| Common Name: | CLINGING 9.5% HYDROCHLORIC ACID BOWL CLEANER |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 9/17/2007 |
| SDS Format: | No Format Specified |
| Item Number(s): | 2LEF7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
TOUGH GUY
CLINGING 9.5% HYDROCHLORIC ACID BOWL CLEANER
HMIS NFPA
HEALTH 3 3
FIRE HAZARD 0 0
REACTIVITY 0 0
PERSONAL PROTECTIVE EQUIPMENT:
CHEMICAL GOGGLES
GLOVES
BOOTS
VERSION NUMBER: 1
PREPARATION DATE: 2007-09-17
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: CLINGING 9.5% HYDROCHLORIC ACID BOWL CLEANER
MSDS #: MS0600449
PRODUCT CODE: 2LEF7
RECOMMENDED USE: RESTROOM CARE.
MANUFACTURER, IMPORTER, SUPPLIER:
MANUFACTURED FOR:
W. W. GRAINGER, INC.
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045-5201
PHONE: 1-847-535-1000
TECHNICAL SERVICE: 1-847-535-5400
EMERGENCY TELEPHONE NUMBER: 1-800-983-4582
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER. CORROSIVE. CAUSES SKIN AND EYE BURNS. HARMFUL OR FATAL IF
SWALLOWED.
PRINCIPLE ROUTES OF EXPOSURE: EYE CONTACT. SKIN CONTACT. INHALATION.
EYE CONTACT: CORROSIVE. CAUSES PERMANENT EYE DAMAGE, INCLUDING BLINDNESS.
SKIN CONTACT: CORROSIVE. CAUSES PERMANENT DAMAGE.
INHALATION:
MAY CAUSE IRRITATION AND CORROSIVE EFFECTS TO NOSE, THROAT AND
RESPIRATORY TRACT.
INGESTION: CORROSIVE. CAUSES BURNS TO MOUTH, THROAT AND STOMACH.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENTS:
INGREDIENT(S) CAS # WEIGHT %
HYDROCHLORIC ACID 7647-01-0 10 - 20%
n-ALKYL (60% C14, 30% C16, 5% C12, 68391-01-5 <0.1%
5% C18) DIMETHYL BENZYL AMMONIUM
CHLORIDE
n-ALKYL (68% C14, 32% C16) DIMETHYL 68956-79-6 <0.1%
ETHYLBENZYL AMMONIUM CHLORIDE
INGREDIENT(S) LD50 ORAL - RAT LD50 DERMAL LC50 INHALATION
- RABBIT - RAT
HYDROCHLORIC ACID =700 MG/KG >5010 MG/KG =3124 PPM (1 H)
n-ALKYL (60% C14, NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
30% C16, 5% C12,
5% C18) DIMETHYL
BENZYL AMMONIUM
CHLORIDE
n-ALKYL (68% C14, NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
32% C16) DIMETHYL
ETHYLBENZYL
AMMONIUM CHLORIDE
| 4. FIRST AID MEASURES | |
EYE CONTACT:
HOLD EYE OPEN AND RINSE SLOWLY AND GENTLY WITH WATER FOR 15-20 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5 MINUTES, THEN
CONTINUE RINSING EYES. CALL MEDICAL ATTENDANT, MEDICAL DOCTOR, OR
POISON CONTROL CENTER.
SKIN CONTACT:
TAKE OFF CONTAMINATED CLOTHING. RINSE SKIN IMMEDIATELY WITH PLENTY OF
WATER FOR 15-20 MINUTES. CALL MEDICAL ATTENDANT, MEDICAL DOCTOR, OR
POISON CONTROL CENTER.
INHALATION:
IF BREATHING IS AFFECTED, REMOVE TO FRESH AIR. IF PERSON IS NOT BREATHING,
CALL 911 OR AN AMBULANCE AND THEN GIVE ARTIFICIAL RESPIRATION, PREFERABLY
BY MOUTH TO MOUTH, IF POSSIBLE. CALL MEDICAL ATTENDANT, MEDICAL DOCTOR,
OR POISON CONTROL CENTER.
INGESTION:
CALL MEDICAL ATTENDANT, DOCTOR, OR POISON CONTROL CENTER IMMEDIATELY.
HAVE PERSON SIP A GLASS OF WATER IF ABLE TO SWALLOW. DO NOT INDUCE
VOMITING UNLESS TOLD TO DO SO BY A POISON CONTROL CENTER OR DOCTOR.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
NOTES TO PHYSICIAN:
PROBABLE MUCOSAL DAMAGE MAY CONTRAINDICATE THE USE OF GASTRIC LAVAGE.
AGGRAVATED MEDICAL CONDITIONS:
INDIVIDUALS WITH CHRONIC RESPIRATORY DISORDERS SUCH AS ASTHMA, CHRONIC
BRONCHITIS, EMPHYSEMA, ETC., MAY BE MORE SUSCEPTIBLE TO IRRITATING
EFFECTS.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
EXTINGUISH FIRE USING AGENT SUITABLE FOR SURROUNDING FIRE. USE DRY
CHEMICAL, CO2, WATER SPRAY OR "ALCOHOL" FOAM.
SPECIFIC HAZARDS: NOT APPLICABLE
UNUSUAL HAZARDS: CORROSIVE MATERIAL (SEE SECTIONS 8 AND 10).
SPECIFIC METHODS: NO SPECIAL METHODS REQUIRED
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
EXTINGUISHING MEDIA WHICH MUST NOT BE USED FOR SAFETY REASONS:
NO INFORMATION AVAILABLE
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8.).
ENVIRONMENTAL PRECAUTIONS AND CLEAN-UP METHODS:
USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION. SOAK
UP WITH INERT ABSORBENT MATERIAL. SWEEP UP AND SHOVEL INTO SUITABLE
CONTAINERS FOR DISPOSAL. KEEP IN SUITABLE AND CLOSED CONTAINERS FOR
DISPOSAL. USE A WATER RINSE FOR FINAL CLEAN-UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. DO NOT TASTE OR SWALLOW.
AVOID BREATHING VAPORS OR MISTS. USE ONLY WITH ADEQUATE VENTILATION.
REMOVE AND WASH CONTAMINATED CLOTHING AND FOOTWEAR BEFORE RE-USE.
WASH THOROUGHLY AFTER HANDLING. PRODUCT RESIDUE MAY REMAIN ON/IN EMPTY
CONTAINERS. ALL PRECAUTIONS FOR HANDLING THE PRODUCT MUST BE USED IN
HANDLING THE EMPTY CONTAINER AND RESIDUE. DO NOT MIX WITH AMMONIA, BLEACH,
OR OTHER CHLORINATED COMPOUNDS. CAN REACT TO RELEASE CHLORINE GAS. FOR
COMMERCIAL AND INDUSTRIAL USE ONLY.
STORAGE:
PROTECT FROM FREEZING. KEEP TIGHTLY CLOSED IN A DRY, COOL AND
WELL-VENTILATED PLACE. KEEP OUT OF REACH OF CHILDREN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING MEASURES TO REDUCE EXPOSURE:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL AIRBORNE LEVELS.
RESPIRATORY PROTECTION IS NOT REQUIRED IF GOOD VENTILATION IS MAINTAINED.
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: CHEMICAL-SPLASH GOGGLES.
HAND PROTECTION: CHEMICAL-RESISTANT GLOVES
SKIN AND BODY PROTECTION:
PROTECTIVE FOOTWEAR. IF MAJOR EXPOSURE IS POSSIBLE, WEAR SUITABLE
PROTECTIVE CLOTHING AND FOOTWEAR.
RESPIRATORY PROTECTION:
IN CASE OF INSUFFICIENT VENTILATION WEAR SUITABLE RESPIRATORY EQUIPMENT.
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND
ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS
WARRANT A RESPIRATOR'S USE.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE
INGREDIENT(S) CAS # ACGIH OSHA MEXICO
HYDROCHLORIC ACID 7647-01-0 2 PPM 5 PPM 5 PPM
(CEILING) (CEILING) (CEILING)
7 MG/M3 7 MG/M3
(CEILING) (CEILING)
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
BULK DENSITY: NO INFORMATION AVAILABLE
pH: <1
DILUTION pH: NO INFORMATION AVAILABLE.
APPEARANCE: LIQUID
VAPOR DENSITY: NO INFORMATION AVAILABLE
COLOR: BLUE
EVAPORATION RATE: NO INFORMATION AVAILABLE
ODOR: MINTY
BOILING POINT/RANGE: NOT DETERMINED
SPECIFIC GRAVITY: 1.048
MELTING POINT/RANGE: NOT DETERMINED
DENSITY: 8.72 LBS/GAL
DECOMPOSITION TEMPERATURE: NOT DETERMINED
VOC: 1% *
AUTOIGNITION TEMPERATURE: NO INFORMATION AVAILABLE
FLASH POINT: NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (n-OCTANOL/WATER): NO INFORMATION AVAILABLE
SOLUBILITY: COMPLETELY SOLUBLE
SOLUBILITY IN OTHER SOLVENTS: NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
ELEMENTAL PHOSPHORUS: 0 %P
* - TITLE 17, CALIFORNIA CODE OF REGULATIONS, DIVISION 3, CHAPTER 1,
SUBCHAPTER 8.5, ARTICLE 2, CONSUMER PRODUCTS, SECTIONS 94508
| 10. STABILITY AND REACTIVITY | |
STABILITY: THE PRODUCT IS STABLE
POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
HAZARDOUS DECOMPOSITION PRODUCTS: NONE REASONABLY FORESEEABLE.
MATERIALS TO AVOID: AMMONIA. DO NOT MIX WITH CHLORINATED PRODUCTS.
CONDITIONS TO AVOID:
DO NOT FREEZE. DO NOT MIX WITH ANY OTHER PRODUCT OR CHEMICAL.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY: CORROSIVE
COMPONENT INFORMATION: SEE SECTION 3
CHRONIC TOXICITY: NONE KNOWN
SPECIFIC EFFECTS:
CARCINOGENIC EFFECTS: NONE KNOWN
MUTAGENIC EFFECTS: NONE KNOWN
REPRODUCTIVE TOXICITY: NONE KNOWN
TARGET ORGAN EFFECTS: NONE KNOWN
| 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL INFORMATION: NO DATA AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL
PESTICIDE STORAGE:
STORE IN A COOL, DRY LOCATION, IN LOCKED AREA INACCESSIBLE TO CHILDREN.
DO NOT REUSE EMPTY CONTAINER.
PESTICIDE DISPOSAL:
PESTICIDE WASTES ARE ACUTELY HAZARDOUS. IMPROPER DISPOSAL OF EXCESS
PESTICIDE, SPRAY MIXTURE, OR RINSATE IS A VIOLATION OF FEDERAL LAW.
CONTAINER DISPOSAL:
WRAP EMPTY CONTAINER IN PLASTIC BAG AND DISCARD IN TRASH OR RINSE
THOROUGHLY WITH WATER AND RECYCLE.
| 14. TRANSPORT INFORMATION | |
DOT/TDG:
PLEASE REFER TO THE BILL OF LADING/RECEIVING DOCUMENTS FOR UP TO DATE
SHIPPING INFORMATION
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE FOLLOWING INVENTORIES:
U.S.A. (TSCA).
U.S. REGULATIONS:
EPA REG. NO.: 8155-6-84533
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS UNDER
CALIFORNIA'S PROPOSITION 65
CERCLA/SARA:
INGREDIENT(S) CAS # WEIGHT % CERCLA/SARA SECTION 302 SECTION
RQ (LBS) TPQ (LBS) 313
HYDROCHLORIC 7647-01-0 10 - 20% 5000 5000 X
ACID
INGREDIENT(S) CAA HAP CAA ODS CWA PRIORITY POLLUTANTS
HYDROCHLORIC ACID X
SARA 311/312 HAZARD CATEGORIES:
IMMEDIATE (X)
DELAYED ( )
FIRE ( )
REACTIVITY ( )
SUDDEN RELEASE OF PRESSURE ( )
| 16. OTHER INFORMATION | |
REASON FOR REVISION: NOT APPLICABLE
PREPARED BY: NAPRAC
ADDITIONAL ADVICE: NONE
NOTICE TO READER:
THIS DOCUMENT HAS BEEN PREPARED USING DATA FROM SOURCES CONSIDERED
TECHNICALLY RELIABLE. IT DOES NOT CONSTITUTE A WARRANTY, EXPRESS
OR IMPLIED, AS TO THE ACCURACY OF THE INFORMATION CONTAINED WITHIN.
ACTUAL CONDITIONS OF USE AND HANDLING ARE BEYOND SELLER'S CONTROL. USER
IS RESPONSIBLE TO EVALUATE ALL AVAILABLE INFORMATION WHEN USING PRODUCT
FOR ANY PARTICULAR USE AND TO COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL
AND LOCAL LAWS AND REGULATIONS.