| Common Name: | ACETONE |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 4/24/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 5CVU3, 9TYX9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
ACETONE
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 11/12/1998
REVISION DATE: 04/24/2018
SUPERSEDES: 04/24/2018
VERSION: 1.3
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: SUBSTANCE
SUBSTANCE NAME: ACETONE
CHEMICAL NAME: 2-PROPANONE
CAS-NO.: 67-64-1
PRODUCT CODE: LC10420, LC10425
FORMULA: C3H6O
SYNONYMS:
2-PROPANONE / BETA-KETOPROPANE / DIMETHYL FORMALDEHYDE / DIMETHYL KETONE /
DIMETHYLKETAL / DMK (=DIMETHYL KETONE) / KETO PROPANE / METHYL KETONE /
PYROACETIC ACID / PYROACETIC ETHER / PYROACETIC SPIRIT
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE:
SOLVENT
CLEANING PRODUCT
CHEMICAL RAW MATERIAL
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM, INC.
JACKSON'S POINTE COMMERCE PARK BUILDING 1000, 1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR +1-703-741-5970
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAMMABLE LIQUIDS CATEGORY 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A:
H319: CAUSES SERIOUS EYE IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3:
H336: MAY CAUSE DROWSINESS OR DIZZINESS
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS US LABELING:
HAZARD PICTOGRAMS (GHS US):
GHS02: FLAME
GHS07: EXCLAMATION MARK
SIGNAL WORD (GHS US): DANGER
HAZARD STATEMENTS (GHS US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H319: CAUSES SERIOUS EYE IRRITATION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
PRECAUTIONARY STATEMENTS (GHS US):
P210: KEEP AWAY FROM HEAT, HOT SURFACES, OPEN FLAMES, SPARKS. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL, LIGHTING, VENTILATING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P261: AVOID BREATHING MIST, SPRAY, VAPORS.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR EYE PROTECTION, FACE PROTECTION, PROTECTIVE CLOTHING, PROTECTIVE
GLOVES.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P370+P378:
IN CASE OF FIRE:
USE DRY CHEMICAL POWDER, ALCOHOL-RESISTANT FOAM, CARBON DIOXIDE (CO2) TO
EXTINGUISH
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
P235: KEEP COOL.
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES:
SUBSTANCE TYPE: MONO-CONSTITUENT
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
ACETONE (MAIN CONSTITUENT) (CAS-NO.) 67-64-1 100 FLAM. LIQ. 2, H225
EYE IRRIT. 2A, H319
STOT SE 3, H336
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
3.2. MIXTURES: NOT APPLICABLE
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
CHECK THE VITAL FUNCTIONS. UNCONSCIOUS: MAINTAIN ADEQUATE AIRWAY AND
RESPIRATION. RESPIRATORY ARREST: ARTIFICIAL RESPIRATION OR OXYGEN. CARDIAC
ARREST: PERFORM RESUSCITATION. VICTIM CONSCIOUS WITH LABORED BREATHING:
HALF-SEATED. VICTIM IN SHOCK: ON HIS BACK WITH LEGS SLIGHTLY RAISED.
VOMITING: PREVENT ASPHYXIA/ASPIRATION PNEUMONIA. PREVENT COOLING BY
COVERING THE VICTIM (NO WARMING UP). KEEP WATCHING THE VICTIM. GIVE
PSYCHOLOGICAL AID. KEEP THE VICTIM CALM, AVOID PHYSICAL STRAIN. DEPENDING
ON THE VICTIM'S CONDITION: DOCTOR/HOSPITAL.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE THE VICTIM INTO FRESH AIR. RESPIRATORY PROBLEMS: CONSULT A
DOCTOR/MEDICAL SERVICE.
FIRST-AID MEASURES AFTER SKIN CONTACT:
WASH IMMEDIATELY WITH LOTS OF WATER. SOAP MAY BE USED. DO NOT APPLY
(CHEMICAL) NEUTRALIZING AGENTS. REMOVE CLOTHING BEFORE WASHING. TAKE VICTIM
TO A DOCTOR IF IRRITATION PERSISTS.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER. REMOVE CONTACT LENSES, IF PRESENT
AND EASY TO DO. CONTINUE RINSING. DO NOT APPLY NEUTRALIZING AGENTS. TAKE
VICTIM TO AN OPHTHALMOLOGIST IF IRRITATION PERSISTS.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH WITH WATER. IMMEDIATELY AFTER INGESTION: GIVE LOTS OF
WATER TO DRINK. DO NOT GIVE MILK/OIL TO DRINK. DO NOT INDUCE VOMITING.
GIVE ACTIVATED CHARCOAL. CALL POISON INFORMATION CENTRE
(WWW.BIG.BE/ANTIGIF.HTM). CONSULT A DOCTOR/MEDICAL SERVICE IF YOU FEEL
UNWELL. INGESTION OF LARGE QUANTITIES: IMMEDIATELY TO HOSPITAL. DOCTOR:
GASTRIC LAVAGE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS:
NOT EXPECTED TO PRESENT A SIGNIFICANT HAZARD UNDER ANTICIPATED CONDITIONS
OF NORMAL USE.
SYMPTOMS/EFFECTS AFTER INHALATION:
EXPOSURE TO HIGH CONCENTRATIONS:
FEELING OF WEAKNESS. IRRITATION OF THE RESPIRATORY TRACT. NAUSEA. VOMITING.
HEADACHE. CENTRAL NERVOUS SYSTEM DEPRESSION. DIZZINESS. NARCOSIS.
EXCITED/RESTLESS. DRUNKENNESS. DISTURBED MOTOR RESPONSE. RESPIRATORY
DIFFICULTIES. DISTURBANCES OF CONSCIOUSNESS.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
ON CONTINUOUS EXPOSURE/CONTACT: DRY SKIN. CRACKING OF THE SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: IRRITATION OF THE EYE TISSUE.
SYMPTOMS/EFFECTS AFTER INGESTION:
DRY/SORE THROAT. RISK OF ASPIRATION PNEUMONIA. SYMPTOMS SIMILAR TO THOSE
LISTED UNDER INHALATION. AFTER ABSORPTION OF LARGE QUANTITIES: IRRITATION
OF THE GASTRIC/INTESTINAL MUCOSA. CHANGE IN THE BLOOD COMPOSITION. CHANGE
IN URINE OUTPUT. RENAL DISEASE. ENLARGEMENT/DISEASE OF THE LIVER.
SYMPTOMS/EFFECTS UPON INTRAVENOUS ADMINISTRATION: NOT AVAILABLE.
CHRONIC SYMPTOMS:
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
RED SKIN. SKIN RASH/INFLAMMATION. DRY/SORE THROAT. HEADACHE. NAUSEA.
FEELING OF WEAKNESS. LOSS OF WEIGHT. POSSIBLE INFLAMMATION OF THE
RESPIRATORY TRACT.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
QUICK-ACTING ABC POWDER EXTINGUISHER. QUICK-ACTING BC POWDER EXTINGUISHER.
QUICK-ACTING CLASS B FOAM EXTINGUISHER. QUICK-ACTING CO2 EXTINGUISHER.
CLASS B FOAM (ALCOHOL-RESISTANT). WATER SPRAY IF PUDDLE CANNOT EXPAND.
UNSUITABLE EXTINGUISHING MEDIA:
WATER (QUICK-ACTING EXTINGUISHER, REEL); RISK OF PUDDLE EXPANSION. WATER;
RISK OF PUDDLE EXPANSION.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD:
DIRECT FIRE HAZARD. HIGHLY FLAMMABLE LIQUID AND VAPOUR. GAS/VAPOR FLAMMABLE
WITH AIR WITHIN EXPLOSION LIMITS. INDIRECT FIRE HAZARD. MAY BE IGNITED BY
SPARKS. GAS/VAPOR SPREADS AT FLOOR LEVEL: IGNITION HAZARD. REACTIONS
INVOLVING A FIRE HAZARD: SEE "REACTIVITY HAZARD".
EXPLOSION HAZARD:
DIRECT EXPLOSION HAZARD. GAS/VAPOUR EXPLOSIVE WITH AIR WITHIN EXPLOSION
LIMITS. INDIRECT EXPLOSION HAZARD. HEAT MAY CAUSE PRESSURE RISE IN
TANKS/DRUMS: EXPLOSION RISK. MAY BE IGNITED BY SPARKS. REACTIONS WITH
EXPLOSION HAZARDS: SEE "REACTIVITY HAZARD".
REACTIVITY:
VIOLENT TO EXPLOSIVE REACTION WITH MANY COMPOUNDS. PROLONGED STORAGE: ON
EXPOSURE TO LIGHT: RELEASE OF HARMFUL GASES/VAPOURS.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
COOL TANKS/DRUMS WITH WATER SPRAY/REMOVE THEM INTO SAFETY.
PHYSICAL EXPLOSION RISK:
EXTINGUISH/COOL FROM BEHIND COVER. DO NOT MOVE THE LOAD IF EXPOSED TO
HEAT. AFTER COOLING: PERSISTANT RISK OF PHYSICAL EXPLOSION.
PROTECTION DURING FIREFIGHTING:
HEAT/FIRE EXPOSURE: COMPRESSED AIR/OXYGEN APPARATUS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
GLOVES. PROTECTIVE GOGGLES. PROTECTIVE CLOTHING. LARGE SPILLS/IN ENCLOSED
SPACES: COMPRESSED AIR APPARATUS.
EMERGENCY PROCEDURES:
KEEP UPWIND. MARK THE DANGER AREA. CONSIDER EVACUATION. SEAL OFF LOW-LYING
AREAS. CLOSE DOORS AND WINDOWS OF ADJACENT PREMISES. STOP ENGINES AND NO
SMOKING. NO NAKED FLAMES OR SPARKS. SPARK-AND EXPLOSION-PROOF APPLIANCES
AND LIGHTING EQUIPMENT. KEEP CONTAINERS CLOSED. WASH CONTAMINATED CLOTHES.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS: PREVENT SPREADING IN SEWERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. PLUG THE LEAK,
CUT OFF THE SUPPLY. DAM UP THE LIQUID SPILL. TRY TO REDUCE EVAPORATION.
MEASURE THE CONCENTRATION OF THE EXPLOSIVE GAS-AIR MIXTURE. DILUTE/DISPERSE
COMBUSTIBLE GAS/VAPOUR WITH WATER CURTAIN. PROVIDE EQUIPMENT/RECEPTACLES
WITH EARTHING. DO NOT USE COMPRESSED AIR FOR PUMPING OVER SPILLS.
METHODS FOR CLEANING UP:
TAKE UP LIQUID SPILL INTO INERT ABSORBENT MATERIAL, E.G.: SAND, EARTH,
VERMICULITE. SCOOP ABSORBED SUBSTANCE INTO CLOSING CONTAINERS. SPILL
MUST NOT RETURN IN ITS ORIGINAL CONTAINER. CAREFULLY COLLECT THE
SPILL/LEFTOVERS. DAMAGED/COOLED TANKS MUST BE EMPTIED. DO NOT USE
COMPRESSED AIR FOR PUMPING OVER SPILLS. CLEAN CONTAMINATED SURFACES
WITH AN EXCESS OF WATER. TAKE COLLECTED SPILL TO MANUFACTURER/COMPETENT
AUTHORITY. WASH CLOTHING AND EQUIPMENT AFTER HANDLING.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
USE SPARK-/EXPLOSIONPROOF APPLIANCES AND LIGHTING SYSTEM. TAKE PRECAUTIONS
AGAINST ELECTROSTATIC CHARGES. KEEP AWAY FROM NAKED FLAMES/HEAT. KEEP AWAY
FROM IGNITION SOURCES/SPARKS. MEASURE THE CONCENTRATION IN THE AIR
REGULARLY. WORK UNDER LOCAL EXHAUST/VENTILATION. COMPLY WITH THE LEGAL
REQUIREMENTS. REMOVE CONTAMINATED CLOTHING IMMEDIATELY. CLEAN CONTAMINATED
CLOTHING. HANDLE UNCLEANED EMPTY CONTAINERS AS FULL ONES. THOROUGHLY
CLEAN/DRY THE INSTALLATION BEFORE USE. DO NOT DISCHARGE THE WASTE INTO THE
DRAIN. DO NOT USE COMPRESSED AIR FOR PUMPING OVER. KEEP CONTAINER TIGHTLY
CLOSED.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP
AND WATER BEFORE EATING, DRINKING OR SMOKING AND WHEN LEAVING WORK.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: HEAT SOURCES, DIRECT SUNLIGHT, INCOMPATIBLE MATERIALS. KEEP
CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: STRONG BASES. STRONG ACIDS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
STORAGE TEMPERATURE: 15 - 20 DEG. C
HEAT-IGNITION:
KEEP SUBSTANCE AWAY FROM: HEAT SOURCES. IGNITION SOURCES.
PROHIBITIONS ON MIXED STORAGE:
KEEP SUBSTANCE AWAY FROM:
OXIDIZING AGENTS. REDUCING AGENTS. STRONG ACIDS. (STRONG) BASES. HALOGENS.
AMINES.
STORAGE AREA:
STORE IN A COOL AREA. KEEP OUT OF DIRECT SUNLIGHT. STORE IN A DRY AREA.
STORE IN A DARK AREA. VENTILATION AT FLOOR LEVEL. FIREPROOF STOREROOM.
PROVIDE FOR AN AUTOMATIC SPRINKLER SYSTEM. PROVIDE FOR A TUB TO COLLECT
SPILLS. PROVIDE THE TANK WITH EARTHING. MEET THE LEGAL REQUIREMENTS.
SPECIAL RULES ON PACKAGING:
SPECIAL REQUIREMENTS:
CLOSING. WITH PRESSURE RELIEF VALVE. CLEAN. OPAQUE. CORRECTLY LABELLED.
MEET THE LEGAL REQUIREMENTS. SECURE FRAGILE PACKAGINGS IN SOLID CONTAINERS.
PACKAGING MATERIALS:
SUITABLE MATERIAL:
STEEL. STAINLESS STEEL. CARBON STEEL. ALUMINIUM. IRON. COPPER. NICKEL.
BRONZE. GLASS.
MATERIAL TO AVOID: SYNTHETIC MATERIAL.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
ACETONE (67-64-1):
ACGIH:
ACGIH TWA (PPM): 250 PPM
ACGIH:
ACGIH STEL (PPM): 500 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 590 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 250 PPM
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
SAFETY GLASSES. GLOVES. PROTECTIVE CLOTHING. FACE SHIELD.
HIGH GAS/VAPOR CONCENTRATION: GAS MASK WITH FILTER TYPE A.
MATERIALS FOR PROTECTIVE CLOTHING:
GIVE GOOD RESISTANCE: BUTYL RUBBER. TETRAFLUOROETHYLENE.
GIVE LESS RESISTANCE:
CHLOROSULFONATED POLYETHYLENE. NATURAL RUBBER. NEOPRENE. POLYURETHANE. PVA.
STYRENE-BUTADIENE RUBBER.
GIVE POOR RESISTANCE:
NITRILE RUBBER. POLYETHYLENE. PVC. VITON. NITRILE RUBBER/PVC
HAND PROTECTION: GLOVES
EYE PROTECTION: SAFETY GLASSES
SKIN AND BODY PROTECTION: HEAD/NECK PROTECTION. PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
FULL FACE MASK WITH FILTER TYPE AX AT CONC. IN AIR >EXPOSURE LIMIT
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE:
LIQUID.
COLOURLESS
AROMATIC ODOUR SWEET ODOUR FRUITY ODOUR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 7 (10 G/L)
MELTING POINT: -95 DEG. C
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 56 DEG. C
CRITICAL TEMPERATURE: 235 DEG. C
CRITICAL PRESSURE: 47010 HPA
FLASH POINT: -17 DEG. C (CLOSED CUP)
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): 6
RELATIVE EVAPORATION RATE (ETHER=1): 2
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: 247 HPA (20 DEG. C)
VAPOR PRESSURE AT 50 DEG. C: 828 HPA
RELATIVE VAPOR DENSITY AT 20 DEG. C: 2
RELATIVE DENSITY: 0.79
RELATIVE DENSITY OF SATURATED GAS/AIR MIXTURE: 1.2
SPECIFIC GRAVITY / DENSITY: 786 KG/M3
MOLECULAR MASS: 58.08 G/MOL
SOLUBILITY:
SOLUBLE IN WATER. SOLUBLE IN ETHANOL. SOLUBLE IN ETHER. SOLUBLE IN DIMETHYL
ETHER. SOLUBLE IN PETROLEUM SPIRIT. SOLUBLE IN CHLOROFORM. SOLUBLE IN
DIMETHYLFORMAMIDE. SOLUBLE IN OILS/FATS.
WATER: COMPLETE
ETHANOL: COMPLETE
ETHER: COMPLETE
LOG POW: -0.24 (TEST DATA)
AUTO-IGNITION TEMPERATURE: 465 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: 0.417 MM2/S
VISCOSITY, DYNAMIC: 0.32 MPA.S (20 DEG. C)
EXPLOSION LIMITS:
2 - 12.8 VOL %
60 - 310 G/M3
LOWER EXPLOSIVE LIMIT (LEL): 2 VOL %
UEL: 12.8 VOL %
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE.
OXIDIZING PROPERTIES: NONE.
9.2. OTHER INFORMATION:
MINIMUM IGNITION ENERGY: 1.15 MJ
SPECIFIC CONDUCTIVITY: 6000000 PS/M (25 DEG. C)
SATURATION CONCENTRATION: 589 G/M3
VOC CONTENT: 100%
OTHER PROPERTIES:
GAS/VAPOUR HEAVIER THAN AIR AT 20 DEG. C. CLEAR. HIGHLY VOLATILE. NEUTRAL
REACTION.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
VIOLENT TO EXPLOSIVE REACTION WITH MANY COMPOUNDS. PROLONGED STORAGE: ON
EXPOSURE TO LIGHT: RELEASE OF HARMFUL GASES/VAPOURS.
10.2. CHEMICAL STABILITY: UNSTABLE ON EXPOSURE TO LIGHT.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: REACTS WITH (STRONG) OXIDIZERS.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS. STRONG BASES. STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
FUME. CARBON MONOXIDE. CARBON DIOXIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
ACETONE (67-64-1):
LD50 ORAL RAT:
5800 MG/KG (EQUIVALENT OR SIMILAR TO OECD 401, RAT, FEMALE, EXPERIMENTAL
VALUE, ORAL)
LD50 DERMAL RABBIT:
20000 MG/KG (EQUIVALENT OR SIMILAR TO OECD 402, RABBIT, MALE, EXPERIMENTAL
VALUE, DERMAL)
LC50 INHALATION RAT (MG/L):
76 MG/L (OTHER, 4 H, RAT, FEMALE, EXPERIMENTAL VALUE, INHALATION (VAPOURS))
ATE US (ORAL): 5800 MG/KG BODY WEIGHT
ATE US (DERMAL): 20000 MG/KG BODY WEIGHT
ATE US (GASES): 30000 PPMV/4H
ATE US (VAPORS): 71 MG/L/4H
ATE US (DUST, MIST): 71 MG/L/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: 7 (10 G/L)
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
PH: 7 (10 G/L)
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS OR DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/EFFECTS AFTER INHALATION:
EXPOSURE TO HIGH CONCENTRATIONS:
FEELING OF WEAKNESS. IRRITATION OF THE RESPIRATORY TRACT. NAUSEA. VOMITING.
HEADACHE. CENTRAL NERVOUS SYSTEM DEPRESSION. DIZZINESS. NARCOSIS.
EXCITED/RESTLESS. DRUNKENNESS. DISTURBED MOTOR RESPONSE. RESPIRATORY
DIFFICULTIES. DISTURBANCES OF CONSCIOUSNESS.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT:
ON CONTINUOUS EXPOSURE/CONTACT: DRY SKIN. CRACKING OF THE SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: IRRITATION OF THE EYE TISSUE.
SYMPTOMS/EFFECTS AFTER INGESTION:
DRY/SORE THROAT. RISK OF ASPIRATION PNEUMONIA. SYMPTOMS SIMILAR TO THOSE
LISTED UNDER INHALATION.
AFTER ABSORPTION OF LARGE QUANTITIES:
IRRITATION OF THE GASTRIC/INTESTINAL MUCOSA. CHANGE IN THE BLOOD
COMPOSITION. CHANGE IN URINE OUTPUT. RENAL DISEASE. ENLARGEMENT/DISEASE OF
THE LIVER.
SYMPTOMS/EFFECTS UPON INTRAVENOUS ADMINISTRATION: NOT AVAILABLE.
CHRONIC SYMPTOMS:
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
RED SKIN. SKIN RASH/INFLAMMATION. DRY/SORE THROAT. HEADACHE. NAUSEA.
FEELING OF WEAKNESS. LOSS OF WEIGHT. POSSIBLE INFLAMMATION OF THE
RESPIRATORY TRACT.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL:
NOT CLASSIFIED AS DANGEROUS FOR THE ENVIRONMENT ACCORDING TO THE CRITERIA
OF REGULATION (EC) NO 1272/2008.
ECOLOGY - AIR:
NOT INCLUDED IN THE LIST OF SUBSTANCES WHICH MAY CONTRIBUTE TO THE
GREENHOUSE EFFECT (IPCC). NOT INCLUDED IN THE LIST OF FLUORINATED
GREENHOUSE GASES (REGULATION (EU) NO 517/2014). NOT CLASSIFIED AS
DANGEROUS FOR THE OZONE LAYER (REGULATION (EC) NO 1005/2009).
ECOLOGY - WATER:
NOT HARMFUL TO CRUSTACEA. NOT HARMFUL TO FISHES. INHIBITION OF ACTIVATED
SLUDGE. NOT HARMFUL TO ALGAE. NOT HARMFUL TO PLANKTON.
ACETONE (67-64-1):
LC50 FISH 1:
5540 MG/L (EU METHOD C.1, 96 H, SALMO GAIRDNERI, STATIC SYSTEM, FRESH
WATER, EXPERIMENTAL VALUE, NOMINAL CONCENTRATION)
12.2. PERSISTENCE AND DEGRADABILITY:
ACETONE (67-64-1):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN THE SOIL UNDER ANAEROBIC
CONDITIONS. READILY BIODEGRADABLE IN WATER.
BIOCHEMICAL OXYGEN DEMAND (BOD): 1.43 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.92 G O2/G SUBSTANCE
THOD: 2.2 G O2/G SUBSTANCE
BOD (% OF THOD): 0.872 (20 DAY(S), LITERATURE STUDY)
12.3. BIOACCUMULATIVE POTENTIAL:
ACETONE (67-64-1):
BCF FISH 1: 0.69 (PISCES)
BCF OTHER AQUATIC ORGANISMS 1: 3 (BCFWIN, CALCULATED VALUE)
LOG POW: -0.24 (TEST DATA)
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
12.4. MOBILITY IN SOIL:
ACETONE (67-64-1):
SURFACE TENSION: 0.0237 N/M
ECOLOGY - SOIL: NO (TEST)DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE.
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DO NOT DISCHARGE INTO DRAINS OR THE ENVIRONMENT. REMOVE WASTE IN ACCORDANCE
WITH LOCAL AND/OR NATIONAL REGULATIONS. HAZARDOUS WASTE SHALL NOT BE MIXED
TOGETHER WITH OTHER WASTE. DIFFERENT TYPES OF HAZARDOUS WASTE SHALL NOT BE
MIXED TOGETHER IF THIS MAY ENTAIL A RISK OF POLLUTION OR CREATE PROBLEMS
FOR THE FURTHER MANAGEMENT OF THE WASTE. HAZARDOUS WASTE SHALL BE MANAGED
RESPONSIBLY. ALL ENTITIES THAT STORE, TRANSPORT OR HANDLE HAZARDOUS WASTE
SHALL TAKE THE NECESSARY MEASURES TO PREVENT RISKS OF POLLUTION OR DAMAGE
TO PEOPLE OR ANIMALS. RECYCLE BY DISTILLATION. INCINERATE UNDER
SURVEILLANCE WITH ENERGY RECOVERY.
ADDITIONAL INFORMATION:
HAZARDOUS WASTE ACCORDING TO DIRECTIVE 2008/98/EC, AS AMENDED BY REGULATION
(EU) NO 1357/2014 AND REGULATION (EU) NO 2017/997.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1090 ACETONE, 3, II
UN-NO.(DOT): UN1090
PROPER SHIPPING NAME (DOT): ACETONE
TRANSPORT HAZARD CLASS(ES) (DOT):
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB2 - AUTHORIZED IBCS: METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND
31H2); COMPOSITE (31HZ1). ADDITIONAL REQUIREMENT: ONLY LIQUIDS WITH A VAPOR
PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C (1.1 BAR AT 122 F), OR 130
KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED. T4 - 2.65 178.274(D)(2)
NORMAL..... 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 150
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
B - (I) THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO
VESSEL AND ON A PASSENGER VESSEL CARRYING A NUMBER OF PASSENGERS LIMITED TO
NOT MORE THAN THE LARGER OF 25 PASSENGERS, OR ONE PASSENGER PER EACH 3 M OF
OVERALL VESSEL LENGTH; AND (II) "ON DECK ONLY" ON PASSENGER VESSELS IN
WHICH THE NUMBER OF PASSENGERS SPECIFIED IN PARAGRAPH (K)(2)(I) OF THIS
SECTION IS EXCEEDED.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
TRANSPORTATION OF DANGEROUS GOODS:
TRANSPORT DOCUMENT DESCRIPTION: UN1090 ACETONE, 3, II
UN-NO. (TDG): UN1090
PROPER SHIPPING NAME (TRANSPORTATION OF DANGEROUS GOODS): ACETONE
TDG PRIMARY HAZARD CLASSES: 3 - CLASS 3 - FLAMMABLE LIQUIDS
PACKING GROUP: II - MEDIUM DANGER
EXPLOSIVE LIMIT AND LIMITED QUANTITY INDEX: 1 L
PASSENGER CARRYING ROAD VEHICLE OR PASSENGER CARRYING RAILWAY VEHICLE
INDEX: 5 L
PASSENGER CARRYING SHIP INDEX: FORBIDDEN
TRANSPORT BY SEA:
TRANSPORT DOCUMENT DESCRIPTION (IMDG): UN 1090 ACETONE, 3, II
UN-NO. (IMDG): 1090
PROPER SHIPPING NAME (IMDG): ACETONE
CLASS (IMDG): 3 - FLAMMABLE LIQUIDS
PACKING GROUP (IMDG): II - SUBSTANCES PRESENTING MEDIUM DANGER
EMS-NO. (1): F-E
EMS-NO. (2): S-D
AIR TRANSPORT:
TRANSPORT DOCUMENT DESCRIPTION (IATA): UN 1090 ACETONE, 3, II
UN-NO. (IATA): 1090
PROPER SHIPPING NAME (IATA): ACETONE
CLASS (IATA): 3 - FLAMMABLE LIQUIDS
PACKING GROUP (IATA): II - MEDIUM DANGER
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
ACETONE (67-64-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
ACETONE (67-64-1): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
ACETONE (67-64-1): LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR
REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 04/24/2018
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H319: CAUSES SERIOUS EYE IRRITATION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
NFPA HEALTH HAZARD 1 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SIGNIFICANT IRRITATION.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 1 SLIGHT HAZARD - IRRITATION OR MINOR REVERSIBLE INJURY
POSSIBLE
FLAMMABILITY 3 SERIOUS HAZARD - MATERIALS CAPABLE OF IGNITION UNDER
ALMOST ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73 F AND
BOILING POINTS ABOVE 100 F. AS WELL AS LIQUIDS WITH
FLASH POINTS BETWEEN 73 F AND 100 F.
(CLASSES IB & IC)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION C
C - SAFETY GLASSES, GLOVES, SYNTHETIC APRON
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
04/23/2019
EN (ENGLISH US)