| Common Name: | BUFFER SOLUTION PH 11.00 |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 12/20/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 8GE98, 9FKW6, 9TEM3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LSS
BUFFER SOLUTION PH 11.00
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 12/09/2013
REVISION DATE: 12/20/2016
SUPERSEDES: 12/09/2013
VERSION: 1.1
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURE
PRODUCT NAME: BUFFER SOLUTION PH 11.00
PRODUCT CODE: 8GE98, 9TEM3, 9FKW6
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE:
FOR LABORATORY AND MANUFACTURING USE ONLY.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
W. W. GRAINGER INC.
LAKE FOREST, IL 60045
U.S.A.
T: 1-800-356-0783
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER: 1-800-535-5053
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION: NOT CLASSIFIED
2.2. LABEL ELEMENTS: NOT CLASSIFIED AS A HAZARDOUS CHEMICAL.
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
WATER (CAS NO) 7732-18-5 99.64 NOT CLASSIFIED
SODIUM PHOSPHATE, (CAS NO) 7558-79-4 0.35 EYE IRRIT. 2B, H320
DIBASIC, ANHYDROUS
SODIUM HYDROXIDE (CAS NO) 1310-73-2 0.01 ACUTE TOX. 4 (DERMAL), H312
SKIN CORR. 1A, H314
EYE DAM. 1, H318
AQUATIC ACUTE 3, H402
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ALLOW VICTIM TO BREATHE FRESH AIR. ALLOW THE VICTIM TO REST.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE AFFECTED CLOTHING AND WASH ALL EXPOSED SKIN AREA WITH MILD SOAP AND
WATER, FOLLOWED BY WARM WATER RINSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER. OBTAIN MEDICAL ATTENTION IF PAIN,
BLINKING OR REDNESS PERSIST.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES:
NOT EXPECTED TO PRESENT A SIGNIFICANT HAZARD UNDER ANTICIPATED CONDITIONS
OF NORMAL USE.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO ADDITIONAL INFORMATION AVAILABLE
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: SAFETY GLASSES. GLOVES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR.
HYGIENE MEASURES: WASH CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS: KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS. SILVER NITRATE. STRONG ACIDS.
INCOMPATIBLE MATERIALS: INCOMPATIBLE MATERIALS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
SODIUM PHOSPHATE, DIBASIC, ANHYDROUS (7558-79-4): NOT APPLICABLE
WATER (7732-18-5): NOT APPLICABLE
SODIUM HYDROXIDE (1310-73-2):
ACGIH:
ACGIH CEILING (MG/M3):
2 MG/M3 (SODIUM HYDROXIDE; USA; MOMENTARY VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 2 MG/M3
IDLH:
US IDLH (MG/M3): 10 MG/M3
SODIUM HYDROXIDE (1310-73-2):
NIOSH:
NIOSH REL (CEILING) (MG/M3): 2 MG/M3
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE.
PERSONAL PROTECTIVE EQUIPMENT:
SAFETY GLASSES.
GLOVES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NOT REQUIRED IN NORMAL CONDITIONS.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: NONE.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 11
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 1 G/ML
SOLUBILITY: MISCIBLE WITH WATER.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE.
OXIDIZING PROPERTIES: NONE.
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
INCOMPATIBLE MATERIALS. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS:
SILVER NITRATE. STRONG OXIDIZERS. STRONG ACIDS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
PHOSPHINE. PHOSPHORUS OXIDES. PHOSGENE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
SODIUM PHOSPHATE, DIBASIC, ANHYDROUS (7558-79-4):
LD50 ORAL RAT: 5950 MG/KG
LD50 DERMAL RABBIT: >/= 7940 MG/KG
ATE US (ORAL): 5950.000 MG/KG BODY WEIGHT
ATE US (DERMAL): 7940.000 MG/KG BODY WEIGHT
WATER (7732-18-5):
LD50 ORAL RAT: >/= 90000 MG/KG
ATE US (ORAL): 90000.000 MG/KG BODY WEIGHT
SODIUM HYDROXIDE (1310-73-2):
ATE US (DERMAL): 1350.000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: 11
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: 11
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
SODIUM PHOSPHATE, DIBASIC, ANHYDROUS (7558-79-4):
LC50 FISH 1: >/= 100 MG/L
EC50 DAPHNIA 1: >/= 100 MG/L
SODIUM HYDROXIDE (1310-73-2):
LC50 FISH 1:
45.4 MG/L (LC50; OTHER; 96 H; SALMO GAIRDNERI; STATIC SYSTEM; FRESH WATER;
EXPERIMENTAL VALUE)
12.2. PERSISTENCE AND DEGRADABILITY:
BUFFER SOLUTION PH 11.00:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
SODIUM PHOSPHATE, DIBASIC, ANHYDROUS (7558-79-4):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
SODIUM HYDROXIDE (1310-73-2):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY:
NOT APPLICABLE. NO TEST DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
12.3. BIOACCUMULATIVE POTENTIAL:
BUFFER SOLUTION PH 11.00:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
SODIUM PHOSPHATE, DIBASIC, ANHYDROUS (7558-79-4):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
SODIUM HYDROXIDE (1310-73-2):
BIOACCUMULATIVE POTENTIAL: NO BIOACCUMULATION DATA AVAILABLE.
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT: NOT REGULATED
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
SODIUM PHOSPHATE, DIBASIC, ANHYDROUS (7558-79-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
NOT SUBJECT TO REPORTING REQUIREMENTS OF THE UNITED STATES SARA SECTION 313
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
WATER (7732-18-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SODIUM HYDROXIDE (1310-73-2):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
NOT SUBJECT TO REPORTING REQUIREMENTS OF THE UNITED STATES SARA SECTION 313
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 1000 LB
SARA SECTION 311/312 HAZARD CLASSES: IMMEDIATE (ACUTE) HEALTH HAZARD
15.2. INTERNATIONAL REGULATIONS:
CANADA:
BUFFER SOLUTION PH 11.00:
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
SODIUM PHOSPHATE, DIBASIC, ANHYDROUS (7558-79-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
WATER (7732-18-5):
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
SODIUM HYDROXIDE (1310-73-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST):
WHMIS CLASSIFICATION: CLASS E - CORROSIVE MATERIAL
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
SODIUM PHOSPHATE, DIBASIC, ANHYDROUS (7558-79-4):
NOT LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 12/20/2016
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES:
SEE SECTION 16:
H312: HARMFUL IN CONTACT WITH SKIN
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H318: CAUSES SERIOUS EYE DAMAGE
H320: CAUSES EYE IRRITATION
H402: HARMFUL TO AQUATIC LIFE
NFPA HEALTH HAZARD 1 - EXPOSURE COULD CAUSE IRRITATION BUT ONLY MINOR
RESIDUAL INJURY EVEN IF NO TREATMENT IS GIVEN.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
HMIS III RATING:
HEALTH 1 SLIGHT HAZARD - IRRITATION OR MINOR REVERSIBLE INJURY
POSSIBLE
FLAMMABILITY 0 MINIMAL HAZARD - MATERIALS THAT WILL NOT BURN
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION B B - SAFETY GLASSES, GLOVES
SDS US GRAINGER
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING ANY
SPECIFIC PROPERTY OF THE PRODUCT
EN (ENGLISH US)