| Common Name: | GE284 3GG-TUBE (0.198 LBS-0.090 KG) SILICONE SEALANT |
| Manufacturer: | MOMENTIVE PERFORMANCE MATERIALS |
| SDS Revision Date: | 7/6/2007 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3LA50 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
MOMENTIVE PERFORMANCE MATERIALS
VERSION: 1.2
07/06/2007
GE284 3GG-TUBE (0.198 LBS-0.090 KG) SILICONE SEALANT
| 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
MANUFACTURED BY:
WATERFORD PLANT
260 HUDSON RIVER RD
WATERFORD, NY 12188
REVISED: 07/06/2007
PREPARER: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
CHEMTREC: 1-800-424-9300
CHEMICAL FAMILY/USE: SEALANT
FORMULA: MIXTURE
HMIS:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
NFPA:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
| 2. COMPOSITION/INFORMATION ON INGREDIENTS | |
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HAZARDOUS:
HEXAMETHYL DISILAZANE 999-97-3 1 - 5 %
METHYL TRIMETHOXYSILANE 1185-55-3 1 - 5 %
DISTILLATES, PETROLEUM, HYDROTREATED 64742-47-8 5 - 10 %
B. NON-HAZARDOUS:
TREATED FILLER 68611-44-9 10 - 30 %
POLYDIMETHYLSILOXANE 63148-62-9 10 - 30 %
METHOXYPOLYDIMETHYLSILOXANE 68037-58-1 60 - 90 %
| 3. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING!
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED. MAY CAUSE
SKIN, EYE, AND STOMACH IRRITATION. MAY CAUSE CENTRAL NERVOUS SYSTEM
DEPRESSION. MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS. ADVERSE REPRODUCTIVE
EFFECTS REPORTED IN ANIMALS.
FORM: SOLID
COLOR: TRANSLUCENT
ODOR: AMMONIA
POTENTIAL HEALTH EFFECTS:
INGESTION:
MAY BE HARMFUL IF SWALLOWED. MAY CAUSE STOMACH DISCOMFORT. MAY CAUSE
CENTRAL NERVOUS SYSTEM EFFECTS. MAY CAUSE GASTROINTESTINAL IRRITATION,
NAUSEA, VOMITING, AND DIARRHEA. NOT AN ANTICIPATED ROUTE OF EXPOSURE.
SKIN:
SKIN IRRITATION IS POSSIBLE AFTER CONTACT WITH THE UNCURED PRODUCT. UNCURED
PRODUCT CONTACT WILL IRRITATE LIPS, GUMS AND TONGUE. MAY CAUSE MILD SKIN
IRRITATION. MAY BE ABSORBED THROUGH SKIN AND PRODUCE EFFECTS AS LISTED
UNDER "INGESTION".
INHALATION:
CAUSES MILD RESPIRATORY TRACT IRRITATION. APPLIES IN UNCURED STATE. MAY
ALSO CAUSE OTHER EFFECTS AS LISTED UNDER "INGESTION".
EYES:
EYE IRRITATION ON CONTACT WITH THE UNCURED PRODUCT. MAY CAUSE MILD EYE
IRRITATION.
MEDICAL CONDITIONS AGGRAVATED: PRE-EXISTING SKIN OR RESPIRATORY DISEASES.
SUBCHRONIC (TARGET ORGAN):
SKIN
CENTRAL NERVOUS SYSTEM
CHRONIC EFFECTS / CARCINOGENICITY:
THIS PRODUCT OR ONE OF ITS INGREDIENTS PRESENT AT 0.1% OR MORE IS NOT
LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN BY NTP, IARC, OR OSHA.
ROUTES OF EXPOSURE:
INHALATION
DERMAL
EYES
ORAL.
| 4. FIRST AID MEASURES | |
INGESTION:
DO NOT INDUCE VOMITING. IF VICTIM IS CONSCIOUS, GIVE 1-3 GLASSES OF WATER
TO DRINK. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET
MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN:
TO CLEAN FROM SKIN, REMOVE COMPLETELY WITH A DRY CLOTH OR PAPER TOWEL,
BEFORE WASHING WITH DETERGENT AND WATER. GET MEDICAL ATTENTION IF
IRRITATION PERSISTS.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION USING A BARRIER DEVICE. IF BREATHING IS DIFFICULT GIVE OXYGEN.
GET MEDICAL ATTENTION.
EYES:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES AND GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
NOTE TO PHYSICIAN: NONE KNOWN.
| 5. FIRE-FIGHTING MEASURES | |
METHOD: NOT APPLICABLE
IGNITION TEMPERATURE: UNKNOWN
FLAMMABLE LIMITS IN AIR - LOWER (%): NOT APPLICABLE
FLAMMABLE LIMITS IN AIR - UPPER (%): NOT APPLICABLE
SENSITIVITY TO MECHANICAL IMPACT: NO
EXTINGUISHING MEDIA: ALL STANDARD EXTINGUISHING AGENTS ARE SUITABLE.
SPECIAL FIRE FIGHTING PROCEDURES:
FIREFIGHTERS MUST WEAR NIOSH/MSHA APPROVED POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACE MASK AND FULL PROTECTIVE CLOTHING.
| 6. ACCIDENTAL RELEASE MEASURES | |
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
WIPE, SCRAPE OR SOAK UP IN AN INERT MATERIAL AND PUT IN A CONTAINER FOR
DISPOSAL. WASH WALKING SURFACES WITH DETERGENT AND WATER TO REDUCE SLIPPING
HAZARD. WEAR PROPER PROTECTIVE EQUIPMENT AS SPECIFIED IN THE PROTECTIVE
EQUIPMENT SECTION.
PERSONAL PRECAUTIONS:
AVOID CONTACT WITH SKIN AND EYES. PRODUCT RELEASES METHANOL DURING
APPLICATION AND CURING. USE MECHANICAL VENTILATION TO STAY BELOW TLV OF 25
PPM AMMONIA. KEEP CONTAINER TIGHTLY CLOSED. REMOVE CONTACT LENSES BEFORE
USING SEALANT. DO NOT HANDLE LENSES UNTIL ALL SEALANT HAS BEEN CLEANED FROM
THE FINGERTIPS, NAILS AND CUTICLES. RESIDUAL SEALANT MAY REMAIN ON FINGERS
FOR SEVERAL DAYS AND TRANSFER TO LENSES AND CAUSE SEVERE EYE IRRITATION.
STORE AWAY FROM HEAT, SOURCES OF IGNITION, AND INCOMPATIBLES. KEEP AWAY
FROM CHILDREN.
| 7. HANDLING AND STORAGE | |
ADVICE ON SAFE HANDLING: SENSITIVITY TO STATIC DISCHARGE IS NOT EXPECTED.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
EYEWASH STATIONS
SHOWERS
RESPIRATORY PROTECTION:
IF EXPOSURE LIMITS ARE EXCEEDED OR RESPIRATORY IRRITATION IS EXPERIENCED,
NIOSH/MSHA APPROVED RESPIRATORY PROTECTION SHOULD BE WORN. SUPPLIED AIR
RESPIRATORS MAY BE REQUIRED FOR NON-ROUTINE OR EMERGENCY SITUATIONS.
RESPIRATORY PROTECTION MUST BE PROVIDED IN ACCORDANCE WITH OSHA REGULATIONS
(SEE 29 CFR 1910.134).
PROTECTIVE GLOVES: CLOTH GLOVES.
EYE AND FACE PROTECTION: SAFETY GLASSES
OTHER PROTECTIVE EQUIPMENT:
WEAR SUITABLE PROTECTIVE CLOTHING AND EYE/FACE PROTECTION.
EXPOSURE GUIDELINES:
COMPONENT CAS RN SOURCE VALUE
ABSENCE OF VALUES INDICATES NONE FOUND
PEL - OSHA PERMISSIBLE EXPOSURE LIMIT
TLV - ACGIH THRESHOLD LIMIT VALUE
TWA - TIME WEIGHTED AVERAGE
OSHA REVOKED THE FINAL RULE LIMITS OF JANUARY 19, 1989 IN RESPONSE TO THE
11TH CIRCUIT COURT OF APPEALS DECISION (AFL-CIO V. OSHA) EFFECTIVE JUNE 30,
1993. SEE 29 CFR 1910.1000 (58 FR 35338).
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT - C & F: NOT APPLICABLE
VAPOR PRESSURE (20 C) (MMHg): NOT APPLICABLE
VAPOR DENSITY (AIR=1): NO DATA AVAILABLE
FREEZING POINT: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
PHYSICAL STATE: SOLID
ODOR: AMMONIA
COLOR: TRANSLUCENT
EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
SPECIFIC GRAVITY (WATER=1): CA. 1.05
DENSITY: CA. 1,050 G/CM3
ACID / ALKALINITY (MEQ/G): NOT APPLICABLE
pH: NOT APPLICABLE
VOLATILE ORGANIC CONTENT (VOL): NOT APPLICABLE
SOLUBILITY IN WATER (20 C): INSOLUBLE
SOLUBILITY IN ORGANIC SOLVENT (STATE SOLVENT): PARTIAL IN TOLUENE
VOC EXCL. H2O & EXEMPTS (G/L): 27
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS:
METHANOL
CARBON DIOXIDE (CO2)
FORMALDEHYDE
CARBON MONOXIDE
AMMONIA
SILICON DIOXIDE.
INCOMPATIBILITY (MATERIALS TO AVOID): NONE KNOWN.
CONDITIONS TO AVOID: NONE KNOWN.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE ORAL:
REMARKS: UNKNOWN
ACUTE DERMAL:
REMARKS: UNKNOWN
ACUTE INHALATION:
REMARKS: UNKNOWN
OTHER:
CONTAINS DIBUTYLTIN COMPOUND(S):
MAY IMPAIR FERTILITY. MAY CAUSE HARM TO UNBORN CHILD.
SENSITIZATION: NO DATA AVAILABLE
EYE IRRITATION: NO DATA AVAILABLE
MUTAGENICITY: UNKNOWN
OTHER EFFECTS OF OVEREXPOSURE:
THIS PRODUCT CONTAINS METHYLPOLYSILOXANES WHICH CAN GENERATE FORMALDEHYDE
AT APPROXIMATELY 300 DEGREES FAHRENHEIT (150 DEG. C) AND ABOVE, IN
ATMOSPHERES WHICH CONTAIN OXYGEN. FORMALDEHYDE IS A SKIN AND RESPIRATORY
SENSITIZER, EYE AND THROAT IRRITANT, ACUTE TOXICANT, AND POTENTIAL CANCER
HAZARD. A MSDS FOR FORMALDEHYDE IS AVAILABLE FROM MOMENTIVE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGY:
CHEMICAL FATE: NO DATA AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHOD:
DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS.
| 14. TRANSPORT INFORMATION | |
| 15. REGULATORY INFORMATION | |
INVENTORIES:
CANADA DSL INVENTORY: Y (POSITIVE LISTING)
KOREA EXISTING CHEMICALS INVENTORY (KECI): Y (POSITIVE LISTING)
CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES: Y (POSITIVE LISTING)
AUSTRALIA INVENTORY OF CHEMICAL SUBSTANCES (AICS): Y (POSITIVE LISTING)
PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES (PICCS):
Y (POSITIVE LISTING)
EU LIST OF EXISTING CHEMICAL SUBSTANCES: Y (POSITIVE LISTING)
CANADA NDSL INVENTORY: N (NEGATIVE LISTING)
JAPAN INVENTORY OF EXISTING & NEW CHEMICAL SUBSTANCES (ENCS):
N (NEGATIVE LISTING)
TSCA LIST: E (SPECIAL CASE)
FOR INVENTORIES THAT ARE MARKED AS QUANTITY RESTRICTED OR SPECIAL CASES,
PLEASE CONTACT MOMENTIVE.
US REGULATORY INFORMATION:
SARA (311, 312) HAZARD CLASS:
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
SARA (313) CHEMICALS: 58-36-6, 10, 10'-OXYBISPHENOXARSINE
CANADIAN REGULATORY INFORMATION:
WHMIS HAZARD CLASS:
D2A VERY TOXIC MATERIALS
D2B TOXIC MATERIALS
OTHER:
SCHDLE B/HTSUS: 3214.10 MASTIC BASED ON RUBBER
ECCN: EAR99
CALIFORNIA PROPOSITION 65:
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. 108-88-3, TOLUENE.
| 16. OTHER INFORMATION | |
OTHER:
C = CEILING LIMIT
NEGL = NEGLIGIBLE
EST = ESTIMATED
NF = NONE FOUND
NA = NOT APPLICABLE
UNKN = UNKNOWN
NE = NONE ESTABLISHED
REC = RECOMMENDED
ND = NONE DETERMINED
V = RECOMMENDED BY VENDOR
SKN = SKIN
TS = TRADE SECRET
R = RECOMMENDED
MST = MIST
NT = NOT TESTED
STEL = SHORT TERM EXPOSURE LIMIT
PPM = PARTS PER MILLION
PPB = PARTS PER BILLION
BY-PRODUCT = REACTION BY-PRODUCT
TSCA INVENTORY STATUS NOT REQUIRED UNDER 40 CFR PART 720.30(H-2).
THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS PRODUCT
SPECIFICATIONS. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS MADE. THE
RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO
BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE
RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE
WHETHER THEY ARE APPROPRIATE.