| Common Name: | 3-IN-ONE WHITE LITHIUM GREASE AEROSOL |
| Manufacturer: | WD-40 |
| SDS Revision Date: | 10/3/2007 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4GY81 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3 IN 1
3-IN-ONE(R*) PROFESSIONAL
WD-40 COMPANY
MATERIAL SAFETY DATA SHEET
| 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
MANUFACTURER: WD-40 COMPANY
ADDRESS:
1061 CUDAHY PLACE (92110)
P.O. BOX 80607
SAN DIEGO, CALIFORNIA
USA
92138-0607
TELEPHONE:
EMERGENCY ONLY(PROSAR): 1-888-324-7596
INFORMATION: 1-888-324-7596
TRADE NAME: 3-IN-ONE WHITE LITHIUM GREASE AEROSOL
CHEMICAL NAME: ORGANIC MIXTURE
PRODUCT USE: CLEANER, LUBRICANT
MSDS DATE OF PREPARATION: 10/3/07
| 2 - HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING!
EXTREMELY FLAMMABLE AEROSOL. CONTENTS UNDER PRESSURE. COMBUSTIBLE LIQUID
AND VAPOR. IF SWALLOWED, MAY BE ASPIRATED AND CAUSE LUNG DAMAGE. MAY CAUSE
EYE, SKIN AND RESPIRATORY TRACT IRRITATION. USE WITH ADEQUATE VENTILATION.
KEEP AWAY FROM HEAT, SPARKS AND ALL OTHER SOURCES OF IGNITION.
SYMPTOMS OF OVEREXPOSURE:
INHALATION:
MIST OR VAPOR CAN IRRITATE THE THROAT AND LUNGS. HIGH CONCENTRATIONS MAY
CAUSE NASAL AND RESPIRATORY IRRITATION AND CENTRAL NERVOUS SYSTEM EFFECTS
SUCH AS HEADACHE, DIZZINESS AND NAUSEA. INTENTIONAL ABUSE MAY BE HARMFUL OR
FATAL.
SKIN CONTACT:
MAY CAUSE MILD SKIN IRRITATION WITH SHORT-TERM EXPOSURE WITH REDNESS,
ITCHING AND BURNING OF THE SKIN. PROLONGED AND/OR REPEATED CONTACT MAY
PRODUCE DEFATTING AND POSSIBLE DERMATITIS.
EYE CONTACT:
CONTACT MAY BE MILDLY IRRITATING TO EYES. MAY CAUSE REDNESS, STINGING,
SWELLING AND TEARING.
INGESTION:
THIS PRODUCT HAS LOW ORAL TOXICITY. IF SWALLOWED, THIS MATERIAL MAY CAUSE
IRRITATION OF THE MOUTH, THROAT AND ESOPHAGUS. THIS PRODUCT IS AN
ASPIRATION HAZARD. IF SWALLOWED, CAN ENTER THE LUNGS AND MAY CAUSE CHEMICAL
PNEUMONITIS, SEVERE LUNG DAMAGE AND DEATH.
CHRONIC EFFECTS:
PROLONGED OR REPEATED SKIN CONTACT MAY DEFEAT THE SKIN RESULTING IN
IRRITATION AND DERMATITIS.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
PREEXISTING EYE, SKIN AND RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY
EXPOSURE.
SUSPECTED CANCER AGENT:
YES ( )
NO (X)
| 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT CAS # WEIGHT PERCENT
PETROLEUM SOLVENT 64742-47-8 25-35%
LITHIUM GREASE MIXTURE 15-25%
ZINC OXIDE 1314-13-2 <1-5%
HYDROCARBON PROPELLANT 68476-86-8 40-50%
SEE SECTION 8 FOR EXPOSURE LIMITS
| 4 - FIRST AID MEASURES | |
INGESTION (SWALLOWED):
ASPIRATION HAZARD. DO NOT INDUCE VOMITING. CALL PHYSICIAN, POISON CONTROL
CENTER OR THE WD-40 SAFETY HOTLINE AT 1-888-324-7596 IMMEDIATELY.
EYE CONTACT:
FLUSH THOROUGHLY WITH WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF IRRITATION DEVELOPS AND PERSISTS, GET MEDICAL
ATTENTION.
INHALATION (BREATHING):
IF IRRITATION IS EXPERIENCED, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF
IRRITATION OR OTHER SYMPTOMS DEVELOP AND PERSIST.
| 5 - FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
USE WATER FOG, DRY CHEMICAL, CARBON DIOXIDE OR FOAM. COOL FIRE EXPOSED
CONTAINERS WITH WATER.
SPECIAL FIRE FIGHTING PROCEDURES:
FIREFIGHTERS SHOULD ALWAYS WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE CLOTHING. COOL FIRE-EXPOSED CONTAINERS WITH
WATER. USE SHIDLDING TO PROTECT AGAINST BURSTING CANS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTENTS UNDER PRESSURE. KEEP AWAY FROM IGNITION SOURCE AND OPEN FIRE.
EXPOSURE OF CONTAINERS TO EXTREME HEAT AND FLAMES CAN CAUSE THEM TO RUPTURE
OFTEN WITH VIOLENT FORCE. COMBUSTIBLE LIQUID AND VAPOR. THIS MATERIAL CAN
RELEASE FLAMMABLE VAPORS WHEN HEATED ABOVE AMBIENT TEMPERATURES. VAPORS CAN
CAUSE A FLASH FIRE. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG
SURFACES TO REMOTE IGNITION SOURCES AND FLASH BACK. A VAPOR AND AIR MIXTURE
CAN CREATE AN EXPLOSION HAZARD IN CONFINED SPACES.
| 6 - ACCIDENTAL RELEASE MEASURES | |
WEAR APPROPRIATE PROTECTIVE CLOTHING (SEE SECTION 8). ELIMINATE ALL SOURCES
OF IGNITION AND VENTILATE AREA. CONTAIN AND COLLECT LIQUID WITH AN INERT
ABSORBENT AND PLACE IN A CONTAINER FOR DISPOSAL. CLEAN SPILL AREA
THOROUGHLY. REPORT SPILLS TO AUTHORITIES AS REQUIRED.
| 7 - HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES. AVOID PROLONGED CONTACT WITH SKIN. AVOID BREATHING
VAPORS OR AEROSOLS. USE WITH ADEQUATE VENTILATION. KEEP AWAY FROM HEAT,
SPARKS, HOT SURFACES AND OPEN FLAMES. WASH THOROUGHLY WITH SOAP AND WATER
AFTER HANDLING. KEEP CONTAINERS CLOSED WHEN NOT IN USE. KEEP OUT OF THE
REACH OF CHILDREN. DO NOT PUNCTURE OR INCINERATE CONTAINERS.
STORAGE:
STORE IN A COOL, WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS. DO
NOT STORE IN DIRECT SUNLIGHT OR ABOVE 120 DEG. F. U.F.C (NFPA 30B) LEVEL 3
AEROSOL.
| 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL OCCUPATIONAL EXPOSURE LIMITS
PETROLEUM SOLVENT 200 MG/M3 SKIN TWA ACGIH TLV
(AS TOTAL HYDROCARBON VAPOR)
LITHIUM GREASE NONE LISTED
HYDROCARBON PROPELLANT NONE LISTED
THE FOLLOWING CONTROLS ARE RECOMMENDED FOR NORMAL CONSUMER USE OF THIS
PRODUCT ENGINEERING CONTROLS:
USE IN A WELL-VENTILATED AREA.
PERSONAL PROTECTION:
EYE PROTECTION: AVOID EYE CONTACT. ALWAYS SPRAY AWAY FROM FACE.
SKIN PROTECTION:
AVOID PROLONGED SKIN CONTACT. CHEMICAL RESISTANT GLOVES RECOMMENDED FOR
OPERATIONS WHERE PROLONGED SKIN CONTACT IS LIKELY.
RESPIRATORY PROTECTION:
NONE NEEDED FOR NORMAL USE WITH ADEQUATE VENTILATION.
FOR BULK PROCESSING OR WORKPLACE USE THE FOLLOWING CONTROLS ARE RECOMMENDED
ENGINEERING CONTROLS:
USE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION TO MAINTAIN EXPOSURE
LEVELS BELOW THAT OCCUPATIONAL EXPOSURE LIMITS.
PERSONAL PROTECTION:
EYE PROTECTION: SAFETY GOGGLES RECOMMENDED WHERE EYE CONTACT IS POSSIBLE.
SKIN PROTECTION: WEAR CHEMICAL RESISTANT GLOVES.
RESPIRATORY PROTECTION:
NONE REQUIRED IF VENTILATION IS ADEQUATE. IF THE OCCUPATIONAL EXPOSURE
LIMITS ARE EXCEEDED, WEAR A NIOSH APPROVED RESPIRATOR. RESPIRATOR SELECTION
AND USE SHOULD BE BASED ON CONTAMINANT TYPE, FORM AND CONCENTRATION. FOLLOW
OSHA 1910.134, ANSI Z88.2 AND GOOD INDUSTRIAL HYGIENE PRACTICE.
WORK/HYGIENE PRACTICES: WASH WITH SOAP AND WATER AFTER HANDLING.
| 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT: 218-257 DEG. C (424-495 DEG. F) (PETROLEUM SOLVENT)
SPECIFIC GRAVITY: 0.74
SOLUBILITY IN WATER: INSOLUBLE
pH: NOT APPLICABLE
VAPOR PRESSURE: 35-60 PSI @ 70 DEG. F
VAPOR DENSITY: NOT DETERMINED
PERCENT VOLATILE: 76.6%
VOC: NOT DETERMINED
COEFFICIENT OF WATER/OIL DISTRIBUTION: NOT DETERMINED
APPEARANCE/ODOR: OFF-WHITE LIQUID WITH A PETROLEUM ODOR.
FLASH POINT: -20 DEG. F (TOC)
FLAMMABLE LIMITS:
LEL: 1.8%
UEL: 9.5%
| 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, FLAMES AND OTHER SOURCES OF IGNITION.
INCOMPATIBILITIES: STRONG ACIDS, ALKALIS, AND OXIDIZERS.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE, SMOKE FUMES, AND/OR UNBURNED
HYDROCARBONS.
| 11 - TOXICOLOGICAL INFORMATION | |
THE ORAL TOXICITY OF THIS PRODUCT IS ESTIMATED TO BE GREATER THAN
5,000 MG/KG BASED ON AN ASSESSMENT OF THE INGREDIENTS. THIS PRODUCT IS NOT
CLASSIFIED AS TOXIC BY ESTABLISHED CRITERIA. IT IS AN ASPIRATION HAZARD.
NONE OF THE COMPONENTS OF THIS PRODUCT IS LISTED AS A CARCINOGEN OR
SUSPECTED CARCINOGEN OR IS CONSIDERED A REPRODUCTIVE HAZARD.
| 12 - ECOLOGICAL INFORMATION | |
NO DATA IS CURRENTLY AVAILABLE.
| 13 - DISPOSAL CONSIDERATIONS | |
IF THIS PRODUCT BECOMES A WASTE, IT WOULD BE EXPECTED TO MEET THE CRITERIA
OF A RCRA IGNITABLE HAZARDOUS WASTE (D001). HOWEVER, IT IS THE
RESPONSIBILITY OF THE GENERATOR TO DETERMINE AT THE TIME OF DISPOSAL THE
PROPER CLASSIFICATION AND METHOD OF DISPOSAL. DISPOSE IN ACCORDANCE WITH
FEDERAL, STATE, AND LOCAL REGULATIONS. DO NOT PUNCTURE OR INCINERATE
CONTAINERS.
| 14 - TRANSPORTATION INFORMATION | |
DOT SURFACE SHIPPING DESCRIPTION: CONSUMER COMMODITY, ORM-D
IMDG SHIPPING DESCRIPTION: UN 1950, AEROSOLS, 2, LTD QTY
| 15 - REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA 103 REPORTABLE QUANTITY:
THIS PRODUCT IS NOT SUBJECT TO CERCLA REPORTING REQUIREMENTS, HOWEVER, OIL
SPILLS ARE REPORTABLE TO THE NATIONAL RESPONSE CENTER UNDER THE CLEAN WATER
ACT AND MANY STATES HAVE MORE STRINGENT RELEASE REPORTING REQUIREMENTS.
REPORT SPILLS REQUIRED UNDER FEDERAL, STATE AND LOCAL REGULATIONS.
SARA TITLE III:
HAZARD CATEGORY FOR SECTION 311/312: ACUTE HEALTH, FIRE HAZARD
SECTION 313 TOXIC CHEMICALS:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO SARA TITLE III
SECTION 313 REPORTING REQUIREMENTS:
ZINC OXIDE: <1-5%
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (TPQ): NONE
EPA TOXIC SUBSTANCES CONTROL ACT (TSCA) STATUS:
ALL OF THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY
CANADIAN ENVIRONMENTAL PROTECTION ACT:
ALL OF THE INGREDIENTS ARE LISTED ON THE CANADIAN DOMESTIC SUBSTANCES LIST
OR EXEMPT FROM NOTIFICATION
CANADIAN WHMIS CLASSIFICATION:
CLASS B-5 (FLAMMABLE AEROSOL)
CLASS D-2-B (TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS)
THIS MSDS HAS BEEN PREPARED ACCORDING TO THE CRITERIA OF THE CONTROLLED
PRODUCTS REGULATION (CPR) AND THE MSDS CONTAINS ALL OF THE INFORMATION
REQUIRED BY THE CPR.
| 16 - OTHER INFORMATION | |
HMIS HAZARD RATING:
HEALTH 1 (SLIGHT HAZARD)
FIRE HAZARD 4 (SEVERE HAZARD)
REACTIVITY 0 (MINIMAL HAZARD)
REVISION DATE: OCTOBER 2007
SUPERCEDES: DECEMBER, 2004
SIGNATURE:
TITLE: DIRECTOR OF GLOBAL QUALITY ASSURANCE
REVISION DATE: 10/3/07
SUPERSEDES: 12/01/2004