| Common Name: | CARBON DIOXIDE |
| Manufacturer: | LINDE GAS |
| SDS Revision Date: | 7/12/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 8PCU1, 8UKR9, 8ZDT4, 9EVC5, 9U221 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
ISSUE DATE: 17-FEB-2015
REVISION DATE: 12-JUL-2016
VERSION: 1.1
THE LINDE GROUP
LINDE
CARBON DIOXIDE
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: CARBON DIOXIDE
OTHER MEANS OF IDENTIFICATION:
SAFETY DATA SHEET NUMBER: LIND-P023
UN/ID NO.: UN1013
SYNONYMS:
LASER CARBON DIOXIDE, LASER CARBON DIOXIDE ULTRA, MAPAX(R*) C, CARBONIC
ANHYDRIDE, CARBONIC ACID GAS, CARBON DIOXIDE USP
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: INDUSTRIAL AND PROFESSIONAL USE.
USES ADVISED AGAINST: CONSUMER USE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LINDE GAS NORTH AMERICA LLC - LINDE MERCHANT PRODUCTION INC. - LINDE LLC
200 SOMERSET CORPORATE BLVD, SUITE 7000
BRIDGEWATER, NJ 08807
PHONE: 908-464-8100
WWW.LINDEUS.COM
LINDE GAS PUERTO RICO, INC.
ROAD 869, KM 1.8
BARRIO PALMAS, CATANO, PR 00962
PHONE: 787-641-7445
WWW.PR.LINDEGAS.COM
LINDE CANADA LIMITED
5860 CHEDWORTH WAY
MISSISSAUGA, ONTARIO L5R 0A2
PHONE: 905-501-2500/905-501-1700
WWW.LINDECANADA.COM
* MAY INCLUDE SUBSIDIARIES OR AFFILIATE COMPANIES/DIVISIONS.
FOR ADDITIONAL PRODUCT INFORMATION CONTACT YOUR LOCAL CUSTOMER SERVICE.
EMERGENCY TELEPHONE NUMBER:
COMPANY PHONE NUMBER:
+1 800-232-4726 (LINDE NATIONAL OPERATIONS CENTER, US)
905-501-0802 (CANADA)
CHEMTREC:
1-800-424-9300 (NORTH AMERICA)
+1-703-527-3887 (INTERNATIONAL)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
OSHA REGULATORY STATUS:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
GASES UNDER PRESSURE: LIQUEFIED GAS
SIMPLE ASPHYXIANTS: YES
LABEL ELEMENTS: GAS CYLINDER
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION
MAY CAUSE FROSTBITE
MAY INCREASE RESPIRATION AND HEART RATE
PRECAUTIONARY STATEMENTS - PREVENTION:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
AVOID BREATHING GAS
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING
USE AND STORE ONLY OUTDOORS OR IN A WELL VENTILATED PLACE
USE A BACKFLOW PREVENTIVE DEVICE IN PIPING
USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE
CLOSE VALVE AFTER EACH USE AND WHEN EMPTY
PRECAUTIONARY STATEMENTS - RESPONSE:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. GET MEDICAL
ATTENTION/ADVICE.
IF ON SKIN:
GET IMMEDIATE MEDICAL ADVICE/ATTENTION. THAW FROSTED PARTS WITH LUKEWARM
WATER. DO NOT RUB AFFECTED AREA.
PRECAUTIONARY STATEMENTS - STORAGE:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C/125 DEG. F
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO. VOLUME % CHEMICAL FORMULA
CARBON DIOXIDE 124-38-9 100 CO2
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE: SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
INHALATION:
REMOVE TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL
RESPIRATION. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
FOR DERMAL CONTACT OR SUSPECTED FROSTBITE, REMOVE CONTAMINATED CLOTHING AND
FLUSH AFFECTED AREAS WITH LUKEWARM WATER. DO NOT USE HOT WATER. A PHYSICIAN
SHOULD SEE THE PATIENT PROMPTLY IF CONTACT WITH THE PRODUCT HAS RESULTED IN
BLISTERING OF THE DERMAL SURFACE OR IN DEEP TISSUE FREEZING.
EYE CONTACT:
IF FROSTBITE IS SUSPECTED, FLUSH EYES WITH COOL WATER FOR 15 MINUTES AND
OBTAIN IMMEDIATE MEDICAL ATTENTION.
INGESTION: NOT AN EXPECTED ROUTE OF EXPOSURE.
SELF-PROTECTION OF THE FIRST AIDER:
RESCUE PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED BREATHING
APPARATUS.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
SIMPLE ASPHYXIANT. MAY CAUSE SUFFOCATION BY DISPLACING THE OXYGEN IN THE
AIR. EXPOSURE TO OXYGEN-DEFICIENT ATMOSPHERE (<19.5%) MAY CAUSE DIZZINESS,
DROWSINESS, NAUSEA, VOMITING, EXCESS SALIVATION, DIMINISHED MENTAL
ALERTNESS, LOSS OF CONSCIOUSNESS AND DEATH. EXPOSURE TO ATMOSPHERES
CONTAINING 8-10% OR LESS OXYGEN WILL BRING ABOUT UNCONSCIOUSNESS WITHOUT
WARNING AND SO QUICKLY THAT THE INDIVIDUALS CANNOT HELP OR PROTECT
THEMSELVES. LACK OF SUFFICIENT OXYGEN MAY CAUSE SERIOUS INJURY OR DEATH.
DEPENDING ON CONCENTRATION AND DURATION OF EXPOSURE TO CARBON DIOXIDE MAY
CAUSE INCREASED RESPIRATIONS, HEADACHE, MILD NARCOTIC EFFECTS, INCREASED
BLOOD PRESSURE AND PULSE, AND ASPHYXIATION. SYMPTOMS OF OVEREXPOSURE BECOME
MORE APPARENT WHEN ATMOSPHERIC OXYGEN IS DECREASED TO 15-17%. CONTACT WITH
LIQUID MAY CAUSE COLD BURNS/FROSTBITE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTE TO PHYSICIANS: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
SPECIFIC EXTINGUISHING METHODS:
CONTINUE TO COOL FIRE EXPOSED CYLINDERS UNTIL FLAMES ARE EXTINGUISHED.
DAMAGED CYLINDERS SHOULD BE HANDLED ONLY BY SPECIALISTS.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
NON-FLAMMABLE GAS. CYLINDERS MAY RUPTURE UNDER EXTREME HEAT.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
EVACUATE PERSONNEL TO SAFE AREAS. ENSURE ADEQUATE VENTILATION, ESPECIALLY
IN CONFINED AREAS. MONITOR OXYGEN LEVEL. WEAR SELF-CONTAINED BREATHING
APPARATUS WHEN ENTERING AREA UNLESS ATMOSPHERE IS PROVED TO BE SAFE.
OTHER INFORMATION:
GAS/VAPOR IS HEAVIER THAN AIR. PREVENT FROM ENTERING SEWERS, BASEMENTS AND
WORKPITS, OR ANY PLACE WHERE ACCUMULATION MAY BE DANGEROUS.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
PREVENT SPREADING OF VAPORS THROUGH SEWERS, VENTILATION SYSTEMS AND
CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP THE FLOW OF GAS OR REMOVE CYLINDER TO OUTDOOR LOCATION IF THIS CAN BE
DONE WITHOUT RISK. IF LEAK IS IN CONTAINER OR CONTAINER VALVE, CONTACT THE
APPROPRIATE EMERGENCY TELEPHONE NUMBER IN SECTION 1 OR CALL YOUR CLOSEST
LINDE LOCATION.
METHODS FOR CLEANING UP:
RETURN CYLINDER TO LINDE OR AN AUTHORIZED DISTRIBUTOR.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
FOR APPLICATIONS WITH MOIST CARBON DIOXIDE, 316, 309 AND 310 STAINLESS
STEELS MAY BE USED AS WELL AS HASTELLOY(R*) A, B, & C AND MONEL(R*).
FERROUS NICKEL ALLOYS ARE SLIGHTLY SUSPECTIBLE TO CORROSION. AT NORMAL
TEMPERATURES CARBON DIOXIDE IS COMPATIBLE WITH MOST PLASTICS AND
ELASTOMERS.
PROTECT CYLINDERS FROM PHYSICAL DAMAGE; DO NOT DRAG, ROLL, SLIDE OR DROP.
WHEN MOVING CYLINDERS, EVEN FOR SHORT DISTANCE, USE A CART DESIGNED TO
TRANSPORT CYLINDERS. NEVER ATTEMPT TO LIFT A CYLINDER BY ITS VALVE
PROTECTION CAP. NEVER INSERT AN OBJECT (E.G. WRENCH, SCREWDRIVER, PRY
BAR, ETC.) INTO VALVE CAP OPENINGS. DOING SO MAY DAMAGE VALVE, CAUSING LEAK
TO OCCUR. USE AN ADJUSTABLE STRAP WRENCH TO REMOVE OVER-TIGHT OR RUSTED
CAPS. USE ONLY WITH ADEQUATE VENTILATION. USE A BACKFLOW PREVENTIVE DEVICE
IN PIPING. USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE. CLOSE VALVE
AFTER EACH USE AND WHEN EMPTY. IF USER EXPERIENCES ANY DIFFICULTY OPERATING
CYLINDER VALVE DISCONTINUE USE AND CONTACT SUPPLIER. ENSURE THE COMPLETE
GAS SYSTEM HAS BEEN CHECKED FOR LEAKS BEFORE USE.
NEVER PUT CYLINDERS INTO TRUNKS OF CARS OR UNVENTILATED AREAS OF PASSENGER
VEHICLES. NEVER ATTEMPT TO REFILL A COMPRESSED GAS CYLINDER WITHOUT THE
OWNER'S WRITTEN CONSENT. NEVER STRIKE AN ARC ON A COMPRESSED GAS CYLINDER
OR MAKE A CYLINDER A PART OF AN ELECTRICAL CIRCUIT.
ONLY EXPERIENCED AND PROPERLY INSTRUCTED PERSONS SHOULD HANDLE GASES UNDER
PRESSURE. ALWAYS STORE AND HANDLE COMPRESSED GAS CYLINDERS IN ACCORDANCE
WITH COMPRESSED GAS ASSOCIATION, PAMPHLET CGA-P1, SAFE HANDLING OF
COMPRESSED GASES IN CONTAINERS.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE IN COOL, DRY, WELL-VENTILATED AREA OF NON-COMBUSTIBLE CONSTRUCTION
AWAY FROM HEAVILY TRAFFICKED AREAS AND EMERGENCY EXITS. KEEP AT
TEMPERATURES BELOW 52 DEG. C / 125 DEG. F. CYLINDERS SHOULD BE STORED
UPRIGHT WITH VALVE PROTECTION CAP IN PLACE AND FIRMLY SECURED TO PREVENT
FALLING. FULL AND EMPTY CYLINDERS SHOULD BE SEGREGRATED. USE A "FIRST
IN-FIRST OUT" INVENTORY SYSTEM TO PREVENT FULL CYLINDERS FROM BEING STORED
FOR EXCESSIVE PERIODS OF TIME. STORED CONTAINERS SHOULD BE PERIODICALLY
CHECKED FOR GENERAL CONDITION AND LEAKAGE.
INCOMPATIBLE MATERIALS:
CERTAIN REACTIVE METALS, HYDRIDES, MOIST CESIUM MONOXIDE, OR LITHIUM
ACETYLENE CARBIDE DIAMMINO MAY IGNITE. PASSING CARBON DIOXIDE OVER A
MIXTURE OF SODIUM PEROXIDE AND ALUMINUM OR MAGNESIUM MAY EXPLODE. CARBON
DIOXIDE IS INCOMPATIBLE WITH:
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
CARBON DIOXIDE STEL = 30000 PPM TWA: 5000 PPM IDLH: 40000 PPM
124-38-9 TWA: 5000 PPM TWA: 9000 MG/M3 TWA: 5000 PPM
(VACATED) TWA: TWA: 9000 MG/M3
10000 PPM STEL: 30000 PPM
(VACATED) TWA: STEL: 54000 MG/M3
18000 MG/M3
(VACATED) STEL:
30000 PPM
(VACATED) STEL:
54000 MG/M3
ACGIH TLV:
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS - THRESHOLD LIMIT
VALUE.
OSHA PEL:
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION - PERMISSIBLE EXPOSURE
LIMITS.
NIOSH IDLH:
IMMEDIATELY DANGEROUS TO LIFE OR HEALTH IMMEDIATELY DANGEROUS TO LIFE OR
HEALTH.
OTHER INFORMATION:
VACATED LIMITS REVOKED BY THE COURT OF APPEALS DECISION IN AFL-CIO V. OSHA,
965 F.2D 962 (11TH CIR., 1992).
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
LOCAL EXHAUST VENTILATION TO PREVENT ACCUMULATION OF HIGH CONCENTRATIONS
AND MAINTAIN AIR-OXYGEN LEVELS AT OR ABOVE 19.5%. OXYGEN DETECTORS SHOULD
BE USED WHEN ASPHYXIATING GASES MAY BE RELEASED. SYSTEMS UNDER PRESSURE
SHOULD BE REGULARLY CHECKED FOR LEAKAGES. SHOWERS. EYEWASH STATIONS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES). IF SPLASHES ARE LIKELY
TO OCCUR, WEAR: GOGGLES. FACE-SHIELD.
SKIN AND BODY PROTECTION:
WORK GLOVES AND SAFETY SHOES ARE RECOMMENDED WHEN HANDLING CYLINDERS. WEAR
COLD INSULATING GLOVES WHEN HANDLING LIQUID.
RESPIRATORY PROTECTION:
USE POSITIVE PRESSURE AIRLINE RESPIRATOR WITH ESCAPE CYLINDER OR SELF
CONTAINED BREATHING APPARATUS FOR OXYGEN-DEFICIENT ATMOSPHERES (<19.5%). IF
EXPOSURE LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, NIOSH APPROVED
RESPIRATORY PROTECTION SHOULD BE WORN. POSITIVE-PRESSURE SUPPLIED AIR
RESPIRATORS MAY BE REQUIRED FOR HIGH AIRBORNE CONTAMINANT CONCENTRATIONS.
RESPIRATORY PROTECTION MUST BE PROVIDED IN ACCORDANCE WITH CURRENT LOCAL
REGULATIONS.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. DO
NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: COMPRESSED LIQUEFIED GAS
APPEARANCE: COLORLESS.
ODOR: ODORLESS.
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: -56.6 DEG. C / -69.8 DEG. F
EVAPORATION RATE: NOT APPLICABLE
LOWER FLAMMABILITY LIMIT: NOT APPLICABLE
UPPER FLAMMABILITY LIMIT: NOT APPLICABLE
FLASH POINT: NOT APPLICABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
WATER SOLUBILITY: 0.145 G/ML @ 25 DEG. C
PARTITION COEFFICIENT: NO DATA AVAILABLE
KINEMATIC VISCOSITY: NOT APPLICABLE
COMPONENT LEVEL INFORMATION:
CHEMICAL NAME MOLECULAR WEIGHT BOILING POINT VAPOR PRESSURE
CARBON DIOXIDE 44.01 -78.5 DEG. C 838 PSIG (5778
(SUBLIMES) KPA) @ 21.1 DEG. C
CHEMICAL NAME VAPOR DENSITY GAS DENSITY CRITICAL
(AIR=1) KG/M3 @ 20 DEG. C TEMPERATURE
CARBON DIOXIDE 1.522 1.839 31.1 DEG. C
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT REACTIVE UNDER NORMAL CONDITIONS
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: NONE.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID:
DUE TO THE PRESENCE OF CARBON DIOXIDE, CARBONIC ACID IS FORMED IN THE
PRESENCE OF MOISTURE.
INCOMPATIBLE MATERIALS:
CERTAIN REACTIVE METALS, HYDRIDES, MOIST CESIUM MONOXIDE, OR LITHIUM
ACETYLENE CARBIDE DIAMMINO MAY IGNITE. PASSING CARBON DIOXIDE OVER A
MIXTURE OF SODIUM PEROXIDE AND ALUMINUM OR MAGNESIUM MAY EXPLODE. CARBON
DIOXIDE IS INCOMPATIBLE WITH:
HAZARDOUS DECOMPOSITION PRODUCTS: OXYGEN. CARBON MONOXIDE (CO).
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
ACIDOSIS, ADRENAL CORTICAL EXHAUSTION, AND OTHER METABOLIC STRESSES HAVE
RESULTED FROM PROLONGED CONTINUOUS EXPOSURE TO 1-2% CARBON DIOXIDE (10,000
PPM-20,000 PPM). THE ACGIH TLV OF 5,000 PPM IS EXPECTED TO PROVIDE A GOOD
MARGIN OF SAFETY FROM ASPHYXIATION AND UNDUE METABOLIC STRESS PROVIDED
SUFFICIENT OXYGEN LEVELS ARE MAINTAINED IN THE AIR. INCREASED PHYSICAL
ACTIVITY, DURATION OF EXPOSURE, AND DECREASED OXYGEN CONTENT CAN AFFECT
SYSTEMIC AND RESPIRATORY EFFECTS RESULTING FROM EXPOSURE TO CARBON DIOXIDE.
SKIN CONTACT: CONTACT WITH LIQUID MAY CAUSE COLD BURNS/FROSTBITE.
EYE CONTACT: CONTACT WITH LIQUID MAY CAUSE COLD BURNS/FROSTBITE.
INGESTION: NOT AN EXPECTED ROUTE OF EXPOSURE.
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS:
DEPENDING ON CONCENTRATION AND DURATION OF EXPOSURE TO CARBON DIOXIDE MAY
CAUSE INCREASED RESPIRATIONS, HEADACHE, MILD NARCOTIC EFFECTS, INCREASED
BLOOD PRESSURE AND PULSE, AND ASPHYXIATION. SYMPTOMS OF OVEREXPOSURE BECOME
MORE APPARENT WHEN ATMOSPHERIC OXYGEN IS DECREASED TO 15-17%.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
IRRITATION: NOT CLASSIFIED.
SENSITIZATION: NOT CLASSIFIED.
GERM CELL MUTAGENICITY: NOT CLASSIFIED.
CARCINOGENICITY:
THIS PRODUCT DOES NOT CONTAIN ANY CARCINOGENS OR POTENTIAL CARCINOGENS
LISTED BY OSHA, IARC OR NTP.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED.
STOT - SINGLE EXPOSURE: NOT CLASSIFIED.
STOT - REPEATED EXPOSURE: NOT CLASSIFIED.
CHRONIC TOXICITY:
CHRONIC HARMFUL EFFECTS ARE NOT KNOWN FROM REPEATED INHALATION OF
CONCENTRATIONS BELOW PEL/TLV.
TARGET ORGAN EFFECTS: CENTRAL VASCULAR SYSTEM (CVS), RESPIRATORY SYSTEM.
ASPIRATION HAZARD: NOT APPLICABLE.
NUMERICAL MEASURES OF TOXICITY:
COMPONENT LEVEL INFORMATION:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50 INHALATION LC50
(CGA P-20)
CARBON DIOXIDE 470,000 PPM
124-38-9 (RAT)
PRODUCT INFORMATION:
ORAL LD50: NO INFORMATION AVAILABLE
DERMAL LD50: NO INFORMATION AVAILABLE
INHALATION LC50: TCLO - 10,000 PPM (RAT) 24 HOURS/30 DAYS-CONTINUOUS
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: NO KNOWN ACUTE AQUATIC TOXICITY.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: NO INFORMATION AVAILABLE
GLOBAL WARMING POTENTIAL (GWP): 1
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
DO NOT ATTEMPT TO DISPOSE OF RESIDUAL WASTE OR UNUSED QUANTITIES. RETURN IN
THE SHIPPING CONTAINER PROPERLY LABELED WITH ANY VALVE OUTLET PLUGS OR CAPS
SECURED AND VALVE PROTECTION CAP IN PLACE TO LINDE FOR PROPER DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN/ID NO.: UN1013
PROPER SHIPPING NAME: CARBON DIOXIDE
HAZARD CLASS: 2.2
DESCRIPTION: UN1013, CARBON DIOXIDE, 2.2
EMERGENCY RESPONSE GUIDE NUMBER: 120
TDG:
UN/ID NO.: UN1013
PROPER SHIPPING NAME: CARBON DIOXIDE
HAZARD CLASS: 2.2
DESCRIPTION: UN1013, CARBON DIOXIDE, 2.2
MEX:
UN/ID NO.: UN1013
PROPER SHIPPING NAME: CARBON DIOXIDE
HAZARD CLASS: 2.2
DESCRIPTION: UN1013, CARBON DIOXIDE, 2.2
IATA:
UN/ID NO.: UN1013
PROPER SHIPPING NAME: CARBON DIOXIDE
HAZARD CLASS: 2.2
ERG CODE: 2L
DESCRIPTION: UN1013, CARBON DIOXIDE, 2.2
IMDG:
UN/ID NO.: UN1013
PROPER SHIPPING NAME: CARBON DIOXIDE
HAZARD CLASS: 2.2
EMS-NO.: F-C, S-V
DESCRIPTION: UN1013, CARBON DIOXIDE, 2.2
ADR:
UN/ID NO.: UN1013
PROPER SHIPPING NAME: CARBON DIOXIDE
HAZARD CLASS: 2.2
CLASSIFICATION CODE: 2A
TUNNEL RESTRICTION CODE: (C/E)
SPECIAL PROVISIONS: 584, 653
DESCRIPTION: UN1013, CARBON DIOXIDE, 2.2, (C/E)
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: COMPLIES
DSL/NDSL: COMPLIES
EINECS/ELINCS: COMPLIES
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372.
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: NO
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
REACTIVE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: YES
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL.
CLEAN AIR ACT, SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) (SEE 40 CFR 61):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS HAZARDOUS AIR
POLLUTANTS (HAPS) UNDER SECTION 112 OF THE CLEAN AIR ACT AMENDMENTS OF
1990.
CWA (CLEAN WATER ACT):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
RISK AND PROCESS SAFETY MANAGEMENT PROGRAMS:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY REGULATED SUBSTANCES WITH
SPECIFIED THRESHOLDS UNDER 40 CFR PART 68. THIS PRODUCT DOES NOT CONTAIN
ANY SUBSTANCES REGULATED AS HIGHLY HAZARDOUS CHEMICALS PURSUANT TO THE 29
CFR PART 1910.110.
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA
CARBON DIOXIDE X X X
124-38-9
CHEMICAL NAME CARCINOGENICITY EXPOSURE LIMITS
CARBON DIOXIDE MEXICO: TWA=5000 PPM
MEXICO: TWA=9000 MG/M3
MEXICO: STEL=15000 PPM
MEXICO: STEL=27000 MG/M3
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS 2
FLAMMABILITY 0
INSTABILITY 0
PHYSICAL AND CHEMICAL PROPERTIES SIMPLE ASPHYXIANT
NOTE:
RATINGS WERE ASSIGNED IN ACCORDANCE WITH COMPRESSED GAS ASSOCIATION (CGA)
GUIDELINES AS PUBLISHED IN CGA PAMPHLET P-19-2009, CGA RECOMMENDED HAZARD
RATINGS FOR COMPRESSED GASES, 3RD EDITION.
ISSUE DATE: 17-FEB-2015
REVISION DATE: 12-JUL-2016
REVISION NOTE: SDS SECTIONS UPDATED; 1
GENERAL DISCLAIMER:
FOR TERMS AND CONDITIONS, INCLUDING LIMITATION OF LIABILITY, PLEASE REFER
TO THE PURCHASE AGREEMENT IN EFFECT BETWEEN LINDE LLC, LINDE MERCHANT
PRODUCTION, INC. OR LINDE GAS NORTH AMERICA LLC (OR ANY OF THEIR AFFILIATES
AND SUBSIDIARIES) AND THE PURCHASER.
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES:
ALTHOUGH REASONABLE CARE HAS BEEN TAKEN IN THE PREPARATION OF THIS
DOCUMENT, WE EXTEND NO WARRANTIES AND MAKE NO REPRESENTATIONS AS TO THE
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