| Common Name: | SPIC AND SPAN FLOOR CLEANER WITH BLEACH (NON-PHOSPHATE & PHOSPHATE) |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 8/1/2001 |
| SDS Format: | No Format Specified |
| Item Number(s): | 2NDT1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G
PROCTER & GAMBLE
CPG TN 6
2 PROCTER & GAMBLE PLAZA
CINCINNATI, OH 45202
MATERIAL SAFETY DATA SHEET
SUPERSEDES: N/A
ISSUE DATE: 8/01
ISSUE DATE: N/A
| SECTION I - CHEMICAL PRODUCT |  |
IDENTITY: GRANULAR CLEANER WITH BLEACH
BRANDS:
SPIC AND SPAN FLOOR CLEANER WITH BLEACH (NON-PHOSPHATE & PHOSPHATE)
HAZARD RATING: 1
HEALTH 1
FLAMMABILITY 0
REACTIVITY 0
4=EXTREME
3=HIGH
2=MODERATE
1=SLIGHT
EMERGENCY TELEPHONE NUMBER:
1-800-332-7787 OR CALL LOCAL POISON CONTROL CENTER
| SECTION II - COMPOSITION AND INGREDIENTS | |
INGREDIENTS/CHEMICAL NAME:
ANIONIC SURFACTANTS, WATER SOFTENERS (SODIUM CARBONATE, COMPLEX SODIUM
PHOSPHATES (PHOSPHATE VERSION)), DRY CHLORINE BLEACH, PROCESSING AIDS
(SODIUM SULFATE), METAL PROTECTION AGENTS (SODIUM SILICATES).
THIS PRODUCT IS A MILD EYE IRRITANT WITHIN THE MEANING OF THE OSHA HAZARD
COMMUNICATION STANDARD
HAZARDOUS INGREDIENTS AS DEFINED BY OSHA, 29 CFR 1910.1200.
CHEMICAL NAME COMMON CAS NO. RECOMMENDED COMPOSITION LD50/LC50
NAME LIMITS RANGE
SODIUM CARBONATE SODA ASH 497-19-8 N/A 15-40% (OP) LD50:
10-25% (P) 1.86 G/KG
LC50: N/A
SODIUM SODIUM 2893-78-9 AGCY TLV: 10-15% LD50:
DICHLOROISOCYNA- DCC 10 MG/M3 735 MG/KG
NURATE OSHA PEL: RAT
DIHYDRATE 15 MG/M3
LINEAR ALKYL C12.3 68081-81-2 N/A 15-30% LD50:
BENZENE LAS 0.65-1.26
SULFONATE G/KG
LC50: N/A
| SECTION III - HAZARDS IDENTIFICATION | |
HEALTH HAZARDS & SYMPTOMS (ACUTE AND CHRONIC):
INGESTION:
MAY CAUSE TRANSIENT GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND/OR
DIARRHEA.
EYE CONTACT:
MAY CAUSE MILD, TRANSIENT IRRITATION WITH STINGING, TEARING, ITCHING,
SWELLING AND REDNESS.
INHALATION:
HEAVY OR PROLONGED EXPOSURE TO DUST MAY CAUSE TRANSIENT RESPIRATORY TRACT
IRRITATION WITH COUGHING, SORE THROAT, WHEEZING OR TRANSITORY SHORTNESS OF
BREATH.
| SECTION IV - FIRST AID INFORMATION | |
EMERGENCY AND FIRST AID PROCEDURES:
INGESTION:
DRINK 1 OR 2 LARGE GLASSES OF WATER. IF LARGE AMOUNTS ARE INGESTED, CALL A
PHYSICIAN.
EYE CONTACT: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT 10-15 MINUTES.
SKIN: RINSE SKIN THOROUGHLY WITH WATER. DISCONTINUE USE.
INHALATION: LEAVE DUSTY AREA.
OTHER:
PRODUCT PACKAGE HAS A CAUTION STATEMENT:
CAUTION:
MAY CAUSE EYE/SKIN IRRITATION. EYE IRRITANT. AVOID EYE CONTACT. DO NOT MIX
WITH OTHER CLEANING PRODUCTS AS IRRITATING FUMES MAY BE RELEASED. MAY BE
IRRITATING TO SKIN. FOR SENSITIVE SKIN OR PROLONGED USE, WEAR GLOVES. IF EYE
OR SKIN CONTACT OCCURS, FLUSH WITH WATER FOR 15 MINUTES. IF IRRITATION
PERSISTS, SEEK MEDICAL ATTENTION. KEEP OUT OF REACH OF CHILDREN
| SECTION V - FIRE FIGHTING INFORMATION | |
FLASH POINT (METHOD USED): N/A
EXPLOSIVE LIMITS:
LEL: N/A
UEL: N/A
EXTINGUISHING MEDIA: CO2, WATER, OR DRY CHEMICAL
SPECIAL FIRE FIGHTING PROCEDURES: NONE KNOWN.
UNUSUAL FIRE HAZARDS: N/A
| SECTION VI - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS: NONE
ENVIRONMENTAL PRECAUTIONS:
DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS. SOLUTIONS MAY BE DISPOSED OF IN SEWER. DRY PRODUCT MAY BE
LANDFILLED IF PERMITTED BY LOCAL REGULATIONS. DISCARD EMPTY CONTAINER IN
TRASH.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
DISPOSE AS DRY SCRAP OR FLUSH SMALL QUANTITIES DOWN ACCEPTABLE SEWER
(CONTAINS BIODEGRADABLE SURFACTANTS). DISPOSE OF ACCORDING TO LOCAL
REGULATIONS. PREVENT HEAVY EXPOSURE TO DUST WITH NIOSH APPROVED DUST MASK.
| SECTION VII - HANDLING AND STORAGE | |
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
STORE IN A COOL, DRY PLACE. KEEP PRODUCT DRY TO MAINTAIN FREE-FLOWING
GRANULES.
OTHER PRECAUTIONS: NONE
| SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION | |
RESPIRATORY PROTECTION (SPECIFY TYPE): NONE REQUIRED WITH NORMAL USE.
VENTILATION:
LOCAL EXHAUST: NONE REQUIRED WITH NORMAL USE.
MECHANICAL (GENERAL): ACCEPTABLE.
SPECIAL: NONE
OTHER: NONE
EYE PROTECTION: NONE REQUIRED WITH NORMAL USE.
MANUFACTURING SETTING:
WITH DUSTY CONDITIONS OR IF A SPLASH IS LIKELY, CHEMICAL GOGGLES MAY BE
NEEDED.
PROTECTIVE GLOVES: NONE REQUIRED WITH NORMAL USE.
MANUFACTURING SETTING:
PROTECTIVE GLOVES (RUBBER, NEOPRENE) SHOULD BE USED FOR ANY PROLONGED DIRECT
CONTACT.
OTHER PROTECTIVE EQUIPMENT: NONE REQUIRED WITH NORMAL USE.
| SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT DEG. F: N/A
SPECIFIC GRAVITY (H2O=1): N/A
VAPOR PRESSURE (MMHg): N/A
PERCENT VOLATILE BY VOLUME (%): N/A
VAPOR DENSITY (AIR=1): N/A
EVAPORATION RATE (nBuOAc=1): N/A
ODOR THRESHOLD: N/A
FREEZING POINT: N/A
COEFFICIENT OF WATER/OIL DISTRIBUTION: N/A
pH (1% SOLUTION): APPROX. 10.9
SCOOPED DENSITY: 0.4/CC (BULK DENSITY)
SOLUBILITY IN WATER: MOSTLY
APPEARANCE AND ODOR: WHITE GRANULE WITH GREEN SPECKS AND BLAND ODOR
RESERVE ALKALINITY: 4.0 MAX
| SECTION X - STABILITY AND REACTIVITY | |
POSSIBLE HAZARDOUS REACTIONS/CONDITIONS: NONE KNOWN
CONDITIONS TO AVOID: NONE
MATERIALS TO AVOID: PRODUCTS WHICH CONTAIN AMMONIA OR ARE ACIDIC
HAZARDOUS DECOMPOSITION PRODUCTS: CHLORINE GAS
OTHER RECOMMENDATIONS: NONE
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
| SECTION XI - TOXICOLOGICAL INFORMATION | |
LD50 (RATS ORAL): 2.9 G/KG
| SECTION XII - ECOLOGICAL INFORMATION | |
NONE
| SECTION XIII - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS. SMALL QUANTITIES MAY BE DISPOSED OF IN SEWER. DRY PRODUCT MAY
BE LANDFILLED. DISCARD EMPTY CONTAINER IN TRASH.
| SECTION XIV - TRANSPORT INFORMATION | |
DOT CLASSIFICATION: THE FINISHED PRODUCT IS NOT DOT HAZARDOUS.
| SECTION XV - ADDITIONAL REGULATORY INFORMATION | |
ALL COMPONENTS ARE LISTED ON THE US TSCA INVENTORY. NO COMPONENTS ARE
AFFECTED BY SIGNIFICANT NEW USE RULES (SNURS) UNDER TSCA SUBSECTION 5.
NO COMPONENTS OF SPIC AND SPAN WITH BLEACH ARE SUBJECT TO CALIFORNIA
PROPOSITION 65.
ALL INGREDIENTS ARE CEPA APPROVED FOR IMPORT TO CANADA BY PROCTER & GAMBLE.
THIS PRODUCT HAS BEEN CLASSIFIED WITH HAZARD CRITERIA OF THE CANADIAN
CONTROL PRODUCTS REGULATION (CPR) AND THIS MSDS CONTAINS ALL INFORMATION
REQUIRED BY THE CANADIAN PRODUCTS REGULATION.
| SECTION XVI - OTHER INFORMATION | |
*N/A. - NOT APPLICABLE
*N/K. - NOT KNOWN
THE SUBMISSION OF THIS MSDS MAY BE REQUIRED BY LAW, BUT THIS IS NOT AN
ASSERTION THAT THE SUBSTANCE IS HAZARDOUS WHEN USED IN ACCORDANCE WITH
PROPER SAFETY PRACTICES AND NORMAL HANDLING PROCEDURES. DATA SUPPLIED IS
FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH.
THE INFORMATION CONTAINED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED
BY PROCTER & GAMBLE TO BE DEPENDABLE AND IS ACCURATE TO THE BEST OF THE
COMPANY'S KNOWLEDGE. THE INFORMATION RELATES TO THE SPECIFIC MATERIAL
DESIGNATED HEREIN, AND DOES NOT RELATE TO THE USE IN COMBINATION WITH ANY
OTHER MATERIAL OR ANY OTHER PROCESS. PROCTER & GAMBLE ASSUMED NO
RESPONSIBILITY FOR INJURY TO THE RECIPIENT OR THIRD PERSONS, FOR ANY DAMAGE
TO ANY PROPERTY RESULTING FROM MISUSE OF THE CONTROLLED PRODUCT.