| Common Name: | SILVER NITRATE |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 2/20/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 9NW22 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE WITH CHEMISTRY
SILVER NITRATE
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 11/21/1998
REVISION DATE: 02/20/2018
SUPERSEDES: 02/20/2018
VERSION: 2.0
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: SUBSTANCE
SUBSTANCE NAME: SILVER NITRATE
CAS-NO.: 7761-88-8
PRODUCT CODE: LC22500
FORMULA: AgNO3
SYNONYMS:
LUNAR CAUSTIC / NITRATE OF SILVER / NITRIC ACID SILVER SALT / NITRIC ACID
SILVER(1+) SALT / SILVER MONONITRATE / SILVER NITRATE / SILVER(I) NITRATE /
SILVER(I) SALT NITRIC ACID
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE:
LABORATORY CHEMICAL
CHEMICAL INTERMEDIATE
WATER TREATMENT
OXIDANT
PHOTOGRAPHIC CHEMICAL: COMPONENT
COSMETIC PRODUCT: DYESTUFF
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM, INC.
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR +1-703-741-5970
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS US CLASSIFICATION:
OXIDIZING SOLIDS CATEGORY 2:
H272: MAY INTENSIFY FIRE; OXIDIZER
SKIN CORROSION/IRRITATION CATEGORY 1B:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1:
H400: VERY TOXIC TO AQUATIC LIFE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 1:
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS US LABELING:
HAZARD PICTOGRAMS (GHS US):
FLAME OVER CIRCLE
CORROSION
ENVIRONMENT
SIGNAL WORD (GHS US): DANGER
HAZARD STATEMENTS (GHS US):
H272: MAY INTENSIFY FIRE; OXIDIZER
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS (GHS US):
P210: KEEP AWAY FROM HEAT, OPEN FLAMES, SPARKS. - NO SMOKING.
P220: KEEP/STORE AWAY FROM COMBUSTIBLE MATERIALS
P221: TAKE ANY PRECAUTION TO AVOID MIXING WITH COMBUSTIBLES
P260: DO NOT BREATHE DUST.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR EYE PROTECTION, FACE PROTECTION, PROTECTIVE GLOVES, PROTECTIVE
CLOTHING.
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P391: COLLECT SPILLAGE.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES:
SUBSTANCE TYPE: MONO-CONSTITUENT
NAME PRODUCT IDENTIFIER % GHS US CLASSIFICATION
SILVER NITRATE (CAS-NO.) 7761-88-8 100 OX. SOL. 2, H272
(MAIN CONSTITUENT) SKIN CORR. 1B, H314
EYE DAM. 1, H318
AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
3.2. MIXTURES: NOT APPLICABLE
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL: CHECK THE VITAL FUNCTIONS.
UNCONSCIOUS: MAINTAIN ADEQUATE AIRWAY AND RESPIRATION.
RESPIRATORY ARREST: ARTIFICIAL RESPIRATION OR OXYGEN.
CARDIAC ARREST: PERFORM RESUSCITATION.
VICTIM CONSCIOUS WITH LABORED BREATHING: HALF-SEATED.
VICTIM IN SHOCK: ON HIS BACK WITH LEGS SLIGHTLY RAISED.
VOMITING:
PREVENT ASPHYXIA/ASPIRATION PNEUMONIA. PREVENT COOLING BY COVERING THE
VICTIM (NO WARMING UP). KEEP WATCHING THE VICTIM. GIVE PSYCHOLOGICAL AID.
KEEP THE VICTIM CALM, AVOID PHYSICAL STRAIN.
DEPENDING ON THE VICTIM'S CONDITION: DOCTOR/HOSPITAL.
FIRST-AID MEASURES AFTER INHALATION: REMOVE THE VICTIM INTO FRESH AIR.
RESPIRATORY PROBLEMS: CONSULT A DOCTOR/MEDICAL SERVICE.
FIRST-AID MEASURES AFTER SKIN CONTACT:
WASH IMMEDIATELY WITH LOTS OF WATER (15 MINUTES)/SHOWER. DO NOT APPLY
(CHEMICAL) NEUTRALIZING AGENTS WITHOUT MEDICAL ADVICE. REMOVE CLOTHING
WHILE WASHING. DO NOT REMOVE CLOTHING IF IT STICKS TO THE SKIN. COVER
WOUNDS WITH STERILE BANDAGE. CONSULT A DOCTOR/MEDICAL SERVICE.
IF BURNED SURFACE >10%: TAKE VICTIM TO HOSPITAL.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER FOR 15 MINUTES. REMOVE CONTACT
LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. DO NOT APPLY
(CHEMICAL) NEUTRALIZING AGENTS WITHOUT MEDICAL ADVICE. TAKE VICTIM TO AN
OPHTHALMOLOGIST.
FIRST-AID MEASURES AFTER INGESTION: RINSE MOUTH WITH WATER.
IMMEDIATELY AFTER INGESTION:
GIVE LOTS OF WATER TO DRINK. DO NOT INDUCE VOMITING. DO NOT APPLY
(CHEMICAL) NEUTRALIZING AGENTS WITHOUT MEDICAL ADVICE. IMMEDIATELY CONSULT
A DOCTOR/MEDICAL SERVICE. CALL POISON INFORMATION CENTRE
(WWW.BIG.BE/ANTIGIF.HTM).
INGESTION OF LARGE QUANTITIES: IMMEDIATELY TO HOSPITAL.
DOCTOR: ADMINISTRATION OF CHEMICAL ANTIDOTE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/EFFECTS:
NOT EXPECTED TO PRESENT A SIGNIFICANT HAZARD UNDER ANTICIPATED CONDITIONS
OF NORMAL USE.
SYMPTOMS/EFFECTS AFTER INHALATION:
AFTER INHALATION OF DUST: DRY/SORE THROAT. COUGHING.
FOLLOWING SYMPTOMS MAY APPEAR LATER: RISK OF LUNG EDEMA.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
CAUSTIC BURNS/CORROSION OF THE SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
CORROSION OF THE EYE TISSUE. PERMANENT EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
AFTER ABSORPTION OF LARGE QUANTITIES:
BURNS TO THE GASTRIC/INTESTINAL MUCOSA. VOMITING. ABDOMINAL PAIN.
DIARRHOEA. SHOCK. DIZZINESS. LOW ARTERIAL PRESSURE. DISTURBANCES OF
CONSCIOUSNESS. CRAMPS/UNCONTROLLED MUSCULAR CONTRACTIONS. RESPIRATORY
COLLAPSE.
CHRONIC SYMPTOMS:
MAY STAIN THE SKIN. BLUE/GREY DISCOLORATION OF THE SKIN.
INFLAMMATION/DAMAGE OF THE EYE TISSUE. VISUAL DISTURBANCES. POSSIBLE
INFLAMMATION OF THE RESPIRATORY TRACT.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
OBTAIN MEDICAL ASSISTANCE. TREAT SYMPTOMATICALLY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER. QUICK-ACTING ABC POWDER EXTINGUISHER. QUICK-ACTING CO2 EXTINGUISHER.
QUANTITIES OF WATER.
UNSUITABLE EXTINGUISHING MEDIA: FOAM. FOAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD:
DIRECT FIRE HAZARD.: NON COMBUSTIBLE.
INDIRECT FIRE HAZARD.: MAY INTENSIFY FIRE; OXIDIZER.
REACTIONS INVOLVING A FIRE HAZARD: SEE "REACTIVITY HAZARD".
EXPLOSION HAZARD:
INDIRECT EXPLOSION HAZARD.:
REACTIONS WITH EXPLOSION HAZARDS: SEE "REACTIVITY HAZARD".
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
PRECAUTIONARY MEASURES FIRE:
EXPOSURE TO FIRE/HEAT: KEEP UPWIND.
EXPOSURE TO FIRE/HEAT: CONSIDER EVACUATION.
EXPOSURE TO FIRE/HEAT: HAVE NEIGHBORHOOD CLOSE DOORS AND WINDOWS.
FIREFIGHTING INSTRUCTIONS:
COOL TANKS/DRUMS WITH WATER SPRAY/REMOVE THEM INTO SAFETY. DILUTE TOXIC
GASES WITH WATER SPRAY. TAKE ACCOUNT OF TOXIC/CORROSIVE PRECIPITATION
WATER. TAKE ACCOUNT OF TOXIC FIRE-FIGHTING WATER. USE WATER MODERATELY AND
IF POSSIBLE COLLECT OR CONTAIN IT.
PROTECTION DURING FIREFIGHTING:
HEAT/FIRE EXPOSURE: COMPRESSED AIR/OXYGEN APPARATUS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: GLOVES. FACE-SHIELD. CORROSION-PROOF SUIT.
DUST CLOUD PRODUCTION: COMPRESSED AIR/OXYGEN APPARATUS.
EMERGENCY PROCEDURES:
MARK THE DANGER AREA. PREVENT DUST CLOUD FORMATION. NO NAKED FLAMES. KEEP
CONTAINERS CLOSED. WASH CONTAMINATED CLOTHES.
IN CASE OF HAZARDOUS REACTIONS: KEEP UPWIND.
IN CASE OF REACTIVITY HAZARD: CONSIDER EVACUATION.
MEASURES IN CASE OF DUST RELEASE:
IN CASE OF DUST PRODUCTION: KEEP UPWIND.
IN CASE OF DUST PRODUCTION: CONSIDER EVACUATION.
DUST PRODUCTION: HAVE NEIGHBORHOOD CLOSE DOORS AND WINDOWS.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA. STOP RELEASE.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT SOIL AND WATER POLLUTION. PREVENT SPREADING IN SEWERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. PLUG THE LEAK,
CUT OFF THE SUPPLY. DAM UP THE SOLID SPILL. KNOCK DOWN/DILUTE DUST CLOUD
WITH WATER SPRAY. TAKE ACCOUNT OF TOXIC/CORROSIVE PRECIPITATION WATER.
METHODS FOR CLEANING UP:
PREVENT DISPERSION BY COVERING WITH DRY SAND. SCOOP SOLID SPILL INTO
CLOSING CONTAINERS OR SYNTHETIC BAGS. CAREFULLY COLLECT THE
SPILL/LEFTOVERS. SPILL MUST NOT RETURN IN ITS ORIGINAL CONTAINER. CLEAN
CONTAMINATED SURFACES WITH AN EXCESS OF WATER. TAKE COLLECTED SPILL TO
MANUFACTURER/COMPETENT AUTHORITY. WASH CLOTHING AND EQUIPMENT AFTER
HANDLING.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
AVOID RAISING DUST. KEEP AWAY FROM NAKED FLAMES/HEAT. MEASURE THE
CONCENTRATION IN THE AIR REGULARLY. CARRY OPERATIONS IN THE OPEN/UNDER
LOCAL EXHAUST/VENTILATION OR WITH RESPIRATORY PROTECTION. COMPLY WITH THE
LEGAL REQUIREMENTS. REMOVE CONTAMINATED CLOTHING IMMEDIATELY. CLEAN
CONTAMINATED CLOTHING. KEEP THE SUBSTANCE FREE FROM CONTAMINATION.
THOROUGHLY CLEAN/DRY THE INSTALLATION BEFORE USE. DO NOT DISCHARGE THE
WASTE INTO THE DRAIN. KEEP CONTAINER TIGHTLY CLOSED.
HYGIENE MEASURES:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM : COMBUSTIBLE MATERIALS, INCOMPATIBLE MATERIALS. KEEP CONTAINER CLOSED
WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS:
STRONG BASES. COMBUSTIBLE MATERIALS. SODIUM HYPOCHLORITE. STRONG ACIDS.
INCOMPATIBLE MATERIALS:
COMBUSTIBLE MATERIAL. SOURCES OF IGNITION. DIRECT SUNLIGHT.
STORAGE TEMPERATURE: 5 - 30 DEG. C
HEAT-IGNITION:
KEEP SUBSTANCE AWAY FROM: HEAT SOURCES.
PROHIBITIONS ON MIXED STORAGE:
KEEP SUBSTANCE AWAY FROM:
COMBUSTIBLE MATERIALS. REDUCING AGENTS. (STRONG) BASES. ORGANIC MATERIALS.
ALCOHOLS.
STORAGE AREA:
STORE IN A COOL AREA. STORE IN A DRY AREA. STORE IN A DARK AREA. KEEP
CONTAINER IN A WELL-VENTILATED PLACE. KEEP LOCKED UP. UNAUTHORIZED PERSONS
ARE NOT ADMITTED. MEET THE LEGAL REQUIREMENTS. KEEP ONLY IN THE ORIGINAL
CONTAINER.
SPECIAL RULES ON PACKAGING:
SPECIAL REQUIREMENTS:
CLOSING. WATERTIGHT. CLEAN. OPAQUE. CORRECTLY LABELED. MEET THE LEGAL
REQUIREMENTS. SECURE FRAGILE PACKAGINGS IN SOLID CONTAINERS.
PACKAGING MATERIALS:
SUITABLE MATERIAL: IRON. SYNTHETIC MATERIAL.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
SILVER NITRATE (7761-88-8):
ACGIH:
ACGIH TWA (MG/M3): 0.01 MG/M3
NIOSH:
NIOSH REL (TWA) (MG/M3): 0.01 MG/M3
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
GLOVES. SAFETY GLASSES. CHEMICAL RESISTANT APRON. FACE SHIELD. PROTECTIVE
CLOTHING.
DUST PRODUCTION: DUST MASK WITH FILTER TYPE P3.
MATERIALS FOR PROTECTIVE CLOTHING:
GIVE EXCELLENT RESISTANCE: NITRILE RUBBER.
GIVE GOOD RESISTANCE: BUTYL RUBBER. NEOPRENE. PVA
HAND PROTECTION: GLOVES
EYE PROTECTION: FACE SHIELD.
IN CASE OF DUST PRODUCTION: PROTECTIVE GOGGLES
SKIN AND BODY PROTECTION: CORROSION-PROOF CLOTHING.
IN CASE OF DUST PRODUCTION: HEAD/NECK PROTECTION
RESPIRATORY PROTECTION:
DUST PRODUCTION: DUST MASK WITH FILTER TYPE P3.
HIGH DUST PRODUCTION: SELF-CONTAINED BREATHING APPARATUS
PERSONAL PROTECTIVE EQUIPMENT SYMBOL(S):
GLOVES
SAFETY GLASSES
APRON
FACE SHIELD
FULL SUIT
DUST MASK
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
APPEARANCE: CRYSTALLINE SOLID.
COLOR: COLORLESS TO GREY ON EXPOSURE TO LIGHT: DARK GREY TO BLACK
ODOR: ODORLESS
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 7
MELTING POINT: 212 DEG. C
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE (DECOMPOSES)
FLASH POINT: NOT APPLICABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: NOT APPLICABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: 5.8
RELATIVE DENSITY: 4.35 (20 DEG. C)
SPECIFIC GRAVITY / DENSITY: 4352 KG/M3
MOLECULAR MASS: 169.87 G/MOL
SOLUBILITY:
SOLUBLE IN WATER. SUBSTANCE SINKS IN WATER. SOLUBLE IN AMMONIA. SOLUBLE IN
GLYCEROL.
WATER: 71 G/100 ML (25 DEG. C)
ACETONE: 0.4 G/100 ML
LOG POW: 0.19 (ESTIMATED VALUE)
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: 440 DEG. C
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: MAY INTENSIFY FIRE; OXIDIZER.
9.2. OTHER INFORMATION:
VOC CONTENT: 0%
OTHER PROPERTIES: TRANSLUCENT. NEUTRAL REACTION.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
DECOMPOSES ON EXPOSURE TO LIGHT. THIS REACTION IS ACCELERATED ON EXPOSURE
TO IMPURITIES.
VIOLENT TO EXPLOSIVE REACTION WITH MANY COMPOUNDS E.G.:
WITH (STRONG) REDUCERS.
VIOLENT TO EXPLOSIVE REACTION WITH COMBUSTIBLE MATERIALS:
RISK OF SPONTANEOUS IGNITION. MAY BE CORROSIVE TO METALS.
10.2. CHEMICAL STABILITY: UNSTABLE ON EXPOSURE TO LIGHT.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. HIGH TEMPERATURE. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS:
COMBUSTIBLE MATERIALS. STRONG BASES. STRONG REDUCING AGENTS. STRONG ACIDS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
NITROGEN OXIDES. FUME. CARBON MONOXIDE. CARBON DIOXIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY (ORAL): NOT CLASSIFIED
ACUTE TOXICITY (DERMAL): NOT CLASSIFIED
ACUTE TOXICITY (INHALATION): NOT CLASSIFIED
SILVER NITRATE (7761-88-8):
LD50 ORAL RAT:
>2000 MG/KG BODY WEIGHT (OECD 401: ACUTE ORAL TOXICITY, RAT, MALE / FEMALE,
EXPERIMENTAL VALUE, ORAL, 14 DAY(S))
LD50 DERMAL RAT:
>2000 MG/KG BODY WEIGHT (OECD 402: ACUTE DERMAL TOXICITY, 24 H, RAT, MALE /
FEMALE, EXPERIMENTAL VALUE, DERMAL, 15 DAY(S))
LC50 INHALATION RAT (MG/L):
>0.75 MG/L (OECD 403: ACUTE INHALATION TOXICITY, 4 H, RAT, MALE / FEMALE,
EXPERIMENTAL VALUE, (MAXIMUM ACHIEVABLE CONCENTRATION), INHALATION
(AEROSOL), 14 DAY(S))
SKIN CORROSION/IRRITATION: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
PH: 7
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
PH: 7
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
STOT-SINGLE EXPOSURE: NOT CLASSIFIED
STOT-REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
LIKELY ROUTES OF EXPOSURE: INHALATION. SKIN AND EYE CONTACT.
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/EFFECTS:
NOT EXPECTED TO PRESENT A SIGNIFICANT HAZARD UNDER ANTICIPATED CONDITIONS
OF NORMAL USE.
SYMPTOMS/EFFECTS AFTER INHALATION:
AFTER INHALATION OF DUST: DRY/SORE THROAT. COUGHING.
FOLLOWING SYMPTOMS MAY APPEAR LATER: RISK OF LUNG EDEMA.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
CAUSTIC BURNS/CORROSION OF THE SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
CORROSION OF THE EYE TISSUE. PERMANENT EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
AFTER ABSORPTION OF LARGE QUANTITIES:
BURNS TO THE GASTRIC/INTESTINAL MUCOSA. VOMITING. ABDOMINAL PAIN.
DIARRHOEA. SHOCK. DIZZINESS. LOW ARTERIAL PRESSURE. DISTURBANCES OF
CONSCIOUSNESS. CRAMPS/UNCONTROLLED MUSCULAR CONTRACTIONS. RESPIRATORY
COLLAPSE.
CHRONIC SYMPTOMS:
MAY STAIN THE SKIN. BLUE/GREY DISCOLORATION OF THE SKIN.
INFLAMMATION/DAMAGE OF THE EYE TISSUE. VISUAL DISTURBANCES. POSSIBLE
INFLAMMATION OF THE RESPIRATORY TRACT.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL: DANGEROUS FOR THE ENVIRONMENT.
ECOLOGY - AIR:
NOT INCLUDED IN THE LIST OF SUBSTANCES WHICH MAY CONTRIBUTE TO THE
GREENHOUSE EFFECT (IPCC). NOT INCLUDED IN THE LIST OF FLUORINATED
GREENHOUSE GASES (REGULATION (EU) NO 517/2014). NOT CLASSIFIED AS DANGEROUS
FOR THE OZONE LAYER (REGULATION (EC) NO 1005/2009).
ECOLOGY - WATER:
VERY TOXIC TO CRUSTACEA. VERY TOXIC TO FISHES. SEVERE WATER POLLUTANT
(SURFACE WATER). VERY TOXIC TO ALGAE. MAY CAUSE EUTROPHICATION.
SILVER NITRATE (7761-88-8):
LC50 FISH 1:
1.2 (MICRO) G/L (96 H, PIMEPHALES PROMELAS, SEMI-STATIC SYSTEM, FRESH
WATER, EXPERIMENTAL VALUE, SILVER ION)
12.2. PERSISTENCE AND DEGRADABILITY:
SILVER NITRATE (7761-88-8):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY: NOT APPLICABLE.
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
BOD (% OF THOD): NOT APPLICABLE
12.3. BIOACCUMULATIVE POTENTIAL:
SILVER NITRATE (7761-88-8):
BCF FISH 1:
70 (30 DAY(S), CYPRINUS CARPIO, STATIC SYSTEM, FRESH WATER, EXPERIMENTAL
VALUE)
LOG POW: 0.19 (ESTIMATED VALUE)
BIOACCUMULATIVE POTENTIAL:
LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
REGIONAL LEGISLATION (WASTE):
DISPOSAL MUST BE DONE ACCORDING TO OFFICIAL REGULATIONS.
WASTE TREATMENT METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LICENSED COLLECTOR'S
SORTING INSTRUCTIONS.
WASTE DISPOSAL RECOMMENDATIONS:
REMOVE WASTE IN ACCORDANCE WITH LOCAL AND/OR NATIONAL REGULATIONS.
HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER WITH OTHER WASTE. DIFFERENT
TYPES OF HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER IF THIS MAY ENTAIL A
RISK OF POLLUTION OR CREATE PROBLEMS FOR THE FURTHER MANAGEMENT OF THE
WASTE. HAZARDOUS WASTE SHALL BE MANAGED RESPONSIBLY. ALL ENTITIES THAT
STORE, TRANSPORT OR HANDLE HAZARDOUS WASTE SHALL TAKE THE NECESSARY
MEASURES TO PREVENT RISKS OF POLLUTION OR DAMAGE TO PEOPLE OR ANIMALS.
RECYCLE/REUSE. REMOVE TO AN AUTHORIZED DUMP (CLASS I).
ADDITIONAL INFORMATION:
HAZARDOUS WASTE ACCORDING TO DIRECTIVE 2008/98/EC, AS AMENDED BY REGULATION
(EU) NO 1357/2014 AND REGULATION (EU) NO 2017/997.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1493 SILVER NITRATE, 5.1, II
UN-NO.(DOT): UN1493
PROPER SHIPPING NAME (DOT): SILVER NITRATE
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 5.1 - OXIDIZER
DANGEROUS FOR THE ENVIRONMENT: YES
MARINE POLLUTANT: YES
ENVIRONMENT
DOT PACKAGING NON BULK (49 CFR 173.XXX): 212
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB8 - AUTHORIZED IBCS:
METAL (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B AND 31N); RIGID PLASTICS
(11H1, 11H2, 21H1, 21H2, 31H1 AND 31H2); COMPOSITE (11HZ1, 11HZ2, 21HZ1,
21HZ2, 31HZ1 AND 31HZ2); FIBERBOARD (11G); WOODEN (11C, 11D AND 11F);
FLEXIBLE (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 OR
13M2).
IP2 - WHEN IBCS OTHER THAN METAL OR RIGID PLASTICS IBCS ARE USED, THEY MUST
BE OFFERED FOR TRANSPORTATION IN A CLOSED FREIGHT CONTAINER OR A CLOSED
TRANSPORT VEHICLE.
IP4 - FLEXIBLE, FIBERBOARD OR WOODEN IBCS MUST BE SIFT-PROOF AND
WATER-RESISTANT OR BE FITTED WITH A SIFT-PROOF AND WATER-RESISTANT LINER.
T3 - 2.65 178.274(D)(2) NORMAL............. 178.275(D)(2)
TP33 - THE PORTABLE TANK INSTRUCTION ASSIGNED FOR THIS SUBSTANCE APPLIES
FOR GRANULAR AND POWDERED SOLIDS AND FOR SOLIDS WHICH ARE FILLED AND
DISCHARGED AT TEMPERATURES ABOVE THEIR MELTING POINT WHICH ARE COOLED AND
TRANSPORTED AS A SOLID MASS. SOLID SUBSTANCES TRANSPORTED OR OFFERED FOR
TRANSPORT ABOVE THEIR MELTING POINT ARE AUTHORIZED FOR TRANSPORTATION IN
PORTABLE TANKS CONFORMING TO THE PROVISIONS OF PORTABLE TANK INSTRUCTION T4
FOR SOLID SUBSTANCES OF PACKING GROUP III OR T7 FOR SOLID SUBSTANCES OF
PACKING GROUP II, UNLESS A TANK WITH MORE STRINGENT REQUIREMENTS FOR
MINIMUM SHELL THICKNESS, MAXIMUM ALLOWABLE WORKING PRESSURE,
PRESSURE-RELIEF DEVICES OR BOTTOM OUTLETS ARE ASSIGNED IN WHICH CASE THE
MORE STRINGENT TANK INSTRUCTION AND SPECIAL PROVISIONS SHALL APPLY. FILLING
LIMITS MUST BE IN ACCORDANCE WITH PORTABLE TANK SPECIAL PROVISION TP3.
SOLIDS MEETING THE DEFINITION OF AN ELEVATED TEMPERATURE MATERIAL MUST BE
TRANSPORTED IN ACCORDANCE WITH THE APPLICABLE REQUIREMENTS OF THIS
SUBCHAPTER.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 152
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 25 KG
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
SILVER NITRATE (7761-88-8):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 1 LB
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD: OXIDIZER (LIQUID, SOLID OR GAS)
HEALTH HAZARD: ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
HEALTH HAZARD: SKIN CORROSION OR IRRITATION
HEALTH HAZARD: SERIOUS EYE DAMAGE OR EYE IRRITATION
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
SILVER NITRATE (7761-88-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
REVISION DATE: 02/20/2018
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16:
H272: MAY INTENSIFY FIRE; OXIDIZER
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H318: CAUSES SERIOUS EYE DAMAGE
H400: VERY TOXIC TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
NFPA HEALTH HAZARD 1 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SIGNIFICANT IRRITATION.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN UNDER TYPICAL FIRE
CONDITIONS, INCLUDING INTRINSICALLY NONCOMBUSTIBLE
MATERIALS SUCH AS CONCRETE, STONE, AND SAND.
NFPA REACTIVITY 3 - MATERIALS THAT IN THEMSELVES ARE CAPABLE OF
DETONATION OR EXPLOSIVE DECOMPOSITION OR EXPLOSIVE
REACTION BUT THAT REQUIRE A STRONG INITIATING
SOURCE OR MUST BE HEATED UNDER CONFINEMENT BEFORE
INITIATION.
NFPA SPECIFIC HAZARD OX - MATERIALS THAT POSSES OXIDIZING PROPERTIES.
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 0 MINIMAL HAZARD - MATERIALS THAT WILL NOT BURN
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION F
F - SAFETY GLASSES, GLOVES, SYNTHETIC APRON, DUST
RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
11/08/2019
EN (ENGLISH US)