| Common Name: | 23% HYDROCHLORIC BOWL CLEANER |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 10/15/2007 |
| SDS Format: | No Format Specified |
| Item Number(s): | 2LEF5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
TOUGH GUY
23% HYDROCHLORIC BOWL CLEANER
VERSION NUMBER: 1
PREPARATION DATE: 2007-10-15
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: 23% HYDROCHLORIC BOWL CLEANER
MSDS #: MS0600433
PRODUCT CODE: 2LEF5
RECOMMENDED USE: RESTROOM CARE.
MANUFACTURER, IMPORTER, SUPPLIER:
MANUFACTURED FOR:
W.W. GRAINGER, INC.
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045-5201
PHONE: 1-847-535-1000
TECHNICAL SERVICE: 1-847-535-5400
EMERGENCY TELEPHONE NUMBER: 1-800-983-4582
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER
CORROSIVE
CAUSES SKIN AND EYE BURNS
HARMFUL OR FATAL IF SWALLOWED
PRINCIPLE ROUTES OF EXPOSURE:
EYE CONTACT
SKIN CONTACT
INHALATION
EYE CONTACT:
CORROSIVE
CAUSES PERMANENT EYE DAMAGE, INCLUDING BLINDNESS
SKIN CONTACT:
CORROSIVE
CAUSES PERMANENT DAMAGE
INHALATION:
MAY CAUSE IRRITATION AND CORROSIVE EFFECTS TO NOSE, THROAT AND RESPIRATORY
TRACT
INGESTION:
CORROSIVE
CAUSES BURNS TO MOUTH, THROAT AND STOMACH
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENTS:
INGREDIENT(S) CAS # WEIGHT %
HYDROCHLORIC ACID 7647-01-0 10 - 30%
HAZARDOUS COMPONENTS:
INGREDIENT(S) LD50 ORAL - LD50 DERMAL - LC50 INHALATION -
RAT (MG/KG) RABBIT RAT
HYDROCHLORIC ACID 700 >5010 MG/KG =3124 PPM (1 H)
| 4. FIRST AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH RUNNING WATER FOR 15-20 MINUTES, KEEPING
EYELIDS OPEN
GET MEDICAL ATTENTION IMMEDIATELY
SKIN CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15-20 MINUTES
GET MEDICAL ATTENTION IMMEDIATELY
INHALATION:
IF BREATHING IS AFFECTED, REMOVE TO FRESH AIR
GET MEDICAL ATTENTION IMMEDIATELY
INGESTION:
IF SWALLOWED, RINSE MOUTH
GIVE A CUPFUL OF WATER OR MILK
THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON CENTER
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON
AGGRAVATED MEDICAL CONDITIONS:
INDIVIDUALS WITH CHRONIC RESPIRATORY DISORDERS SUCH AS ASTHMA, CHRONIC
BRONCHITIS, EMPHYSEMA, ETC., MAY BE MORE SUSCEPTIBLE TO IRRITATING EFFECTS
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: NOT APPLICABLE
SPECIFIC HAZARDS: NOT APPLICABLE
UNUSUAL HAZARDS: NONE KNOWN
SPECIFIC METHODS: NO SPECIAL METHODS REQUIRED
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
EXTINGUISHING MEDIA WHICH MUST NOT BE USED FOR SAFETY REASONS:
NO INFORMATION AVAILABLE
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS: USE PERSONAL PROTECTIVE EQUIPMENT
ENVIRONMENTAL PRECAUTIONS AND CLEAN-UP METHODS: NO INFORMATION AVAILABLE
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING
DO NOT TASTE OR SWALLOW
AVOID BREATHING VAPORS OR MISTS
USE ONLY WITH ADEQUATE VENTILATION
REMOVE AND WASH CONTAMINATED CLOTHING AND FOOTWEAR BEFORE RE-USE
WASH THOROUGHLY AFTER HANDLING
PRODUCT RESIDUE MAY REMAIN ON/IN EMPTY CONTAINERS
ALL PRECAUTIONS FOR HANDLING THE PRODUCT MUST BE USED IN HANDLING THE EMPTY
CONTAINER AND RESIDUE
MIX ONLY WITH WATER
DO NOT MIX WITH AMMONIA, BLEACH, OR OTHER CHLORINATED COMPOUNDS
FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
STORAGE:
PROTECT FROM FREEZING
KEEP TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE
KEEP OUT OF REACH OF CHILDREN
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING MEASURES TO REDUCE EXPOSURE:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL AIRBORNE LEVELS
RESPIRATORY PROTECTION IS NOT REQUIRED IF GOOD VENTILATION IS MAINTAINED
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: CHEMICAL-SPLASH GOGGLES
HAND PROTECTION: CHEMICAL-RESISTANT GLOVES
SKIN AND BODY PROTECTION:
PROTECTIVE FOOTWEAR
IF MAJOR EXPOSURE IS POSSIBLE, WEAR SUITABLE PROTECTIVE CLOTHING AND
FOOTWEAR
RESPIRATORY PROTECTION:
IN CASE OF INSUFFICIENT VENTILATION WEAR SUITABLE RESPIRATORY EQUIPMENT
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHAS 29 CFR 1910.134 AND
ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS
WARRANT A RESPIRATOR'S USE
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE
PERSONAL PROTECTIVE EQUIPMENT:
CHEMICAL GOGGLES
GLOVES
BOOTS
INGREDIENT(S) CAS # ACGIH OSHA MEXICO
HYDROCHLORIC 7647-01-0 2 PPM 5 PPM (CEILING) 5 PPM (CEILING)
ACID (CEILING) 7 MG/M3 (CEILING) 7 MG/M3 (CEILING)
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
APPEARANCE: NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: NO INFORMATION AVAILABLE
pH: NO INFORMATION AVAILABLE
DILUTION pH: NO INFORMATION AVAILABLE.
ELEMENTAL PHOSPHORUS: 0% P
DENSITY: NO INFORMATION AVAILABLE.
BULK DENSITY: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
SOLUBILITY: NO INFORMATION AVAILABLE
VOC: 0% *
VISCOSITY: NO INFORMATION AVAILABLE
SOLUBILITY IN OTHER SOLVENTS: NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (n-OCTANOL/WATER): NO INFORMATION AVAILABLE
COLOR: WHITE
ODOR: ACIDIC
BOILING POINT/RANGE: NOT DETERMINED
MELTING POINT/RANGE: NOT DETERMINED
FLASH POINT:
>200 DEG. F
>93.3 DEG. C
DECOMPOSITION TEMPERATURE: NOT DETERMINED
AUTOIGNITION TEMPERATURE: NO INFORMATION AVAILABLE
* - TITLE 17, CALIFORNIA CODE OF REGULATIONS, DIVISION 3, CHAPTER 1,
SUBCHAPTER 8.5, ARTICLE 2, CONSUMER PRODUCTS, SECTIONS 94508
| 10. STABILITY AND REACTIVITY | |
STABILITY: THE PRODUCT IS STABLE
POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
HAZARDOUS DECOMPOSITION PRODUCTS: NONE REASONABLY FORESEEABLE.
MATERIALS TO AVOID:
AMMONIA
DO NOT MIX WITH CHLORINATED PRODUCTS
BASES
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
ORAL LD50: ESTIMATED TO BE BETWEEN 500 - 2000 MG/KG.
DERMAL LD50: ESTIMATED TO BE > 2000 MG/KG.
COMPONENT INFORMATION: SEE SECTION 3
CHRONIC TOXICITY: NONE KNOWN
SPECIFIC EFFECTS:
CARCINOGENIC EFFECTS: NONE KNOWN
MUTAGENIC EFFECTS: NONE KNOWN
REPRODUCTIVE TOXICITY: NONE KNOWN
TARGET ORGAN EFFECTS: NONE KNOWN
| 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL INFORMATION: NO DATA AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
WASTE FROM RESIDUES / UNUSED PRODUCTS:
UNDILUTED PRODUCT IS REGULATED UNDER ENVIRONMENTAL AND TRANSPORTATION LAWS
AS A CORROSIVE WASTE
DISPOSE OF IN COMPLIANCE WITH ALL FEDERAL, STATE, PROVINCIAL, AND LOCAL
LAWS AND REGULATIONS. INCINERATION IS THE PREFERRED METHOD. RELATIVELY
SMALL QUANTITIES OF PRODUCT MAY BE NEUTRALIZED AS STATED ABOVE, AND IF IN
ACCORDANCE WITH LOCAL LAWS AND THE OPERATORS OF THE LOCAL SEWAGE TREATMENT
PLANT, THE NEUTRALIZED MATERIAL MAY BE DISCHARGED INTO THE SEWER SYSTEM
RCRA HAZARD CLASS: D002
| 14. TRANSPORT INFORMATION | |
DOT/TDG:
PLEASE REFER TO THE BILL OF LADING/RECEIVING DOCUMENTS FOR UP TO DATE
SHIPPING INFORMATION
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE FOLLOWING INVENTORIES:
U.S.A. (TSCA).
U.S. REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS UNDER
CALIFORNIA'S PROPOSITION 65
SARA 311/312 HAZARD CATEGORIES:
IMMEDIATE (X)
DELAYED ( )
FIRE ( )
REACTIVITY ( )
SUDDEN RELEASE OF PRESSURE ( )
CANADA:
WHMIS HAZARD CLASS: NOT FOR SALE IN CANADA.
STATE RIGHT TO KNOW:
INGREDIENT(S) CAS # NJRTK MARTK PARTK RIRTK
WATER 7732-18-5
HYDROCHLORIC ACID 7647-01-0 X X X X
ALCOHOL ETHOXYLATES 68131-39-5
OPACIFER N/A*
CERCLA/ SARA:
INGREDIENT(S) CAS # WEIGHT % CERCLA/SARA SECTION 302 SECTION
RQ (LBS) TPQ (LBS) 313
HYDROCHLORIC ACID 7647-01-0 10 - 30% 5000 5000 X
INGREDIENT(S) CAA HAP CAA ODS CWA PRIORITY POLLUTANTS
HYDROCHLORIC ACID X
| 16. OTHER INFORMATION | |
HMIS:
HEALTH 3
FIRE HAZARD 0
REACTIVITY 1
NFPA:
HEALTH 3
FLAMMABILITY 0
INSTABILITY 1
REASON FOR REVISION: NOT APPLICABLE
PREPARED BY: NAPRAC
ADDITIONAL ADVICE: NONE
NOTICE TO READER:
THIS DOCUMENT HAS BEEN PREPARED USING DATA FROM SOURCES CONSIDERED
TECHNICALLY RELIABLE. IT DOES NOT CONSTITUTE A WARRANTY, EXPRESS OR
IMPLIED, AS TO THE ACCURACY OF THE INFORMATION CONTAINED WITHIN. ACTUAL
CONDITIONS OF USE AND HANDLING ARE BEYOND SELLER'S CONTROL. USER IS
RESPONSIBLE TO EVALUATE ALL AVAILABLE INFORMATION WHEN USING PRODUCT FOR
ANY PARTICULAR USE AND TO COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL AND
LOCAL LAWS AND REGULATIONS.