| Common Name: | GE5000 12G-CRTRG (0.730 LBS-0.331 KG) SILICONE RUBBER SEALANT |
| Manufacturer: | GENERAL ELECTRIC |
| SDS Revision Date: | 12/14/2006 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4UH03 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
GE
ADVANCED MATERIALS - SILICONES
VERSION: 1.4
12/14/2006
GE5000 12G-CRTRG (0.730 LBS-0.331 KG) SILICONE RUBBER SEALANT
| 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
MANUFACTURED BY:
GES WATERFORD PLANT
260 HUDSON RIVER RD
WATERFORD, NY 12188
REVISED: 12/14/2006
PREPARER: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
CHEMTREC: 1-800-424-9300
CHEMICAL FAMILY/USE: SILICONE RUBBER
FORMULA: MIXTURE
HMIS:
HEALTH 1
FLAMMABILITY 0
REACTIVITY 0
PROT. EQUIPM.
NFPA:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
SPECIAL HAZ.
| 2. COMPOSITION/INFORMATION ON INGREDIENTS | |
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HAZARDOUS:
DISTILLATES, PETROLEUM, HYDROTREATED LIGHT 64742-47-8 5 - 10%
HEXAMETHYLDISILAZANE 999-97-3 1 - 5%
METHYLTRIMETHOXYSILANE 1185-55-3 1 - 5%
B. NON-HAZARDOUS:
TREATED FUMED SILICA 68583-49-3 10 - 30%
POLYDIMETHYLSILOXANE 63148-62-9 10 - 30%
METHOXYPOLYDIMETHYLSILOXANE 68037-58-1 30 - 60%
| 3. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING!
MAY BE HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. IRRITATING
TO EYES, RESPIRATORY SYSTEM AND SKIN. MAY CAUSE CENTRAL NERVOUS SYSTEM
DEPRESSION. MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS. ADVERSE REPRODUCTIVE
EFFECTS REPORTED IN ANIMALS.
FORM: SOLID
COLOR: TRANSLUCENT
ODOR: AMMONIA
POTENTIAL HEALTH EFFECTS:
INGESTION:
MAY BE HARMFUL IF SWALLOWED. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. MAY
CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, AND DIARRHEA.
SKIN:
UNCURED PRODUCT CONTACT WILL IRRITATE LIPS, GUMS AND TONGUE. MAY CAUSE SKIN
IRRITATION. MAY BE ABSORBED THROUGH SKIN AND PRODUCE EFFECTS AS LISTED
UNDER "INGESTION".
INHALATION:
APPLIES IN UNCURED STATE. MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY ALSO
CAUSE OTHER EFFECTS AS LISTED UNDER "INGESTION".
EYES: EYE IRRITATION ON CONTACT WITH THE UNCURED PRODUCT.
MEDICAL CONDITIONS AGGRAVATED:
RESPIRATORY DISORDER. CENTRAL NERVOUS SYSTEM DISORDERS. SKIN DISORDERS.
SUBCHRONIC (TARGET ORGAN): LIVER; CENTRAL NERVOUS SYSTEM
CHRONIC EFFECTS / CARCINOGENICITY:
THIS PRODUCT OR ONE OF ITS INGREDIENTS PRESENT AT 0.1% OR MORE IS NOT
LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN BY NTP, IARC, OR OSHA.
ROUTES OF EXPOSURE: DERMAL; EYES
| 4. FIRST AID MEASURES | |
INGESTION:
DO NOT INDUCE VOMITING. SLOWLY DILUTE WITH 1-2 GLASSES OF WATER OR MILK AND
SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.
SKIN:
TO CLEAN FROM SKIN, REMOVE COMPLETELY WITH A DRY CLOTH OR PAPER TOWEL,
BEFORE WASHING WITH DETERGENT AND WATER.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION USING A BARRIER DEVICE. IF BREATHING IS DIFFICULT GIVE OXYGEN.
GET MEDICAL ATTENTION.
EYES:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES AND GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
NOTE TO PHYSICIAN: TREATMENT IS SYMPTOMATIC AND SUPPORTIVE.
| 5. FIRE-FIGHTING MEASURES | |
FLASH POINT:
METHOD: NOT APPLICABLE
IGNITION TEMPERATURE:: UNKNOWN
FLAMMABLE LIMITS IN AIR - LOWER (%): NOT APPLICABLE
FLAMMABLE LIMITS IN AIR - UPPER (%): NOT APPLICABLE
SENSITIVITY TO MECHANICAL IMPACT: NO
SENSITIVITY TO STATIC DISCHARGE:
SENSITIVITY TO STATIC DISCHARGE IS NOT EXPECTED.
EXTINGUISHING MEDIA:
ALL STANDARD EXTINGUISHING AGENTS ARE SUITABLE. NONE
SPECIAL FIRE FIGHTING PROCEDURES:
FIREFIGHTERS MUST WEAR NIOSH/MSHA APPROVED POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACE MASK AND FULL PROTECTIVE CLOTHING.
| 6. ACCIDENTAL RELEASE MEASURES | |
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
WIPE, SCRAPE OR SOAK UP IN AN INERT MATERIAL AND PUT IN A CONTAINER FOR
DISPOSAL. WASH WALKING SURFACES WITH DETERGENT AND WATER TO REDUCE SLIPPING
HAZARD. WEAR PROPER PROTECTIVE EQUIPMENT AS SPECIFIED IN THE PROTECTIVE
EQUIPMENT SECTION. INCREASE AREA VENTILATION.
| 7. HANDLING AND STORAGE | |
STORAGE:
STORE AWAY FROM HEAT, SOURCES OF IGNITION, AND INCOMPATIBLES. KEEP OUT OF
THE REACH OF CHILDREN.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
AVOID CONTACT WITH SKIN AND EYES. REMOVE CONTACT LENSES BEFORE USING
SEALANT. DO NOT HANDLE LENSES UNTIL ALL SEALANT HAS BEEN CLEANED FROM THE
FINGERTIPS, NAILS AND CUTICLES. RESIDUAL SEALANT MAY REMAIN ON FINGERS FOR
SEVERAL DAYS AND TRANSFER TO LENSES AND CAUSE SEVERE EYE IRRITATION. USE
ONLY IN WELL-VENTILATED AREAS. KEEP CONTAINER CLOSED WHEN NOT IN USE.
PRODUCT RELEASES METHANOL DURING APPLICATION AND CURING. PRODUCT RELEASES
AMMONIA DURING APPLICATION AND CURING.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
EYEWASH STATIONS; SHOWERS; VENTILATION AND OTHER FORMS OF ENGINEERING
CONTROLS ARE PREFERRED FOR CONTROLLING EXPOSURES. RESPIRATORY PROTECTION
MAY BE NEEDED FOR NON-ROUTINE OR EMERGENCY SITUATIONS.
RESPIRATORY PROTECTION:
IF EXPOSURE LIMITS ARE EXCEEDED OR RESPIRATORY IRRITATION IS EXPERIENCED,
NIOSH/MSHA APPROVED RESPIRATORY PROTECTION SHOULD BE WORN. SUPPLIED AIR
RESPIRATORS MAY BE REQUIRED FOR NON-ROUTINE OR EMERGENCY SITUATIONS.
RESPIRATORY PROTECTION MUST BE PROVIDED IN ACCORDANCE WITH OSHA REGULATIONS
(SEE 29 CFR 1910.134),
PROTECTIVE GLOVES: CLOTH GLOVES.
EYE AND FACE PROTECTION: SAFETY GLASSES
OTHER PROTECTIVE EQUIPMENT:
WEAR SUITABLE PROTECTIVE CLOTHING AND EYE/FACE PROTECTION.
EXPOSURE GUIDELINES:
COMPONENT CAS RN SOURCE VALUE
TREATED FUMED SILICA 68583-49-3 ACGIH, TWA RESPIRABLE DUST.
3 MG/M3
TREATED FUMED SILICA 68583-49-3 ACGIH, TWA INHALABLE DUST.
10 MG/M3
TREATED FUMED SILICA 68583-49-3 OSHA Z1, TWA PEL RESPIRABLE DUST.
5 MG/M3
TREATED FUMED SILICA 68583-49-3 OSHA Z1, TWA PEL TOTAL DUST.
15 MG/M3
ABSENCE OF VALUES INDICATES NONE FOUND
PEL - OSHA PERMISSIBLE EXPOSURE LIMIT
TLV - ACGIH THRESHOLD LIMIT VALUE
TWA - TIME WEIGHTED AVERAGE
OSHA REVOKED THE FINAL RULE LIMITS OF JANUARY 19, 1989 IN RESPONSE TO THE
11TH CIRCUIT COURT OF APPEALS DECISION (AFL-CIO V. OSHA) EFFECTIVE JUNE
30, 1993. SEE 29 CFR 1910.1000 (58 FR 35338).
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT - C & F: NOT APPLICABLE
VAPOR PRESSURE (20 C) (MMHG): NOT APPLICABLE
VAPOR DENSITY (AIR=1):
FREEZING POINT: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
PHYSICAL STATE: SOLID
ODOR: AMMONIA
COLOR: TRANSLUCENT
EVAPORATION RATE (BUTYL ACETATE=1): <1
SPECIFIC GRAVITY (WATER=1): CA. 1.05
DENSITY: NOT APPLICABLE
ACID / ALKALINITY (MEQ/G): UNKNOWN
pH: NOT APPLICABLE
VOLATILE ORGANIC CONTENT (VOL): NOT APPLICABLE
SOLUBILITY IN WATER (20 C): NEGLIGIBLE
SOLUBILITY IN ORGANIC SOLVENT (STATE SOLVENT): TOLUENE
VOC EXCL. H2O & EXEMPTS (G/L): CA. 27
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS:
CARBON MONOXIDE; CARBON DIOXIDE (CO2); SILICON DIOXIDE.; METHANOL;
FORMALDEHYDE; AMMONIA
INCOMPATIBILITY (MATERIALS TO AVOID): NONE KNOWN.
CONDITIONS TO AVOID:
VAPOR AND/OR LIQUID REACT WITH WATER TO FORM AMMONIA. APPLIES IN UNCURED
STATE.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE ORAL:
REMARKS: UNKNOWN
ACUTE DERMAL:
REMARKS: UNKNOWN
ACUTE INHALATION:
REMARKS: UNKNOWN
OTHER:
NONE., CONTAINS DIBUTYLTIN COMPOUND(S) - MAY IMPAIR FERTILITY. MAY CAUSE
HARM TO UNBORN CHILD.
SENSITIZATION: NO DATA AVAILABLE
SKIN IRRITATION: NO DATA AVAILABLE
EYE IRRITATION: NO DATA AVAILABLE
MUTAGENICITY: UNKNOWN
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGY: ECOTOXICOLOGICAL DATA FOR THIS PRODUCT IS NOT AVAILABLE.
CHEMICAL FATE: NO DATA AVAILABLE
DISTRIBUTION: NO DATA AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHOD:
DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS.
| 14. TRANSPORT INFORMATION | |
FURTHER INFORMATION:
THIS PRODUCT IS NOT REGARDED AS DANGEROUS GOODS ACCORDING TO THE NATIONAL
AND INTERNATIONAL REGULATIONS ON THE TRANSPORT OF DANGEROUS GOODS.
| 15. REGULATORY INFORMATION | |
INVENTORIES:
CANADA DSL INVENTORY: Y (POSITIVE LISTING)
KOREA EXISTING CHEMICALS INVENTORY (KECI): Y (POSITIVE LISTING)
CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES: Y (POSITIVE LISTING)
AUSTRALIA INVENTORY OF CHEMICAL SUBSTANCES (AICS): Y (POSITIVE LISTING)
PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES (PICCS):
Y (POSITIVE LISTING)
TSCA LIST: Y (POSITIVE LISTING)
EU LIST OF EXISTING CHEMICAL SUBSTANCES: Y (POSITIVE LISTING)
CANADA NDSL INVENTORY: N (NEGATIVE LISTING)
JAPAN INVENTORY OF EXISTING & NEW CHEMICAL SUBSTANCES (ENCS):
N (NEGATIVE LISTING)
FOR INVENTORIES THAT ARE MARKED AS QUANTITY RESTRICTED OR SPECIAL CASES,
PLEASE CONTACT GE.
US REGULATORY INFORMATION:
CERCLA:
PRODUCT COMPOSITION CHEMICAL CERCLA REPORTABLE QUANTITY
CLEAN AIR ACT:
CLEAN WATER ACT:
SARA SECTION 302:
SARA (311, 312) HAZARD CLASS: ACUTE HEALTH HAZARD
SARA (313) CHEMICALS:
CANADIAN REGULATORY INFORMATION:
WHMIS HAZARD CLASS:
D2A: VERY TOXIC MATERIALS
D2B: TOXIC MATERIALS
OTHER:
SCHDLE B/HTSUS: 3214.10 MASTIC BASED ON RUBBER
ECCN: EAR99
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH, OR ANY OTHER REPRODUCTIVE DEFECTS.
| 16. OTHER INFORMATION | |
OTHER:
C = CEILING LIMIT
NEGL = NEGLIGIBLE
EST = ESTIMATED
NF = NONE FOUND
NA = NOT APPLICABLE
UNKN = UNKNOWN
NE = NONE ESTABLISHED
REC = RECOMMENDED
ND = NONE DETERMINED
V = RECOMMENDED BY VENDOR
SKN = SKIN
TS = TRADE SECRET
R = RECOMMENDED
MST = MIST
NT = NOT TESTED
STEL = SHORT TERM EXPOSURE LIMIT
PPM = PARTS PER MILLION
PPB = PARTS PER BILLION
BY-PRODUCT = REACTION BY-PRODUCT, TSCA INVENTORY STATUS NOT REQUIRED UNDER
40 CFR PART 720.30(H-2).
THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS PRODUCT
SPECIFICATIONS. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS MADE. THE
RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO
BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE
RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE
WHETHER THEY ARE APPROPRIATE.