| Common Name: | P-DIHYDROXYBENZENE |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 10/31/2017 |
| SDS Format: | No Format Specified |
| Item Number(s): | 9RCM2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
HYDROQUINONE
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 02/18/2015
REVISION DATE: 10/31/2017
SUPERSEDES: 10/31/2017
VERSION: 1.2
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: SUBSTANCE
SUBSTANCE NAME: HYDROQUINONE
CHEMICAL NAME: P-DIHYDROXYBENZENE
CAS-NO.: 123-31-9
PRODUCT CODE: LC15490
FORMULA: C6H4(OH2)
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
ACUTE TOXICITY (ORAL) CATEGORY 4:
H302: HARMFUL IF SWALLOWED
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE
SKIN SENSITIZATION, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
GERM CELL MUTAGENICITY CATEGORY 2:
H341: SUSPECTED OF CAUSING GENETIC DEFECTS
CARCINOGENICITY CATEGORY 2:
H351: SUSPECTED OF CAUSING CANCER
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1:
H400: VERY TOXIC TO AQUATIC LIFE
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS05: CORROSION
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
GHS09: ENVIRONMENT
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H302: HARMFUL IF SWALLOWED
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H318: CAUSES SERIOUS EYE DAMAGE
H341: SUSPECTED OF CAUSING GENETIC DEFECTS
H351: SUSPECTED OF CAUSING CANCER
H400: VERY TOXIC TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P261: AVOID BREATHING DUST
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
P272: CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
P273: AVOID RELEASE TO THE ENVIRONMENT
P280: WEAR PROTECTIVE GLOVES, EYE PROTECTION
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE
P391: COLLECT SPILLAGE
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES:
SUBSTANCE TYPE: MONO-CONSTITUENT
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
HYDROQUINONE (CAS-NO.) 123-31-9 100 ACUTE TOX. 4 (ORAL), H302
(MAIN CONSTITUENT) EYE DAM. 1, H318
SKIN SENS. 1, H317
MUTA. 2, H341
CARC. 2, H351
AQUATIC ACUTE 1, H400
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
3.2. MIXTURES: NOT APPLICABLE
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE). SUSPECTED OF CAUSING
CANCER.
FIRST-AID MEASURES AFTER INHALATION:
ALLOW VICTIM TO BREATHE FRESH AIR. ALLOW THE VICTIM TO REST.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE AFFECTED CLOTHING AND WASH ALL EXPOSED SKIN AREA WITH MILD SOAP AND
WATER, FOLLOWED BY WARM WATER RINSE. IF SKIN IRRITATION OR RASH OCCURS: GET
MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS: SUSPECTED OF CAUSING GENETIC DEFECTS.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
NO ADDITIONAL INFORMATION AVAILABLE
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
SAFETY GLASSES. PROTECTIVE CLOTHING. GLOVES. DUST MASK.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
ON LAND, SWEEP OR SHOVEL INTO SUITABLE CONTAINERS. MINIMIZE GENERATION OF
DUST. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. AVOID BREATHING DUST. OBTAIN
SPECIAL INSTRUCTIONS BEFORE USE. USE PERSONAL PROTECTIVE EQUIPMENT AS
REQUIRED. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED SKIN
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS: KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
HYDROQUINONE (123-31-9):
ACGIH:
ACGIH TWA (MG/M3): 1 MG/M3
OSHA:
OSHA PEL (TWA) (MG/M3): 2 MG/M3
IDLH:
US IDLH (MG/M3): 50 MG/M3
NIOSH:
NIOSH REL (CEILING) (MG/M3): 2 MG/M3 15 MIN.
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE. ENSURE ADEQUATE VENTILATION. MATERIAL SHOULD BE
HANDLED IN A LABORATORY HOOD WHENEVER POSSIBLE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
CHEMICAL RESISTANT APRON. GLOVES. FACE SHIELD. PROTECTIVE CLOTHING. SAFETY
GLASSES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NOT REQUIRED IN NORMAL CONDITIONS
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
APPEARANCE: CRYSTALLINE SOLID.
COLOR: COLORLESS TO WHITE ON EXPOSURE TO LIGHT: DISCOLORS
ODOR: NONE.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 3.75 70 G/L @ 20 DEG. C
MELTING POINT: 170 - 172 DEG. C
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 285 - 287
FLASH POINT: 165 DEG. C
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 1.32 G/CM3
MOLECULAR MASS: 110.11 G/MOL
SOLUBILITY: SOLUBLE IN ETHANOL. SOLUBLE IN ETHER. SOLUBLE IN WATER.
WATER: 70 G/L
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: 515 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY:
DISCOLORS ON EXPOSURE TO AIR. DISCOLORS ON EXPOSURE TO LIGHT.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE. CARBON DIOXIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY:
ORAL: HARMFUL IF SWALLOWED.
HYDROQUINONE (123-31-9):
LD50 ORAL RAT: 302 MG/KG
ATE US (ORAL): 302 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: 3.75 70 G/L @ 20 DEG. C
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
PH: 3.75 70 G/L @ 20 DEG. C
RESPIRATORY OR SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: SUSPECTED OF CAUSING GENETIC DEFECTS.
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER.
HYDROQUINONE (123-31-9):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. HARMFUL
IF SWALLOWED.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/EFFECTS AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - WATER: VERY TOXIC TO AQUATIC LIFE.
12.2. PERSISTENCE AND DEGRADABILITY:
HYDROQUINONE (123-31-9):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
HYDROQUINONE (123-31-9):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S., 9, III
UN-NO.(DOT): UN3077
PROPER SHIPPING NAME (DOT):
ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.
TRANSPORT HAZARD CLASS(ES) (DOT):
9 - CLASS 9 - MISCELLANEOUS HAZARDOUS MATERIAL 49 CFR 173.140
PACKING GROUP (DOT): III - MINOR DANGER
HAZARD LABELS (DOT): 9 - CLASS 9 (MISCELLANEOUS DANGEROUS MATERIALS)
CLASS 9, CLASS/DIVISION 9 PACKING GROUP III
DANGEROUS FOR THE ENVIRONMENT: YES
MARINE POLLUTANT: YES
DOT PACKAGING NON BULK (49 CFR 173.XXX): 213
DOT PACKAGING BULK (49 CFR 173.XXX): 240
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
DOT SPECIAL PROVISIONS (49 CFR 172.102):
8 A HAZARDOUS SUBSTANCE THAT IS NOT A HAZARDOUS WASTE MAY BE SHIPPED
UNDER THE SHIPPING DESCRIPTION "OTHER REGULATED SUBSTANCES, LIQUID OR
SOLID, N.O.S.", AS APPROPRIATE. IN ADDITION, FOR SOLID MATERIALS, SPECIAL
PROVISION B54 APPLIES.
146 - THIS DESCRIPTION MAY BE USED FOR A MATERIAL THAT POSES A HAZARD TO
THE ENVIRONMENT BUT DOES NOT MEET THE DEFINITION FOR A HAZARDOUS WASTE OR
A HAZARDOUS SUBSTANCE, AS DEFINED IN
171.8 OF THIS SUBCHAPTER, OR ANY HAZARD CLASS AS DEFINED IN PART 173 OF
THIS SUBCHAPTER, IF IT IS DESIGNATED AS ENVIRONMENTALLY HAZARDOUS BY THE
COMPETENT AUTHORITY OF THE COUNTRY OF ORIGIN, TRANSIT OR DESTINATION.
335 MIXTURES OF SOLIDS THAT ARE NOT SUBJECT TO THIS SUBCHAPTER AND
ENVIRONMENTALLY HAZARDOUS LIQUIDS OR SOLIDS MAY BE CLASSIFIED AS
ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S UN3077 AND MAY BE
TRANSPORTED UNDER THIS ENTRY, PROVIDED THERE IS NO FREE LIQUID VISIBLE AT
THE TIME THE MATERIAL IS LOADED OR AT THE TIME THE PACKAGING OR TRANSPORT
UNIT IS CLOSED. EACH TRANSPORT UNIT MUST BE LEAK-PROOF WHEN USED AS BULK
PACKAGING.
A112 - NOTWITHSTANDING THE QUANTITY LIMITS SHOWN IN COLUMN (9A) AND (9B)
FOR THIS ENTRY, THE FOLLOWING IBCS ARE AUTHORIZED FOR TRANSPORTATION ABOARD
PASSENGER AND CARGO-ONLY AIRCRAFT. EACH IBC MAY NOT EXCEED A MAXIMUM NET
QUANTITY OF 1,000 KG:
A. METAL: 11A, 11B, 11N, 21A, 21B AND 21N
B. RIGID PLASTICS: 11H1, 11H2, 21H1 AND 21H2
C. COMPOSITE WITH PLASTIC INNER RECEPTACLE: 11HZ1, 11HZ2, 21HZ1 AND 21HZ2
D. FIBERBOARD: 11G
E. WOODEN: 11C, 11D AND 11F (WITH INNER LINERS)
F. FLEXIBLE:
13H2, 13H3, 13H4, 13H5, 13L2, 13L3, 13L4, 13M1 AND 13M2 (FLEXIBLE IBCS MUST
BE SIFT-PROOF AND WATER RESISTANT OR MUST BE FITTED WITH A SIFT-PROOF AND
WATER RESISTANT LINER).
B54 - OPEN-TOP, SIFT-PROOF RAIL CARS ARE ALSO AUTHORIZED.
IB8 - AUTHORIZED IBCS:
METAL (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B AND 31N); RIGID PLASTICS
(11H1, 11H2, 21H1, 21H2, 31H1 AND 31H2); COMPOSITE (11HZ1, 11HZ2, 21HZ1,
21HZ2, 31HZ1 AND 31HZ2); FIBERBOARD (11G); WOODEN (11C, 11D AND 11F);
FLEXIBLE (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 OR
13M2).
IP3 - FLEXIBLE IBCS MUST BE SIFT-PROOF AND WATER-RESISTANT OR MUST BE
FITTED WITH A SIFT-PROOF AND WATER-RESISTANT LINER.
N20 - A 5M1 MULTI-WALL PAPER BAG IS AUTHORIZED IF TRANSPORTED IN A CLOSED
TRANSPORT VEHICLE.
T1 - 1.5 178.274(D)(2) NORMAL............. 178.275(D)(2)
TP33 - THE PORTABLE TANK INSTRUCTION ASSIGNED FOR THIS SUBSTANCE APPLIES
FOR GRANULAR AND POWDERED SOLIDS AND FOR SOLIDS WHICH ARE FILLED AND
DISCHARGED AT TEMPERATURES ABOVE THEIR MELTING POINT WHICH ARE COOLED AND
TRANSPORTED AS A SOLID MASS. SOLID SUBSTANCES TRANSPORTED OR OFFERED FOR
TRANSPORT ABOVE THEIR MELTING POINT ARE AUTHORIZED FOR TRANSPORTATION IN
PORTABLE TANKS CONFORMING TO THE PROVISIONS OF PORTABLE TANK INSTRUCTION T4
FOR SOLID SUBSTANCES OF PACKING GROUP III OR T7 FOR SOLID SUBSTANCES OF
PACKING GROUP II, UNLESS A TANK WITH MORE STRINGENT REQUIREMENTS FOR
MINIMUM SHELL THICKNESS, MAXIMUM ALLOWABLE WORKING PRESSURE,
PRESSURE-RELIEF DEVICES OR BOTTOM OUTLETS ARE ASSIGNED IN WHICH CASE THE
MORE STRINGENT TANK INSTRUCTION AND SPECIAL PROVISIONS SHALL APPLY. FILLING
LIMITS MUST BE IN ACCORDANCE WITH PORTABLE TANK SPECIAL PROVISION TP3.
SOLIDS MEETING THE DEFINITION OF AN ELEVATED TEMPERATURE MATERIAL MUST BE
TRANSPORTED IN ACCORDANCE WITH THE APPLICABLE REQUIREMENTS OF THIS
SUBCHAPTER.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 155
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): NO LIMIT
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): NO LIMIT
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
HYDROQUINONE (123-31-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 100 LB
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ):
10000 LB 500LB IF THE SUBSTANCE IS SOLID IN POWDER FORM WITH PARTICLE SIZE
LESS THAN 100 MICRONS, OR IS IN SOLUTION OR MOLTEN FORM
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
HYDROQUINONE CAS-NO. 123-31-9 100%
15.2. INTERNATIONAL REGULATIONS:
CANADA:
HYDROQUINONE (123-31-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
HYDROQUINONE (123-31-9):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR
REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 10/31/2017
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16:
H302: HARMFUL IF SWALLOWED
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H318: CAUSES SERIOUS EYE DAMAGE
H341: SUSPECTED OF CAUSING GENETIC DEFECTS
H351: SUSPECTED OF CAUSING CANCER
H400: VERY TOXIC TO AQUATIC LIFE
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 1 - MATERIALS THAT MUST BE PREHEATED BEFORE IGNITION CAN
OCCUR.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 1 SLIGHT HAZARD - MATERIALS THAT MUST BE PREHEATED
BEFORE IGNITION WILL OCCUR. INCLUDES LIQUIDS, SOLIDS
AND SEMI SOLIDS HAVING A FLASH POINT ABOVE 200 F.
(CLASS IIIB)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION F
F - SAFETY GLASSES, GLOVES, SYNTHETIC APRON, DUST
RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)