| Common Name: | VICTOR LOCK DE-ICER |
| Manufacturer: | ULTRAMOTIVE |
| SDS Revision Date: | 8/20/2004 |
| SDS Format: | No Format Specified |
| Item Number(s): | 1EZH2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
PREPARED TO U.S. OSHA, CMA, ANSI, CANADIAN WHMIS STANDARDS AND EUROPEAN EC
DIRECTIVES. THIS MATERIAL SAFETY DATA SHEET IS OFFERED PURSUANT TO OSHA'S
HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). OTHER GOVERNMENT
REGULATIONS MUST BE REVIEWED FOR APPLICABILITY TO THIS PRODUCT.
PART I: WHAT IS THE MATERIAL AND WHAT DO I NEED TO KNOW IN AN EMERGENCY?
| 1. PRODUCT IDENTIFICATION |  |
TRADE NAME (AS LABELED): VICTOR LOCK DE-ICER
CHEMICAL NAME/CLASS: FLAMMABLE AEROSOL MIXTURE
SYNONYMS: NOT APPLICABLE
PRODUCT USE: DE-ICING OF LOCKS
SUPPLIER/MANUFACTURER'S NAME: ULTRAMOTIVE CORPORATION
ADDRESS:
PO BOX 58
CUSHING BLVD
BETHEL, VT 05032
EMERGENCY PHONE:
NORTH AMERICA: 1-800-424-9300 (CHEMTREC)
INTERNATIONAL: 1-703-527-3887 (CHEMTREC)
BUSINESS PHONE: 1-802-234-9901
DATE OF PREPARATION: AUGUST 20, 2004
| 2. HAZARD IDENTIFICATION | |
EMERGENCY OVERVIEW:
THIS PRODUCT IS A COLORLESS, ODORLESS, FLAMMABLE LIQUID IN A PRESSURIZED
CAN, WITH CARBON DIOXIDE AS A PROPELLANT.
HEALTH HAZARDS:
THE HEALTH HAZARDS ASSOCIATED WITH OVEREXPOSURE ARE MINIMAL, DUE TO THE
SMALL SIZE OF THE CONTAINER AND SMALL VOLUME OF THE CONTENTS. THE LIQUID IS
IN SUCH SMALL QUANTITY THAT IT DOES NOT NORMALLY PRESENT A HEALTH HAZARD. IF
A RELEASE OF MANY CONTAINERS OF THIS PRODUCT OCCURS AT THE SAME TIME,
INHALATION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. IN ADDITION, UNDER
THESE CIRCUMSTANCES AN OXYGEN-DEFICIENT ENVIRONMENT CAN OCCUR, RESULTING IN
A HAZARD OF ASPHYXIATION. IF THE CONTAINER IS HEATED OR PUNCTURED, RUPTURE
OF THE CONTAINER MAY OCCUR, AND MAY CAUSE INJURY. FROSTBITE CAN BE CAUSED BY
CONTACT WITH RAPIDLY EXPANDING GASES.
FLAMMABILITY HAZARDS:
DUE TO THE HIGH LEVEL OF ISOPROPANOL IN THIS PRODUCT, IT MUST BE CONSIDERED
AS FLAMMABLE. VAPORS OF THIS PRODUCT ARE HEAVIER THAN AIR AND MAY SPREAD
LONG DISTANCES; DISTANT IGNITION AND FLASH-BACK ARE POSSIBLE.
REACTIVITY HAZARDS: THIS PRODUCT IS NOT REACTIVE.
ENVIRONMENTAL HAZARDS:
RELEASE OF THIS PRODUCT TO THE ENVIRONMENT IS NOT EXPECTED TO CAUSE HARM
UNLESS A LARGE QUANTITY OF CONTAINERS IS RELEASED.
EMERGENCY RECOMMENDATIONS:
PERSONS RESPONDING TO AN EMERGENCY SUCH AS A FIRE THAT INVOLVES THIS PRODUCT
MUST TAKE PRECAUTIONS TO AVOID POTENTIAL INJURY FROM CONTAINERS THAT RUPTURE
AND FOR THE FLAMMABILITY OF THE PRODUCT.
EC CLASSIFICATION:
DUE TO THE OVERALL SMALL AMOUNT OF PRODUCT CONTAINED IN EACH CAN (LESS THAN
10 ML), NO CLASSIFICATION OF THIS PRODUCT IS REQUIRED, PER COUNCIL DIRECTIVE
83/265/EEC, 16 MAY, 1983, ARTICLE 6, 6
RISK PHRASES: NOT APPLICABLE.
SAFETY PHRASES: NOT APPLICABLE.
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE:
CONTACT WITH THIS PRODUCT IS NOT EXPECTED TO CAUSE SIGNIFICANT ADVERSE
HEALTH EFFECTS, DUE TO THE SMALL SIZE OF CONTAINER AND LIMITED AMOUNT OF
GAS WITHIN THE CONTAINER.
INHALATION:
INHALATION OF VAPORS CAN IRRITATE THE MUCOUS MEMBRANES, THE NOSE, THROAT AND
RESPIRATORY TRACT. HUMAN SYSTEMIC EFFECTS FOLLOWING EXPOSURE VIA INHALATION
(AND INGESTION) INCLUDE FLUSHING, PULSE RATE DECREASE, LOWERING OF BLOOD
PRESSURE, HEADACHE, ANESTHESIA, NARCOSIS, DIZZINESS, MENTAL DEPRESSION,
HALLUCINATIONS, DISTORTED PERCEPTIONS, DYSPNEA, RESPIRATORY DEPRESSION,
NAUSEA OR VOMITING AND IN EXTREME CASES, COMA HAVE BEEN REPORTED FOR THE
MAIN COMPONENT, ISOPROPANOL. HIGH CONCENTRATIONS OF VAPORS, AS MAY OCCUR IF
THE PRODUCT IS USED OR RELEASED IN A POORLY-VENTILATED AREA OR CONFINED
SPACE (OR DURING A RELEASE OF LARGE VOLUMES OF THIS PRODUCT), CAN CAUSE
UNCONSCIOUSNESS. IN ADDITION, SUCH CONDITIONS MAY PRODUCE AN
OXYGEN-DEFICIENT ENVIRONMENT. INDIVIDUALS BREATHING SUCH AN ATMOSPHERE MAY
EXPERIENCE SYMPTOMS WHICH INCLUDE HEADACHES, RINGING IN EARS, DIZZINESS,
DROWSINESS, UNCONSCIOUSNESS, NAUSEA, VOMITING, AND DEPRESSION OF ALL THE
SENSES. UNDER SOME CIRCUMSTANCES OF OVEREXPOSURE, DEATH MAY OCCUR. THE
EFFECTS ASSOCIATED WITH VARIOUS LEVELS OF OXYGEN ARE AS FOLLOWS:
CONCENTRATION OF OXYGEN OBSERVED EFFECT
12-16% OXYGEN BREATHING AND PULSE RATE INCREASE,
MUSCULAR COORDINATION SLIGHTLY DISTURBED.
10-14% OXYGEN EMOTIONAL UPSET, ABNORMAL FATIGUE,
DISTURBED RESPIRATION.
6-10% OXYGEN NAUSEA, VOMITING, COLLAPSE, OR LOSS OF
CONSCIOUSNESS.
BELOW 6% CONVULSIVE MOVEMENTS, POSSIBLE RESPIRATORY
COLLAPSE, AND DEATH.
VAPORS OF THIS PRODUCT ARE HEAVIER THAN AIR. HIGH CONCENTRATIONS CAN
ACCUMULATE IN LOW-LYING AREAS, RESULTING IN A HAZARD OF INHALATION OF AN
OXYGEN-DEFICIENT ATMOSPHERE, WHICH MAY BE FATAL.
CONTACT WITH SKIN OR EYES:
CONTACT OF THIS PRODUCT WITH THE SKIN IS NOT EXPECTED TO CAUSE ADVERSE
EFFECT. IF THIS PRODUCT IS SPRAYED OR RELEASED DIRECTLY INTO THE EYES OR TO
THE SKIN, FROSTBITE MAY OCCUR, WITH DAMAGE TO TISSUE. REPEATED SKIN CONTACT
MAY CAUSE DEFATTING OF THE SKIN, RESULTING IN DERMATITIS, WITH DRY, RED,
ITCHY SKIN.
INGESTION: NOT A LIKELY ROUTE OF EXPOSURE.
HEALTH EFFECTS OR RISKS FROM EXPOSURE:
AN EXPLANATION IN LAY TERMS. OVER-EXPOSURE TO THIS GAS MIXTURE MAY CAUSE THE
FOLLOWING HEALTH EFFECTS.
ACUTE:
THERE ARE NO ANTICIPATED ACUTE EFFECTS AFTER EXPOSURE TO THIS PRODUCT. IN
THE EVENT THAT A VERY LARGE NUMBER OF CONTAINERS ARE RELEASED
SIMULTANEOUSLY, ADVERSE EFFECTS ON THE CENTRAL NERVOUS SYSTEM AND IRRITATION
MAY OCCUR AND AN OXYGEN-DEFICIENT ENVIRONMENT MAY BE PRODUCED.
CHRONIC: CHRONIC EXPOSURE TO THIS PRODUCT MAY CAUSE DERMATITIS TO THE SKIN.
TARGET ORGANS:
ACUTE: EYES, RESPIRATORY SYSTEM, CARDIOVASCULAR AND CENTRAL NERVOUS SYSTEMS.
CHRONIC: SKIN.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM:
HEALTH HAZARD (BLUE) 1
FLAMMABILITY HAZARD (RED) 3
PHYSICAL HAZARD (YELLOW) 0
PROTECTIVE EQUIPMENT
EYES: CHEMICAL GOGGLES
RESPIRATORY: SEE SECTION 8
HANDS: GLOVES
BODY: SEE SECTION 8
FOR ROUTINE INDUSTRIAL USE AND HANDLING APPLICATIONS
SEE ORIGINAL MSDS FOR DEFINITION OF RATINGS
| 3. COMPOSITION AND INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS# EINECS # % W/W
CARBON DIOXIDE (PROPELLANT GAS) 124-38-9 204-696-6 TRACE
WHITE MINERAL OIL 8042-47-5 232-455-8 3.9%
ISOPROPANOL 67-63-0 200-661-7 96.1%
NE = NOT ESTABLISHED.
SEE ORIGINAL MSDS FOR DEFINITIONS OF TERMS USED.
NOTE (1):
ALL WHMIS REQUIRED INFORMATION IS INCLUDED IN APPROPRIATE SECTIONS BASED
ON THE ANSI Z400.1-1998 FORMAT. THIS PRODUCT HAS BEEN CLASSIFIED IN
ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL
THE INFORMATION REQUIRED BY THE CPR.
PART II: WHAT SHOULD I DO IF A HAZARDOUS SITUATION OCCURS?
| 4. FIRST-AID MEASURES | |
VICTIMS OF CHEMICAL EXPOSURE MUST BE TAKEN FOR MEDICAL ATTENTION, IF ADVERSE
HEALTH EFFECTS OCCUR. RESCUERS SHOULD BE TAKEN FOR MEDICAL ATTENTION, IF
NECESSARY. TAKE COPY OF LABEL AND MSDS TO HEALTH PROFESSIONAL WITH VICTIM.
SKIN EXPOSURE:
IF SKIN CONTACT RESULTS IN IRRITATION OR OTHER ADVERSE EFFECT, SEEK THE
ADVICE OF A DOCTOR.
EYE EXPOSURE:
IF THIS PRODUCT ENTERS THE EYES, OPEN VICTIM'S EYES WHILE UNDER GENTLE
RUNNING WATER. USE SUFFICIENT FORCE TO OPEN EYELIDS. HAVE VICTIM "ROLL"
EYES. MINIMUM FLUSHING IS FOR 15 MINUTES. VICTIM MUST SEEK MEDICAL ATTENTION
IF ADVERSE HEALTH EFFECTS OCCUR.
INHALATION:
IF THIS GAS INHALED, REMOVE VICTIM TO FRESH AIR. IF NECESSARY, USE
ARTIFICIAL RESPIRATION TO SUPPORT VITAL FUNCTIONS. SEEK MEDICAL ATTENTION
IF ADVERSE EFFECT OCCURS.
INGESTION: NOT A LIKELY ROUTE OF EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
PRE-EXISTING CENTRAL NERVOUS SYSTEM OR SKIN DISORDERS MAY BE AGGRAVATED BY
THIS PRODUCT.
RECOMMENDATIONS TO PHYSICIANS: TREAT SYMPTOMS AND ELIMINATE OVEREXPOSURE.
| 5. FIRE-FIGHTING MEASURES | |
FLASH POINT: NOT DETERMINED FOR PRODUCT.
FOR ISOPROPANOL: 11.7 DEG. C (53 DEG. F)
AUTOIGNITION TEMPERATURE: NOT DETERMINED FOR PRODUCT.
FOR ISOPROPANOL: 399 DEG. C (750 DEG. F)
FLAMMABLE LIMITS (IN AIR BY VOLUME, %):
LOWER (LEL): NOT DETERMINED FOR PRODUCT.
FOR ISOPROPANOL: 2.0%
UPPER (UEL): NOT DETERMINED FOR PRODUCT.
FOR ISOPROPANOL: 12.0%
FIRE EXTINGUISHING MATERIALS:
IF THIS PRODUCT IS INVOLVED IN A FIRE, USE EXTINGUISHING MATERIALS
APPROPRIATE FOR SURROUNDING MATERIALS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
THE MAIN COMPONENT OF THIS PRODUCT, ISOPROPANOL, IS A CLASS IC FLAMMABLE
LIQUID. WHEN INVOLVED IN A FIRE, THIS PRODUCT MAY DECOMPOSE AND PRODUCE
TOXIC GASES (INCLUDING CARBON MONOXIDE AND CARBON DIOXIDE). VAPORS OF THIS
PRODUCT MAY FORM EXPLOSIVE MIXTURES WITH AIR, AT OR ABOVE 11.7 DEG. C
(53 DEG. F). THE VAPORS OF THIS PRODUCT ARE HEAVIER THAN AIR AND MAY SPREAD
LONG DISTANCES; DISTANT IGNITION AND FLASH-BACK ARE POSSIBLE. VAPORS CAN
ACCUMULATE IN CONFINED SPACES, CREATING AN OXYGEN-DEFICIENT ATMOSPHERE AND
FLAMMABILITY HAZARD.
EXPLOSION SENSITIVITY TO MECHANICAL IMPACT: NOT SENSITIVE.
EXPLOSION SENSITIVITY TO STATIC DISCHARGE: NOT SENSITIVE.
SPECIAL FIRE-FIGHTING PROCEDURES:
INCIPIENT FIRE RESPONDERS SHOULD WEAR EYE PROTECTION. STRUCTURAL
FIREFIGHTERS MUST WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL
PROTECTIVE EQUIPMENT. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE
WITHOUT RISK TO PERSONNEL. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS
COOL. IF POSSIBLE, PREVENT RUN-OFF WATER FROM ENTERING STORM DRAINS, BODIES
OF WATER, OR OTHER ENVIRONMENTALLY SENSITIVE AREAS.
NFPA RATING:
HEALTH 1
FLAMMABILITY 3
INSTABILITY 0
OTHER
SEE ORIGINAL MSDS FOR DEFINITION OF RATINGS
| 6. ACCIDENTAL RELEASE MEASURES | |
LEAK RESPONSE:
A RELEASE OF A SINGLE CONTAINER OR SEVERAL CONTAINERS PRESENTS A MINIMAL
HAZARD. ALLOW CONTAINERS TO VENT AND REMOVE CONTAINER FOR APPROPRIATE
DISPOSAL. IF A LARGE QUANTITY OF CANS OF THIS PRODUCT IS INVOLVED, EVACUATE
IMMEDIATE AREA. VAPORS OF THIS PRODUCT THAN AIR; RELEASES WILL CONCENTRATE
IN LOW-LYING AREAS, CREATING POCKETS OF AN OXYGEN-DEFICIENT ATMOSPHERE AND
MAY CREATE A FLAMMABILITY HAZARD. UNCONTROLLED RELEASES SHOULD BE RESPONDED
TO BY TRAINED PERSONNEL USING PRE-PLANNED PROCEDURES. PROPER PROTECTIVE
EQUIPMENT SHOULD BE USED. ELIMINATE ALL SOURCES OF IGNITION BEFORE CLEANUP
OPERATIONS BEGIN. USE NON-SPARKING TOOLS. IF A LARGE QUANTITY OF PRODUCT IS
INVOLVED, THE MINIMUM PERSONAL PROTECTIVE EQUIPMENT SHOULD BE LEVEL B:
SELF-CONTAINED BREATHING APPARATUS. ALLOW THE PRODUCT TO DISSIPATE. MONITOR
THE SURROUNDING AREA FOR THE LEVEL OF OXYGEN. MONITOR THE SURROUNDING AREA
FOR COMBUSTIBLE VAPOR LEVELS. THE LEVEL OF COMBUSTIBLE VAPORS MUST BE BELOW
10% OF THE LEL OF COMPONENTS (SEE SECTION 5, FIRE-FIGHTING MEASURES) AND
THE ATMOSPHERE MUST HAVE AT LEAST 19.5 PERCENT OXYGEN BEFORE PERSONNEL ARE
ALLOWED INTO THE SPILL AREA. DISPOSE OF INVOLVED CANS IN ACCORDANCE WITH
APPLICABLE U.S. FEDERAL, STATE, OR LOCAL PROCEDURES, OR APPROPRIATE CANADIAN
STANDARDS AND THOSE OF EC MEMBER STATES (SEE SECTION 13, DISPOSAL
CONSIDERATIONS).
PART III: HOW CAN I PREVENT HAZARDOUS SITUATIONS FROM OCCURRING
| 7. HANDLING AND STORAGE | |
WORK PRACTICES AND HYGIENE PRACTICES:
DO NOT EAT OR DRINK WHILE HANDLING THIS MATERIAL. USE VENTILATION AND OTHER
ENGINEERING CONTROLS TO MINIMIZE POTENTIAL EXPOSURE TO THE AEROSOL OF THIS
PRODUCT.
STORAGE AND HANDLING PRACTICES:
STORE CONTAINERS IN A COOL, DRY LOCATION, AWAY FROM DIRECT SUNLIGHT, SOURCES
OF INTENSE HEAT, OR WHERE FREEZING IS POSSIBLE. MATERIAL SHOULD BE STORED
IN SECONDARY CONTAINERS OR IN A DIKED AREA, AS APPROPRIATE. STORE CONTAINERS
AWAY FROM INCOMPATIBLE CHEMICALS (SEE SECTION 10, STABILITY AND REACTIVITY).
CONTAINERS SHOULD BE SEPARATED FROM OXIDIZING MATERIALS BY A MINIMUM
DISTANCE OF 20 FT. OR BY A BARRIER OF NON-COMBUSTIBLE MATERIAL AT LEAST
5 FT. HIGH HAVING A FIRE-RESISTANCE RATING OF AT LEAST 0.5 HOURS. STORAGE
AREAS SHOULD BE MADE OF FIRE RESISTANT MATERIALS, POST WARNING AND "NO
SMOKING" SIGNS IN STORAGE AND USE AREAS, AS APPROPRIATE. HAVE APPROPRIATE
EXTINGUISHING EQUIPMENT IN THE STORAGE AREA (I.E., SPRINKLER SYSTEM,
PORTABLE FIRE EXTINGUISHERS). INSPECT ALL INCOMING CONTAINERS BEFORE STORAGE
TO ENSURE CONTAINERS ARE PROPERLY LABELED AND NOT DAMAGED. REFER TO NFPA 30,
FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE, FOR ADDITIONAL INFORMATION ON
STORAGE. EMPTY CONTAINERS MAY CONTAIN RESIDUAL LIQUID OR VAPORS WHICH ARE
FLAMMABLE; THEREFORE, EMPTY CONTAINERS SHOULD BE HANDLED WITH CARE. DO NOT
INCINERATE EMPTY OR PARTIALLY FILLED CONTAINERS.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT:
NOT APPLICABLE.
| 8. EXPOSURE CONTROLS - PERSONAL PROTECTION | |
EXPOSURE LIMITS/GUIDELINES:
CHEMICAL NAME CAS #
CARBON DIOXIDE 124-38-9
MINERAL OIL 8042-47-5
ISOPROPANOL 67-63-0
CHEMICAL EXPOSURE LIMITS IN AIR
NAME ACGIH-TLV OSHA-PEL NIOSH IDLH OTHER
TWA STEL TWA STEL TWA STEL PPM PPM
PPM PPM PPM PPM PPM PPM
CARBON 5000 30.000 5000 30,000 5000 30,000 40,000 DFG
DIOXIDE 10,000 (VACA- MAKS:
(VACA- TED TWA: 5000
TED 1989 PEAK: 2
1989 PEL) MAK 15
PEL) MIN.,
AVERAGE
VALUE,
1-HR
INTERVAL
MINERAL NIC: NE NE NE NE NE NE CARCI-
OIL 0.2 NOGEN:
(INHA- IARC-3
LABLE
FRAC-
TION)
ISOPROPANOL 200 400 400 500 400 500 2000 DFG
(VACA- (BASED MAKS:
TED ON 10% TWA: 200
1989 OF PEAK: 2
PEL) LEL) MAK 15
MIN.,
AVERAGE
VALUE,
1-HR
INTERVAL
MAK
PREGNANCY
RISK
GROUP
CLASSIFI-
CATION: C
CARCI-
NOGEN:
IARC-3
TLV-A4
NE = NOT ESTABLISHED.
SEE ORIGINAL MSDS FOR DEFINITIONS OF TERMS USED.
VENTILATION AND ENGINEERING CONTROLS:
NOT NECESSARY UNDER NORMAL CONDITIONS OF USE.
RESPIRATORY PROTECTION:
NO RESPIRATORY PROTECTION IS NORMALLY REQUIRED WHEN USING THIS PRODUCT.
MAINTAIN AIRBORNE CONTAMINANT CONCENTRATIONS BELOW GUIDELINES LISTED IN
SECTION 2 (COMPOSITION AND INFORMATION ON INGREDIENTS), IF APPLICABLE. IF
RESPIRATORY PROTECTION IS NEEDED, USE ONLY PROTECTION AUTHORIZED IN THE
U.S. FEDERAL OSHA STANDARD (29 CFR 1910.134), APPLICABLE U.S. STATE
REGULATIONS, OR THE CANADIAN CSA STANDARD Z94.4-93 AND APPLICABLE STANDARDS
OF CANADIAN PROVINCES, AND, THE EUROPEAN STANDARD EN149, AND EC MEMBER
STATES. OXYGEN LEVELS BELOW 19.5% ARE CONSIDERED IDLH BY OSHA. IN SUCH
ATMOSPHERES, USE OF A FULL-FACEPIECE PRESSURE/DEMAND SCBA OR A FULL
FACEPIECE, SUPPLIED AIR RESPIRATOR WITH AUXILIARY SELF-CONTAINED AIR SUPPLY
IS REQUIRED UNDER OSHA'S RESPIRATORY PROTECTION STANDARD (1910.134-1998).
THE FOLLOWING ARE NIOSH RESPIRATORY PERSONAL PROTECTIVE EQUIPMENT GUIDELINES
FOR THE MAIN COMPONENT, ISOPROPANOL.
ISOPROPANOL:
CONCENTRATION RESPIRATORY PROTECTION
UP TO 2000 PPM ANY SUPPLIED-AIR RESPIRATOR (SAR) OPERATED IN A
CONTINUOUS-FLOW MODE, OR ANY CHEMICAL CARTRIDGE
RESPIRATOR WITH A FULL FACEPIECE AND ORGANIC VAPOR
CARTRIDGE(S), OR ANY AIR-PURIFYING, FULL-FACEPIECE
RESPIRATOR (GAS MASK) WITH A CHIN-STYLE, FRONT - OR
BACK-MOUNTED ORGANIC VAPOR CANISTER, OR ANY POWERED,
AIR-PURIFYING RESPIRATOR (PAPR) WITH ORGANIC VAPOR
CARTRIDGE(S), OR ANY SELF-CONTAINED BREATHING
APPARATUS (SCBA) WITH A FULL FACEPIECE, OR ANY SAR
WITH A FULL FACEPIECE.
EMERGENCY OR PLANNED ANY SCBA THAT HAS A FULL FACEPIECE AND IS OPERATED
ENTRY INTO UNKNOWN IN A PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE
CONCENTRATIONS OR MODE, OR ANY SAR THAT HAS A FULL FACEPIECE AND IS
IDLH CONDITIONS OPERATED IN A PRESSURE-DEMAND OR OTHER
POSITIVE-PRESSURE MODE IN COMBINATION WITH AN
AUXILIARY SCBA OPERATED IN PRESSURE-DEMAND OR OTHER
POSITIVE-PRESSURE MODE.
ESCAPE ANY AIR-PURIFYING, FULL-FACEPIECE RESPIRATOR
(GAS MASK) WITH A CHIN-STYLE, FRONT - OR
BACK-MOUNTED ORGANIC VAPOR CANISTER, OR ANY
APPROPRIATE ESCAPE-TYPE, SCBA.
EYE PROTECTION:
NONE NEEDED UNDER NORMAL USE. IF A HAZARD OF FLYING DEBRIS MAY OCCUR, WEAR
SAFETY GLASSES OR GOGGLES. IF NECESSARY, REFER TO U.S. OSHA 29 CFR 1910.133,
OR APPROPRIATE CANADIAN STANDARDS. IF NECESSARY, REFER TO U.S. OSHA 29 CFR
1910.133, CANADIAN STANDARDS, OR THE EUROPEAN STANDARD EN166.
HAND PROTECTION:
NONE NEEDED UNDER NORMAL CONDITIONS OF USE. IF NECESSARY, REFER TO U.S. OSHA
29 CFR 1910.138 APPROPRIATE STANDARDS OF CANADA, OR THE EUROPEAN ECONOMIC
COMMUNITY.
BODY PROTECTION:
NONE NEEDED FOR NORMAL CIRCUMSTANCES OF USE. IF NECESSARY, REFER TO
APPROPRIATE STANDARDS OF CANADA AND THE EUROPEAN ECONOMIC COMMUNITY. IF
A HAZARD OF INJURY TO THE FEET EXISTS DUE TO FALLING OBJECTS, ROLLING
OBJECTS, WHERE OBJECTS MAY PIERCE THE SOLES OF THE FEET OR WHERE EMPLOYEE'S
FEET MAY BE EXPOSED TO ELECTRICAL HAZARDS, USE FOOT PROTECTION, AS DESCRIBED
IN U.S. OSHA 29 CFR.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
THE FOLLOWING VALUES ARE FOR THE MAIN COMPONENT, ISOPROPANOL.
VAPOR DENSITY (AIR = 1): 2.07
BOILING POINT: 82.3 DEG. C (180 DEG. F)
FREEZING/MELTING POINT: -88.5 DEG. C (-127 DEG. F)
pH: NOT ESTABLISHED.
SPECIFIC GRAVITY @ 20 DEG. C (68 DEG. F) WATER = 1: 0.785
MOLECULAR WEIGHT: 60.09
SOLUBILITY IN WATER @ 25 DEG. C (77 DEG. F): MISCIBLE
EXPANSION RATIO: NOT APPLICABLE.
EVAPORATION RATE (nBuAc = 1): 1.5
SPECIFIC VOLUME: NOT APPLICABLE.
VAPOR PRESSURE 20 DEG. C (68 DEG. F): 33 MMHg; 4.4 KPA
LOG COEFFICIENT WATER/OIL DISTRIBUTION:
LOG P (OCT): 0.05
ODOR THRESHOLD:
3.3-610 PPM (GEOMETRIC MEAN 43 PPM) (DETECTION)
7.6-49 PPM (GEOMETRIC MEAN 19 PPM) (RECOGNITION)
THE FOLLOWING INFORMATION IS FOR THE PRODUCT:
APPEARANCE, ODOR AND COLOR:
THIS PRODUCT IS A COLORLESS, ODORLESS LIQUID IN A PRESSURIZED CAN, WITH
CARBON DIOXIDE AS A PROPELLANT.
HOW TO DETECT THIS SUBSTANCE (WARNING PROPERTIES):
THERE ARE NO DISTINCT WARNING PROPERTIES IN EVENT OF A RELEASE OF THIS
PRODUCT.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER CONDITIONS OF NORMAL TEMPERATURE AND PRESSURE.
DECOMPOSITION PRODUCTS:
IF EXPOSED TO FIRE, THIS PRODUCT MAY DECOMPOSE, YIELDING TOXIC PRODUCTS
(E.G., CARBON OXIDES).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE:
DUE TO THE HIGH LEVEL OF ISOPROPANOL, THIS PRODUCT WILL BE INCOMPATIBLE WITH
STRONG OXIDIZING AGENTS (I.E. PEROXIDES, PERCHLORATES, CHROMIUM TRIOXIDE),
WHICH WILL INCREASE THE RISK OF FIRE AND EXPLOSION. THE PRODUCT MAY REACT
VIOLENTLY OR VIGOROUSLY WITH STRONG ACIDS, SUCH AS NITRIC ACID, SULFURIC
ACID AND OLEUM, ACID ANHYDRIDES, DUE TO THE PRESENCE OF ISOPROPANOL, THIS
PRODUCT MAY GIVE OFF FLAMMABLE HYDROGEN GAS IN THE PRESENCE OF ALKALI OR
ALKALINE EARTH METALS. THE ISOPROPANOL COMPONENT REACTS VIGOROUSLY AND GIVES
OFF HEAT WITH ALUMINUM. ISOPROPANOL WILL REACT VIOLENTLY WITH CROTONALDEHYDE
OR PHOSGENE. ISOPROPANOL, IN CONTACT WITH POTASSIUM TERT-BUTOXIDE, MAY CAUSE
IGNITION. MIXTURES OR REACTIONS OF ISOPROPANOL WITH THE FOLLOWING MATERIALS
MAY CAUSE EXPLOSIONS: BARIUM PERCHLORATE, CHLORINE, DIOXYGENYL
TETRAFLUOROBORATE, HYPOCHLOROUS ACID, ETHYLENE OXIDE, HEXAMETHYLENE
DIISOCYANATE AND OTHER ISOCYANATES, NITROGEN PEROXIDE, PERMONOSULFURIC ACID
AND TRI-ISOBUTYL ALUMINUM. THIS PRODUCT MAY ATTACK SOME FORMS OF RUBBER,
PLASTICS AND COATINGS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
CONDITIONS TO AVOID: EXTREME TEMPERATURES, INCOMPATIBLE MATERIALS.
PART IV IS THERE ANY OTHER USEFUL INFORMATION ABOUT THIS MATERIAL?
| 11. TOXICOLOGICAL INFORMATION | |
TOXICITY DATA:
THE FOLLOWING ARE TOXICOLOGICAL DATA FOR COMPONENTS OF GREATER THAN 1%:
ISOPROPANOL:
STANDARD DRAIZE TEST (SKIN-RABBIT) 500 MG: MILD
STANDARD DRAIZE TEST (EYE-RABBIT) 100 MG: SEVERE
STANDARD DRAIZE TEST (EYE-RABBIT) 10 MG: MODERATE
STANDARD DRAIZE TEST (EYE-RABBIT) 100 MG/24 HOURS: MODERATE
TDLO (ORAL-HUMAN): 286 MG/KG
CARDIAC: ARRHYTHMIAS (INCLUDING CHANGES IN CONDUCTION)
BEHAVIORAL: COMA; KIDNEY, URETER
BLADDER: OTHER CHANGES
TDLO (ORAL-HUMAN): 223 MG/KG
BEHAVIORAL: HALLUCINATIONS, DISTORTED PERCEPTIONS
CARDIAC: PULSE RATE
VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION
TDLO (ORAL-MAN): 14,432 MG/KG
BEHAVIORAL: COMA
VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
TDLO (ORAL-INFANT): 13 GM/KG
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY), IRRITABILITY
GASTROINTESTINAL: NAUSEA OR VOMITING
TDLO (UNREPORTED-INFANT): 1375 MG/KG
SENSE ORGANS AND SPECIAL SENSES (EYE): EFFECT, NOT OTHERWISE SPECIFIED
BEHAVIORAL:
SOMNOLENCE (GENERAL DEPRESSED ACTIVITY), HALLUCINATIONS, DISTORTED
PERCEPTIONS
LDLO (ORAL-HUMAN): 571 ML/KG
LDLO (ORAL-MAN): 5272 MG/KG
BEHAVIORAL: COMA
VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION
LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA
LDLO (ORAL-HUMAN): 3570 MG/KG
BEHAVIORAL: COMA
LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
GASTROINTESTINAL: NAUSEA OR VOMITING
LDLO (UNREPORTED-HUMAN): 2 ML/KG
LDLO (UNREPORTED-HUMAN): 2770 MG/KG
LC50 (INHALATION-RAT): 72,600 MG/M3
BEHAVIORAL: GENERAL ANESTHETIC
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
LC50 (INHALATION-MOUSE): 53,000 MG/M3
BEHAVIORAL: GENERAL ANESTHETIC
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
LD50 (ORAL-RAT): 5045 MG/KG
BEHAVIORAL:
ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX), (GENERAL DEPRESSED
ACTIVITY)
LD50 (ORAL-RAT): 5000 MG/KG
BEHAVIORAL: GENERAL ANESTHETIC
LD50 (ORAL-MOUSE): 3600 MG/KG
BEHAVIORAL: GENERAL ANESTHETIC
LD50 (ORAL-RABBIT): 6410 MG/KG
LD50 (INTRAVENOUS-MOUSE): 1509 MG/KG
LD50 (SKIN-RABBIT): 12,800 MG/KG
LD50 (INTRAVENOUS-RABBIT): 1184 MG/KG
LD50 (INTRAPERITONEAL-RABBIT): 667 MG/KG
LD50 (INTRAPERITONEAL-GUINEA PIG): 2560 MG/KG
LD50 (INTRAPERITONEAL-HAMSTER): 3444 MG/KG
LDLO (ORAL-DOG): 1537 MG/KG
GASTROINTESTINAL: NAUSEA OR VOMITING
LDLO (ORAL-CAT): 6 ML/KG
LDLO (INTRAVENOUS-DOG): 1024 MG/KG
LDLO (INTRAVENOUS-CAT): 1963 MG/KG
LDLO (PARENTERAL-FROG): 20 GM/KG
PERIPHERAL NERVE AND SENSATION:
SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
LDLO (SUBCUTANEOUS-MOUSE): 6 GM/KG
LDLO (SUBCUTANEOUS-MAMMAL-SPECIES UNSPECIFIED): 6 GM/KG
PERIPHERAL NERVE AND SENSATION:
SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
BEHAVIORAL: GENERAL ANESTHETIC
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
TDLO (ORAL-RAT): 7 ML/KG/7 DAYS-INTERMITTENT
LIVER: OTHER CHANGES
BIOCHEMICAL:
EFFECT ON SPECIFIC COENZYME: B VITAMINS INCLUDING FOLATE
TDLO (ORAL-RAT): 11,340 MG/KG/45 DAYS-INTERMITTENT
ENDOCRINE: EFFECT ON MENSTRUAL CYCLE
TDLO (ORAL-RAT): 2196 MG/KG/122 DAYS-INTERMITTENT
ENDOCRINE: EFFECT ON MENSTRUAL CYCLE
TDLO (ORAL-RAT): 2196 MG/KG/122 DAYS-INTERMITTENT
REPRODUCTIVE:
PATERNAL EFFECTS:
SPERMATOGENESIS (INCL. GENETIC MATERIAL, SPERM MORPHOLOGY, MOTILITY, AND
COUNT)
TDLO (ORAL-RAT): 11,340 MG/KG FEMALE 45 DAY(S) PRE-MATING
REPRODUCTIVE:
MATERNAL EFFECTS: MENSTRUAL CYCLE CHANGES OR DISORDERS
TDLO (ORAL-RAT): 5040 MG/KG
FEMALE 1-20 DAY(S) AFTER CONCEPTION:
REPRODUCTIVE:
FERTILITY: LITTER SIZE (E.G. # FETUSES PER LITTER; MEASURED BEFORE BIRTH)
TDLO (ORAL-RAT): 8 GM/KG
FEMALE 6-15 DAY(S) AFTER CONCEPTION:
REPRODUCTIVE:
EFFECTS ON EMBRYO OR FETUS: FETOTOXICITY (EXCEPT DEATH, E.G., STUNTED FETUS)
TDLO (ORAL-RAT): 32,400 (MICRO)G/KG:
FEMALE 26 WEEK(S) PRE-MATING:
REPRODUCTIVE:
EFFECTS ON EMBRYO OR FETUS: FETAL DEATH
TDLO (ORAL-RAT): 3500 GM/KG
MULTIGENERATION:
REPRODUCTIVE:
FERTILITY:
MATING PERFORMANCE (E.G. # SPERM POSITIVE FEMALES PER # FEMALES MATED; #
COPULATIONS PER # ESTRUS CYCLES)
TDLO (INTRAPERITONEAL-RAT): 800 MG/KG
BEHAVIORAL: ATAXIA
TCLO (INHALATION-RAT):
8000 PPM/8 HOURS/20 WEEKS-INTERMITTENT:
PERIPHERAL NERVE AND SENSATION:
SENSORY CHANGE INVOLVING PERIPHERAL NERVE, RECORDING FROM PERIPHERAL MOTOR
NERVE
TCLO (INHALATION-RAT):
100 MG/M3/4 HOURS/17 WEEKS-INTERMITTENT: KIDNEY, URETER
BLADDER: OTHER CHANGES IN URINE COMPOSITION
BLOOD: CHANGES IN SERUM COMPOSITION (E.G. TP, BILIRUBIN, CHOLESTEROL)
BIOCHEMICAL:
ENZYME INHIBITION, INDUCTION, OR CHANGE IN BLOOD OR TISSUE LEVELS:
TRUE CHOLINESTERASE
TCLO (INHALATION-RAT): 5000 PPM/6 HOURS/90 DAYS-INTERMITTENT
BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
TCLO (INHALATION-RAT):
2500 PPM/6 HOURS/2 YEARS-INTERMITTENT:
LIVER
CHANGES IN LIVER WEIGHT
KIDNEY, URETER, BLADDER:
OTHER CHANGES IN URINE COMPOSITION, CHANGES IN BLADDER WEIGHT
TCLO (INHALATION-RAT): 500 MG/M3/4 HOURS/122 DAYS-INTERMITTENT
LIVER: MULTIPLE EFFECTS
KIDNEY, URETER, BLADDER: OTHER CHANGES
NUTRITIONAL AND GROSS METABOLIC: WEIGHT LOSS OR DECREASED WEIGHT GAIN
TCLO (INHALATION-RAT): 20 MG/M3/24 HOURS/90 DAYS-CONTINUOUS
BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
LIVER: MULTIPLE EFFECTS
TCLO (INHALATION-RAT): 3500 PPM/7 HOURS
FEMALE 1-19 DAY(S) AFTER CONCEPTION:
REPRODUCTIVE:
EFFECTS ON EMBRYO OR FETUS: FETOTOXICITY (EXCEPT DEATH, E.G., STUNTED FETUS)
TCLO (INHALATION-RAT): 10000 PPM/7 HOURS
FEMALE 1-19 DAY(S) AFTER CONCEPTION:
REPRODUCTIVE:
FERTILITY:
PRE-IMPLANTATION MORTALITY (E.G. REDUCTION IN NUMBER OF IMPLANTS PER FEMALE;
TOTAL NUMBER OF IMPLANTS PER CORPORA LUTEA), POST-IMPLANTATION MORTALITY
(E.G. DEAD AND/OR RESORBED IMPLANTS PER TOTAL NUMBER OF IMPLANTS)
EFFECTS ON EMBRYO OR FETUS: FETAL DEATH
TCLO (INHALATION-RAT): 4900 MG/M3/6 HOURS/2 WEEKS-INTERMITTENT
BIOCHEMICAL:
ENZYME INHIBITION, INDUCTION, OR CHANGE IN BLOOD OR TISSUE LEVELS:
MULTIPLE ENZYME EFFECTS
TCLO (INHALATION-RAT): 7000 PPM/7 HOURS
FEMALE 1-19 DAY(S) AFTER CONCEPTION:
REPRODUCTIVE: SPECIFIC
DEVELOPMENTAL:
ABNORMALITIES: MUSCULOSKELETAL SYSTEM
TCLO (INHALATION-RAT):
1000 MG/M3/6 HOURS/4 WEEKS-INTERMITTENT:
SENSE ORGANS AND SPECIAL SENSES (EYE): OPTIC NERVE NEUROPATHY
TCLO (INHALATION-MOUSE):
10000 PPM/6 HOURS/11 DAYS-INTERMITTENT:
BEHAVIORAL: GENERAL ANESTHETIC, ATAXIA; RELATED TO CHRONIC DATA; DEATH
TCLO (INHALATION-MOUSE): 5000 PPM/6 HOURS/13 WEEKS-INTERMITTENT
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
LIVER: CHANGES IN LIVER WEIGHT
BLOOD: PIGMENTED OR NUCLEATED RED BLOOD CELLS
TCLO (INHALATION-MOUSE): 5000 PPM/6 HOURS/13 WEEKS-INTERMITTENT
BEHAVIORAL: GENERAL ANESTHETIC, ATAXIA
LIVER: CHANGES IN LIVER WEIGHT
TCLO (INHALATION-MOUSE): 5000 PPM/6 HOURS/78 WEEKS-INTERMITTENT
BRAIN AND COVERINGS: CHANGES IN BRAIN WEIGHT
LIVER: CHANGES IN LIVER WEIGHT
KIDNEY, URETER, BLADDER:
CHANGES IN TUBULES (INCLUDING ACUTE RENAL FAILURE, ACUTE TUBULAR NECROSIS)
TCLO (INHALATION-MOUSE): 3000 PPM/6 MINUTES
LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
TCLO (INHALATION-GUINEA PIG):
980 MG/M3/24 HOURS: SENSE ORGANS AND SPECIAL SENSES (EAR)
EFFECT, NOT OTHERWISE SPECIFIED; BEHAVIORAL: GENERAL ANESTHETIC
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
TDLO (ORAL-RABBIT): 6240 MG/KG
FEMALE 6-18 DAY(S) AFTER CONCEPTION:
REPRODUCTIVE:
MATERNAL EFFECTS: OTHER EFFECTS
TDLO (ORAL-RAT): 3276 MG/KG
FEMALE 182 DAY(S) PRE-MATING:
REPRODUCTIVE: SPECIFIC DEVELOPMENTAL
ABNORMALITIES: OTHER DEVELOPMENTAL ABNORMALITIES
EFFECTS ON NEWBORN:
VIABILITY INDEX (E.G., # ALIVE AT DAY 4 PER # BORN ALIVE), GROWTH STATISTICS
(E.G.%, REDUCED WEIGHT GAIN)
CYTOGENETIC ANALYSIS (INHALATION-RAT):
1030 (MICRO)G/M3/16 WEEKS-INTERMITTENT
WHITE MINERAL OIL:
TDLO (ORAL-RAT): 92 GM/KG/92 DAYS-CONTINUOUS
LIVER: CHANGES IN LIVER WEIGHT
BLOOD: CHANGES IN LEUKOCYTE (WBC) COUNT
NUTRITIONAL AND GROSS METABOLIC: WEIGHT LOSS OR DECREASED WEIGHT GAIN
SUSPECTED CANCER AGENT:
COMPONENTS OF THIS PRODUCT ARE LISTED BY AGENCIES TRACKING CARCINOGENIC
POTENTIAL OF CHEMICAL COMPOUNDS, AS FOLLOWS:
ISOPROPYL ALCOHOL:
IARC-3:
(UNCLASSIFIABLE AS TO CARCINOGENICITY ICILY IN HUMANS)
ACGIH TLV-A4 (NOT CLASSIFIABLE AS A HUMAN CARCINOGEN)
WHITE MINERAL OIL:
IARC-3: (UNCLASSIFIABLE AS TO CARCINOGENICITY IN HUMANS)
THE REMAINING COMPONENTS OF THIS PRODUCT ARE NOT FOUND ON THE FOLLOWING
LISTS:
FEDERAL OSHA Z LIST, NTP, IARC, AND CAL/OSHA, AND THEREFORE ARE NOT
CONSIDERED TO BE, NOR SUSPECTED TO BE, CANCER-CAUSING AGENTS BY THESE
AGENCIES.
IRRITANCY OF PRODUCT:
THIS PRODUCT MAY BE IRRITATING IF CONTACT IS PROLONGED.
SENSITIZATION TO THE PRODUCT:
COMPONENTS OF THIS PRODUCT ARE NOT KNOWN TO BE A HUMAN SKIN OR RESPIRATORY
SENSITIZER.
REPRODUCTIVE TOXICITY INFORMATION:
LISTED BELOW IS INFORMATION CONCERNING THE EFFECTS OF THIS PRODUCT AND ITS
COMPONENTS ON THE HUMAN REPRODUCTIVE SYSTEM.
MUTAGENICITY:
COMPONENTS OF THIS PRODUCT ARE NOT REPORTED TO PRODUCE MUTAGENIC EFFECTS IN
HUMANS. DATA ARE AVAILABLE FOR ISOPROPANOL IN MICROORGANISMS.
EMBRYOTOXICITY:
COMPONENTS OF THIS PRODUCT ARE NOT REPORTED TO PRODUCE EMBRYOTOXIC EFFECTS
IN HUMAN.
TERATOGENICITY:
COMPONENTS OF THIS PRODUCT ARE NOT REPORTED TO CAUSE TERATOGENIC EFFECTS IN
HUMANS.
REPRODUCTIVE TOXICITY:
COMPONENTS OF THIS PRODUCT ARE NOT REPORTED TO CAUSE ADVERSE REPRODUCTIVE
EFFECTS IN HUMANS. ANIMAL REPRODUCTIVE TOXICITY DATA ARE AVAILABLE FOR
ISOPROPANOL; THESE DATA WERE OBTAINED DURING CLINICAL STUDIES ON SPECIFIC
ANIMAL TISSUES EXPOSED TO OF THIS COMPOUND.
A MUTAAEN IS A CHEMICAL WHICH CAUSES PERMANENT CHANGES TO GENETIC MATERIAL
(DNA) SUCH THAT THE CHANGES WILL PROPAGATE THROUGH GENERATIONAL LINES.
AN EMBRYOTOXIN IS A CHEMICAL WHICH CAUSES DAMAGE TO A DEVELOPING EMBRYO
(I.E. WITHIN THE FIRST EIGHT WEEKS OF PREGNANCY IN HUMANS), BUT THE DAMAGE
DOES NOT PROPAGATE ACROSS GENERATIONAL LINES.
A TERATOGEN IS A CHEMICAL WHICH CAUSES DAMAGE TO A DEVELOPING FETUS, BUT THE
DAMAGE DOES NOT PROPAGATE ACROSS GENERATIONAL LINES.
A REPRODUCTIVE TOXIN IS ANY SUBSTANCE WHICH INTERFERES IN ANY WAY WITH THE
REPRODUCTIVE PROCESS.
BIOLOGICAL EXPOSURE INDICES:
CURRENTLY, THERE ARE NO FOLLOWING BIOLOGICAL EXPOSURE INDICES (BEIS)
DETERMINED FOR THE COMPONENTS OF THIS PRODUCT.
| 12. ECOLOGICAL INFORMATION | |
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY:
THE FOLLOWING IS ENVIRONMENTAL FATE INFORMATION FOR COMPONENTS OF THIS
PRODUCT.
ISOPROPANOL:
TERRESTRIAL FATE:
BASED ON A CLASSIFICATION SCHEME, AN ESTIMATED KOC VALUE OF 25, DETERMINED
FROM A LOG KOW OF 0.05(2) AND A REGRESSION-DERIVED EQUATION, INDICATES THAT
ISOPROPANOL IS EXPECTED TO HAVE VERY HIGH MOBILITY IN SOIL. VOLATILIZATION
OF ISOPROPANOL FROM MOIST SOIL SURFACES IS EXPECTED TO BE AN IMPORTANT FATE
PROCESS GIVEN A HENRY'S LAW CONSTANT OF 8.10X10-6 ATM-CU M/MOLE. THE
POTENTIAL FOR VOLATILIZATION OF ISOPROPANOL FROM DRY SOIL SURFACES MAY EXIST
BASED UPON A VAPOR PRESSURE OF 45.4 MMHg. ISOPROPANOL IS READILY DEGRADED
IN AEROBIC SYSTEMS; THE RANGE OF HALF-LIVES FOR AEROBIC DEGRADATION USING A
SEWAGE SLUDGE INOCULUM ARE <1 DAY TO 48 DAYS. ISOPROPANOL HAS ALSO BEEN
SHOWN TO BE READILY DEGRADED UNDER ANAEROBIC CONDITIONS.
AQUATIC FATE:
BASED ON A CLASSIFICATION SCHEME, AN ESTIMATED KOC VALUE OF 25, DETERMINED
FROM A LOG KOW OF 0.05 AND A REGRESSION-DERIVED EQUATION, INDICATES THAT
ISOPROPANOL IS NOT EXPECTED TO ADSORB TO SUSPENDED SOLIDS AND SEDIMENT.
VOLATILIZATION FROM WATER SURFACES IS EXPECTED BASED UPON A HENRY'S LAW
CONSTANT OF 8.10X10-6 ATM-CU M/MOLE. USING THIS HENRY'S LAW CONSTANT AND
AN ESTIMATION METHOD, VOLATILIZATION HALF-LIVES FOR A MODEL RIVER AND MODEL
LAKE ARE 57 HOURS AND 29 DAYS, RESPECTIVELY. ACCORDING TO A CLASSIFICATION
SCHEME, AN ESTIMATED BCF OF 3, FROM A LOG KOW AND A REGRESSION-DERIVED
EQUATION, SUGGESTS THE POTENTIAL FOR BIOCONCENTRATION IN AQUATIC ORGANISMS
IS LOW. ISOPROPANOL IS READILY DEGRADED IN AEROBIC SYSTEMS; THE RANGE OF
HALF-LIVES FOR AEROBIC DEGRADATION USING A SEWAGE SLUDGE INOCULUM ARE <1
DAY TO 48 DAYS, ISOPROPANOL HAS ALSO BEEN SHOWN TO BE READILY DEGRADED UNDER
ANAEROBIC CONDITIONS.
ATMOSPHERIC FATE:
ACCORDING TO A MODEL OF GAS/PARTICLE PARTITIONING OF SEMI-VOLATILE ORGANIC
COMPOUNDS IN THE ATMOSPHERE, ISOPROPANOL, WHICH HAS A VAPOR PRESSURE OF
45.4 MMHg AT 25 DEG. C), IS EXPECTED TO EXIST SOLELY AS A VAPOR IN THE
AMBIENT ATMOSPHERE. VAPOR-PHASE ISOPROPANOL IS DEGRADED IN THE ATMOSPHERE
BY REACTION WITH PHOTOCHEMICALLY-PRODUCED HYDROXYL RADICALS; THE HALF-LIFE
FOR THIS REACTION IN AIR IS ESTIMATED TO BE 3.2 DAYS, CALCULATED FROM ITS
RATE CONSTANT OF 5.07X10-12 CU CM/MOLECULE-SEC AT 25 DEG. C.
BIOCONCENTRATION:
AN ESTIMATED BCF OF 3 WAS CALCULATED FOR ISOPROPANOL, USING A LOG KOW OF
0.05 AND A REGRESSION-DERIVED EQUATION. ACCORDING TO A CLASSIFICATION
SCHEME, THIS BCF SUGGESTS THE POTENTIAL FOR BIOCONCENTRATION IN AQUATIC
ORGANISMS IS LOW.
EFFECT OF MATERIAL ON PLANTS OR ANIMALS:
THIS PRODUCT IS NOT EXPECTED TO BE HARMFUL TO PLANT AND ANIMAL LIFE.
EFFECT OF CHEMICAL ON AQUATIC LIFE:
THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE EFFECTS TO AN AQUATIC
ENVIRONMENT. THE FOLLOWING ARE AQUATIC TOXICITY DATA FOR COMPONENTS OF THIS
PRODUCT:
ISOPROPANOL:
EC0 (MICROCYSTIS AERUGINOSA) 8 DAYS: 1,000 MG/L
EC0 (SCENEDESMUS QUADRICAUDA GREEN ALGAE) 7 DAYS: 1,800 MG/L
EC0 (ENTOSIPHON SULCATUM PROTOZOA) 72 HOURS: 4,930 MG/L
EC0 (URONEMA PARDUCZI CHATTON-LWOFF): 3,425 MG/L
EC50 (PHOTOBACTERIUM) 5 MINUTES: 22,800 MG/L
EC50 (DAPHNIA MAGNA): 3,010 MG/L
EC50 (PSEUDOMONAS PUTIDA) 16 HOURS: 1,050 MG/L
TOXIC (CHLORELLA PYRENOIDOSA ALGAE): 17,400 MG/L
NOEC (DAPHNIA MAGNA): 757-2,100 MG/L
LC0 (CREEK CHUB) 24 HOURS: 900 MG/L
LC50 (ARTEMIA SALINA) 24 HOURS: 16,700 MG/L
LC50 (STREPTOCEPHALUS PROBOSCIDEUS) 24 HOURS: 11,600 MG/L
LC50 (DAPHNIA MAGNA) 24 HOURS: 9500 MG/L
LC50 (BRACHIONUS CALYCIFLORUS) 24 HOURS: 28,600 MG/L
LC50 (CRANGON BROWN SHRIMP) 48 HOURS: 1,400 MG/L
LC50 (CRANGON BROWN SHRIMP) 98 HOURS: 1,150 MG/L
LC50 (GOLDFISH) 24 HOURS: >500 MG/L
LC50 (FATHEAD MINNOW) 1 HOUR: 11,830 MG/L
LC50 (FATHEAD MINNOW) 24 HOURS: 11,160 MG/L
LC50 (FATHEAD MINNOW) 48 HOURS: 11,130 MG/L
LC50 (FATHEAD MINNOW) 72 HOURS: 11,130 MG/L
LC50 (FATHEAD MINNOW) 96 HOURS: 11,130 MG/L
LC5O (POECILIA RETICULATA GUPPY) 7 DAYS: 7,060 MG/L
LC50 (DAPHNIA MAGNA): 4,600 MG/L
LC100 (CREEK CHUB) 24 HOURS: 1,100 MG/L
| 13. DISPOSAL CONSIDERATIONS | |
PREPARING WASTES FOR DISPOSAL:
PRODUCT REMOVED FROM THE CYLINDER MUST BE DISPOSED OF IN ACCORDANCE WITH
APPROPRIATE U.S. FEDERAL, STATE, AND LOCAL REGULATIONS, THOSE OF CANADA AND
ITS PROVINCES AND THE EC AND EC MEMBER STATES.
U.S. EPA WASTE NUMBER:
NOT APPLICABLE TO WASTES CONSISTING ONLY OF THIS PRODUCT.
| 14. TRANSPORTATION INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING REGULATIONS:
THIS PRODUCT IS CLASSIFIED (PER 49 CFR 172.101) BY THE U.S. DEPARTMENT OF
TRANSPORTATION, AS FOLLOWS.
PROPER SHIPPING NAME: CONSUMER COMMODITY
HAZARD CLASS NUMBER AND DESCRIPTION: ORM-D
UN IDENTIFICATION NUMBER: NOT APPLICABLE
PACKING GROUP: NOT APPLICABLE
DOT LABEL(S) REQUIRED: NONE
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): 171
MARINE POLLUTANT:
THE COMPONENTS OF THIS PRODUCT ARE NOT DESIGNATED BY THE DEPARTMENT OF
TRANSPORTATION TO BE MARINE POLLUTANTS (49 CFR 172.101, APPENDIX B).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:
THIS PRODUCT IS CLASSIFIED, PER REGULATIONS OF TRANSPORT CANADA. THE USE OF
THE ABOVE U.S. DOT INFORMATION FROM THE U.S. 49 CFR REGULATIONS IS ALLOWED
FOR SHIPMENTS THAT ORIGINATE IN THE U.S. FOR SHIPMENTS VIA GROUND VEHICLE OR
RAIL THAT ORIGINATE IN CANADA, THE FOLLOWING INFORMATION IS APPLICABLE.
PROPER SHIPPING NAME: CONSUMER COMMODITY (ISOPROPANOL)
HAZARD CLASS NUMBER AND DESCRIPTION: CLASS 2.1 (FLAMMABLE GAS)
UN IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NOT APPLICABLE
HAZARD LABEL(S) REQUIRED: CLASS 2.1 (FLAMMABLE GAS)
MARINE POLLUTANT: NOT APPLICABLE
SPECIAL PROVISIONS: 80
EXPLOSIVE LIMIT & LIMITED QUANTITY INDEX: 1
ERAP INDEX: NONE
PASSENGER CARRYING SHIP INDEX: NONE
PASSENGER CARRYING ROAD OR RAIL VEHICLE INDEX: 75
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA):
THIS PRODUCT IS CONSIDERED AS DANGEROUS GOODS UNDER THE RULES OF IATA.
PROPER SHIPPING NAME: CONSUMER COMMODITY
HAZARD CLASS NUMBER AND DESCRIPTION: 9 (MISCELLANEOUS HAZARDOUS MATERIAL)
UN IDENTIFICATION NUMBER: UN 8000
PACKING GROUP: NOT APPLICABLE
HAZARD LABEL(S) REQUIRED: CLASS 9 (MISCELLANEOUS)
PASSENGER & CARGO AIRCRAFT PACKING INSTRUCTION: 910
PASSENGER & CARGO AIRCRAFT MAXIMUM NET QUANTITY/PKG: 25 KG
CARGO AIRCRAFT ONLY PACKING INSTRUCTION: 910
CARGO AIRCRAFT ONLY MAXIMUM NET QUANTITY/PKG: 25 KG
SPECIAL PROVISIONS: A112
ERG CODE: 9L
INTERNATIONAL MARITIME ORGANIZATION (IMO):
THIS PRODUCT IS CLASSIFIED AS FOLLOWS, PER RULES OF THE IMO.
UN IDENTIFICATION NUMBER: UN 1950
PROPER SHIPPING NAME: AEROSOLS
CLASS: 2
SUBSIDIARY RISK: NONE
PACKING GROUP: NOT APPLICABLE
SPECIAL PROVISIONS: 63, 190, 191, 277, 913
HAZARD LABEL(S) REQUIRED: CLASS 2.1 (FLAMMABLE GAS)
LIMITED QUANTITIES: SEE SP 277
PACKING INSTRUCTION: P003
EMS: F-D, S-U
STOWAGE AND SEGREGATION:
CATEGORY A SEGREGATION, AS PER CLASS 9, BUT "AWAY FROM" SOURCES OF HEAT AND
"SEPARATED FROM" CLASS 1, EXCEPT DIVISION 1.4.
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS
BY ROAD (ADR):
THIS IS CLASSIFIED AS FOLLOWS, PER REGULATIONS OF THE U.N. ECONOMIC
COMMISSION FOR EUROPE.
UN NUMBER: UN 1950
NAME AND DESCRIPTION: AEROSOLS, FLAMMABLE
CLASS: 2
CLASSIFICATION CODE: 5F
PACKING GROUP: NOT APPLICABLE
LABELS: 2.1
SPECIAL PROVISIONS: 190, 625
LIMITED QUANTITIES: LQ2
PACKING INSTRUCTION: P204
MIXED PACKING INSTRUCTION: MP9
HAZARD IDENTIFICATION NUMBER: S2
| 15. REGULATORY INFORMATION | |
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS:
THE COMPONENTS OF THIS PRODUCT ARE SUBJECT TO THE REPORTING REQUIREMENTS
OF SECTIONS 302, 304, AND 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT, AS FOLLOWS:
COMPOUND SARA 302 SARA 304 SARA 313
(40 CFR 355, (40 CFR TABLE (40 CFR 372.65)
APPENDIX A) 302.4)
ISOPROPANOL NO NO YES (MANUFACTURING / STRONG
ACID PROCESS ONLY)
U.S. SARA THRESHOLD PLANNING QUANTITY:
NO COMPONENT OF THIS PRODUCT HAS SPECIFIC THRESHOLD PLANNING QUANTITIES FOR
ANY COMPONENT OF THIS PRODUCT. THE DEFAULT FEDERAL MSDS SUBMISSION AND
INVENTORY REQUIREMENT FILING THRESHOLD OF 10,000 LBS. (4,540 KG) THEREFORE
APPLIES, PER 40 CFR 370.20.
U.S. SARA HAZARD CATEGORIES (SECTION 311/312, 40 CFR 370-21):
ACUTE: YES
CHRONIC: NO
FIRE: YES
REACTIVE: NO
SUDDEN RELEASE: NO
U.S. TSCA INVENTORY STATUS:
THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY.
U.S. CERCLA REPORTABLE QUANTITY (RQ): NOT APPLICABLE.
ANSI LABELING (Z129.1) (PRECAUTIONARY STATEMENTS):
CAUTION!
KEEP AWAY FROM CHILDREN. FLAMMABLE AEROSOL UNDER PRESSURE, IF RELEASED IN
LARGE QUANTITY, A FLAMMABILITY HAZARD MAY RESULT OR MAY REDUCE OXYGEN
AVAILABLE FOR BREATHING. MAY CAUSE ADVERSE CENTRAL NERVOUS SYSTEM EFFECTS.
AVOID BREATHING GAS, VAPOR, OR MISTS. AVOID CONTACT WITH SKIN, CLOTHING,
AND EYES. USE ONLY WITH ADEQUATE VENTILATION. WASH THOROUGHLY IN CASE OF
CONTACT. WEAR GLOVES, GOGGLES, AND APPROPRIATE BODY PROTECTION WHEN
HANDLING. DO NOT PUNCTURE OR INCINERATE CONTAINER. DISPOSE OF IN ACCORDANCE
WITH FEDERAL, STATE, AND LOCAL REQUIREMENTS.
FIRST-AID:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN OR EYES FOR AT LEAST 15 MINUTES
WITH WATER, REMOVE CONTAMINATED CLOTHING AND SHOES. IF INHALED, MOVE TO
FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION IMMEDIATELY.
IN CASE OF FIRE:
USE FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE. REFER TO MATERIAL SAFETY DATA
SHEET FOR ADDITIONAL INFORMATION ON THIS PRODUCT.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS:
THE COMPONENT OF THIS PRODUCT IS ON THE DSL INVENTORY.
OTHER CANADIAN REGULATIONS: NOT APPLICABLE.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS:
THE COMPONENTS OF THIS PRODUCT ARE NOT ON THE CEPA FIRST PRIORITIES
SUBSTANCE LISTS.
CANADIAN WHMIS CLASSIFICATION AND SYMBOLS:
CLASS A: COMPRESSED GAS
CLASS B5: FLAMMABLE AEROSOLS
CLASS D2B: SKIN OR EYE IRRITATION
EUROPEAN COMMUNITY REGULATIONS:
EC LABELING AND CLASSIFICATION:
THIS PRODUCT IS DEFINED AS AN AEROSOL, AS DEFINED IN EC DIRECTIVE,
75/324/EEC. AS SUCH CONTAINERS AND PACKINGS OF THIS PRODUCT MUST BE CLEARLY
AND LEGIBLY MARKED AS FOLLOWS:
"PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C.
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT SPRAY ON NAKED FLAME OR ANY
INCANDESCENT MATERIAL".
EC CLASSIFICATION:
DUE TO THE OVERALL SMALL AMOUNT OF PRODUCT CONTAINED IN EACH CAN (LESS THAN
10 ML), NO CLASSIFICATION OF THIS PRODUCT IS REQUIRED, PER COUNCIL DIRECTIVE
83/265/EEC, 16 MAY, 1983, ARTICLE 6, 6
EC RISK PHRASES: NOT APPLICABLE.
EC SAFETY PHRASES: NOT APPLICABLE.
EUROPEAN COMMUNITY ANNEX II HAZARD SYMBOLS: NOT APPLICABLE.
| 16. OTHER INFORMATION | |
PREPARED BY:
CHEMICAL SAFETY ASSOCIATES, INC.
PO BOX 3519
LA MESA, CA 91944-3519
619/670-0609
DATE OF PRINTING: NOVEMBER 16, 2005
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. ULTRAMOTIVE
CORPORATION ASSUMES NO RESPONSIBILITY FOR INJURY TO THE VENDEE OR THIRD
PERSONS PROXIMATELY CAUSED BY THE MATERIAL IF REASONABLE SAFETY PROCEDURES
ARE NOT ADHERED TO AS STIPULATED IN THE DATA SHEET. ADDITIONALLY,
ULTRAMOTIVE CORPORATION, INC. ASSUMES NO RESPONSIBILITY FOR INJURY TO VENDEE
OR THIRD PERSONS PROXIMATELY CAUSED BY ABNORMAL USE OF THE MATERIAL EVEN IF
REASONABLE SAFETY PROCEDURES ARE FOLLOWED. FURTHERMORE, VENDEE ASSUMES THE
RISK IN HIS USE OF THE MATERIAL.
EFFECTIVE DATE: AUGUST 19, 2004