| Common Name: | RUST TOUGH RUST PREVENTIVE ENAMEL, SAFETY BLUE (OSHA BLUE), R00241 |
| Manufacturer: | SHERWIN-WILLIAMS |
| SDS Revision Date: | 7/2/2006 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3VZT3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
MATERIAL SAFETY DATA SHEET
R00241
16 00
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NUMBER: R00241
PRODUCT NAME: RUST TOUGH* RUST PREVENTIVE ENAMEL, SAFETY BLUE (OSHA BLUE)
HMIS CODES:
HEALTH 2*
FLAMMABILITY 2
REACTIVITY 0
MANUFACTURER'S NAME:
THE SHERWIN-WILLIAMS COMPANY
DIVERSIFIED BRANDS
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NO.: (216) 566-2917
INFORMATION TELEPHONE NO.: (800) 247-3266
DATE OF PREPARATION: 02-JUL-06
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
% BY WT CAS NO. INGREDIENT UNITS VAPOR PRESSURE
39 64742-88-7 MINERAL SPIRITS 2 MM
ACGIH TLV: 100 PPM
OSHA PEL: 100 PPM
0.1 100-41-4 ETHYLBENZENE 7.1 MM
ACGIH TLV: 100 PPM
ACGIH TLV: 125 PPM STEL
OSHA PEL: 100 PPM
OSHA PEL: 125 PPM STEL
0.1 136-52-7 COBALT 2-ETHYLHEXANOATE
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
0.6 14808-60-7 QUARTZ
ACGIH TLV: 0.05 MG/M3 AS RESP. DUST
OSHA PEL: 0.1 MG/M3 AS RESP. DUST
5 13463-67-7 TITANIUM DIOXIDE
ACGIH TLV: 10 MG/M3 AS DUST
OSHA PEL: 10 MG/M3 TOTAL DUST
OSHA PEL: 5 MG/M3 RESPIRABLE FRACTION
| SECTION 3 - HAZARDS IDENTIFICATION | |
ROUTES OF EXPOSURE:
INHALATION OF VAPOR OR SPRAY MIST.
EYE OR SKIN CONTACT WITH THE PRODUCT, VAPOR OR SPRAY MIST.
EFFECTS OF OVEREXPOSURE:
EYES: IRRITATION.
SKIN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION.
INHALATION:
IRRITATION OF THE UPPER RESPIRATORY SYSTEM.
MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN
UNCONSCIOUSNESS AND POSSIBLY DEATH.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN
EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE GENERALLY RECOGNIZED.
CANCER INFORMATION:
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.
| SECTION 4 - FIRST AID MEASURES | |
EYES:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES.
GET MEDICAL ATTENTION.
SKIN:
WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE?USE.
INHALATION:
IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM AND QUIET.
INGESTION:
DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: 100 F PMCC
LEL: 1.0
UEL: 6.0
FLAMMABILITY CLASSIFICATION: COMBUSTIBLE, FLASH ABOVE 99 AND BELOW 200 F
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT.
OBTAIN MEDICAL ATTENTION.
SPECIAL FIRE FIGHTING PROCEDURES:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO
EXTREME HEAT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA.
REMOVE WITH INERT ABSORBENT.
| SECTION 7 - HANDLING AND STORAGE | |
STORAGE CATEGORY: DOL STORAGE CLASS II
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
CONTENTS ARE COMBUSTIBLE. KEEP AWAY FROM HEAT AND OPEN FLAME.
CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES.
KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED CONTAINERS
WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE INTERNALLY. KEEP OUT
OF THE REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRECAUTIONS TO BE TAKEN IN USE:
USE ONLY WITH ADEQUATE VENTILATION.
AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR AND SPRAY MIST.
WASH HANDS AFTER USING.
THIS COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECTION 2) WHICH MAY BE PRESENT AT HAZARDOUS LEVELS
ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. IF NO SPECIFIC DUSTS
ARE LISTED IN SECTION 2, THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE
ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION),
OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
VENTILATION:
LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO
MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION:
IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY
VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR
APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS IN SECTION 2.
WHEN SANDING OR ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR
APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,
UNDERLYING PAINT, OR THE ABRASIVE.
PROTECTIVE GLOVES:
WEAR GLOVES WHICH ARE RECOMMENDED BY GLOVE SUPPLIER FOR PROTECTION AGAINST
MATERIALS IN SECTION 2.
EYE PROTECTION: WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
OTHER PRECAUTIONS:
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
CAN BE HARMFUL OR FATAL.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
PRODUCT WEIGHT:
8.20 LB/GAL
982 G/L
SPECIFIC GRAVITY: 0.99
BOILING POINT:
300 - 395 F
148 - 201 C
MELTING POINT: NOT AVAILABLE
VOLATILE VOLUME: 54%
EVAPORATION RATE: SLOWER THAN ETHER
VAPOR DENSITY: HEAVIER THAN AIR
SOLUBILITY IN WATER: N.A.
VOLATILE ORGANIC COMPOUNDS (VOC THEORETICAL - AS PACKAGED):
3.48 LB/GAL 417 G/L LESS WATER AND FEDERALLY EXEMPT SOLVENTS
3.48 LB/GAL 417 G/L EMITTED VOC
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
CHRONIC HEALTH HAZARDS:
ETHYLBENZENE IS CLASSIFIED BY IARC AS POSSIBLY CARCINOGENIC TO HUMANS (2B)
BASED ON INADEQUATE EVIDENCE IN HUMANS AND SUFFICIENT EVIDENCE IN
LABORATORY ANIMALS. LIFETIME INHALATION EXPOSURE OF RATS AND MICE TO HIGH
ETHYLBENZENE CONCENTRATIONS RESULTED IN INCREASES IN CERTAIN TYPES OF
CANCER, INCLUDING KIDNEY TUMORS IN RATS AND LUNG AND LIVER TUMORS IN MICE.
THESE EFFECTS WERE NOT OBSERVED IN ANIMALS EXPOSED TO LOWER CONCENTRATIONS.
THERE IS NO EVIDENCE THAT ETHYLBENZENE CAUSES CANCER IN HUMANS.
CRYSTALLINE SILICA (QUARTZ, CRISTOBALITE) IS LISTED BY IARC AND NTP. LONG
TERM EXPOSURE TO HIGH LEVELS OF SILICA DUST, WHICH CAN OCCUR ONLY WHEN
SANDING OR ABRADING THE DRY FILM, MAY CAUSE LUNG DAMAGE (SILICOSIS) AND
POSSIBLY CANCER.
COBALT AND COBALT COMPOUNDS ARE CLASSIFIED BY IARC AS POSSIBLY CARCINOGENIC
TO HUMANS (GROUP 2B) BASED ON EXPERIMENTAL ANIMAL DATA, HOWEVER, THERE IS
INADEQUATE EVIDENCE IN HUMANS FOR ITS CARCINOGENICITY.
PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS IN SECTION 2 MAY CAUSE ADVERSE
EFFECTS TO THE LIVER AND URINARY SYSTEMS.
RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG./M3 DEVELOPED LUNG CANCER,
HOWEVER, SUCH EXPOSURE LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
TOXICOLOGY DATA:
CAS NO. INGREDIENT NAME
64742-88-7 MINERAL SPIRITS
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
100-41-4 ETHYLBENZENE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 3500 MG/KG
136-52-7 COBALT 2-ETHYLHEXANOATE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
14808-60-7 QUARTZ
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
13463-67-7 TITANIUM DIOXIDE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261.
WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA
HAZARDOUS WASTE NUMBERS.
INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINER.
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL, AND LOCAL
REGULATIONS REGARDING POLLUTION.
| SECTION 14 - TRANSPORT INFORMATION | |
NO DATA AVAILABLE.
| SECTION 15 - REGULATORY INFORMATION | |
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION:
CAS NO. CHEMICAL/COMPOUND % BY WT % ELEMENT
100-41-4 ETHYLBENZENE 0.1
COBALT COMPOUND 0.1 0.02
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
TSCA CERTIFICATION:
ALL CHEMICALS IN THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE
TSCA INVENTORY.
| SECTION 16 - OTHER INFORMATION | |
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS
ALL OF THE INFORMATION REQUIRED BY THE CPR.
THE ABOVE INFORMATION PERTAINS TO THIS PRODUCT AS CURRENTLY FORMULATED,
AND IS ASED ON THE INFORMATION AVAILABLE AT THIS TIME. ADDITION OF
REDUCERS OR OTHER ADDITIVES TO THIS PRODUCT MAY SUBSTANTIALLY ALTER THE
COMPOSITION AND HAZARDS OF THE PRODUCT. SINCE CONDITIONS OF USE ARE
OUTSIDE OUR CONTROL, WE MAKE NO WARRANTIES, EXPRESS OR IMPLIED, AND
ASSUME NO LIABILITY IN CONNECTION WITH ANY USE OF THIS INFORMATION.