| Common Name: | ETERNACLEAN |
| Manufacturer: | ETERNABOND |
| SDS Revision Date: | 12/4/2007 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3GYE9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
PROVIDED BY:
ETERNABOND, INC.
75 E. DIVISION ST.
MUNDELEIN, IL 60060
847-837-9400
THIS FORM IS DESIGNED TO MEET THE REQUIREMENTS OF THE U.S. LABOR DEPARTMENT
OSHA FORM NO 174.
| SECTION I: PRODUCT & COMPANY IDENTIFICATION |  |
PRODUCT NAME: ETERNACLEAN
24 HOUR EMERGENCY ASSISTANCE - INFOTRAC: (800)-535-5053
| SECTION II: COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NUMBER % BY WEIGHT
ACETONE 67-64-1 45-55
TOLUENE 108-88-3 25-35
METHANOL 67-56-1 10-20
CARBON DIOXIDE 124-38-9 5-10
| SECTION III: HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
APPEARANCE & ODOR: CLEAR, WATER-WHITE LIQUID.
DANGER:
EXTREMELY FLAMMABLE. VAPOR HARMFUL. HARMFUL OR FATAL IF SWALLOWED. MAY BE
FATAL OR CAUSE BLINDNESS IF SWALLOWED. EYE AND SKIN IRRITANT. CONTENTS
UNDER PRESSURE.
POTENTIAL HEALTH EFFECTS:
EYE:
MODERATE EYE IRRITANT. EXPOSURE CAN CAUSE IRRITATION INCLUDING STINGING,
TEARING, REDNESS, BLURRED VISION, AND SWELLING OF THE EYES.
SKIN:
MODERATE SKIN IRRITANT. PROLONGED OR REPEATED CONTACT MAY DRY THE SKIN.
SYMPTOMS MAY INCLUDE REDNESS, BURNING, DRYING AND CRACKING OF THE SKIN,
AND SKIN BURNS. PASSAGE OF THIS MATERIAL INTO THE BODY THROUGH THE SKIN
IS POSSIBLE, BUT IT IS UNLIKELY THAT THIS WOULD RESULT IN HARMFUL EFFECTS
DURING SAFE HANDLING AND USE.
INHALATION:
BREATHING LARGE AMOUNTS OF THIS MATERIAL MAY BE HARMFUL. SYMPTOMS INCLUDE
IRRITATION OF THE NOSE AND THROAT AND CENTRAL NERVOUS SYSTEM EXCITATION
(GIDDINESS), FOLLOWED BY CNS DEPRESSION (DIZZINESS, DROWSINESS, WEAKNESS,
HEADACHE, NAUSEA, UNCONSCIOUSNESS.)
INGESTION:
SWALLOWING SMALL AMOUNTS IS NOT LIKELY TO CAUSE HARMFUL EFFECTS. MAY CAUSE
STOMACH OR INTESTINAL UPSET. SWALLOWING LARGER AMOUNTS MAY BE HARMFUL AS
THIS MATERIAL MAY BE ASPIRATED INTO THE LUNGS DURING SWALLOWING OR
VOMITING. THIS RESULTS IN LUNG INFLAMMATION AND OTHER LUNG INJURY.
CHRONIC EFFECTS: OVEREXPOSURE TO METHANOL MAY LEAD TO VISUAL IMPAIRMENT.
TARGET ORGANS: LIVER, KIDNEYS, BLOOD, CENTRAL NERVOUS SYSTEM, EYES.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
SKIN SENSITIVITIES, LUNG CONDITIONS, CENTRAL NERVOUS SYSTEM CONDITIONS.
| SECTION IV: FIRST AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. CALL A PHYSICIAN
IF IRRITATION PERSISTS.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND WASH AFFECTED AREA WITH SOAP AND WATER.
CALL A PHYSICIAN IF IRRITATION PERSISTS. WASH CONTAMINATED CLOTHING PRIOR
TO RE-USE.
INHALATION:
REMOVE PERSON TO FRESH AIR. KEEP PERSON CALM. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A
PHYSICIAN.
INGESTION:
SEEK MEDICAL ATTENTION. DO NOT INDUCE VOMITING UNLESS INSTRUCTED BY A
MEDICAL PERSONNEL. HAVE VICTIM DRINK A GLASS OF WATER IS CONSCIENCE.
NOTE TO PHYSICIANS:
THIS MATERIAL IS AN ASPIRATION HAZARD. THIS MATERIAL (OR A COMPONENT)
HAS PRODUCED HYPERGLYCEMIA AND KETOSIS, FOLLOWING SUBSTANTIAL INGESTION.
INHALATION OF HIGH CONCENTRATIONS OF THIS MATERIAL MAY BE ASSOCIATED WITH
CARDIAC ARRHYTHMIAS. SYMPATHOMIMETIC DRUGS MAY INITIATE CARDIAC ARRHYTHMIAS
IN PERSONS EXPOSED TO THIS MATERIAL. THIS PRODUCT CONTAINS METHANOL. THE
METABOLITES OF METHANOL CAN CAUSE METABOLIC ACIDOSIS, VISUAL DISTURBANCES
AND BLINDNESS.
| SECTION V: FIRE-FIGHTING MEASURES | |
FLAMMABLE PROPERTIES:
THIS PRODUCT IS EXTREMELY FLAMMABLE IN ACCORDANCE WITH AEROSOL FLAMMABILITY
DEFINITIONS (16 CFR 1500.3(C)(6)).
FLASHPOINT: <0 DEG. F
METHOD: TCC
LEL: 2.6
UEL: 12.8
AUTOIGNITION TEMPERATURE: 725 F
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL-RESISTANT FOAM, CLASS B
EXTINGUISHERS.
PRODUCTS OF COMBUSTION: OXIDES OF CARBON.
PROTECTION OF FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR SELF-CONTAINED, NIOSH-APPROVED BREATHING
APPARATUS FOR PROTECTION AGAINST SUFFOCATION AND POSSIBLE TOXIC
DECOMPOSITION PRODUCTS. VAPORS ARE HEAVIER THAN AIR AND WILL ACCUMULATE
NEAR THE GROUND. PROPER EYE AND SKIN PROTECTION SHOULD BE PROVIDED. USE
WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL AND TO KNOCK DOWN VAPORS
WHICH MAY RESULT FROM PRODUCT DECOMPOSITION.
| SECTION VI: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS: USE PERSONAL PROTECTION RECOMMENDATION IN SECTION 8.
ENVIRONMENTAL PRECAUTIONS:
TAKE PRECAUTIONS TO PREVENT CONTAMINATION OF GROUND AND SURFACE WATERS.
DO NOT FLUSH INTO SEWERS OR STORM DRAINS.
METHODS FOR CONTAINMENT 7 CLEAN-UP:
ELIMINATE SOURCES OF IGNITION. DIKE AREA TO CONTAIN SPILL. VENTILATE THE
AREA WITH FRESH AIR. IF IN A CONFINED SPACE OR LIMITED AIR CIRCULATION
AREA, CLEAN-UP WORKERS SHOULD WEAR APPROPRIATE RESPIRATORY PROTECTION.
RECOVER OR ABSORB SPILLED MATERIAL USING AN ABSORBENT DESIGNED FOR
CHEMICAL SPILLS. PLACE USED ABSORBENTS INTO PROPER WASTE CONTAINERS.
| SECTION VII: HANDLING AND STORAGE | |
HANDLING PROCEDURES:
DO NOT USE NEAR POTENTIAL SOURCES OF IGNITION. DO NOT USE ON ENERGIZED
EQUIPMENT. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH SKIN AND
EYES. AVOID INHALING VAPORS.
STORAGE PROCEDURES:
STORE IN A COOL DRY AREA OUT OF DIRECT SUNLIGHT. AEROSOL CANS MUST BE
MAINTAINED BELOW 120 F TO PREVENT CANS FROM RUPTURING.
AEROSOL LEVEL: III
| SECTION VIII: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
COMPONENT OSHA ACGIH OTHER
TWA STEL TWA STEL TWA SOURCE UNIT
ACETONE 1000 NE 500 750 NE PPM
TOLEUNE 200 300(C) 20 NE NE PPM
METHONOL 200 NE 200 250(S) NE PPM
CARBON DIOXIDE 5000 30000(V) 5000 30000 NE PPM
NE - NOT ESTABLISHED
(C) - CEILING
(S) - SKIN
(V) - VACATED
ENGINEERING CONTROLS:
AREA SHOULD HAVE VENTILATION TO PROVIDE FRESH AIR. LOCAL EXHAUST
VENTILATION IS GENERALLY PREFERRED BECAUSE IT CAN CONTROL THE EMISSIONS OF
THE CONTAMINANT AT THE SOURCE, PREVENTING DISPERSION INTO THE GENERAL WORK
AREA. USE MECHANICAL MEANS IF NECESSARY TO MAINTAIN VAPOR LEVELS BELOW THE
EXPOSURE GUIDELINES. IF WORKING IN A CONFINED SPACE, FOLLOW APPLICABLE
OSHA REGULATIONS.
RESPIRATORY:
NONE REQUIRED FOR NORMAL WORK WHERE ADEQUATE VENTILATION IS PROVIDED. IF
ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE APPLICABLE
EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS IN CONFINED
SPACES AND FOR EMERGENCIES.
EYE/FACE PROTECTION:
FOR NORMAL CONDITIONS, WEAR SAFETY GLASSES. WHERE THERE IS A REASONABLE
PROBABILITY OF LIQUID CONTACT, WEAR SPLASH-PROOF GOGGLES.
SKIN PROTECTION:
USE PROTECTIVE GLOVES SUCH AS NITRILE, PVA, OR NEOPRENE. ALSO, USE FULL
PROTECTIVE CLOTHING IF THERE IS A PROLONGED OR REPEATED CONTACT OF LIQUID
WITH SKIN.
| SECTION IX: PHYSICAL & CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: CLEAR
ODOR: SOLVENT
SPECIFIC GRAVITY: 0.814
INITIAL BOILING POINT: 132F
FREEZING POINT: ND
VAPOR PRESSURE: ND
VAPOR DENSITY: >1 (AIR = 1)
EVAPORATION RATE: >1 (BUTYL ACETATE = 1)
SOLUBILITY: SLIGHTLY SOLUBLE IN WATER
pH: NA
VOLATILE ORGANIC COMPOUNDS:
WT %: 43.8
G/L: 356.5
LBS./GAL: 2.97
| SECTION X: STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: SOURCES OF IGNITION; TEMPERATURE EXTREMES
INCOMPATIBLE MATERIALS:
ACIDS, ALKALIS, REDUCING AGENTS, STRONG OXIDIZING AGENTS, HYPOCHLORITES,
PEROXIDES, REACTIVE METALS SUCH AS ALUMINUM AND MAGNESIUM, SODIUM, ZINC
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON, VARIOUS HYDROCARBONS
POSSIBILITY OF HAZARDOUS REACTIONS: NO
| SECTION XI: TOXICOLOGICAL INFORMATION | |
LONG-TERM TOXICOLOGICAL STUDIES HAVE NOT BEEN CONDUCTED FOR THIS PRODUCT.
THE FOLLOWING INFORMATION IS AVAILABLE FOR COMPONENTS OF THIS PRODUCT.
ACUTE EFFECTS:
COMPONENT TEST RESULT ROUTE SPECIES
ACETONE LD50 5800 MG/KG ORAL RAT
ACETONE LD50 16,000 PPM/4H INHALATION RAT
ACETONE LD50 20,000 MG/KG DERMAL RABBIT
METHANOL LD50 5045 MG/KG ORAL RAT
METHANOL LD50 12,800 MG/KG DERMAL RABBIT
CHRONIC EFFECTS:
CARCINOGENICITY:
COMPONENT RESULT
OSHA NONE LISTED
IARC NONE LISTED
NTP NONE LISTED
MUTAGENICITY: NO INFORMATION AVAILABLE
| SECTION XII: ECOLOGICAL INFORMATION | |
ECOLOGICAL STUDIES HAVE NOT BEEN CONDUCTED FOR THIS PRODUCT. THE FOLLOWING
INFORMATION IS AVAILABLE FOR COMPONENTS OF THIS PRODUCT.
ECOTOXICITY:
ACETONE - 48H LC50 DAPHNIA: 10 MG/L
PERSISTENCE/DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATION/ACCUMULATION: NO INFORMATION AVAILABLE
MOBILITY IN ENVIRONMENT: NO INFORMATION AVAILABLE
| SECTION XIII: DISPOSAL CONSIDERATIONS | |
DISPOSAL:
THE DISPENSED LIQUID PRODUCT IS A RCRA HAZARDOUS WASTE FOR THE
CHARACTERISTIC OF IGNITABILITY WITH THE FOLLOWING POTENTIAL WASTE CODE(S):
D001, F003, F005 (SEE 40 CFR PART 261.20 - 261.33). AEROSOL CONTAINERS
SHOULD BE FULLY EMPTIED AND DEPRESSURIZED BEFORE DISPOSAL.
ALL DISPOSAL ACTIVITIES MUST COMPLY WITH FEDERAL, STATE, AND LOCAL
REGULATIONS. LOCAL REGULATIONS MAY BE MORE STRINGENT THAN STATE OR
NATIONAL REQUIREMENTS.
| SECTION XIV: TRANSPORTATION INFORMATION | |
PROPER SHIPPING DESCRIPTION:
US DOT (GROUND): CONSUMER COMMODITY, ORM-D
SPECIAL PROVISIONS: NONE
| SECTION XV: REGULATORY INFORMATION | |
U.S. FEDERAL:
TOXIC SUBSTANCES CONTROL ACT (TSCA):
ALL INGREDIENTS ARE EITHER LISTED ON THE TSCA INVENTORY OR ARE EXEMPT.
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT
(CERCLA):
REPORTABLE QUANTITIES (RQ'S) EXIST FOR THE FOLLOWING INGREDIENTS:
ACETONE (5000 LBS), TOLUENE (1000 LBS), METHONAL (5000 LBS)
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS
RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOU LOCAL EMERGENCY PLANNING COMMITTEE.
SUPERFUND AMENDMENTS REAUTHORIZATION ACT (SARA) TITLE III:
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (EHS): NONE
SECTION 311/312 HAZARDOUS CATEGORIES:
FIRE HAZARD: YES
REACTIVE HAZARD: NO
RELEASE OF PRESSURE: YES
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
SECTION 313 TOXIC CHEMICALS:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
TOLUENE(<30%)
METHONAL (<20%)
CLEAN AIR ACT:
SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS): TOLUENE, METHONAL
STATE REGULATIONS:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROP 65):
THIS PRODUCT MAY CONTAIN THE FOLLOWING CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM:
TOLUENE
STATE RIGHT TO KNOW:
NEW JERSEY: 67-64-1, 108-88-3, 67-56-1, 124-3
PENNSYLVANIA: 67-64-1, 108-88-3, 67-56-1, 124-3
MASSACHUSETTS: 67-64-1, 108-88-3, 67-56-1, 124-3
RHODE ISLAND: 67-64-1, 108-88-3, 67-56-1, 124-3
ADDITIONAL REGULATORY INFORMATION: NONE
| SECTION XVI: ADDITIONAL INFORMATION | |
NFPA:
HEALTH 2
FLAMMABILITY 3
REACTIVITY 0
HMIS:
HEALTH 2
FLAMMABILITY 3
REACTIVITY 0
PREPARED BY: MICHELLE RUDNICK
DATE: 12/04/2007
TECHNICAL INFORMATION: (800) 521-3168
CRC #: 594M-Q
CHANGES SINCE LAST REVISION:
MSDS REFORMATTED IN ACCORDANCE WITH ANSI Z400.1-2004
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC INDUSTRIES' KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED
BY CRC TO BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND
DIRECTIONS ON THE LABEL.
CAS: CHEMICAL ABSTRACT SERVICE
PPM: PARTS PER MILLION
TCC: TAG CLOSED CUP
LEL: LOWER EXPLOSIVE LIMIT
UEL: UPPER EXPLOSIVE LIMIT
PPE: PERSONAL PROTECTION EQUIPMENT
COC: CLEVELAND CLOSED CUP
TWA: TIME WEIGHTED AVERAGE
ACGIH: AMERICAN CONFERENCE OF GOV. IND. HYGIENISTS
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY & HEALTH
NA: NOT APPLICABLE
ND: NOT DETERMINED
NE: NOT ESTABLISHED
G/L: GRAMS PER LITER
LBS./GAL: POUNDS PER GALLON
RQ: REPORTABLE QUANTITY
PMCC: PENSKY-MARTENS CLOSED CUP
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMIN.
STEL: SHORT TERM EXPOSURE LIMIT