| Common Name: | TOUGH GUY ULTRA-FLAT BLACK 12 OZ SPRAY |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 5/13/2009 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4WGC1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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4WGC1
TOUGH GUY ULTRA-FLAT BLACK 12 OZ SPRAY
MATERIAL SAFETY DATA SHEET
24 HOUR ASSISTANCE: 800-228-5635
| SECTION 1 - CHEMICAL PRODUCT / COMPANY INFORMATION |  |
PRODUCT NAME: TOUGH GUY ULTRA-FLAT BLACK 12 OZ SPRAY
REVISION DATE: 05/13/2009
IDENTIFICATION NUMBER: 4WGC1
PRODUCT USE/CLASS: TOPCOAT/AEROSOLS
SUPPLIER:
W.W. GRAINGER
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045-5201
USA
MANUFACTURER:
W.W. GRAINGER
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045-5201
USA
PREPARER: REGULATORY DEPARTMENT
| SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NUMBER WEIGHT % LESS THAN
ACETONE 67-64-1 35.0
LIQUEFIED PETROLEUM GAS 68476-86-8 30.0
MINERAL SPIRITS 64742-88-7 10.0
ALIPHATIC HYDROCARBON 64742-89-8 10.0
XYLENE 1330-20-7 5.0
NAPHTHA 8032-32-4 5.0
MAGNESIUM SILICATE 14807-96-6 5.0
PIGMENT BLACK 7 1333-86-4 5.0
ETHYLBENZENE 100-41-4 5.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL CEILING
ACETONE 500 PPM 750 PPM 750 PPM N.E.
LIQUEFIED PETROLEUM GAS 1000 PPM N.E. 1000 PPM N.E.
MINERAL SPIRITS 100 PPM N.E. 100 PPM N.E.
ALIPHATIC HYDROCARBON 300 PPM N.E. 300 PPM N.E.
XYLENE 100 PPM 150 PPM 100 PPM N.E.
NAPHTHA 300 PPM N.E. N.E. N.E.
MAGNESIUM SILICATE 10 MG/M3 N.E. 15 MG/M3 N.E.
PIGMENT BLACK 7 3.5 MG/M3 N.E. 3.5 MG/M3 N.E.
ETHYLBENZENE 100 PPM 125 PPM 100 PPM N.E.
| SECTION 3 - HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
CONTENTS UNDER PRESSURE. HARMFUL IF INHALED. MAY AFFECT THE BRAIN OR
NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. HARMFUL IF SWALLOWED.
EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY CAUSE FLASH FIRE OR
EXPLOSION.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES EYE IRRITATION.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION. SUBSTANCE MAY
CAUSE SLIGHT SKIN IRRITATION.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND
LUNGS. HARMFUL IF INHALED. HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS
MAY BE HARMFUL IF INHALED. AVOID BREATHING VAPORS OR MISTS.
EFFECTS OF OVEREXPOSURE - INGESTION:
ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND CAUSE DAMAGE. SUBSTANCE
MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
IARC LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B).
MAY CAUSE CENTRAL NERVOUS SYSTEM DISORDER (E.G., NARCOSIS INVOLVING A LOSS
OF COORDINATION, WEAKNESS, FATIGUE, MENTAL CONFUSION, AND BLURRED VISION)
AND/OR DAMAGE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH LIVER
ABNORMALITIES, KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS WELL AS
REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC OVEREXPOSURE,
HAVE INCLUDED LIVER, CARDIAC ABNORMALITIES AND NERVOUS SYSTEM DAMAGE.
CONTAINS CARBON BLACK. CHRONIC INFLAMMATION, LUNG FIBROSIS, AND LUNG TUMORS
HAVE BEEN OBSERVED IN SOME RATS EXPERIMENTALLY EXPOSED FOR LONG PERIODS OF
TIME TO EXCESSIVE CONCENTRATIONS OF CARBON BLACK AND SEVERAL INSOLUBLE FINE
DUST PARTICLES. TUMORS HAVE NOT BEEN OBSERVED IN OTHER ANIMAL SPECIES
(I.E., MOUSE AND HAMSTER) UNDER SIMILAR CIRCUMSTANCES AND STUDY CONDITIONS.
EPIDEMIOLOGICAL STUDIES OF NORTH AMERICAN WORKERS SHOW NO EVIDENCE OF
CLINICALLY SIGNIFICANT ADVERSE HEALTH EFFECTS DUE TO OCCUPATIONAL EXPOSURE
TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4-"NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND THE
ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA.
PRIMARY ROUTE(S) OF ENTRY:
SKIN CONTACT, SKIN ABSORPTION, INHALATION, EYE CONTACT
| SECTION 4 - FIRST AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION.
FIRST AID - SKIN CONTACT:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR
PERSISTS.
FIRST AID - INHALATION:
IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ASSISTANCE
IMMEDIATELY.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN
ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: -156 F (SETAFLASH)
LOWER EXPLOSIVE LIMIT: 0.7%
UPPER EXPLOSIVE LIMIT: 12.8%
EXTINGUISHING MEDIA: DRY CHEMICAL, FOAM, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
WATER SPRAY MAY BE INEFFECTIVE. FLASH POINT IS LESS THAN 20 DEG. F. -
EXTREMELY FLAMMABLE LIQUID AND VAPOR!
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. VAPORS MAY FORM
EXPLOSIVE MIXTURES WITH AIR. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND
FLASH BACK. KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL
EQUIPMENT, SPARKS AND OPEN FLAME. PERFORATION OF THE PRESSURIZED CONTAINER
MAY CAUSE BURSTING OF THE CAN.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE
WITH INERT ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF ACCORDING TO LOCAL,
STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED
CONTAINERS.
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING:
FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED BECAUSE
IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING VAPOR OR MIST. WASH
THOROUGHLY AFTER HANDLING. USE ONLY IN A WELL-VENTILATED AREA. WASH HANDS
BEFORE EATING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. DO NOT STORE ABOVE 120 DEG. F. STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS I
FLAMMABLE LIQUIDS. CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO HEAT OR STORE
ABOVE 120 DEG. F.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR
OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS. USE EXPLOSION-PROOF VENTILATION EQUIPMENT.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH AN
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE
LIMITS.
PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE
PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR IN ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING RANGE: -34 - 415 F
VAPOR DENSITY: HEAVIER THAN AIR
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
APPEARANCE: AEROSOLIZED MIST
EVAPORATION RATE: FASTER THAN ETHER
SOLUBILITY IN H2O: SLIGHT
FREEZE POINT: N.D.
SPECIFIC GRAVITY: 0.759
VAPOR PRESSURE: N.D.
pH: N.A.
PHYSICAL STATE: LIQUID
(SEE SECTION 16 FOR ABBREVIATION LEGEND)
| SECTION 10 - STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEG. F. AVOID ALL POSSIBLE SOURCES OF
IGNITION.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
PRODUCT LD50: N.D.
PRODUCT LC50: N.D.
CHEMICAL NAME LD50 LC50
ACETONE 5800 MG/KG (RAT) 50100 MG/M3 (RAT, 8 HR)
LIQUEFIED PETROLEUM GAS N.E. N.E.
MINERAL SPIRITS >8 MG/KG >1400 PPM
(RAT, ORAL) (RAT, INHALATION, 4 HR)
ALIPHATIC HYDROCARBON >5000 MG/KG N.E.
(RAT, ORAL)
XYLENE 4300 MG/KG 5000 PPM
(RAT, ORAL) (RAT, INHALATION, 4 HR)
NAPHTHA >5000 MG/KG N.E.
(RAT, ORAL)
MAGNESIUM SILICATE N.E. TCLO:
11 MG/M3 (INHALATION)
PIGMENT BLACK 7 >8000 MG/KG N.E.
(RAT, ORAL)
ETHYLBENZENE 3500 MG/KG N.E.
(RAT, ORAL)
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| SECTION 13 - DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER STORM DRAINS OR SEWER SYSTEMS.
| SECTION 14 - TRANSPORTATION INFORMATION | |
DOT PROPER SHIPPING NAME: AEROSOLS
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: 2.1
DOT UN/NA NUMBER: UN1950
PACKING GROUP: N.A.
HAZARD SUBCLASS: N.A.
RESP. GUIDE PAGE: 126
| SECTION 15 - REGULATORY INFORMATION | |
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES"
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD, PRESSURIZED
GAS HAZARD
SARA SECTION 313:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE
SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS NUMBER
XYLENE 1330-20-7
ETHYLBENZENE 100-41-4
TOXIC SUBSTANCES CONTROL ACT:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE
UNITED STATES:
U.S. STATE REGULATIONS: AS FOLLOWS
NEW JERSEY RIGHT-TO-KNOW:
THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE
COMPONENTS IN THIS PRODUCT.
CHEMICAL NAME CAS NUMBER
MODIFIED ALKYD PROPRIETARY
PENNSYLVANIA RIGHT-TO-KNOW:
THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT
GREATER THAN 3%.
CHEMICAL NAME CAS NUMBER
MODIFIED ALKYD PROPRIETARY
CALCIUM CARBONATE 1317-65-3
CALIFORNIA PROPOSITION 65:
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN BY THE STATE OF CALIFORNIA TO
CAUSE CANCER.
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
CANADIAN WHMIS CLASS:
AB5
D2A
D2B
| SECTION 16 - OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 4
REACTIVITY 0
PERSONAL PROTECTION X
REASON FOR REVISION: REGULATORY UPDATE
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
THE INFORMATION CONTAINED ON THIS MSDS HAS BEEN CHECKED AND SHOULD BE
ACCURATE. HOWEVER, IT IS THE RESPONSIBILITY OF THE USER TO COMPLY WITH ALL
FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS.