| Common Name: | HCFC-22, GENETRON 22 |
| Manufacturer: | HONEYWELL FLUORINE PRODUCTS NETHERLANDS |
| SDS Revision Date: | 8/28/2007 |
| SDS Format: | No Format Specified |
| Item Number(s): | 2W198, 2W199 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HONEYWELL
SAFETY DATA SHEET
ACCORDING TO REGULATION (EU) NO. 1907/2006
HCFC-22, GENETRON(R*) 22
VERSION: 1.2
REVISION DATE: 28.08.2007
PRINT DATE: 15.11.2007
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT INFORMATION:
TRADE NAME: HCFC-22, GENETRON(R*) 22
USE OF THE SUBSTANCE/PREPARATION: REFRIGERANT
COMPANY/UNDERTAKING IDENTIFICATION:
COMPANY:
HONEYWELL FLUORINE PRODUCTS EUROPE B.V.
LAARDERHOOGTWEG 18
1101 EA AMSTERDAM
TELEPHONE: (31) 020 5656911
TELEFAX: (31) 020 5656600
EMERGENCY TELEPHONE: (32) 14584545
FOR FURTHER INFORMATION, PLEASE CONTACT: SAFETYDATASHEET@HONEYWELL.COM
| 2. HAZARDS IDENTIFICATION | |
RISK ADVICE TO MAN AND THE ENVIRONMENT:
N: DANGEROUS FOR THE ENVIRONMENT
R59: DANGEROUS FOR THE OZONE LAYER.
DANGEROUS FOR THE ENVIRONMENT:
ADDITIONAL ADVICE: RAPID EVAPORATION OF THE LIQUID MAY CAUSE FROSTBITE.
HIGH VAPOR CONCENTRATIONS CAN CAUSE HEADACHES, DIZZINESS, DROWSINESS, AND
NAUSEA, AND MAY LEAD TO UNCONSCIOUSNESS.
MAY CAUSE CARDIAC ARRHYTHMIA.
SEE SECTION 11 FOR MORE DETAILED INFORMATION ON HEALTH EFFECTS AND
SYMPTOMS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION:
CHEMICAL NAME: CHLORODIFLUOROMETHANE
FORMULA: CHClF2
CAS-NO.: 75-45-6
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. EC-NO. INDEX-NO. CLASSIFICATION CONCENTRATION
(%)
CHLORODI- 75-45-6 200-871-9 N; R59 </= 100
FLUOROM DANGEROUS FOR
ETHANE THE
ENVIRONMENT
OCCUPATIONAL EXPOSURE LIMIT(S), IF AVAILABLE, ARE LISTED IN SECTION 8.
FOR THE FULL TEXT OF THE R PHRASES MENTIONED IN THIS SECTION, SEE SECTION
16.
| 4. FIRST AID MEASURES | |
INHALATION:
REMOVE TO FRESH AIR.
ARTIFICIAL RESPIRATION AND/OR OXYGEN MAY BE NECESSARY.
CALL A PHYSICIAN IMMEDIATELY.
SKIN CONTACT:
RAPID EVAPORATION OF THE LIQUID MAY CAUSE FROSTBITE.
IN CASE OF CONTACT WITH LIQUID, THAW FROSTED PARTS WITH WATER,
THEN REMOVE CLOTHING CAREFULLY.
WASH WITH PLENTY OF WATER CONSULT A PHYSICIAN.
TAKE OFF CONTAMINATED CLOTHING AND SHOES IMMEDIATELY.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
EYE CONTACT:
REMOVE CONTACT LENSES.
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS,
FOR AT LEAST 15 MINUTES.
INGESTION:
AS THIS PRODUCT IS A GAS, REFER TO THE INHALATION SECTION.
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
CALL A PHYSICIAN IMMEDIATELY.
NOTES TO PHYSICIAN:
TREATMENT: DO NOT GIVE ADRENALINE OR SIMILAR DRUGS.
SEE SECTION 11 FOR MORE DETAILED INFORMATION ON HEALTH EFFECTS AND
SYMPTOMS.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE.
ASHRAE 34
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIFIC HAZARDS DURING FIRE FIGHTING:
POSSIBILITY OF GENERATING HAZARDOUS REACTIONS DURING A FIRE DUE TO THE
PRESENCE OF F AND CI GROUPS.
HEATING WILL CAUSE PRESSURE RISE WITH RISK OF BURSTING COOL CLOSED
CONTAINERS EXPOSED TO FIRE WITH WATER SPRAY.
THIS PRODUCT IS NOT FLAMMABLE AT AMBIENT TEMPERATURES AND ATMOSPHERIC
PRESSURE.
HOWEVER, THIS MATERIAL CAN IGNITE WHEN MIXED WITH AIR UNDER PRESSURE AND
EXPOSED TO STRONG IGNITION SOURCES.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE SUIT.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
IMMEDIATELY CONTACT EMERGENCY PERSONNEL.
WEAR PERSONAL PROTECTIVE EQUIPMENT.
UNPROTECTED PERSONS MUST BE KEPT AWAY.
ENSURE ADEQUATE VENTILATION.
IN CASE OF INSUFFICIENT VENTILATION WEAR SUITABLE RESPIRATORY EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
THE PRODUCT EVAPORATES READILY.
FOR PERSONAL PROTECTION SEE SECTION 8.
| 7. HANDLING AND STORAGE | |
HANDLING:
ADVICE ON SAFE HANDLING:
OPEN DRUM CAREFULLY AS CONTENT MAY BE UNDER PRESSURE.
THE PRODUCT SHOULD ONLY BE USED IN AREAS FROM WHICH ALL NAKED LIGHTS AND
OTHER SOURCES OF IGNITION HAVE BEEN EXCLUDED.
PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 50 DEG. C.
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT SPRAY ON A NAKED FLAME OR ANY
INCANDESCENT MATERIAL.
DO NOT USE IN AREAS WITHOUT ADEQUATE VENTILATION.
CONTAMINATED EQUIPMENT (BRUSHES, RAGS) MUST BE CLEANED IMMEDIATELY WITH
WATER.
STORAGE:
FURTHER INFORMATION ON STORAGE CONDITIONS:
STORE IN ORIGINAL CONTAINER.
KEEP AWAY FROM DIRECT SUNLIGHT.
KEEP CONTAINERS TIGHTLY CLOSED IN A COOL, WELL-VENTILATED PLACE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE CONTROLS:
COMPONENTS BASIS VALUE CONTROL EXCEEDING FORM OF REMARKS
TYPE PARAMETERS FACTOR EXPOSURE
CHLORODI- EH40 WEL TIME 3.590
FLUOROMETHANE WEIGHTED MG/M3
AVERAGE 1.000 PPM
CHLORODI- EU ELV TIME 3.600
FLUOROMETHANE WEIGHTED MG/M3
AVERAGE 1.000 PPM
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
REMARKS:
IN CASE OF INSUFFICIENT VENTILATION WEAR SUITABLE RESPIRATORY EQUIPMENT.
HAND PROTECTION:
GLOVE MATERIAL: BUTYL-RUBBER HEAT INSULATING GLOVES
EYE PROTECTION:
SAFETY GLASSES WITH SIDE-SHIELDS CONFORMING TO EN166 FACE-SHIELD
SKIN AND BODY PROTECTION: PROTECTIVE FOOTWEAR
PROTECTIVE MEASURES:
THE PERSONAL PROTECTIVE EQUIPMENT MUST BE IN ACCORDANCE WITH EN
STANDARDS:
RESPIRATOR EN 136, 140, 149; SAFETY GLASSES EN 166
PROTECTIVE SUIT: EN 340, 463, 468, 943-1, 943-2
GLOVES EN 374, SAFETY SHOES EN-ISO 20345.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
FORM: LIQUEFIED GAS
COLOR: COLORLESS
ODOR: SLIGHT
MOLECULAR WEIGHT: 86,46 G/MOL
SAFETY DATA:
MELTING POINT/RANGE: -160 DEG. C
BOILING POINT/BOILING RANGE: -40,8 DEG. C
FLASH POINT REMARKS: NOT APPLICABLE
UPPER EXPLOSION LIMIT:
REMARKS: NONE
DENSITY: 1,21 G/CM3
WATER SOLUBILITY: 3,0 G/L
PARTITION COEFFICIENT n-OCTANOL/WATER:
LOG POW: 1,08 - 1,13
REMARKS: THE PRODUCT IS MORE SOLUBLE IN OCTANOL.
RELATIVE VAPOR DENSITY: 3
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
HEATING WILL CAUSE PRESSURE RISE WITH RISK OF BURSTING PRESSURIZED
CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES
EXCEEDING 50 DEG. C.
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT SPRAY ON A NAKED FLAME OR ANY
INCANDESCENT MATERIAL.
MATERIALS TO AVOID:
OXIDIZING SUBSTANCES
POSSIBLE INCOMPATIBILITY WITH ALKALI SENSITIVE MATERIALS.
POWDERED METALS
HAZARDOUS DECOMPOSITION PRODUCTS:
HALOGENATED COMPOUNDS
CARBONYL HALIDES
CARBON OXIDES
HYDROGEN HALIDES
THERMAL DECOMPOSITION: >250 DEG. C
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE INHALATION TOXICITY:
LC50 SPECIES: RAT
DOSE: >300000 PPM
EXPOSURE TIME: 4 H
REPEATED DOSE TOXICITY:
SPECIES: RAT
NOEL: 10000 PPM
INFORMATION DERIVED FROM PRACTICAL EXPERIENCE.:
INHALATION: MAY CAUSE CARDIAC ARRHYTHMIA.
INGESTION: NO HAZARDS TO BE SPECIALLY MENTIONED.
SKIN CONTACT:
RAPID EVAPORATION OF THE LIQUID MAY CAUSE FROSTBITE. IRRITATING TO SKIN.
EYE CONTACT: IRRITATING TO EYES.
CARDIAC SENSITIZATION THRESHOLD (DOG): 50000 PPM.
| 12. ECOLOGICAL INFORMATION | |
OZONE DEPLETION POTENTIAL (ODP): 0,06
GLOBAL WARMING POTENTIAL (GWP): 1.500
ADDITIONAL ECOLOGICAL INFORMATION:
ACCUMULATION IN AQUATIC ORGANISMS IS UNLIKELY.
| 13. DISPOSAL CONSIDERATIONS | |
PRODUCT:
OFFER SURPLUS AND NON-RECYCLABLE SOLUTIONS TO A LICENSED DISPOSAL COMPANY.
REFER TO MANUFACTURER/SUPPLIER FOR INFORMATION ON RECOVERY/RECYCLING.
REMARKS:
THE CLASSIFICATION OF THE PRODUCT MAY MEET THE CRITERIA FOR A HAZARDOUS
WASTE.
WASTE KEY FOR THE UNUSED PRODUCT:
CLASSIFICATION: 14.06.01
| 14. TRANSPORT INFORMATION | |
ADR:
UN NUMBER: 1018
DESCRIPTION OF THE GOODS: CHLORODIFLUOROMETHANE
CLASS: 2
CLASSIFICATION CODE: 2A
HAZARD IDENTIFICATION NO: 20
HAZARD LABEL: 2.2
IATA:
UN NUMBER: 1018
DESCRIPTION OF THE GOODS: CHLORODIFLUOROMETHANE
CLASS: 2.2
HAZARD LABEL: 2.2
PACKING INSTRUCTION (CARGO AIRCRAFT): 200
PACKING INSTRUCTION (PASSENGER AIRCRAFT): 200
IMDG:
UN NUMBER: 1018
DESCRIPTION OF THE GOODS: CHLORODIFLUOROMETHANE
CLASS: 2.2
HAZARD LABEL: 2.2
EMS NUMBER: F-C
MARINE POLLUTANT: NO
RID:
UN NUMBER: 1018
DESCRIPTION OF THE GOODS: CHLORODIFLUOROMETHANE
CLASS: 2
CLASSIFICATION CODE: 2A
HAZARD IDENTIFICATION NO: 20
HAZARD LABEL: 2.2
| 15. REGULATORY INFORMATION | |
LABELING ACCORDING TO EC DIRECTIVES 67/548/EEC:
SYMBOL(S):
N: DANGEROUS FOR THE ENVIRONMENT
R-PHRASE(S):
R59: DANGEROUS FOR THE OZONE LAYER.
S-PHRASE(S):
S7/9: KEEP CONTAINER TIGHTLY CLOSED AND IN A WELL-VENTILATED PLACE.
S23: DO NOT BREATHE GAS.
S59: REFER TO MANUFACTURER/SUPPLIER FOR INFORMATION ON RECOVERY/RECYCLING.
HAZARDOUS COMPONENTS WHICH MUST BE LISTED ON THE LABEL:
CHLORODIFLUOROMETHANE 75-45-6
OTHER REGULATIONS:
FOR INDUSTRIAL USE ONLY.
RESTRICTED TO PROFESSIONAL USERS.
EU REGULATION 842/2006/EC
EU REGULATION 2037/2000/EC
| 16. OTHER INFORMATION | |
TEXT OF R-PHRASES REFERRED TO UNDER HEADING 3
CHLORODIFLUOROMETHANE:
R59: DANGEROUS FOR THE OZONE LAYER.
FURTHER INFORMATION:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT. FINAL DETERMINATION OF SUITABILITY
OF ANY MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER.
THIS INFORMATION SHOULD NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT
PROPERTIES.