| Common Name: | DARK GREEN STAINING COLOR |
| Manufacturer: | ITW DYKEM |
| SDS Revision Date: | 9/4/2006 |
| SDS Format: | No Format Specified |
| Item Number(s): | 2GKX2, 2GKX9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ITW DYKEM(R*)
MATERIAL SAFETY DATA SHEET
HMIS(R*):
HEALTH 2
FLAMMABILITY 3
REACTIVITY 1
PERSONAL PROTECTION B
| SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
IDENTITY: DARK GREEN STAINING COLOR
ITEM NO.: 81206, 81406, 81706, 81806
FORMULA: 8939
NOTE:
BLANK SPACES ARE NOT PERMITTED. IF ANY ITEM IS NOT APPLICABLE, OR NO
INFORMATION IS AVAILABLE, THE SPACE MUST BE MARKED TO INDICATE THAT.
ANOTHER EXCLUSIVE PRODUCT OF: ITW DYKEM
ADDRESS (NUMBER, STREET, CITY, STATE, AND ZIP CODE):
805 EAST OLD 56 HIGHWAY
OLATHE, KS 66061-4914
EMERGENCY TELEPHONE NUMBER:
1-800-535-5053 (DOMESTIC)
1-352-323-3500 (INTERNATIONAL)
TELEPHONE NUMBER FOR INFORMATION: 1-800-443-9536 OR 1-913-397-9889
PRODUCT CLASS: STAINING COLORS
SIGNATURE OF PREPARER (OPTIONAL): REGULATORY DEPT
DATE PREPARED: 9/4/06
| SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENTS CAS NO. OSHA ACGIH- OTHER LIMITS %
(SPECIFIC CHEMICAL PEL TLV RECOMMENDED (OPT.)
IDENTITY, COMMON
NAME(S))
BUTYL ACETATE 123-86-4 TWA: TWA: NO DATA 30 - 40
150 PPM 150 PPM
ETHANOL 64-17-5 TWA: TWA: NO DATA 20 - 30
1000 PPM 1000 PPM
BUTANOL 71-36-3 TWA: TWA: NO DATA 10 - 20
50 PPM 50 PPM
NITROCELLULOSE 9004-70-0 NO DATA NO DATA NO DATA 1 - 10
ETHYL ACETATE 141-78-6 TWA: TWA: NO DATA 1 - 10
400 PPM 400 PPM
n-PROPYL ACETATE 109-60-4 TWA: TWA: NO DATA 1 - 10
200 PPM 200 PPM
ISOPROPANOL 67-63-0 TWA: TWA: NO DATA 1 - 10
400 PPM 400 PPM
DIARYLIDE YELLOW 5468-75-7 TWA: TWA: NO DATA 1 - 10
5 MG/M3 5 MG/M3
TITANIUM DIOXIDE 13463-67-7 TWA: TWA: NO DATA 1 - 10
5 MG/M3 5 MG/M3
IRON BLUE 5869-00-5 TWA: TWA: NO DATA 1 - 10
5 MG/M3 5 MG/M3
| SECTION 3 HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DARK GREEN THIN VISCOSITY LIQUID WITH SWEET SOLVENT ODOR.
WARNING!
FLAMMABLE LIQUID AND VAPOR. KEEP AWAY FROM HEAT SPARKS AND FLAMES. MAY
CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. IF SWALLOWED DO NOT
INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
POTENTIAL HEALTH EFFECTS:
EYES: LIQUID IS MODERATELY IRRITATING TO THE EYES.
SKIN: LIQUID IS MILDLY IRRITATING TO THE SKIN.
INGESTION: INGESTION OF LIQUID MAY CAUSE VOMITING.
INHALATION:
HIGH CONCENTRATION OF VAPORS MAY PRODUCE IRRITATION OF THE RESPIRATORY
TRACT, HEADACHE, DIZZINESS, AND NAUSEA.
CHRONIC HEALTH EFFECTS:
PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN SENSITIZATION OR DERMATITIS.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE
TO SOLVENTS WITH IRREVERSIBLE BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL
MISUSE BY DELIBERATELY CONCENTRATING OR INHALING THIS PRODUCT MAY BE
HARMFUL OR FATAL. INFORMATION SUPPLIED TO ITW DYKEM INDICATES THAT
DIARYLIDE PIGMENTS IN POLYMERS AT TEMPERATURES ABOVE 200 DEG. C
(392 DEG. F) CAN PRODUCE TRACE AMOUNTS OF 3,3' DICHLORBENZIDINE.
3,3' DICHLOROBENZIDINE IS CLASSIFIED AS A SUSPECT CARCINOGEN BY NTP AND
IARC.
| SECTION 4 FIRST AID MEASURES | |
EYES:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION IMMEDIATELY.
INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION.
IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN:
FLUSH SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
INGESTION:
IF LARGE QUANTITIES OF THIS MATERIAL ARE SWALLOWED, GET IMMEDIATE MEDICAL
ATTENTION. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
| SECTION 5 FIRE FIGHTING MEASURES | |
FLASH POINT (METHOD USED): 24 DEG. F
FLAMMABLE LIMITS:
LEL: 1.40
UEL: 19.0
EXTINGUISHING MEDIA:
USE WATER FOG, FOAM, DRY CHEMICAL OR CO2. USE WATER SPRAY TO COOL
FIRE-EXPOSED CONTAINERS AND TO PROTECT PERSONNEL.
SPECIAL FIRE FIGHTING PROCEDURES:
KEEP CONTAINERS COOL AND VAPORS DOWN WITH WATER SPRAY. PREVENT SPILL FROM
ENTERING DRAINS, SEWERS, STREAMS OR OTHER BODIES OF WATER. IF RUN-OFF
OCCURS, NOTIFY PROPER AUTHORITIES. DO NOT ENTER CONFINED FIRE SPACE WITHOUT
FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER
BOOTS), INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED
BREATHING APPARATUS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG GROUND, OR BE MOVED BY
VENTILATION AND BE IGNITED BY IGNITION SOURCE.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
SMALL SPILL:
ABSORB LIQUID WITH NON-COMBUSTIBLE FLOOR ABSORBENT AND PLACE IN NON-LEAKING
CONTAINER; SEAL PROPERLY AND DISPOSE OF PROPERLY IN COMPLIANCE WITH
FEDERAL, STATE, AND LOCAL REGULATIONS.
LARGE SPILL:
EVACUATE AREA OF UNPROTECTED PERSONNEL. ELIMINATE ALL IGNITION SOURCES.
STOP SPILL AT SOURCE IF SAFE TO DO SO. HANDLING EQUIPMENT MUST BE GROUNDED
TO PREVENT SPARKING. PREVENT SPILL FROM ENTERING DRAINS, SEWERS, STREAMS OR
OTHER BODIES OF WATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES. PUMP
OR VACUUM TRANSFER SPILLED PRODUCT TO CLEAN CONTAINERS FOR RECOVERY. ABSORB
UNRECOVERABLE PRODUCT. TRANSFER CONTAMINATED ABSORBENT, SOIL AND OTHER
MATERIALS TO CONTAINERS FOR DISPOSAL. DISPOSE OF PROPERLY IN COMPLIANCE
WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
| SECTION 7 HANDLING AND STORAGE | |
HANDLING:
EMPTY CONTAINERS RETAIN RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE DANGEROUS.
DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH
CONTAINERS TO HEAT, SPARKS, FLAMES, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. MANY HOT ORGANIC CHEMICAL VAPORS OR MISTS ARE SUSCEPTIBLE TO
SUDDEN SPONTANEOUS COMBUSTION WHEN MIXED WITH AIR. IGNITION MAY OCCUR AT
TEMPERATURES BELOW THOSE PUBLISHED IN THE LITERATURE AS "AUTOIGNITION" OR
IGNITION TEMPERATURES. IGNITION TEMPERATURES DECREASE WITH INCREASING VAPOR
VOLUME AND VAPOR VOLUME AND VAPOR/AIR CONTACT TIME, AND ARE INFLUENCED BY
PRESSURE CHANGES. IGNITION OF ORGANIC CHEMICAL VAPORS MAY OCCUR AT TYPICAL
ELEVATED-TEMPERATURE PROCESS CONDITIONS, ESPECIALLY IN PROCESSES OPERATING
UNDER VACUUM IF SUBJECTED TO SUDDEN INGRESS OF AIR, OR OUTSIDE PROCESS
EQUIPMENT OPERATING UNDER ELEVATED PRESSURE IF SUDDEN ESCAPE OF VAPORS
OR MISTS TO THE ATMOSPHERE OCCURS. ANY PROPOSED USE OF THIS PRODUCT IN
ELEVATED-TEMPERATURE PROCESSES SHOULD BE THOROUGHLY EVALUATED TO ASSURE
THAT SAFE OPERATING CONDITIONS ARE ESTABLISHED AND MAINTAINED.
STORAGE:
KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAMES. KEEP OUT OF REACH OF CHILDREN.
KEEP CONTAINER TIGHTLY SEALED WHEN NOT IN USE. STORE IN COOL,
WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS.
| SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
RESPIRATORY PROTECTION (SPECIFY TYPE):
NOT USUALLY NECESSARY. USE WITH ADEQUATE VENTILATION.
USE NIOSH/MSHA APPROVED RESPIRATOR IF PELS OR TLVS ARE EXCEEDED.
ENGINEERING CONTROLS:
LOCAL EXHAUST: NOT USUALLY NEEDED
MECHANICAL (GENERAL): YES
SPECIAL: NONE
OTHER: NONE
PROTECTIVE GLOVES:
CHEMICAL RESISTANT GLOVES IF SKIN CONTACT IS POSSIBLE (CONSULT YOUR SAFETY
EQUIPMENT SUPPLIER).
EYE PROTECTION:
NOT NORMALLY REQUIRED IF USED AS INTENDED. WEAR CHEMICAL SPLASH GOGGLES IN
COMPLIANCE WITH OSHA REGULATION IF SPLASHING IS POSSIBLE.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
NOT USUALLY NECESSARY. FOR BULK MATERIAL, IF DIRECT CONTACT IS POSSIBLE,
WEAR APRON, BOOTS, FACE SHIELD, ETC. AS NEEDED.
WORK/HYGIENIC PRACTICES:
FOLLOW LABEL INSTRUCTIONS. WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, SMOKING, USING RESTROOMS, ETC.
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT: 170 DEG. F - 257 DEG. F
SPECIFIC GRAVITY (H2O=1) @ 70 DEG. F: 0.90
VAPOR PRESSURE (MM-Hg @ 70 DEG. F): NO DATA
MELTING POINT: NO DATA
VAPOR DENSITY (AIR=1): GREATER THAN ONE (1)
EVAPORATION RATE (BUTYL ACETATE = 1): LESS THAN ONE (1)
SOLUBILITY IN WATER: NEGLIGIBLE
pH: NO DATA
APPEARANCE AND ODOR:
DARK GREEN THIN VISCOSITY LIQUID WITH SWEET SOLVENT ODOR.
VOC: THIS PRODUCT CONTAINS 777 GRAMS PER LITER OR 87.49% BY WEIGHT VOC'S.
| SECTION 10 STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
UNSTABLE ( )
STABLE (X)
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY (MATERIALS TO AVOID):
STRONG OXIDIZING AND REDUCING AGENTS, STRONG ALKALIES AND STRONG ACIDS.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, SMOKE, SOOT AND VARIOUS ORGANIC OXIDATION
BY-PRODUCTS.
HAZARDOUS POLYMERIZATION:
MAY OCCUR ( )
WILL NOT OCCUR (X)
CONDITIONS TO AVOID: NO DATA
| SECTION 11 TOXICOLOGICAL INFORMATION | |
ORAL LD50 DERMAL LD50 INHALATION LC50
(RAT) (RABBIT) (RAT)
BUTYL ACETATE 14 G/KG NO DATA NO DATA
ETHANOL 7060 MG/KG NO DATA 20000 PPM/10H
BUTANOL 2500 MG/KG SLIGHT >8000 PPM/4H
NITROCELLULOSE >5000 MG/KG NO DATA NO DATA
ISOPROPANOL 5045 MG/KG NO DATA NO DATA
ETHYL ACETATE 5620 MG/KG NO DATA NO DATA
PLEASE REFER TO SECTION 3 FOR AVAILABLE INFORMATION ON POTENTIAL HEALTH
EFFECTS.
| SECTION 12 ECOLOGICAL INFORMATION | |
NO SPECIFIC ECOLOGICAL DATA ARE AVAILABLE FOR THIS PRODUCT. PLEASE REFER TO
SECTION 6 FOR INFORMATION REGARDING ACCIDENTAL RELEASES AND SECTION 15 FOR
REGULATORY REPORTING INFORMATION.
| SECTION 13 DISPOSAL CONSIDERATIONS | |
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
| SECTION 14 TRANSPORT INFORMATION | |
(NOT MEANT TO BE ALL INCLUSIVE)
DOMESTIC HIGHWAY (CONTAINERS <1 QUART ARE ORM-D)
PROPER SHIPPING NAME: PAINT
HAZARD CLASS/SUBSIDIARY HAZARD: 3
UN/NA NO.: UN1263
PACKING GROUP: II
LABEL REQUIRED: FLAMMABLE LIQUID (3)
DOMESTIC AIR SHIPMENTS: VARIES
PROPER SHIPPING NAME: NO DATA
HAZARD CLASS/SUBSIDIARY HAZARD: NO DATA
UN/NA NO.: NO DATA
PACKING GROUP: NO DATA
LABEL REQUIRED: NO DATA
| SECTION 15 REGULATORY INFORMATION | |
(NOT MEANT TO BE ALL INCLUSIVE - SELECTED REGULATIONS REPRESENTED)
U.S. FEDERAL REGULATIONS:
TSCA: COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY.
CARCINOGENICITY:
NTP?: NO
IARC MONOGRAPHS?: NO
OSHA REGULATED?: NO
OSHA:
HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200).
SECTION 313:
THIS PRODUCT CONTAINS BUTANOL (71-36-3) WHICH IS LISTED AND MAY REQUIRE
REPORTING UNDER SARA TITLE III SEC. 313 IF USED OVER THE THRESHOLD
REPORTING QUANTITY. THIS INFORMATION MUST BE INCLUDED IN ALL MSDSS
THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL.
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT KNOWN TO CONTAIN ANY MATERIAL LISTED UNDER CALIFORNIA'S
PROPOSITION 65.
| SECTION 16 OTHER INFORMATION | |
MSDS STATUS:
REVISED SECTION(S): 5/26/06 ADDED 2 OUNCE PART NUMBER.
WARNING!
THE USE OF THIS PRODUCT IS BEYOND THE CONTROL OF THE MANUFACTURER AND
DISTRIBUTOR; THEREFORE, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE AS TO
THE EFFECTS OF SUCH OR THE RESULTS TO BE OBTAINED IF NOT USED IN ACCORDANCE
WITH DIRECTIONS OR ESTABLISHED SAFE PRACTICE. THE USER MUST ASSUME ALL
RESPONSIBILITY, INCLUDING INJURY OR DAMAGE, RESULTING FROM ITS MISUSE AS
SUCH, OR IN COMBINATION WITH OTHER MATERIALS. THE MANUFACTURER AND
DISTRIBUTOR WARRANT ONLY THAT THIS PRODUCT MEETS THE SPECIFICATIONS
FOR SUCH PRODUCT.
THIS WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, AS TO
DESCRIPTION, QUALITY, MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE,
PRODUCTIVENESS, OR ANY OTHER MATTER OF THIS PRODUCT. THE MANUFACTURER AND
DISTRIBUTOR SHALL BE IN NO WAY RESPONSIBLE FOR THE PROPER USE OF THIS
PRODUCT. THE SOLE AND EXCLUSIVE REMEDY AGAINST THE MANUFACTURER AND
DISTRIBUTOR FOR BREACH OF WARRANTY SHALL BE REIMBURSEMENT OF THE PURCHASE
PRICE OF THE PRODUCT IN THE EVENT THAT A DEFECTIVE CONDITION OF THE PRODUCT
SHALL BE FOUND TO EXIST. NO OTHER REMEDY (INCLUDING BUT NOT LIMITED TO
INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR INJURY TO PERSON OR PROPERTY
OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE.