| Common Name: | PHENOLPHTHALEIN, 0.5% IN 50% ETHANOL |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 7/21/2020 |
| SDS Format: | No Format Specified |
| Item Number(s): | 9TEL1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
PHENOLPHTHALEIN, 0.5% IN 50% ETHANOL
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
ISSUE DATE: 12/17/2013
REVISION DATE: 07/21/2020
SUPERSEDES: 01/23/2018
VERSION: 1.5
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: PHENOLPHTHALEIN, 0.5% IN 50% ETHANOL
PRODUCT CODE: LC18200
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM, INC.
1010 JACKSON'S POINTE CT.
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR +1-703-741-5970
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS US CLASSIFICATION:
FLAMMABLE LIQUIDS CATEGORY 3:
H226: FLAMMABLE LIQUID AND VAPOR
CARCINOGENICITY CATEGORY 1A:
H350: MAY CAUSE CANCER
REPRODUCTIVE TOXICITY CATEGORY 2:
H361: SUSPECTED OF DAMAGING THE UNBORN CHILD. (ORAL)
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 1:
H370:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE) (ORAL,
DERMAL)
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS US LABELING:
HAZARD PICTOGRAMS (GHS US):
FLAME
HEALTH HAZARD
SIGNAL WORD (GHS US): DANGER
HAZARD STATEMENTS (GHS US):
H226: FLAMMABLE LIQUID AND VAPOR
H350: MAY CAUSE CANCER
H361: SUSPECTED OF DAMAGING THE UNBORN CHILD. (ORAL)
H370:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE) (ORAL,
DERMAL)
PRECAUTIONARY STATEMENTS (GHS US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE MIST, VAPORS, SPRAY.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P308+P313 - IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P370+P378:
IN CASE OF FIRE:
USE ALCOHOL RESISTANT FOAM, EXTINGUISHING POWDER, CARBON DIOXIDE (CO2) TO
EXTINGUISH
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS US CLASSIFICATION
WATER (CAS-NO.) 7732-18-5 49.75 NOT CLASSIFIED
ETHANOL (CAS-NO.) 64-17-5 44.899375 FLAM. LIQ. 2, H225
CARC. 1A, H350
REPR. 2, H361
ISOPROPYL ALCOHOL (CAS-NO.) 67-63-0 2.4875 FLAM. LIQ. 2, H225
(2-PROPANOL) EYE IRRIT. 2A, H319
STOT SE 3, H335
METHANOL (CAS-NO.) 67-56-1 2.363125 FLAM. LIQ. 2, H225
ACUTE TOX. 3 (ORAL),
H301
ACUTE TOX. 3 (DERMAL),
H311
ACUTE TOX. 3
(INHALATION), H331
STOT SE 1, H370
PHENOLPHTHALEIN, (CAS-NO.) 77-09-8 0.5 CARC. 2, H351
ACS
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS : SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
FIRST-AID MEASURES AFTER EYE CONTACT:
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. RINSE
CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. OBTAIN MEDICAL ATTENTION IF
PAIN, BLINKING OR REDNESS PERSISTS.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/EFFECTS:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CAUSES DAMAGE TO
ORGANS.
SYMPTOMS/EFFECTS AFTER INHALATION: MAY CAUSE CANCER BY INHALATION.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD: FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
SAFETY GLASSES. PROTECTIVE CLOTHING. GLOVES. COMBINED GAS/DUST MASK WITH
FILTER TYPE A/P3.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. AVOID BREATHING MIST, VAPORS,
SPRAY.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
TAKE UP LIQUID SPILL INTO INERT ABSORBENT MATERIAL. COLLECT SPILLAGE.
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. USE ONLY NON-SPARKING
TOOLS. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL
SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE MIST,
VAPORS, SPRAY.
HYGIENE MEASURES: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
STORAGE CONDITIONS: KEEP CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS. STRONG BASES.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
PHENOLPHTHALEIN, 0.5% IN 50% ETHANOL: NO ADDITIONAL INFORMATION AVAILABLE
PHENOLPHTHALEIN, ACS (77-09-8): NO ADDITIONAL INFORMATION AVAILABLE
ETHANOL (64-17-5):
USA - ACGIH - OCCUPATIONAL EXPOSURE LIMITS:
ACGIH STEL (PPM): 1000 PPM
USA - OSHA - OCCUPATIONAL EXPOSURE LIMITS:
OSHA PEL (TWA) (MG/M3): 1900 MG/M3
OSHA PEL (TWA) (PPM): 1000 PPM
USA - IDLH - OCCUPATIONAL EXPOSURE LIMITS:
US IDLH (PPM): 3300 PPM
USA - NIOSH - OCCUPATIONAL EXPOSURE LIMITS:
NIOSH REL (TWA) (MG/M3): 1900 MG/M3
NIOSH REL (TWA) (PPM): 1000 PPM
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
USA - ACGIH - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: 2-PROPANOL
ACGIH TWA (PPM): 200 PPM
ACGIH STEL (PPM): 400 PPM
REMARK (ACGIH):
TLV(R*) BASIS: EYE & URT IRR; CNS IMPAIR.
NOTATIONS: A4 (NOT CLASSIFIABLE AS A HUMAN CARCINOGEN); BEI
REGULATORY REFERENCE: ACGIH 2020
USA - ACGIH - BIOLOGICAL EXPOSURE INDICES:
LOCAL NAME: 2-PROPANOL
BIOLOGICAL EXPOSURE INDICES (BEI):
40 MG/L PARAMETER: ACETONE - MEDIUM: URINE - SAMPLING TIME: END OF SHIFT AT
END OF WORKWEEK - NOTATIONS: B, NS
REGULATORY REFERENCE: ACGIH 2020
USA - OSHA - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: ISOPROPYL ALCOHOL
OSHA PEL (TWA) (MG/M3): 980 MG/M3
OSHA PEL (TWA) (PPM): 400 PPM
REGULATORY REFERENCE (US-OSHA): OSHA ANNOTATED TABLE Z-1
USA - IDLH - OCCUPATIONAL EXPOSURE LIMITS:
US IDLH (PPM): 2000 PPM
USA - NIOSH - OCCUPATIONAL EXPOSURE LIMITS:
NIOSH REL (TWA) (MG/M3): 980 MG/M3
NIOSH REL (TWA) (PPM): 400 PPM
NIOSH REL (STEL) (MG/M3): 1225 MG/M3
NIOSH REL (STEL) (PPM): 500 PPM
METHANOL (67-56-1):
USA - ACGIH - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: METHANOL
ACGIH TWA (PPM): 200 PPM
ACGIH STEL (PPM): 250 PPM
REMARK (ACGIH):
TLV(R*) BASIS: HEADACHE; EYE DAM; DIZZINESS; NAUSEA.
NOTATIONS: SKIN; BEI
REGULATORY REFERENCE: ACGIH 2020
USA - ACGIH - BIOLOGICAL EXPOSURE INDICES:
LOCAL NAME: METHANOL
BIOLOGICAL EXPOSURE INDICES (BEI):
15 MG/L PARAMETER: METHANOL - MEDIUM: URINE - SAMPLING TIME: END OF SHIFT -
NOTATIONS: B, NS
REGULATORY REFERENCE: ACGIH 2020
USA - OSHA - OCCUPATIONAL EXPOSURE LIMITS:
LOCAL NAME: METHYL ALCOHOL
OSHA PEL (TWA) (MG/M3): 260 MG/M3
OSHA PEL (TWA) (PPM): 200 PPM
REGULATORY REFERENCE (US-OSHA): OSHA ANNOTATED TABLE Z-1
USA - IDLH - OCCUPATIONAL EXPOSURE LIMITS:
US IDLH (PPM): 6000 PPM
USA - NIOSH - OCCUPATIONAL EXPOSURE LIMITS:
NIOSH REL (TWA) (MG/M3): 250 MG/M3
NIOSH REL (TWA) (PPM): 200 PPM
NIOSH REL (STEL) (MG/M3): 325 MG/M3
NIOSH REL (STEL) (PPM): 250 PPM
REMARK (NIOSH): SKIN
WATER (7732-18-5): NO ADDITIONAL INFORMATION AVAILABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST
VENTILATION.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT: GLOVES. SAFETY GLASSES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NOT REQUIRED IN NORMAL CONDITIONS
PERSONAL PROTECTIVE EQUIPMENT SYMBOL(S):
GLOVES
SAFETY GLASSES
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): FLAMMABLE LIQUID AND VAPOR.
VAPOR PRESSURE: 59 HPA
VAPOR PRESSURE AT 50 DEG. C: 300 HPA
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 0.95 G/ML
SOLUBILITY: SOLUBLE IN WATER. SOLUBLE IN METHANOL. SOLUBLE IN ACETONE.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: 363 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: 2.9 MM2/S
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS:
3.3 - 19 VOL %
67 - 290 G/M3
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 49.5 %
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: REACTS EXOTHERMICALLY WITH (STRONG) OXIDIZERS.
10.2. CHEMICAL STABILITY:
FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
MAY REACT VIOLENTLY WITH OXIDANTS.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
OVERHEATING. HEAT. SPARKS.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE. CARBON DIOXIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY (ORAL): NOT CLASSIFIED
ACUTE TOXICITY (DERMAL): NOT CLASSIFIED
ACUTE TOXICITY (INHALATION): NOT CLASSIFIED
ETHANOL (64-17-5):
LD50 ORAL RAT:
10740 MG/KG (RAT; EXPERIMENTAL VALUE, RAT; EXPERIMENTAL VALUE)
LD50 DERMAL RABBIT: >16000 MG/KG (RABBIT, LITERATURE STUDY, DERMAL)
LC50 INHALATION RAT (MG/L):
117 - 125 MG/L AIR (EQUIVALENT OR SIMILAR TO OECD 403, 4 H, RAT, MALE /
FEMALE, EXPERIMENTAL VALUE, INHALATION)
ATE US (ORAL): 10740 MG/KG BODY WEIGHT
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LD50 ORAL RAT:
5840 MG/KG BODY WEIGHT (EQUIVALENT OR SIMILAR TO OECD 401, RAT,
EXPERIMENTAL VALUE, ORAL, 14 DAY(S))
LD50 DERMAL RABBIT:
16400 MG/KG BODY WEIGHT (EQUIVALENT OR SIMILAR TO OECD 402, 24 H, RABBIT,
EXPERIMENTAL VALUE, DERMAL, 14 DAY(S))
LC50 INHALATION RAT (PPM):
>10000 PPM (EQUIVALENT OR SIMILAR TO OECD 403, 6 H, RAT, MALE / FEMALE,
EXPERIMENTAL VALUE, INHALATION (VAPORS), 14 DAY(S))
ATE US (ORAL): 5840 MG/KG BODY WEIGHT
ATE US (DERMAL): 16400 MG/KG BODY WEIGHT
METHANOL (67-56-1):
LD50 ORAL RAT:
1187 - 2769 MG/KG BODY WEIGHT (BASF TEST, RAT, MALE / FEMALE, WEIGHT OF
EVIDENCE, AQUEOUS SOLUTION, ORAL, 7 DAY(S))
LD50 DERMAL RABBIT:
17100 MG/KG (RABBIT, INCONCLUSIVE, INSUFFICIENT DATA, DERMAL)
LC50 INHALATION RAT (MG/L):
128.2 MG/L AIR (BASF TEST, 4 H, RAT, MALE / FEMALE, EXPERIMENTAL VALUE,
INHALATION (VAPORS))
ATE US (ORAL): 100 MG/KG BODY WEIGHT
ATE US (DERMAL): 300 MG/KG BODY WEIGHT
ATE US (GASES): 700 PPMV/4H
ATE US (VAPORS): 3 MG/L/4H
ATE US (DUST, MIST): 0.5 MG/L/4H
WATER (7732-18-5):
LD50 ORAL RAT: >/=90000 MG/KG
ATE US (ORAL): 90000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: MAY CAUSE CANCER.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING THE UNBORN CHILD. (ORAL).
STOT-SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE) (ORAL,
DERMAL).
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
STOT-SINGLE EXPOSURE: MAY CAUSE RESPIRATORY IRRITATION.
METHANOL (67-56-1):
STOT-SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS (LIVER, KIDNEYS, CENTRAL NERVOUS SYSTEM, OPTIC
NERVE) (DERMAL, ORAL).
STOT-REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
VISCOSITY, KINEMATIC: 2.9 MM2/S
LIKELY ROUTES OF EXPOSURE: INHALATION. SKIN AND EYE CONTACT.
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/EFFECTS:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CAUSES DAMAGE TO
ORGANS.
SYMPTOMS/EFFECTS AFTER INHALATION: MAY CAUSE CANCER BY INHALATION.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
PHENOLPHTHALEIN, ACS (77-09-8):
EC50 DAPHNIA 1:
>100 MG/L (OECD 202: DAPHNIA SP. ACUTE IMMOBILIZATION TEST, 48 H, DAPHNIA
MAGNA, STATIC SYSTEM, FRESH WATER, EXPERIMENTAL VALUE, GLP)
ETHANOL (64-17-5):
LC50 FISH 1:
14200 MG/L (US EPA, 96 H, PIMEPHALES PROMELAS, FLOW-THROUGH SYSTEM, FRESH
WATER, EXPERIMENTAL VALUE)
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LC50 FISH 1:
9640 - 10000 MG/L (EQUIVALENT OR SIMILAR TO OECD 203, 96 H, PIMEPHALES
PROMELAS, FLOW-THROUGH SYSTEM, FRESH WATER, EXPERIMENTAL VALUE, LETHAL)
METHANOL (67-56-1):
LC50 FISH 1:
15400 MG/L (EPA 660/3 - 75/009, 96 H, LEPOMIS MACROCHIRUS, FLOW-THROUGH
SYSTEM, FRESH WATER, EXPERIMENTAL VALUE, LETHAL)
EC50 DAPHNIA 1:
18260 MG/L (OECD 202: DAPHNIA SP. ACUTE IMMOBILIZATION TEST, 96 H, DAPHNIA
MAGNA, SEMI-STATIC SYSTEM, FRESH WATER, EXPERIMENTAL VALUE, LOCOMOTOR
EFFECT)
ERC50 (ALGAE):
22000 MG/L (OECD 201: ALGA, GROWTH INHIBITION TEST, 96 H,
PSEUDOKIRCHNERIELLA SUBCAPITATA, STATIC SYSTEM, FRESH WATER, EXPERIMENTAL
VALUE)
12.2. PERSISTENCE AND DEGRADABILITY:
PHENOLPHTHALEIN, 0.5% IN 50% ETHANOL:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
PHENOLPHTHALEIN, ACS (77-09-8):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE IN WATER.
ETHANOL (64-17-5):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABLE IN THE SOIL. READILY BIODEGRADABLE IN WATER.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.8 - 0.967 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.7 G O2/G SUBSTANCE
THOD: 2.1 G O2/G SUBSTANCE
BOD (% OF THOD): 0.43
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN THE SOIL UNDER ANAEROBIC
CONDITIONS. READILY BIODEGRADABLE IN WATER.
BIOCHEMICAL OXYGEN DEMAND (BOD): 1.19 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.23 G O2/G SUBSTANCE
THOD: 2.4 G O2/G SUBSTANCE
METHANOL (67-56-1):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN THE SOIL. READILY BIODEGRADABLE IN WATER.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.6 - 1.12 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.42 G O2/G SUBSTANCE
THOD: 1.5 G O2/G SUBSTANCE
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
PHENOLPHTHALEIN, 0.5% IN 50% ETHANOL:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
PHENOLPHTHALEIN, ACS (77-09-8):
LOG POW: 2.41 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL:
LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
ETHANOL (64-17-5):
BCF FISH 1:
1 (OTHER, 72 H, CYPRINUS CARPIO, STATIC SYSTEM, FRESH WATER, READ-ACROSS)
LOG POW: -0.31 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LOG POW: 0.05 (WEIGHT OF EVIDENCE APPROACH, 25 DEG. C)
BIOACCUMULATIVE POTENTIAL:
LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
METHANOL (67-56-1):
BCF FISH 1:
1 - 4.5 (72 H, CYPRINUS CARPIO, STATIC SYSTEM, FRESH WATER, EXPERIMENTAL
VALUE)
LOG POW: -0.77 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL:
LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
PHENOLPHTHALEIN, ACS (77-09-8):
ECOLOGY - SOIL:
NO (TEST)DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE.
ETHANOL (64-17-5):
SURFACE TENSION: 0.022 N/M (20 DEG. C)
ECOLOGY - SOIL: HIGHLY MOBILE IN SOIL.
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
SURFACE TENSION: 0.021 N/M (25 DEG. C)
LOG KOC: 0.185 - 0.541 (LOG KOC, SRC PCKOCWIN V2.0, CALCULATED VALUE)
ECOLOGY - SOIL: HIGHLY MOBILE IN SOIL.
METHANOL (67-56-1):
SURFACE TENSION: 0.023 N/M (20 DEG. C)
LOG KOC: 0.088 (LOG KOC, SRC PCKOCWIN V2.0, CALCULATED VALUE)
ECOLOGY - SOIL: HIGHLY MOBILE IN SOIL.
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1170 ETHANOL SOLUTIONS, 3, III
UN-NO.(DOT): UN1170
PROPER SHIPPING NAME (DOT): ETHANOL SOLUTIONS
TRANSPORT HAZARD CLASS(ES) (DOT):
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
PACKING GROUP (DOT): III - MINOR DANGER
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SPECIAL PROVISIONS (49 CFR 172.102):
24 - ALCOHOLIC BEVERAGES CONTAINING MORE THAN 70 PERCENT ALCOHOL BY VOLUME
MUST BE TRANSPORTED AS MATERIALS IN PACKING GROUP II. ALCOHOLIC BEVERAGES
CONTAINING MORE THAN 24 PERCENT BUT NOT MORE THAN 70 PERCENT ALCOHOL BY
VOLUME MUST BE TRANSPORTED AS MATERIALS IN PACKING GROUP III.
IB2 - AUTHORIZED IBCS: METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND
31H2); COMPOSITE (31HZ1).
ADDITIONAL REQUIREMENT:
ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C
(1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED.
T4 - 2.65 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 4B;150
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
TRANSPORT BY SEA:
TRANSPORT DOCUMENT DESCRIPTION (IMDG):
UN 1170 ETHANOL (ETHYL ALCOHOL), 3, II
UN-NO. (IMDG): 1170
PROPER SHIPPING NAME (IMDG): ETHANOL (ETHYL ALCOHOL)
CLASS (IMDG): 3 - FLAMMABLE LIQUIDS
PACKING GROUP (IMDG): II - SUBSTANCES PRESENTING MEDIUM DANGER
LIMITED QUANTITIES (IMDG): 1 L
AIR TRANSPORT:
TRANSPORT DOCUMENT DESCRIPTION (IATA): UN 1170 ETHANOL SOLUTION, 3, II
UN-NO. (IATA): 1170
PROPER SHIPPING NAME (IATA): ETHANOL SOLUTION
CLASS (IATA): 3 - FLAMMABLE LIQUIDS
PACKING GROUP (IATA): II - MEDIUM DANGER
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
PHENOLPHTHALEIN, 0.5% IN 50% ETHANOL:
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD: FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARD: CARCINOGENICITY
HEALTH HAZARD: REPRODUCTIVE TOXICITY
HEALTH HAZARD: SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
PHENOLPHTHALEIN, ACS CAS-NO. 77-09-8 0.5%
ISOPROPYL ALCOHOL (2-PROPANOL) CAS-NO. 67-63-0 2.4875%
METHANOL CAS-NO. 67-56-1 2.363125%
PHENOLPHTHALEIN, ACS (77-09-8):
SARA SECTION 311/312 HAZARD CLASSES: HEALTH HAZARD - CARCINOGENICITY
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0)
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD - FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARD - SERIOUS EYE DAMAGE OR EYE IRRITATION
HEALTH HAZARD - SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED
EXPOSURE)
METHANOL (67-56-1):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD: FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARD: ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
HEALTH HAZARD: SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
15.2. INTERNATIONAL REGULATIONS:
CANADA:
PHENOLPHTHALEIN, ACS (77-09-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
METHANOL (67-56-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WATER (7732-18-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
ETHANOL (64-17-5):
LISTED ON IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
15.3. US STATE REGULATIONS:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO PHENOLPHTHALEIN, ACS, WHICH IS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CANCER, AND METHANOL, WHICH IS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR
MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
| SECTION 16: OTHER INFORMATION | |
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
REVISION DATE: 07/21/2020
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H226: FLAMMABLE LIQUID AND VAPOR
H301: TOXIC IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H319: CAUSES SERIOUS EYE IRRITATION
H331: TOXIC IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H350: MAY CAUSE CANCER
H351: SUSPECTED OF CAUSING CANCER
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H370: CAUSES DAMAGE TO ORGANS
NFPA HEALTH HAZARD 3 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SERIOUS OR PERMANENT INJURY.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 3 SERIOUS HAZARD - MAJOR INJURY LIKELY UNLESS PROMPT
ACTION IS TAKEN AND MEDICAL TREATMENT IS GIVEN
* - CHRONIC (LONG-TERM) HEALTH EFFECTS MAY RESULT FROM
REPEATED OVEREXPOSURE
FLAMMABILITY 3 SERIOUS HAZARD - MATERIALS CAPABLE OF IGNITION UNDER
ALMOST ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73 F AND
BOILING POINTS ABOVE 100 F. AS WELL AS LIQUIDS WITH
FLASH POINTS BETWEEN 73 F AND 100 F. (CLASSES IB &
IC)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION H
H - SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, VAPOR
RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)