| Common Name: | INSECT REPELLENT WITH DEET |
| Manufacturer: | ZEP MANUFACTURING |
| SDS Revision Date: | 8/14/2008 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3HVA5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ZEP PROFESSIONAL
ZEP INC.
1310 SEABOARD INDUSTRIAL BLVD.
ATLANTA, GA 30318
1-877-793-7776
MATERIAL SAFETY DATA SHEET
| SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: ZEP INSECT REPELLENT WITH DEET
PRODUCT USE: AEROSOL INSECT REPELLENT
PRODUCT CODE: R058
DATE OF ISSUE: 08/14/08
SUPERSEDES:
THIS PRODUCT IS A REGISTERED PESTICIDE. EPA ID NO. 1021-1600-1270
EMERGENCY TELEPHONE NUMBERS:
FOR MSDS INFORMATION:
COMPLIANCE SERVICES 1-877-793-7776
FOR MEDICAL EMERGENCY:
INFOTRAC: (877) 541-2016 TOLL FREE - ALL CALLS RECORDED
FOR TRANSPORTATION EMERGENCY:
CHEMTREC: (800) 424-9300 - ALL CALLS RECORDED
IN THE DISTRICT OF COLUMBIA: (202) 483-7616
PREPARED BY:
COMPLIANCE SERVICES
1420 SEABOARD INDUSTRIAL BLVD.
ATLANTA, GA 30318
| SECTION 2. HAZARDS IDENTIFICATION | |
*HAZARD DETERMINATION SYSTEM (HDS):
HEALTH 1
FLAMMABILITY 4
REACTIVITY 0
EMERGENCY OVERVIEW:
WARNING!
CAUSES EYE IRRITATION. HARMFUL IF SWALLOWED.
CONTENTS UNDER PRESSURE.
NOTE:
MSDS DATA PERTAINS TO THE PRODUCT AS DELIVERED IN THE ORIGINAL SHIPPING
CONTAINER(S). RISK OF ADVERSE EFFECTS ARE LESSENED BY FOLLOWING ALL
PRESCRIBED SAFETY PRECAUTIONS, INCLUDING THE USE OF PROPER PERSONAL
PROTECTIVE EQUIPMENT.
ACUTE EFFECTS:
ROUTES OF ENTRY: EYE CONTACT. INHALATION.
EYES:
CAUSES EYE IRRITATION. INFLAMMATION OF THE EYE IS CHARACTERIZED BY REDNESS,
WATERING AND ITCHING.
SKIN:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS. MAY CAUSE ALLERGIC
REACTIONS IN CERTAIN INDIVIDUALS.
INHALATION:
AVOID DIRECT INHALATION OF SPRAY. OVER-EXPOSURE BY INHALATION MAY CAUSE
RESPIRATORY IRRITATION.
INGESTION:
HARMFUL IF SWALLOWED. CAN CAUSE GASTROINTESTINAL DISTURBANCES.
CHRONIC EFFECTS:
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS:
KIDNEYS, LIVER, EARS.
ADDITIONAL INFORMATION: SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
ISOPROPYL ALCOHOL; IPA; DIMETHYLCARBINOL; 67-63-0 30 - 40
2-PROPANOL
DEET; DIETHYLTOLUAMIDE; N,N-DIETHYL-M-TOLUAMIDE; 134-62-3 25
METADELPHENE
HYDROCARBON PROPELLANT; BLEND OF PROPANE & 75-28-5; 74-98-6 15 - 25
ISOBUTANE
MGK(R) 264; N-OCTYL BICYCLOHEPTENE DICARBOXIMIDE 113-48-4 5
ACETONE; DIMETHYL KETONE 67-64-1 1 - 5
DIPROPYL ISOCINCHOMERONATE 136-45-8 2.5
| SECTION 4. FIRST AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
THIS PRODUCT IS FORMULATED FOR USE ON SKIN BUT SHOULD BE RINSED OFF WHEN
POSSIBLE. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS.
INHALATION:
MOVE EXPOSED PERSON TO FRESH AIR. IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION.
INGESTION:
ASPIRATION HAZARD IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. DO NOT
INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. IF VOMITING
OCCURS, THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS.
IF AFFECTED PERSON IS CONSCIOUS, GIVE PLENTY OF WATER TO DRINK. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION
IMMEDIATELY.
| SECTION 5. FIRE FIGHTING MEASURES | |
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
1
4
0
FLASH POINT: NOT APPLICABLE
FLAMMABLE LIMITS: NOT AVAILABLE.
FLAMMABILITY: EXTREMELY FLAMMABLE. (CSMA METHOD)
FIRE HAZARD:
CONTENTS UNDER PRESSURE. FLAMMABLE LIQUID AND VAPOR. VAPORS MAY ACCUMULATE
IN LOW OR CONFINED AREAS OR TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE OF
IGNITION AND FLASH BACK. IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL
OCCUR AND THE CONTAINER MAY BURST. BURSTING AEROSOL CONTAINERS MAY BE
PROPELLED FROM A FIRE AT HIGH SPEED.
FIRE-FIGHTING PROCEDURES:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE. COOL
CONTAINERS WITH WATER JET IN ORDER TO PREVENT PRESSURE BUILD-UP,
AUTO-IGNITION OR EXPLOSION.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
SPILL CLEAN UP: LARGE SPILLS ARE UNLIKELY DUE TO PACKAGING.
| SECTION 7. HANDLING AND STORAGE | |
HANDLING:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). STORE AND
USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. AVOID
CONTACT WITH EYES. DO NOT BREATHE VAPOR OR MIST. DO NOT INGEST. USE ONLY
WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. APPLY THIS
PRODUCT ONLY AS SPECIFIED ON THE LABEL.
STORAGE:
CONTENTS UNDER PRESSURE. DO NOT PUNCTURE OR INCINERATE. STORE AWAY FROM
DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM
INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. STORE BELOW 120
DEG. F (49 DEG. C).
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). KEEP OUT OF THE
REACH OF CHILDREN.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRODUCT NAME EXPOSURE LIMITS
ISOPROPYL ALCOHOL; IPA; DIMETHYLCARBINOL; ACGIH TLV (UNITED STATES).
2-PROPANOL TWA: 200 PPM 8 HOUR(S).
OSHA PEL (UNITED STATES).
TWA: 400 PPM 8 HOUR(S).
ACGIH/OSHA (UNITED STATES).
STEL: 400 PPM 15 MINUTE(S).
HYDROCARBON PROPELLANT; BLEND OF ACGIH TLV / OSHA PEL (UNITED
PROPANE & ISOBUTANE STATES). NOTES: PROPANE
TWA: 1000 PPM 8 HOUR(S).
ACETONE; DIMETHYL KETONE ACGIH TLV / OSHA PEL (UNITED
STATES).
TWA: 750 PPM 8 HOUR(S).
ACGIH / OSHA (UNITED STATES).
STEL: 1000 PPM 15 MINUTE(S).
PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYES: NO SPECIAL PROTECTION IS REQUIRED.
BODY: NO SPECIAL PROTECTIVE CLOTHING IS REQUIRED.
RESPIRATORY:
AVOID DIRECT INHALATION OF SPRAY. USE WITH ADEQUATE VENTILATION.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID. (AEROSOL.)
pH: NOT APPLICABLE
BOILING POINT: NOT DETERMINED.
SPECIFIC GRAVITY: 0.89
SOLUBILITY:
VERY SLIGHTLY SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
COLOR: CLEAR.
ODOR: MILD. CHARACTERISTIC.
VAPOR PRESSURE: NOT DETERMINED.
VAPOR DENSITY: >1 (AIR = 1)
EVAPORATION RATE: <1 (ETHER (ANHYDROUS). = 1)
VOC (CONSUMER) 555.29 (G/L). 4.63 LBS/GAL 62.50%
| SECTION 10. STABILITY AND REACTIVITY | |
STABILITY AND REACTIVITY: THE PRODUCT IS STABLE.
INCOMPATIBILITY:
KEEP AWAY FROM HEAT, SPARKS AND FLAME. SLIGHTLY REACTIVE OR INCOMPATIBLE
WITH THE FOLLOWING MATERIALS:
OXIDIZING MATERIALS, ACIDS AND ALKALIS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON OXIDES (CO, CO2), NITROGEN OXIDES (NO, NO2 ETC.)
| SECTION 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
ISOPROPYL ALCOHOL LD50 DERMAL RABBIT 13000 MG/KG
LD50 ORAL RAT 4700 MG/KG
LC50 INHALATION VAPOR RAT 22500 PPM 8 HOURS
LC50 INHALATION VAPOR RAT 19000 PPM 8 HOURS
DIETHYLTOLUAMIDE LD50 ORAL RABBIT 3180 MG/KG
LD50 ORAL RAT 1950 MG/KG
LC50 INHALATION VAPOR RAT 5950 MG/M3 8 HOURS
ACETONE LD50 DERMAL RABBIT 20000 MG/KG
LD50 ORAL MOUSE 9750 MG/KG
LC50 INHALATION VAPOR RAT 16000 PPM 4 HOURS
| SECTION 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
AQUATIC ECOTOXICITY:
PRODUCT/INGREDIENT NAME TEST RESULT SPECIES EXPOSURE
DIETHYLTOLUAMIDE ACUTE EC50 75 MG/L DAPHNIA 48 HOURS
| SECTION 13. DISPOSAL CONSIDERATIONS | |
WASTE INFORMATION:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
ENVIRONMENTAL CONTROL REGULATIONS. CONSULT YOUR LOCAL OR REGIONAL
AUTHORITIES FOR ADDITIONAL INFORMATION.
WASTE STREAM:
CODE: D001
CLASSIFICATION: (HAZARDOUS WASTE)
ORIGIN: (RCRA WASTE.)
| SECTION 14. TRANSPORT INFORMATION | |
REGULATORY UN NUMBER PROPER SHIPPING NAME CLASSES PG* LABEL
INFORMATION
DOT NOT CONSUMER COMMODITY ORM-D
CLASSIFICATION AVAILABLE.
IMDG CLASS NOT
DETERMINED.
NOTE:
DOT CLASSIFICATION APPLIES TO MOST PACKAGE SIZES. FOR SPECIFIC CONTAINER
SIZE CLASSIFICATIONS OR FOR SIZE EXCEPTIONS, REFER TO THE BILL OF LADING
WITH YOUR SHIPMENT.
PG*: PACKING GROUP
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING:
PRODUCT NAME: DIPROPYL ISOCINCHOMERONATE
CLEAN WATER ACT (CWA) 307: NO PRODUCTS WERE FOUND.
CLEAN WATER ACT (CWA) 311: NO PRODUCTS WERE FOUND.
CLEAN AIR ACT (CAA) 112 REGULATED TOXIC SUBSTANCES:
NO PRODUCTS WERE FOUND.
ALL COMPONENTS OF THIS PRODUCT ARE LISTED OR EXEMPT FROM LISTING ON TSCA
INVENTORY.
STATE REGULATIONS:
CALIFORNIA PROP 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL OR CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.:
DIPROPYL ISOCINCHOMERONATE
| SECTION 16. OTHER INFORMATION | |
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE NAMED SUPPLIER NOR ANY OF ITS SUBSIDIARIES
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
*NOTE:
HAZARD DETERMINATION SYSTEM (HDS) RATINGS ARE BASED ON A 0-4 RATING SCALE,
WITH 0 REPRESENTING MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING
SIGNIFICANT HAZARDS OR RISKS ALTHOUGH THESE RATINGS ARE NOT REQUIRED ON
MSDSS UNDER 29 CFR 1910.1200, THE PREPARER MAY CHOOSE TO PROVIDE THEM. HDS
RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED PROGRAM TO RELAY THE
MEANINGS OF THIS SCALE.