH HAZARD. TOXIC IN CONTACT WITH SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: MAY CAUSE SLIGHT IRRITATION.
SYMPTOMS/EFFECTS AFTER INGESTION:
TOXIC IF SWALLOWED. SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL
RESULT IN SERIOUS HEALTH HAZARD.
CHRONIC SYMPTOMS: BLURRED VISION. VISUAL DISTURBANCES.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
METHANOL (67-56-1):
LC50 FISH 1:
15400 MG/L (EPA 660/3 - 75/009, 96 H, LEPOMIS MACROCHIRUS, FLOW-THROUGH
SYSTEM, FRESH WATER, EXPERIMENTAL VALUE)
EC50 DAPHNIA 1:
18260 MG/L (OECD 202: DAPHNIA SP. ACUTE IMMOBILISATION TEST, 96 H, DAPHNIA
MAGNA, SEMI-STATIC SYSTEM, FRESH WATER, EXPERIMENTAL VALUE)
ERC50 (ALGAE):
22000 MG/L (OECD 201: ALGA, GROWTH INHIBITION TEST, 96 H,
PSEUDOKIRCHNERIELLA SUBCAPITATA, STATIC SYSTEM, FRESH WATER, EXPERIMENTAL
VALUE)
12.2. PERSISTENCE AND DEGRADABILITY:
METHANOL, 50% V/V (1+1):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
METHANOL (67-56-1):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABLE IN THE SOIL. READILY BIODEGRADABLE IN WATER.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.6 - 1.12 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.42 G O2/G SUBSTANCE
THOD: 1.5 G O2/G SUBSTANCE
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
METHANOL, 50% V/V (1+1):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
METHANOL (67-56-1):
BCF FISH 1:
1 - 4.5 (72 H, CYPRINUS CARPIO, STATIC SYSTEM, FRESH WATER, EXPERIMENTAL
VALUE)
LOG POW: -0.77 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
METHANOL (67-56-1):
SURFACE TENSION: 0.023 N/M (20 DEG. C)
LOG KOC: -0.89 - -0.21 (LOG KOC, CALCULATED VALUE)
ECOLOGY - SOIL: HIGHLY MOBILE IN SOIL.
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS:
AVOID RELEASE TO THE ENVIRONMENT. HAZARDOUS WASTE DUE TO TOXICITY.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN1993 FLAMMABLE LIQUIDS, N.O.S. (METHANOL), 3, III
UN-NO.(DOT): UN1993
PROPER SHIPPING NAME (DOT): FLAMMABLE LIQUIDS, N.O.S.
TRANSPORT HAZARD CLASS(ES) (DOT):
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
PACKING GROUP (DOT): III - MINOR DANGER
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
DOT PACKAGING NON BULK (49 CFR 173.XXX): 203
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
DOT SPECIAL PROVISIONS (49 CFR 172.102):
B1:
IF THE MATERIAL HAS A FLASH POINT AT OR ABOVE 38 C (100 F) AND BELOW
93 C (200 F), THEN THE BULK PACKAGING REQUIREMENTS OF 173.241 OF THIS
SUBCHAPTER ARE APPLICABLE. IF THE MATERIAL HAS A FLASH POINT OF LESS THAN
38 C (100 F), THEN THE BULK PACKAGING REQUIREMENTS OF 173.242 OF THIS
SUBCHAPTER ARE APPLICABLE.
B52:
NOTWITHSTANDING THE PROVISIONS OF 173.24B OF THIS SUBCHAPTER, NON-RECLOSING
PRESSURE RELIEF DEVICES ARE AUTHORIZED ON DOT 57 PORTABLE TANKS.
IB3:
AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE (31HZ1
AND 31HA2, 31HB2, 31HN2, 31HD2 AND 31HH2).
ADDITIONAL REQUIREMENT:
ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C
(1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED,
EXCEPT FOR UN2672 (ALSO SEE SPECIAL PROVISION IP8 IN TABLE 2 FOR UN2672).
T4: 2.65 178.274(D)(2) NORMAL...... 178.275(D)(3)
TP1:
THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE:
TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS THE
TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
TP29:
A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 1.5 BAR (150.0 KPA) MAY
BE USED PROVIDED THE CALCULATED TEST PRESSURE IS 1.5 BAR OR LESS BASED ON
THE MAWP OF THE HAZARDOUS MATERIALS, AS DEFINED IN 178.275 OF THIS
SUBCHAPTER, WHERE THE TEST PRESSURE IS 1.5 TIMES THE MAWP.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 150
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 60 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 220 L
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
METHANOL, 50% V/V (1+1):
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
METHANOL CAS-NO. 67-56-1 44.5%
METHANOL (67-56-1):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD: FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARD: ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
HEALTH HAZARD: SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
15.2. INTERNATIONAL REGULATIONS:
CANADA:
METHANOL (67-56-1): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
THIS PRODUCT CAN EXPOSE YOU TO METHANOL, WHICH IS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR MORE
INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
METHANOL (67-56-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANT RISK LEVEL (NSRL):
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 05/14/2018
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES:
SEE SECTION 16:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H226: FLAMMABLE LIQUID AND VAPOUR
H301: TOXIC IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H331: TOXIC IF INHALED
H332: HARMFUL IF INHALED
H370: CAUSES DAMAGE TO ORGANS
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH MODERATE HAZARD 2 - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY SERIOUS HAZARD 3 - MATERIALS CAPABLE OF IGNITION UNDER ALMOST
ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW
73 F AND BOILING POINTS ABOVE 100 F. AS
WELL AS LIQUIDS WITH FLASH POINTS BETWEEN
73 F AND 100 F. (CLASSES IB & IC)
PHYSICAL MINIMAL HAZARD 0 - MATERIALS THAT ARE NORMALLY STABLE, EVEN
UNDER FIRE CONDITIONS, AND WILL NOT REACT
WITH WATER, POLYMERIZE, DECOMPOSE,
CONDENSE, OR SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION H
H - SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, VAPOR RESPIRATOR
SDS US LABCHEM:
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
05/15/2018
EN (ENGLISH US)