| Common Name: | FLUID, FYRITE, O2 |
| Manufacturer: | BACHARACH |
| SDS Revision Date: | 3/10/2006 |
| SDS Format: | No Format Specified |
| Item Number(s): | 6T152, 6T153, 6T155, 6T157 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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BACHARACH, INC.
MATERIAL SAFETY DATA SHEET
THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED TO COMPLY WITH THE EC
DIRECTIVE, CANADIAN WHMIS AND OSHA HAZARD COMMUNICATION REGULATIONS.
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND THE COMPANY/UNDERTAKING
BACHARACH, INC.
621 HUNT VALLEY CIRCLE
NEW KENSINGTON, PA 15068
EMERGENCY PHONE: (800) 424-9300 (CHEMTREC)
INFORMATION PHONE: (724) 334-5760
FAX: (724) 334-5763
PRODUCT NAME: FLUID, FYRITE, O2
PRODUCT NUMBER: 11-0059
MSDS NUMBER: 99-0005
REVISION NUMBER: 11
PRODUCT USE: INSTRUMENT FLUID
MSDS DATE OF PREPARATION/REVISION: 3/10/06
| SECTION 2: COMPOSITION/INFORMATION INGREDIENTS | |
CHEMICAL NAME CAS# / EINECS# % EU CLASSIFICATION
(67/548/EEC)
WATER AND PROPRIETARY >90.3% NOT APPLICABLE
CHLORIDE
HYDROCHLORIC 7647-01-0 / 231-595-7 <3% C R34, R37
ACID
ISOOCTYL 68526-83-0 / 271-231-4 <0.8% NOT APPLICABLE
ALCOHOLS (C7-9)
ZINC CHLORIDE 7646-85-7 / 231-592-0 3.8% C, N R34, R37,
(AS Zn) R50/53
CHROMIUM (II) 10049-05-5 / 233-163-3 2.1% Xn R22, R43
CHLORIDE (AS Cr)
SEE SECTION 16 FOR FURTHER INFORMATION ON EU CLASSIFICATION.
| SECTION 3: HAZARDS IDENTIFICATION | |
BLUE LIQUID WITH AN UNPLEASANT CHLORINE ODOR.
EMERGENCY OVERVIEW:
CORROSIVE MATERIAL. LIQUID MAY CAUSE SEVERE IRRITATION OR BURNS TO THE EYES
AND SKIN. VAPORS ARE IRRITATING AND MAY BE HARMFUL. MAY CAUSE NARCOSIS AND
OTHER NERVOUS SYSTEM EFFECTS. MAY CAUSE ALLERGIC SKIN REACTION. TOXIC TO
AQUATIC ORGANISMS, MAY CAUSE LONG-TERM EFFECTS IN THE AQUATIC ENVIRONMENT.
EU PREPARATION CLASSIFICATION (1999/45/EC):
IRRITANT (Xi)
DANGEROUS FOR ENVIRONMENT (N) R36/37/38, R43, R51/53
| SECTION 4: FIRST AID | |
EYE CONTACT:
IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 20 MINUTES,
LIFTING THE UPPER AND LOWER LIDS. GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH WATER WHILE REMOVING ANY CONTAMINATED CLOTHING.
CONTINUE FLUSHING FOR 20 MINUTES. GET MEDICAL ATTENTION IF PAIN OR
IRRITATION PERSISTS.
INHALATION:
IF ACUTE OVEREXPOSURE OCCURS, REMOVE VICTIM TO FRESH AIR. GIVE ARTIFICIAL
RESPIRATION IF NEEDED. GET IMMEDIATE MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. DO NOT GIVE ANYTHING BY MOUTH TO A PERSON WHO IS
UNCONSCIOUS OR CONVULSING. IMMEDIATELY RINSE MOUTH OUT WITH A SMALL AMOUNT
OF WATER. GET IMMEDIATE MEDICAL ATTENTION.
| SECTION 5: FIRE AND EXPLOSION HAZARD DATA | |
EXTINGUISHING MEDIA: USE ANY MEDIA APPROPRIATE FOR SURROUNDING FIRE.
SPECIAL FIRE FIGHTING PROCEDURES:
FIREFIGHTERS SHOULD WEAR NIOSH APPROVED POSITIVE PRESSURE SELF CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING FOR ALL FIRES INVOLVING
CHEMICALS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
ISOOCTYL ALCOHOL HAS A FLASH POINT OF >141 DEG. F AND IS INSOLUBLE IN WATER.
ONLY A SMALL AMOUNT IS PRESENT (<1%) SO ONLY A VERY SLIGHT FIRE HAZARD
EXISTS. THE BALANCE IS NOT COMBUSTIBLE.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON, HYDROGEN CHLORIDE, CHLORINE AND POSSIBLY ZINC AND
CHROMIUM COMPOUNDS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
WEAR RECOMMENDED PROTECTIVE EQUIPMENT. (SEE SECTION 8) CONTAIN SPILL. DILUTE
SPILL WITH WATER AND NEUTRALIZE WITH BAKING SODA OR SODA ASH. ABSORB
NEUTRALIZED MATERIAL AND PLACE IN CONTAINER FOR DISPOSAL. DO NOT RELEASE TO
THE ENVIRONMENT. REFER TO SECTION 13 FOR DISPOSAL INFORMATION.
| SECTION 7: HANDLING AND STORAGE | |
WORK PRACTICES:
PREVENT CONTACT WITH THE EYES, SKIN AND CLOTHING. AVOID BREATHING VAPORS.
USE IN A WELL VENTILATED AREA. WHEN THE FLUID IS USED IN AN INSTRUMENT
(FYRITE), DO NOT VENT IN INVERTED POSITION OR BEFORE THE FLUID HAS DRAINED
FROM THE TOP WELL OF THE FYRITE. HOLD THE FYRITE AWAY FROM THE FACE WHEN
VENTING THE INSTRUMENT.
SPECIAL PRECAUTIONS:
ALWAYS CHANGE FYRITE FLUID IN THE IMMEDIATE VICINITY OF A SINK WITH RUNNING
WATER AVAILABLE IN CASE OF CONTACT BECAUSE OF THE CORROSIVE EFFECT OF FYRITE
FLUID. DO NOT DISPOSE OF FLUID DOWN DRAIN.
STORAGE:
STORE IN A COOL, DRY PLACE, SEPARATE FROM CAUSTIC STORAGE. AVOID CRUSHING
CONTAINERS. WHEN OPENING REFILL CONTAINERS INTERNAL PRESSURE MAY EJECT
PLASTIC PLUG AFTER THE CAP HAS BEEN REMOVED. ALWAYS OPEN CONTAINERS SLOWLY,
HOLDING AWAY FROM FACE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME EXPOSURE LIMITS
WATER AND CHLORIDE NONE ESTABLISHED
HYDROCHLORIC ACID (HYDROGEN CHLORIDE) 5 PPM OSHA PEL-CEILING
2 PPM ACGIH TLV-CEILING
2 PPM TWA DFG-MAK
1 PPM TWA, 5 PPM STEL UK WEL
ISOOCTYL ALCOHOLS (C7-9) 50 PPM TLV-TWA SKIN
50 PPM TWA UK WEL
ZINC CHLORIDE (AS FUME) 1 MG/M3 OSHA PEL-TWA
1 MG/M3 TWA, 2 MG/M3 STEL ACGIH TLV
1 MG/M3 TWA, 2 MG/M3 STEL UK WEL
CHROMIUM (II) CHLORIDE (AS Cr) 0.5 MG/M3 OSHA PEL-TWA
0.5 MG/M3 TWA UK WEL
VENTILATION: GENERAL VENTILATION SHOULD BE ADEQUATE FOR NORMAL USE.
RESPIRATORY PROTECTION: NONE REQUIRED FOR NORMAL USE. DO NOT INHALE VAPORS.
GLOVES:
RUBBER OR OTHER IMPERVIOUS GLOVES REQUIRED WHEN FILLING FYRITE OR PERFORMING
GAS ANALYSIS.
EYE PROTECTION:
WEAR CHEMICAL SAFETY GOGGLES AND FACE SHIELD WHEN FILLING FYRITE OR
PERFORMING GAS ANALYSIS.
OTHER PROTECTIVE EQUIPMENT:
AN AVAILABLE SOURCE OF RUNNING WATER FOR EYE AND SKIN FLUSHING IS
RECOMMENDED.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE AND ODOR:
BLUE LIQUID, UNPLEASANT CHLORINE ODOR. THE ODOR THRESHOLD FOR HYDROCHLORIC
ACID IS REPORTED TO BE 1-5 PPM.
pH: <1
SPECIFIC GRAVITY: >1
BOILING POINT: >100 DEG. C
VAPOR PRESSURE: NOT AVAILABLE
MELTING POINT: <0 DEG. C
VAPOR DENSITY: NOT AVAILABLE
SOLUBILITY IN WATER:
ISOOCTYL ALCOHOL: INSOLUBLE
PERCENT VOLATILE: >50%
OCTANOL/WATER COEFFICIENT: NOT DETERMINED
FLASH POINT: NOT COMBUSTIBLE
TEST METHOD: N/A
AUTOIGNITION TEMPERATURE: N/A
FLAMMABLE LIMITS:
LEL: N/A
UEL: N/A
| SECTION 10: STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: EXTREMELY HIGH TEMPERATURES.
INCOMPATIBILITY:
METALS, BASES, MANY ORGANIC MATERIALS INCLUDING CYANIDES, SULFIDES, AND
ALDEHYDES. AVOID EXPOSURE TO ANY CHEMICAL WHOSE COMPATIBILITY HAS NOT BEEN
ESTABLISHED.
HAZARDOUS DECOMPOSITION PRODUCTS:
REACTION WITH METALS CAN LIBERATE FLAMMABLE HYDROGEN GAS. HEATING TO
DECOMPOSITION WILL RELEASE HYDROGEN CHLORIDE, CHLORINE AND POSSIBLY CHROMIUM
AND ZINC COMPOUNDS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
POTENTIAL HEALTH EFFECTS:
EYE CONTACT:
MAY CAUSE SEVERE IRRITATION WITH POSSIBLE CHEMICAL BURNS AND PERMANENT
DAMAGE.
SKIN CONTACT:
MAY CAUSE IRRITATION OR CHEMICAL BURNS, SEVERITY DEPENDS ON DURATION OF
CONTACT. REPEATED CONTACT MAY RESULT IN ALLERGIC REACTION (SENSITIZATION).
INHALATION:
MAY CAUSE EYE, MUCOUS MEMBRANE AND RESPIRATORY IRRITATION. SEVERE
OVEREXPOSURES MAY CAUSE PULMONARY EDEMA.
INGESTION:
MAY CAUSE GASTROINTESTINAL CORROSION, NAUSEA, VOMITING, INTENSE THIRST AND
SHOCK FOLLOWED BY RENAL FAILURE AND LIVER INJURY. MAY BE FATAL IF SWALLOWED.
CHRONIC HEALTH EFFECTS:
PROLONGED EXPOSURE TO CHROMIUM SALTS MAY CAUSE AN ALLERGIC DERMATITIS,
BRONCHIAL ASTHMA AND PERFORATION OF THE NASAL SEPTUM. DIVALENT AND TRIVALENT
CHROMIUM COMPOUNDS ARE CONSIDERED TO HAVE A LOW ORDER OF SYSTEMIC TOXICITY.
ALTHOUGH HEXAVALENT CHROMIUM IS CONSIDERED TO BE CARCINOGENIC, TRIVALENT AND
DIVALENT CHROMIUM COMPOUNDS ARE NOT. PROLONGED INHALATION OF HYDROCHLORIC
ACID VAPORS MAY CAUSE LUNG CHANGES AND DENTAL EROSION.
CARCINOGEN STATUS:
NONE OF THE COMPONENTS IS LISTED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY
IARC, NTP, OSHA OR THE EU DIRECTIVES.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
PRE-EXISTING SKIN AND RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY EXPOSURE
TO THIS MATERIAL.
ACUTE TOXICITY DATA:
CHROMIUM (II) CHLORIDE:
LD50 ORAL RAT: 1,870 MG/KG.
HYDROCHLORIC ACID:
LC50 INHALATION RAT: 3,124 PPM/1HR.
LD50 ORAL RABBIT: 900 MG/KG
ZINC CHLORIDE:
LD50 ORAL RAT: 350 MG/KG
IRRITANCY DATA: THIS MATERIAL IS CORROSIVE TO TISSUES.
SENSITIZATION:
CHROMIUM SALTS HAVE BEEN REPORTED TO CAUSE SKIN AND RESPIRATORY
SENSITIZATION.
REPRODUCTIVE TOXICITY:
THIS MATERIAL HAS NOT BEEN TESTED AS A WHOLE. ZINC CHLORIDE AND CHROMIUM
(II) CHLORIDE HAVE BEEN REPORTED TO CAUSE ADVERSE REPRODUCTIVE EFFECTS IN
LABORATORY ANIMALS.
TERATOGENICITY:
THIS MATERIAL HAS NOT BEEN TESTED AS A WHOLE. ZINC CHLORIDE, HYDROCHLORIC
ACID AND CHROMIUM (II) CHLORIDE HAVE BEEN REPORTED TO CAUSE BIRTH DEFECTS IN
LABORATORY ANIMALS.
MUTAGENICITY:
THIS MATERIAL HAS NOT BEEN TESTED A WHOLE. HYDROCHLORIC ACID, ZINC CHLORIDE
AND CHROMIUM (II) CHLORIDE HAVE TESTED POSITIVE FOR MUTAGENICITY IN SOME
TEST SYSTEMS.
SYNERGISTIC EFFECTS:
THERE ARE NO CHEMICALS KNOWN TO CAUSE ANY ADDITIVE ADVERSE HEALTH EFFECTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
THE ECOLOGICAL EFFECTS OF THIS PRODUCT HAVE NOT BEEN EVALUATED.
| SECTION 13: DISPOSAL | |
DISPOSE IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL REGULATIONS.
RCRA HAZARDOUS WASTE CODES: D002, D007
| SECTION 14: TRANSPORTATION DATA | |
DOT SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC ACID, ZINC
CHLORIDE)
DOT HAZARD CLASS: 8, PG II
UN NUMBER: UN3264
DOT LABELS REQUIRED (49 CFR 172.101): CORROSIVE
HAZARDOUS SUBSTANCE (49 CFR 172.101): ZINC CHLORIDE
REPORTABLE QUANTITY: 26,300 LBS (PRODUCT)
EMERGENCY RESPONSE GUIDE NUMBER: 154
IATA SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., (HYDROCHLORIC ACID, ZINC
CHLORIDE)
IATA HAZARD CLASS: 8, PG II
UN NUMBER: UN3264
IATA HAZARD LABELS REQUIRED: CORROSIVE (CARGO AIRCRAFT ONLY 1-30 LITERS)
| SECTION 15: OTHER REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 311/312:
HAZARD CATEGORIES FOR SARA SECTION 311/312 REPORTING:
ACUTE HEALTH, CHRONIC HEALTH.
SARA 313:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO ANNUAL RELEASE
REPORTING REQUIREMENTS UNDER SARA SECTION 313 (40 CFR 372):
CHROMIUM (II) CHLORIDE 6.3% (AS Cr)
HYDROCHLORIC ACID 3%
ZINC CHLORIDE 11.4% (AS Zn)
CERCLA SECTION 103 REPORTABLE QUANTITY:
26,300 LBS. (ZINC CHLORIDE - 1000 LBS.)
US TOXIC SUBSTANCES CONTROL ACT:
ALL OF THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA TSCA INVENTORY.
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER AND/OR REPRODUCTIVE HARM: NONE
INTERNATIONAL REGULATIONS:
AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES:
ALL OF THE COMPONENTS IN THIS PRODUCT ARE LISTED ON THE AICS INVENTORY.
CANADIAN WHMIS CLASSIFICATION:
CLASS D-2-B (TOXIC MATERIAL CAUSING OTHER CHRONIC EFFECTS)
CLASS E (CORROSIVE MATERIAL)
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA IN
THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.
EUROPEAN INVENTORY OF COMMERCIAL CHEMICAL SUBSTANCES:
ALL OF THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EINECS INVENTORY.
EUROPEAN COMMUNITY LABELING: CONTAINS CHROMIUM(II) CHLORIDE
CORROSIVE
DANGEROUS FOR THE ENVIRONMENT
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
R43: MAY CAUSE SENSITIZATION BY SKIN CONTACT.
R51/53:
TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
S24/25: AVOID CONTACT WITH SKIN AND EYES.
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE.
S37: WEAR SUITABLE GLOVES.
S61:
AVOID RELEASE TO THE ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/MATERIAL
SAFETY DATA SHEET.
KOREAN EXISTING CHEMICAL INVENTORY:
ALL OF THE COMPONENTS IN THE PRODUCT ARE LISTED ON THE KECL INVENTORY.
PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES:
ALL OF THE COMPONENTS IN THIS PRODUCT ARE LISTED ON THE PICCS INVENTORY.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD RATING:
HEALTH 3
FIRE 0
REACTIVITY 0
EU CLASSES AND RISK PHRASES FOR REFERENCE (SEE SECTIONS 2 AND 3):
C: CORROSIVE
N: DANGEROUS FOR THE ENVIRONMENT
Xi: IRRITANT
Xn: HARMFUL
R22: HARMFUL IF SWALLOWED.
R34: CAUSES BURNS.
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
R37: IRRITATING TO RESPIRATORY SYSTEM.
R43: MAY CAUSE SENSITIZATION BY SKIN CONTACT
R50/53:
VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
R51/53:
TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
DATE OF PREVIOUS MSDS REVISION: 7/16/03
REVISION SUMMARY: REVISED SECTION 2, 3, 6, 8, 9, 11, 15
THE PRECEDING INFORMATION IS BELIEVED TO BE CORRECT AND CURRENT AS OF THE
DATE OF PREPARATION OF THIS MATERIAL SAFETY DATA SHEET. SINCE THE USE OF
THIS INFORMATION AND THE CONDITIONS OF USE OF THE PRODUCT ARE NOT WITHIN THE
CONTROL OF BACHARACH, INC., IT IS THE USERS OBLIGATION TO ASSURE SAFE USE OF
THIS PRODUCT.
N/D=NOT DETERMINED
N/A=NOT APPLICABLE