| Common Name: | LOW ODOR MASTIC REMOVER |
| Manufacturer: | GRAYLING INDUSTRIES |
| SDS Revision Date: | 7/10/2006 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3UAC3, 9CY91 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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GRAYLING INDUSTRIES, INC.
MATERIAL SAFETY DATA SHEET - LOW ODOR MASTIC REMOVER
| I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOW ODOR MASTIC REMOVER
GENERAL OR GENERIC ID: SOLVENT BLEND
ITEM NUMBER: 19105
HFR RATING: 2-2-0
MANUFACTURER:
GRAYLING INDUSTRIES, INC.
1008 BRANCH DRIVE
ALPHARETTA, GA 30004
EMERGENCY PHONE NUMBER:
(800) 535-5053 (INFOTRAC)
INFORMATION: (800) 635-1551
DATE PREPARED: JULY 10, 2006
DATE SUPERCEDED: APRIL 27, 2006
| II. COMPOSITION/INFORMATION ON INGREDIENTS | |
CAS NUMBER:
MEDIUM ALIPHATIC SOLVENT DISTILLATES 64742-88-7
2-BUTOXYETHANOL 111-76-2
HEAVY AROMATIC SOLVENT NAPHTHA 64742-94-5
NONYLPHENOL ETHOXYLATE 9016-45-9
| III. HAZARDS IDENTIFICATION | |
RISK STATEMENTS:
R 65:
HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
R20/65: HARMFUL BY INHALATION, MAY CAUSE LUNG DAMAGE IF SWALLOWED.
SAFETY STATEMENTS:
S24/25: AVOID CONTACT WITH SKIN AND EYES.
| IV. FIRST AID MEASURES | |
EYE CONTACT:
FOR EYES, FLUSH WITH PLENTY OF WATER FOR 15 MINUTES AND GET MEDICAL
ATTENTION.
SKIN CONTACT:
IN CASE OF CONTACT WITH SKIN IMMEDIATELY REMOVE CONTAMINATED CLOTHING. WASH
SKIN THOROUGHLY WITH SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
INHALATION:
AFTER HIGH VAPOR EXPOSURE, REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION.
CALL A PHYSICIAN IMMEDIATELY!
SWALLOWING:
IF SWALLOWED, CALL A PHYSICIAN IMMEDIATELY! DO NOT INDUCE VOMITING!
HAVE PATIENT LIE DOWN AND KEEP WARM. VOMITING MAY LEAD TO PNEUMONITIS, WHICH
MAY BE FATAL.
| V. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
NFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE OR FOAM) FOR CLASS IIIA LIQUID
FIRES.
SPECIAL FIRE FIGHTING PROCEDURES:
WATER SPRAY MAY BE INEFFECTIVE ON FIRE, BUT CAN PROTECT FIRE-FIGHTERS AND
COOL CLOSED CONTAINERS.
USE FOG NOZZLES IF WATER IS USED.
DO NOT ENTER CONFINED FIRE-SPACE WITHOUT FULL BUNKER GEAR.
(HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES, AND RUBBER BOOTS).
USE NIOSH APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS.
UNUSUAL EXPLOSION AND FIRE PROCEDURES:
COMBUSTIBLE !
KEEP CONTAINER TIGHTLY CLOSED.
ISOLATE FROM OXIDIZERS, HEAT, AND OPEN FLAME.
CLOSED CONTAINERS MAY EXPLODE IF EXPOSED TO EXTREME HEAT.
APPLYING TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
EMPTY CONTAINER VERY HAZARDOUS!
CONTINUE ALL LABEL PRECAUTIONS!
| VI. ACCIDENTAL RELEASE MEASURES | |
CONTAINMENT TECHNIQUES:
KEEP UNPROTECTED PERSONNEL AWAY. STOP SPILL AT SOURCE. DIKE AREA AND
CONTAIN.
CLEAN-UP PROCEDURES:
CLEAN UP REMAINDER WITH ABSORBENT MATERIAL. MOP UP AND DISPOSE OF MATERIAL.
| VII. HANDLING AND STORAGE | |
HANDLING:
ISOLATE FROM OXIDIZERS, HEAT, AND OPEN FLAME.
USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING OF VAPOR OR SPRAY MIST.
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
WEAR OSHA STANDARD GOGGLES OR FACE SHIELD. CONSULT SAFETY EQUIPMENT
SUPPLIER. WEAR GLOVES, APRON, AND FOOTWEAR IMPERVIOUS TO THIS MATERIAL.
WASH CLOTHING BEFORE RESUE.
AVOID FREE FALL OF LIQUID. GROUND CONTAINERS WHEN TRANSFERRING. DO NOT FLAME
CUT, BRAZE, OR WELD.
EMPTY CONTAINER VERY HAZARDOUS!
CONTINUE ALL LABEL PRECAUTIONS!
STORAGE:
STORE LARGE AMOUNTS IN STRUCTURES MADE FOR OSHA CLASS IIIA LIQUIDS.
KEEP CONTAINER TIGHTLY CLOSED AND UPRIGHT WHEN NOT IN USE TO PREVENT
LEAKAGE.
| VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
RESPIRATORY EXPOSURE CONTROLS:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 29 CFR 1910.134 AND ANSI
Z86.2 REQUIREMENTS OR EUROPEAN STANDARD EN 149 MUST BE FOLLOWED WHENEVER
WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
VENTILATION:
LOCAL EXHAUST: NECESSARY
MECHANICAL (GENERAL): ACCEPTABLE
SPECIAL: NONE
OTHER: NONE
PERSONAL PROTECTION:
WEAR OSHA STANDARD GOGGLES OR FACE SHIELD. CONSULT SAFETY EQUIPMENT
SUPPLIER. WEAR GLOVES, APRON, AND FOOTWEAR IMPERVIOUS TO THIS MATERIAL.
WASH CLOTHING BEFORE REUSE.
WORK AND HYGIENIC PRACTICES:
PROVIDE READILY ACCESSIBLE EYE WASH STATIONS AND SAFETY SHOWERS.
WASH AT END OF EACH WORK SHIFT AND BEFORE EATING, SMOKING, OR USING THE
TOILET.
PROMPTLY REMOVE CLOTHING THAT BECOMES CONTAMINATED. DESTROY CONTAMINATED
LEATHER ARTICLES, LAUNDER OR DISCARD CONTAMINATED CLOTHING.
| IX. PHYSICAL DATA | |
APPEARANCE: LIQUID, WATER-WHITE
ODOR: AROMATIC
BOILING POINT:
174 DEG. 190 DEG. 196 DEG. * C/346 DEG. 375 DEG. 385 DEG. * F (*=END POINT)
AUTO IGNITION TEMPERATURE: 260 DEG. C/500 DEG. F (LOWEST COMPONENT)
LOWER FLAMMABLE LIMIT IN AIR (% BY VOL): 0.9
FLASH POINT (TEST METHOD): 60 DEG. C/141 DEG. F (TCC) (LOWEST COMPONENT)
FLAMMABILITY CLASSIFICATION: CLASS IIIA
GRAVITY @ 68/68 DEG. F/20/20 DEG. C:
API: 43.9
SPECIFIC GRAVITY (WATER=1): 0.807
POUNDS/GALLON: 6.719
VOC'S (>0.44 LBS/SQ.INCH): 0.0 VOL. %/0.0 G/L/0.000 LBS/GAL
TOTAL VOC'S (TVOC): 99.0 VOL. %/796.1 G/L/6.631 LBS/GAL
NONEXEMPT VOC'S (CVOC): 99.0 VOL. %/796.1 G/L/6.631 LBS/GAL
HAZARDOUS AIR POLLUTANTS (HAPS): 0.0 WT. %/0.0 G/L/0.000 LBS/GAL
VAPOR PRESSURE (MM OF HG @20 DEG. C): 0.5
NONEXEMPT VOC PARTIAL PRESSURE (MM OF HG @ 20 DEG. C): 0.5
VAPOR DENSITY (AIR=1): 5.0
WATER ABSORPTION: APPRECIABLE
REFRACTIVE INDEX: 1.438
MIXED ANILINE POINT (ACID INSOL): 63 DEG. C/147 DEG. F
| X. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID: ISOLATE FROM OXIDIZERS, HEAT, AND OPEN FLAME.
MATERIALS TO AVOID:
ISOLATE FROM STRONG OXIDIZERS SUCH AS PERMANGANATES, CHROMATES, AND
PEROXIDES.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE, CARBON DIOXIDE FROM BURNING.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| XI. TOXICOLOGICAL INFORMATION | |
MATERIAL/CAS#/TWA (OSHA)/TLV (ACGIH)/HAP:
MEDIUM ALIPHATIC SOLVENT NAPHTHA/*64742-88-7/5 MG/M3/5 MG/M3/NO
2-BUTOXYETHANOL/111-76-2/50 PPM S/20 PPM S/NO
HEAVY AROMATIC SOLVENT NAPHTHA/*64742-94-5/100 PPM/5 MP/M3/NO
NONYLPHENOL ETHOXYLATE/9016-45-9/NONE KNOWN/NONE KNOWN/ NO
THIS PRODUCT CONTAINS NO EPQ HAZARDOUS AIR POLLUTANTS (HAP) IN AMOUNTS
>0.1%.
USING MANUFACTURERS' DATA, BASED ON EPA METHOD 311, THE FOLLOWING EPA
HAZARDOUS AIR POLLUTANTS MAY BE PRESENT IN TRACE AMOUNTS (LESS THAN 0.1%):
CUMENE, NAPHTHALENE
MATERIAL/CAS#/CEILING/STEL (OSHA/ACGIH):
-/-/NONE KNOWN/NONE KNOWN
ACUTE HAZARDS:
EYE & SKIN CONTACT:
PRIMARY IRRITATION TO SKIN, DEFATTING, DERMATITIS.
ABSORPTION THRU SKIN INCREASES EXPOSURE.
PRIMARY IRRITATION TO EYES, REDNESS, TEARING, BLURRED VISION.
LIQUID CAN CAUSE EYE IRRITATION. WASH THOROUGHLY AFTER HANDLING.
INHALATION:
ANESTHETIC. IRRITATES RESPIRATORY TRACT. ACUTE OVEREXPOSURE CAN CAUSE
SERIOUS NERVOUS SYSTEM DEPRESSION. VAPOR HARMFUL.
BREATHING VAPOR CAN CAUSE IRRITATION.
ACUTE OVEREXPOSURE CAN CAUSE DAMAGE TO KIDNEYS, BLOOD, NERVES, LIVER &
LUNGS.
SWALLOWING:
HARMFUL OR FATAL IF SWALLOWED.
SWALLOWING CAN CAUSE ABDOMINAL IRRITATION, NAUSEA, VOMITING & DIARRHEA.
SUBCHRONIC HAZARDS/CONDITIONS AGGREVATED:
CONDITIONS AGGREVATED:
CHRONIC OVEREXPOSURE CAN CAUSE DAMAGE TO KIDNEYS, BLOOD, NERVES, LIVER &
LUNGS.
PERSONS WITH SEVERE SKIN, LIVER, OR KIDNEY PROBLEMS SHOULD AVOID USE.
CHRONIC HAZARDS:
CANCER, REPRODUCTIVE & OTHER CHRONIC HAZARDS:
LUNG, LIVER TUMORS HAVE BEEN REPORTED IN LABORATORY MICE.
LEUKEMIA HAS BEEN REPORTED IN HUMANS FROM BENZENE.
THIS PRODUCT CONTAINS LESS THAN 1 PPM OF BENZENE.
NOT CONSIDERED HAZARDOUS IN SUCH LOW CONCENTRATIONS.
ABSORPTION THRU SKIN MAY BE HARMFUL.
| XII. ECOLOGICAL INFORMATION | |
MAMMALIAN INFORMATION:
MATERIAL/CAS #/LOWEST KNOWN LETHAL DOSE DATA:
ETHYLENE GLYCOL BUTYL ETHER/111-76-2/LOWEST KNOWN LD50 (ORAL):
320.0 MG/KG (RABBITS)
ETHYLENE GLYCOL BUTYL ETHER/111-76-2/LOWEST KNOWN LD50 (VAPORS):
700 PPM (MICE)
ETHYLENE GLYCOL BUTYL ETHER/111-76-2/LOWEST KNOWN LD50 (SKIN):
440.0 MG/KG (RABBITS)
AQUATIC ANIMAL INFORMATION:
THE MOST SENSITIVE KNOWN AQUATIC GROUP TO ANY COMPONENT OF THIS PRODUCT IS:
TIDEWATER SILVERSIDES 1250 PPM OR MG/L (96 HOUR EXPOSURE).
KEEP OUT OF SEWERS AND NATURAL WATER SUPPLIES.
MOBILITY: THIS MATERIAL IS A MOBILE LIQUID.
DEGRADABILITY: THIS PRODUCT IS PARTIALLY BIODEGRADABLE.
ACCUMULATION: BIOACCUMULATION OF THIS PRODUCT HAS NOT BEEN DETERMINED.
| XIII. DISPOSAL CONSIDERATION | |
RECYCLE/DISPOSE OF, OBSERVING NATIONAL, REGIONAL, STATE, PROVINCIAL AND
LOCAL HEALTH, SAFETY AND POLLUTION LAWS.
IF QUESTIONS EXIST, CONTACT THE APPROPRIATE AGENCIES.
| XIV. TRANSPORT INFORMATION | |
DOT SHIPPING NAME:
BULK:
COMPOUNDS, CLEANING LIQUID (MEDIUM ALIPHATIC SOLVENT NAPHTHA,
2-BUTOXYETHANOL) COMBUSTIBLE LIQUID, NA1993, PG-III COMBUSTIBLE LIQUID. NOT
DOT REGULATED ON TRUCKS IN CONTAINERS OF < 119 GALLONS.
DRUM LABEL: NONE (COMBUSTIBLE LIQUID)
IATA/ICAO: NONE
IMO/IMDG: NONE
EMERGENCY RESPONSE GUIDEBOOK NUMBER: 128
| XV. REGULATORY INFORMATION | |
EPA REGULATION:
SARA SECTION 311/312 HAZARDS:
ACUTE HEALTH, CHRONIC HEALTH, FIRE ALL COMPONENTS OF THIS PRODUCT ARE ON THE
TSCA LIST.
SARA TITLE III SECTION 313 SUPPLIER NOTIFICATION:
THIS PRODUCT CONTAINS THE INDICATED <*> TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING & COMMUNITY
RIGHT-TO-KNOW ACT OF 1986 & OF 40 CFR 372. THIS INFORMATION MUST BE INCLUDED
IN ALL MSDS'S THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL.
SARA TITLE III INGREDIENTS/CAS #/WT. % (REG.SECTION)/RQ (LBS):
*2-BUTOXYETHANOL/111-76-2/11 (313)/NONE
INTERNATIONAL REGULATIONS:
THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE CHEMICAL INVENTORIES OF THE
FOLLOWING COUNTRIES:
AUSTRALIA, CANADA, EUROPE (EINECS), JAPAN, KOREA, UNITED KINGDOM.
| XVI. OTHER INFORMATION | |
HAZARD RATINGS:
HEALTH (NFPA): 2
HEALTH (HMIS): 3
FLAMMABILITY: 2
REACTIVITY: 0
THIS INFORMATION IS INTENDED SOLELY FOR THE USE OF INDIVIDUALS TRAINED IN
THE NFPA & HMIS HAZARD RATING SYSTEMS.
EMPLOYEE TRAINING:
EMPLOYEES SHOULD BE MADE AWARE OF ALL HAZARDS OF THIS MATERIAL (AS STATED IN
THIS MSDS) BEFORE HANDLING IT.
NOTICE:
THE SUPPLIER DISCLAIMS ALL EXPRESSED OR IMPLIED WARRANTIES OF
MERCHANTABILITY OR FITNESS FOR A SPECIFIC USE, WITH RESPECT TO THE PRODUCT
OR THE INFORMATION PROVIDED HEREIN, EXCEPT FOR CONFORMATION TO CONTRACTED
SPECIFICATIONS.
ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED FROM
MANUFACTURERS AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE INFORMATION IS
BELIEVED TO BE ACCURATE, WE MAKE NO REPRESENTATIONS AS TO ITS ACCURACY OR
SUFFICIENCY.
CONDITIONS OF USE ARE BEYOND OUR CONTROL, AND THEREFORE USERS ARE
RESPONSIBLE FOR VERIFYING THE DATA UNDER THEIR OWN OPERATING CONDITIONS TO
DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR PARTICULAR PURPOSES
AND THEY ASSUME ALL RISKS OF THEIR USE, HANDLING, AND DISPOSAL OF THE
PRODUCT. USERS ALSO ASSUME ALL RISKS IN REGARDS TO THE PUBLICATION OR USE
OF, OR RELIANCE UPON, INFORMATION CONTAINED HEREIN.
THIS INFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN, AND DOES NOT
RELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR PROCESS.
UNLESS UPDATED, THAT MATERIAL SAFETY DATA SHEET (MSDS) IS VALID UNTIL MARCH
2008.