| Common Name: | DIMETHYLGLYOXIME, ACS |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 7/30/2019 |
| SDS Format: | No Format Specified |
| Item Number(s): | 9WUC7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
DIMETHYLGLYOXIME, ACS
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 11/18/2013
REVISION DATE: 07/30/2019
SUPERSEDES: 05/03/2017
VERSION: 2.0
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: SUBSTANCE
SUBSTANCE NAME: DIMETHYLGLYOXIME, ACS
CHEMICAL NAME: 2,3-BUTANEDIONEDIOXIME
CAS-NO.: 95-45-4
PRODUCT CODE: LC13596
FORMULA: C4H8N2O2
SYNONYMS:
2,3-BUTANEDIONEDIOXIME / 2,3-DIISONITROSOBUTANE / BIACETYLDIOXIME /
BUTANEDIOXIME / DIACETYLDIOXIME
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM, INC.
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR +1-703-741-5970
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS US CLASSIFICATION:
FLAMMABLE SOLIDS CATEGORY 2:
H228: FLAMMABLE SOLID
ACUTE TOXICITY (ORAL) CATEGORY 3:
H301: TOXIC IF SWALLOWED
COMBUSTIBLE DUST: MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS US LABELING:
HAZARD PICTOGRAMS (GHS US):
FLAME
SKULLS AND CROSSBONES
SIGNAL WORD (GHS US): DANGER
HAZARD STATEMENTS (GHS US): MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR
H228: FLAMMABLE SOLID
H301: TOXIC IF SWALLOWED
PRECAUTIONARY STATEMENTS (GHS US):
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P280: WEAR PROTECTIVE GLOVES, EYE PROTECTION.
P301+P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P330: IF SWALLOWED, RINSE MOUTH
P370+P378:
IN CASE OF FIRE: USE CARBON DIOXIDE (CO2), FOAM TO EXTINGUISH
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES:
SUBSTANCE TYPE: MONO-CONSTITUENT
NAME PRODUCT IDENTIFIER % GHS US CLASSIFICATION
DIMETHYLGLYOXIME, ACS (CAS-NO.) 95-45-4 100 FLAM. SOL. 2, H228
(MAIN CONSTITUENT) ACUTE TOX. 3 (ORAL), H301
COMB. DUST
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
3.2. MIXTURES: NOT APPLICABLE
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
CHECK THE VITAL FUNCTIONS. UNCONSCIOUS: MAINTAIN ADEQUATE AIRWAY AND
RESPIRATION. RESPIRATORY ARREST: ARTIFICIAL RESPIRATION OR OXYGEN. CARDIAC
ARREST: PERFORM RESUSCITATION. VICTIM CONSCIOUS WITH LABORED BREATHING:
HALF-SEATED. VICTIM IN SHOCK: ON HIS BACK WITH LEGS SLIGHTLY RAISED.
VOMITING: PREVENT ASPHYXIA/ASPIRATION PNEUMONIA. PREVENT COOLING BY
COVERING THE VICTIM (NO WARMING UP). KEEP WATCHING THE VICTIM. GIVE
PSYCHOLOGICAL AID. KEEP THE VICTIM CALM, AVOID PHYSICAL STRAIN. DEPENDING
ON THE VICTIM'S CONDITION: DOCTOR/HOSPITAL. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE
LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
REMOVE THE VICTIM INTO FRESH AIR. RESPIRATORY PROBLEMS: CONSULT A
DOCTOR/MEDICAL SERVICE. ALLOW AFFECTED PERSON TO BREATHE FRESH AIR. ALLOW
THE VICTIM TO REST.
FIRST-AID MEASURES AFTER SKIN CONTACT:
TAKE VICTIM TO A DOCTOR IF IRRITATION PERSISTS. REMOVE AFFECTED CLOTHING
AND WASH ALL EXPOSED SKIN AREA WITH MILD SOAP AND WATER, FOLLOWED BY WARM
WATER RINSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. DO NOT
APPLY NEUTRALIZING AGENTS. RINSE IMMEDIATELY WITH PLENTY OF WATER. OBTAIN
MEDICAL ATTENTION IF PAIN, BLINKING OR REDNESS PERSISTS.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH WITH WATER. GIVE NOTHING TO DRINK. INGESTION OF LARGE
QUANTITIES: IMMEDIATELY TO HOSPITAL. TAKE THE CONTAINER/VOMIT TO THE
DOCTOR/HOSPITAL. DO NOT INDUCE VOMITING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS: TOXIC IF SWALLOWED.
SYMPTOMS/EFFECTS AFTER INHALATION: NO EFFECTS KNOWN.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: NO EFFECTS KNOWN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: NO EFFECTS KNOWN.
SYMPTOMS/EFFECTS AFTER INGESTION:
TOXIC IF SWALLOWED. SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL
RESULT IN SERIOUS HEALTH HAZARD.
CHRONIC SYMPTOMS: NO EFFECTS KNOWN.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
TREAT SYMPTOMATICALLY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CLASS A FOAM EXTINGUISHER. FOAM. DRY POWDER. CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA:
QUICK-ACTING BC POWDER EXTINGUISHER. DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD:
DIRECT FIRE HAZARD. FLAMMABLE SOLID. IN FINELY DIVIDED STATE: INCREASED
FIRE HAZARD. INDIRECT FIRE HAZARD. MAY BE IGNITED BY SPARKS. REACTIONS
INVOLVING A FIRE HAZARD: SEE "REACTIVITY HAZARD". FLAMMABLE SOLID.
EXPLOSION HAZARD:
DIRECT EXPLOSION HAZARD. FINE DUST IS EXPLOSIVE WITH AIR. INDIRECT
EXPLOSION HAZARD. DUST CLOUD CAN BE IGNITED BY A SPARK. MAY FORM
FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
PRECAUTIONARY MEASURES FIRE:
EXPOSURE TO FIRE/HEAT: KEEP UPWIND. EXPOSURE TO FIRE/HEAT: CONSIDER
EVACUATION. EXPOSURE TO FIRE/HEAT: HAVE NEIGHBORHOOD CLOSE DOORS AND
WINDOWS. FIREFIGHTING INSTRUCTIONS: DILUTE TOXIC GASES WITH WATER SPRAY.
TAKE ACCOUNT OF TOXIC FIRE-FIGHTING WATER. USE WATER MODERATELY AND IF
POSSIBLE COLLECT OR CONTAIN IT. USE WATER SPRAY OR FOG FOR COOLING EXPOSED
CONTAINERS. EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT
FIRE-FIGHTING WATER FROM ENTERING ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
HEAT/FIRE EXPOSURE: COMPRESSED AIR/OXYGEN APPARATUS. DO NOT ENTER FIRE AREA
WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
GLOVES. PROTECTIVE CLOTHING. DUST CLOUD PRODUCTION: COMPRESSED AIR/OXYGEN
APPARATUS.
EMERGENCY PROCEDURES:
MARK THE DANGER AREA. PREVENT DUST CLOUD FORMATION, E.G. BY WETTING. NO
NAKED FLAMES. WASH CONTAMINATED CLOTHES. EVACUATE UNNECESSARY PERSONNEL.
MEASURES IN CASE OF DUST RELEASE:
IN CASE OF DUST PRODUCTION: KEEP UPWIND. DUST PRODUCTION: HAVE
NEIGHBORHOOD CLOSE DOORS AND WINDOWS. IN CASE OF DUST PRODUCTION: STOP
ENGINES AND NO SMOKING. IN CASE OF DUST PRODUCTION: NO NAKED FLAMES OR
SPARKS. DUST: SPARK-/EXPLOSION PROOF APPLIANCES/LIGHTING EQUIPMENT.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. DO NOT BREATHE DUST.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT SOIL AND WATER POLLUTION. PREVENT SPREADING IN SEWERS. PREVENT
ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID ENTERS
SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. PLUG THE LEAK,
CUT OFF THE SUPPLY. DAM UP THE SOLID SPILL. KNOCK DOWN/DILUTE DUST CLOUD
WITH WATER SPRAY. TAKE ACCOUNT OF TOXIC/CORROSIVE PRECIPITATION WATER.
POWDERED FORM: NO COMPRESSED AIR FOR PUMPING OVER SPILLS.
METHODS FOR CLEANING UP:
STOP DUST CLOUD BY HUMIDIFYING WITH WATER. SCOOP SOLID SPILL INTO CLOSING
CONTAINERS. CAREFULLY COLLECT THE SPILL/LEFTOVERS. POWDERED: DO NOT USE
COMPRESSED AIR FOR PUMPING OVER SPILLS. CLEAN CONTAMINATED SURFACES WITH AN
EXCESS OF WATER. TAKE COLLECTED SPILL TO MANUFACTURER/COMPETENT AUTHORITY.
WASH CLOTHING AND EQUIPMENT AFTER HANDLING. MINIMIZE GENERATION OF DUST.
STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
AVOID RAISING DUST. KEEP AWAY FROM NAKED FLAMES/HEAT. IN FINELY DIVIDED
STATE: USE SPARK- /EXPLOSION PROOF APPLIANCES. FINELY DIVIDED: KEEP AWAY
FROM IGNITION SOURCES/SPARKS. MEASURE THE CONCENTRATION IN THE AIR
REGULARLY. CARRY OPERATIONS IN THE OPEN/UNDER LOCAL EXHAUST/VENTILATION OR
WITH RESPIRATORY PROTECTION. COMPLY WITH THE LEGAL REQUIREMENTS. CLEAN
CONTAMINATED CLOTHING. POWDERED FORM: NO COMPRESSED AIR FOR PUMPING OVER.
DO NOT DISCHARGE THE WASTE INTO THE DRAIN. KEEP CONTAINER TIGHTLY CLOSED.
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING.
HYGIENE MEASURES:
OBSERVE STRICT HYGIENE. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL EQUIPMENT.
STORAGE CONDITIONS:
KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP IN FIREPROOF PLACE.
INCOMPATIBLE PRODUCTS:
STRONG OXIDIZERS. STRONG REDUCING AGENTS. STRONG ACIDS. STRONG BASES.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
HEAT-IGNITION:
KEEP SUBSTANCE AWAY FROM: HEAT SOURCES. IGNITION SOURCES.
PROHIBITIONS ON MIXED STORAGE:
KEEP SUBSTANCE AWAY FROM: OXIDIZING AGENTS. REDUCING AGENTS. STRONG ACIDS.
STORAGE AREA: STORE IN A DRY AREA. MEET THE LEGAL REQUIREMENTS.
SPECIAL RULES ON PACKAGING:
SPECIAL REQUIREMENTS:
CLOSING. CORRECTLY LABELED. MEET THE LEGAL REQUIREMENTS. SECURE FRAGILE
PACKAGINGS IN SOLID CONTAINERS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS: NO ADDITIONAL INFORMATION AVAILABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST
VENTILATION.
ENVIRONMENTAL EXPOSURE CONTROLS: AVOID CREATING OR SPREADING DUST.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT
PERSONAL PROTECTIVE EQUIPMENT:
SAFETY GLASSES. GLOVES. DUST/AEROSOL MASK WITH FILTER TYPE P3.
MATERIALS FOR PROTECTIVE CLOTHING:
GIVE GOOD RESISTANCE: NITRILE RUBBER
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
SKIN AND BODY PROTECTION: PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
DUST PRODUCTION:
DUST MASK WITH FILTER TYPE P3. HIGH DUST PRODUCTION: SELF-CONTAINED
BREATHING APPARATUS
PERSONAL PROTECTIVE EQUIPMENT SYMBOL(S):
SAFETY GLASSES
GLOVES
FULL-FACE RESPIRATOR
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
APPEARANCE: CRYSTALLINE SOLID. CRYSTALLINE POWDER.
COLOR: WHITE
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: 240 DEG. C
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NOT APPLICABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): FLAMMABLE SOLID.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NOT APPLICABLE (SOLID)
RELATIVE DENSITY: NOT APPLICABLE (SOLID)
SPECIFIC GRAVITY / DENSITY: 500 KG/M3
MOLECULAR MASS: 116.12 G/MOL
SOLUBILITY:
INSOLUBLE IN WATER. SOLUBLE IN ETHANOL. SOLUBLE IN ETHER. SOLUBLE IN
ACETONE.
WATER: <0.1 G/100 ML
LOG POW: -2.16 - -0.29 (CALCULATED)
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NOT APPLICABLE (SOLID)
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NOT APPLICABLE (SOLID)
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 0%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS. FLAMMABLE SOLID. MAY FORM
FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
OVERHEATING. HEAT. SPARKS.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS. STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. NITROGEN OXIDES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY (ORAL): TOXIC IF SWALLOWED.
ACUTE TOXICITY (DERMAL): NOT CLASSIFIED
ACUTE TOXICITY (INHALATION): NOT CLASSIFIED
ATE US (ORAL) 100 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
LIKELY ROUTES OF EXPOSURE: SKIN AND EYE CONTACT. INHALATION.
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS: TOXIC IF SWALLOWED.
SYMPTOMS/EFFECTS AFTER INHALATION: NO EFFECTS KNOWN.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: NO EFFECTS KNOWN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: NO EFFECTS KNOWN.
SYMPTOMS/EFFECTS AFTER INGESTION:
TOXIC IF SWALLOWED. SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL
RESULT IN SERIOUS HEALTH HAZARD.
CHRONIC SYMPTOMS: NO EFFECTS KNOWN.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL:
NOT CLASSIFIED AS DANGEROUS FOR THE ENVIRONMENT ACCORDING TO THE CRITERIA
OF REGULATION (EC) NO 1272/2008.
ECOLOGY - AIR:
NOT INCLUDED IN THE LIST OF FLUORINATED GREENHOUSE GASES (REGULATION (EU)
NO 517/2014). NOT CLASSIFIED AS DANGEROUS FOR THE OZONE LAYER (REGULATION
(EC) NO 1005/2009).
ECOLOGY - WATER: NITRIFICATION OF ACTIVATED SLUDGE IS INHIBITED.
12.2. PERSISTENCE AND DEGRADABILITY:
DIMETHYLGLYOXIME, ACS (95-45-4):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY IN WATER: NO DATA AVAILABLE. NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
DIMETHYLGLYOXIME, ACS (95-45-4):
LOG POW: -2.16 - -0.29 (CALCULATED)
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
12.4. MOBILITY IN SOIL:
DIMETHYLGLYOXIME, ACS (95-45-4):
ECOLOGY - SOIL: NO (TEST)DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE.
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
REGIONAL LEGISLATION (WASTE):
DISPOSAL MUST BE DONE ACCORDING TO OFFICIAL REGULATIONS.
WASTE DISPOSAL RECOMMENDATIONS:
DO NOT DISCHARGE INTO THE SEWER. REMOVE WASTE IN ACCORDANCE WITH LOCAL
AND/OR NATIONAL REGULATIONS. HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER
WITH OTHER WASTE. DIFFERENT TYPES OF HAZARDOUS WASTE SHALL NOT BE MIXED
TOGETHER IF THIS MAY ENTAIL A RISK OF POLLUTION OR CREATE PROBLEMS FOR THE
FURTHER MANAGEMENT OF THE WASTE. HAZARDOUS WASTE SHALL BE MANAGED
RESPONSIBLY. ALL ENTITIES THAT STORE, TRANSPORT OR HANDLE HAZARDOUS WASTE
SHALL TAKE THE NECESSARY MEASURES TO PREVENT RISKS OF POLLUTION OR DAMAGE
TO PEOPLE OR ANIMALS. INCINERATE UNDER SURVEILLANCE WITH ENERGY RECOVERY.
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
HAZARDOUS WASTE ACCORDING TO DIRECTIVE 2008/98/EC, AS AMENDED BY REGULATION
(EU) NO 1357/2014 AND REGULATION (EU) NO 2017/997. HANDLE EMPTY CONTAINERS
WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS:
AVOID RELEASE TO THE ENVIRONMENT. HAZARDOUS WASTE DUE TO TOXICITY.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN2926 FLAMMABLE SOLIDS, TOXIC, ORGANIC, N.O.S. (DIMETHYLGLYOXIME), 4.1
(6.1), III
UN-NO.(DOT): UN2926
PROPER SHIPPING NAME (DOT):
FLAMMABLE SOLIDS, TOXIC, ORGANIC, N.O.S. DIMETHYLGLYOXIME
TRANSPORT HAZARD CLASS(ES) (DOT):
4.1 - CLASS 4.1 - FLAMMABLE SOLID 49 CFR 173.124
PACKING GROUP (DOT): III - MINOR DANGER
SUBSIDIARY RISK (DOT): 6.1 - CLASS 6.1 - POISONOUS MATERIALS 49 CFR 173.132
HAZARD LABELS (DOT):
4.1 - FLAMMABLE SOLID
6.1 - POISON
DOT PACKAGING NON BULK (49 CFR 173.XXX): 213
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SPECIAL PROVISIONS (49 CFR 172.102):
A1 - SINGLE PACKAGING ARE NOT PERMITTED ON PASSENGER AIRCRAFT.
IB6 - AUTHORIZED IBCS: METAL (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B AND
31N); RIGID PLASTICS (11H1, 11H2, 21H1, 21H2, 31H1 AND 31H2); COMPOSITE
(11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 AND 31HZ2). ADDITIONAL REQUIREMENT:
COMPOSITE IBCS 11HZ2 AND 21HZ2 MAY NOT BE USED WHEN THE HAZARDOUS MATERIALS
BEING TRANSPORTED MAY BECOME LIQUID DURING TRANSPORT.
T1 - 1.5 178.274(D)(2) NORMAL............. 178.275(D)(2)
TP33 - THE PORTABLE TANK INSTRUCTION ASSIGNED FOR THIS SUBSTANCE APPLIES
FOR GRANULAR AND POWDERED SOLIDS AND FOR SOLIDS WHICH ARE FILLED AND
DISCHARGED AT TEMPERATURES ABOVE THEIR MELTING POINT WHICH ARE COOLED AND
TRANSPORTED AS A SOLID MASS. SOLID SUBSTANCES TRANSPORTED OR OFFERED FOR
TRANSPORT ABOVE THEIR MELTING POINT ARE AUTHORIZED FOR TRANSPORTATION IN
PORTABLE TANKS CONFORMING TO THE PROVISIONS OF PORTABLE TANK INSTRUCTION T4
FOR SOLID SUBSTANCES OF PACKING GROUP III OR T7 FOR SOLID SUBSTANCES OF
PACKING GROUP II, UNLESS A TANK WITH MORE STRINGENT REQUIREMENTS FOR
MINIMUM SHELL THICKNESS, MAXIMUM ALLOWABLE WORKING PRESSURE,
PRESSURE-RELIEF DEVICES OR BOTTOM OUTLETS ARE ASSIGNED IN WHICH CASE THE
MORE STRINGENT TANK INSTRUCTION AND SPECIAL PROVISIONS SHALL APPLY. FILLING
LIMITS MUST BE IN ACCORDANCE WITH PORTABLE TANK SPECIAL PROVISION TP3.
SOLIDS MEETING THE DEFINITION OF AN ELEVATED TEMPERATURE MATERIAL MUST BE
TRANSPORTED IN ACCORDANCE WITH THE APPLICABLE REQUIREMENTS OF THIS
SUBCHAPTER.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 151
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 25 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 100 KG
DOT VESSEL STOWAGE LOCATION:
B - (I) THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO
VESSEL AND ON A PASSENGER VESSEL CARRYING A NUMBER OF PASSENGERS LIMITED TO
NOT MORE THAN THE LARGER OF 25 PASSENGERS, OR ONE PASSENGER PER EACH 3 M OF
OVERALL VESSEL LENGTH; AND (II) "ON DECK ONLY" ON PASSENGER
VESSELS IN WHICH THE NUMBER OF PASSENGERS SPECIFIED IN PARAGRAPH (K)(2)(I)
OF THIS SECTION IS EXCEEDED.
DOT VESSEL STOWAGE OTHER: 40 - STOW "CLEAR OF LIVING QUARTERS"
EMERGENCY RESPONSE GUIDE (ERG) NUMBER: 134
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
TRANSPORTATION OF DANGEROUS GOODS:
TRANSPORT DOCUMENT DESCRIPTION:
UN2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. (DIMETHYLGLYOXIME), 4.1
(6.1), III
UN-NO. (TDG): UN2926
PROPER SHIPPING NAME (TRANSPORTATION OF DANGEROUS GOODS):
FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S.
TDG PRIMARY HAZARD CLASSES: 4.1 - CLASS 4.1 - FLAMMABLE SOLIDS
PACKING GROUP: III - MINOR DANGER
TDG SUBSIDIARY CLASSES: 6.1
TDG SPECIAL PROVISIONS:
16 - (1) THE TECHNICAL NAME OF AT LEAST ONE OF THE MOST DANGEROUS
SUBSTANCES THAT PREDOMINANTLY CONTRIBUTES TO THE HAZARD OR HAZARDS POSED BY
THE DANGEROUS GOODS MUST BE SHOWN, IN PARENTHESES, ON THE SHIPPING DOCUMENT
FOLLOWING THE SHIPPING NAME IN ACCORDANCE WITH CLAUSE 3.5(1)(C)(II)(A) OF
PART 3 (DOCUMENTATION). THE TECHNICAL NAME MUST ALSO BE SHOWN, IN
PARENTHESES, ON A SMALL MEANS OF CONTAINMENT OR ON A TAG FOLLOWING THE
SHIPPING NAME IN ACCORDANCE WITH SUBSECTIONS 4.11(2) AND (3) OF PART 4
(DANGEROUS GOODS SAFETY MARKS). (2) DESPITE SUBSECTION (1), THE TECHNICAL
NAME FOR THE FOLLOWING DANGEROUS GOODS IS NOT REQUIRED TO BE SHOWN ON A
SHIPPING DOCUMENT OR ON A SMALL MEANS OF CONTAINMENT WHEN CANADIAN LAW FOR
DOMESTIC TRANSPORT OR AN INTERNATIONAL CONVENTION FOR INTERNATIONAL
TRANSPORT PROHIBITS THE DISCLOSURE OF THE TECHNICAL NAME: (A)UN1544,
ALKALOID SALTS, SOLID, N.O.S. OR ALKALOIDS, SOLID, N.O.S; (B)UN1851,
MEDICINE, LIQUID, TOXIC, N.O.S; (C)UN3140, ALKALOID SALTS, LIQUID, N.O.S.
OR ALKALOIDS, LIQUID, N.O.S; (D)UN3248, MEDICINE, LIQUID, FLAMMABLE, TOXIC,
N.O.S; OR (E)UN3249, MEDICINE, SOLID, TOXIC, N.O.S. AN EXAMPLE IN CANADA IS
THE "FOOD AND DRUGS ACT". (3) DESPITE SUBSECTION (1), THE TECHNICAL NAME
FOR THE FOLLOWING DANGEROUS GOODS IS NOT REQUIRED TO BE SHOWN ON A SMALL
MEANS OF CONTAINMENT: (A)UN2814, INFECTIOUS SUBSTANCE, AFFECTING HUMANS; OR
(B)UN2900, INFECTIOUS SUBSTANCE, AFFECTING ANIMALS. SOR/2014-306
EXPLOSIVE LIMIT AND LIMITED QUANTITY INDEX: 5 KG
PASSENGER CARRYING ROAD VEHICLE OR PASSENGER:
CARRYING RAILWAY VEHICLE INDEX: 25 KG
TRANSPORT BY SEA:
TRANSPORT DOCUMENT DESCRIPTION (IMDG):
UN 2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. (DIMETHYLGLYOXIME), 4.1
(6.1), III
UN-NO. (IMDG): 2926
PROPER SHIPPING NAME (IMDG): FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S.
CLASS (IMDG):
4.1 - FLAMMABLE SOLIDS, SELF-REACTIVE SUBSTANCES AND SOLID DESENSITIZED
EXPLOSIVES
PACKING GROUP (IMDG): III - SUBSTANCES PRESENTING LOW DANGER
SUBSIDIARY RISKS (IMDG): 6.1 - TOXIC SUBSTANCES
AIR TRANSPORT:
TRANSPORT DOCUMENT DESCRIPTION (IATA):
UN 2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. (DIMETHYLGLYOXIME), 4.1,
III
UN-NO. (IATA): 2926
PROPER SHIPPING NAME (IATA): FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S.
CLASS (IATA): 4.1 - FLAMMABLE SOLIDS
PACKING GROUP (IATA): III - MINOR DANGER
SUBSIDIARY HAZARDS (IATA): 6.1 - TOXIC SUBSTANCES
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
DIMETHYLGLYOXIME, ACS (95-45-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD - FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARD - ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
DIMETHYLGLYOXIME, ACS (95-45-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR
REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS:
REVISION DATE: 07/30/2019
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16
H228: FLAMMABLE SOLID
H301: TOXIC IF SWALLOWED
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 3 SERIOUS HAZARD - MATERIALS CAPABLE OF IGNITION UNDER
ALMOST ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73 F AND
BOILING POINTS ABOVE 100 F. AS WELL AS LIQUIDS WITH
FLASH POINTS BETWEEN 73 F AND 100 F. (CLASSES IB &
IC)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION E
E - SAFETY GLASSES, GLOVES, DUST RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
07/31/2019
EN (ENGLISH US)