| Common Name: | ALL CEMENTED TUNGSTEN CARBIDE AND CERMET GRADES |
| Manufacturer: | SANDVIK COROMANT |
| SDS Revision Date: | 5/26/2009 |
| SDS Format: | No Format Specified |
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4UNV5, 4UNV6, 4UNV7, 4UNV8, 4UNV9, 4UNW1, 4UNW2, 4UNW3, 4UNW4, 4UNW5, 4UNW6, 4UNW7, 4UNW8, 4UNW9, 4UNX1, 4UNX2, 4UNX3, 4UNX4, 4UNX5, 4UNX6, 4UNX7, 4UNX8, 4UNX9, 4UNY1, 4UNY2, 4UNY3, 4UNY4, 4UNY5, 4UNY6, 4UNY7, 4UNY8, 4UNY9, 4UNZ1, 4UNZ2, 4UNZ3, 4UNZ4, 4UNZ5, 4UNZ6, 4UNZ7, 4UNZ8, 4UNZ9, 4UPA1, 4UPA2, 4UPA3, 4UPA4, 4UPA5, 4UPA6, 4UPA7, 4UPA8, 4UPA9, 4UPC1, 4UPC2, 4UPC3, 4UPC4, 4UPC5, 4UPC6, 4UPC7, 4UPC8, 4UPC9, 4UPD1, 4UPD2, 4UPD3, 4UPD4, 4UPD5, 4UPD6, 4UPD7, 4UPD8, 4UPD9, 4UPE1, 4UPE2, 4UPE3, 4UPE4, 4UPE5, 4UPE6, 4UPE7, 4UPE8, 4UPE9, 4UPF1, 4UPF2, 4UPF3, 4UPF4, 4UPF5, 4UPF6, 4UPF7, 4UPF8, 4UPF9, 4UPG1, 4UPG2, 4UPG3, 4UPG4, 4UPG5, 4UPG6, 4UPG7, 4UPG8, 4UPG9, 4UPH1, 4UPH2, 4UPH3, 4UPH4, 4UPH5, 4UPH6, 4UPH7, 4UPH8, 4UPH9, 4UPJ1, 4UPJ2, 4UPJ3, 4UPJ4, 4UPJ5, 4UPJ6, 4UPJ7, 4UPJ8, 4UPJ9, 4UPK1, 4UPK2, 4UPK3, 4UPK4, 4UPK5, 4UPK6, 4UPK7, 4UPK8, 4UPK9, 4UPL1, 4UPL2, 4UPL3, 4UPL4, 4UPL5, 4UPL6, 4UPL7, 4UPL8, 4UPL9, 4UPN1, 4UPN2, 4UPN3, 4UPN4, 4UPN5, 4UPN6, 4UPN7, 4UPN8, 4UPN9, 4UPP1, 4UPP2, 4UPP3, 4UPP4, 4UPP5, 4UPP6, 4UPP7, 4UPP8, 4UPP9, 4UPR1, 4UPR2, 4UPR3, 4UPR4, 4UPR5, 4UPR6, 4UPR7, 4UPR8, 4UPR9, 4UPT1, 4UPT2, 4UPT3, 4UPT4, 4UPT5, 4UPT6, 4UPT7, 4UPT8, 4UPT9, 4UPU1, 4UPU2, 4UPU3, 4UPU4, 4UPU5, 4UPU6, 4UPU7, 4UPU8, 4UPU9, 4UPV1, 4UPV2, 4UPV3, 4UPV4, 4UPV5, 4UPV6, 4UPV7, 4UPV8, 4UPV9, 4UPW1, 4UPW2, 4UPW3, 4UPW4, 4UPW5, 4UPW6, 4UPW7, 4UPW8, 4UPW9, 4UPX1, 4UPX2, 4UPX3, 4UPX4, 4UPX5, 4UPX6, 4UPX7, 4UPX8, 4UPX9, 4UPY1, 4UPY2, 4UPY3, 4UPY4, 4UPY5, 4UPY6, 4UPY7, 4UPY8, 4UPY9, 4UPZ1, 4UPZ2, 4UPZ3, 4UPZ4, 4UPZ5, 4UPZ6, 4UPZ7, 4UPZ8, 4UPZ9, 4URA1, 4URA2, 4URA3, 4URA4, 4URA5, 4URA6, 4URA7, 4URA8, 4URA9, 4URC1, 4URC2, 4URC3, 4URC4, 4URC5, 4URC6, 4URC7, 4URC8, 4URC9, 4URD1, 4URD2, 4URD3, 4URD4, 4URD5, 4URD6, 4URD7, 4URD8, 4URD9, 4URE1, 4URE2, 4URE3, 4URE4, 4URE5, 4URE6, 4URE7, 4URE8, 4URE9, 4URF1, 4URF2, 4URF3, 4URF4, 4URF5, 4URF6, 4URF7, 4URF8, 4URF9, 4URG1, 4URG2, 4URG3, 4URG4, 4URG5, 4URG6, 4URG7, 4URG8, 4URG9, 4URH1, 4URH2, 4URH3, 4URH4, 4URH5, 4URH6, 4URH7, 4URH8, 4URH9, 4URJ1, 4URJ2, 4URJ3, 4URJ4, 4URJ5, 4URJ6, 4URJ7, 4URJ8, 4URJ9, 4URK1, 4URK2, 4URK3, 4URK4, 4URK5, 4URK6, 4URK7, 4URK8, 4URK9, 4URL1, 4URL2, 4URL3, 4URL4, 4URL5, 4URL6, 4URL7, 4URL8, 4URL9, 4URN1, 4URN2, 4URN3, 4URN4, 4URN5, 4URN6, 4URN7, 4URN8, 4URN9, 4URP1, 4URP2, 4URP3, 4URP4, 4URP5, 4URP6, 4URP7, 4URP8, 4URP9, 4URR1, 4URR2, 4URR3, 4URR4, 4URR5, 4URR6, 4URR7, 4URR8, 4URR9, 4URT1, 4URT2, 4URT3, 4URT4, 4URT5, 4URT6, 4URT7, 4URT8, 4URT9, 4URU1, 4URU2, 4URU3, 4URU4, 4URU5, 4URU6, 4URU7, 4URU8, 4URU9, 4URV1, 4URV2, 4URV3, 4URV4, 4URV5, 4URV6, 4URV7, 4URV8, 4URV9, 4URW1, 4URW2, 4URW3, 4URW4, 4URW5, 4URW6, 4URW7, 4URW8, 4URW9, 4URX1, 4URX2, 4URX3, 4URX4, 4URX5, 4URX6, 4URX7, 4URX8, 4URX9, 4URY1, 4URY2, 4URY3, 4URY4, 4URY5, 4URY6, 4URY7, 4URY8, 4URY9, 4URZ1, 4URZ2, 4URZ3, 4URZ4, 4URZ5, 4URZ6, 4URZ7, 4URZ8, 4URZ9, 4UTA1, 4UTA2, 4UTA3, 4UTA4, 4UTA5, 4UTA6, 4UTA7, 4UTA8, 4UTA9, 4UTC1, 4UTC2, 4UTC3, 4UTC4, 4UTC5, 4UTC6, 4UTC7, 4UTC8, 4UTC9, 4UTD1, 4UTD2, 4UTD3, 4UTD4, 4UTD5, 4UTD6, 4UTD7, 4UTD8, 4UTD9, 4UTE1, 4UTE2, 4UTE3, 4UTE4, 4UTE5, 4UTE6, 4UTE7, 4UTE8, 4UTE9, 4UTF1, 4UTF2, 4UTF3, 4UTF4, 4UTF5, 4UTF6, 4UTF7, 4UTF8, 4UTF9, 4UTG1, 4UTG2, 4UTG3, 4UTG4, 4UTG5, 4UTG6, 4UTG7, 4UTG8, 4UTG9, 4UTH1, 4UTH2, 4UTH3, 4UTH4, 4UTH5, 4UTH6, 4UTH7, 4UTH8, 4UTH9, 4UTJ1, 4UTJ2, 4UTJ3, 4UTJ4, 4UTJ5, 4UTJ6, 4UTJ7, 4UTJ8, 4UTJ9, 4UTK1, 4UTK2, 4UTK3, 4UTK4, 4UTK5, 4UTK6, 4UTK7, 4UTK8, 4UTK9, 4UTL1, 4UTL2, 4UTL3, 4UTL4, 4UTL5, 4UTL6, 4UTL7, 4UTL8, 4UTL9, 4UTN1, 4UTN2, 4UTN3, 4UTN4, 4UTN5, 4UTN6, 4UTN7, 4UTN8, 4UTN9, 4UTP1, 4UTP2, 4UTP3, 4UTP4, 4UTP5, 4UTP6, 4UTP7, 4UTP8, 4UTP9, 4UTR1, 4UTR2, 4UTR3, 4UTR4, 4UTR5, 4UTR6, 4UTR7, 4UTR8, 4UTR9, 4UTT1, 4UTT2, 4UTT3, 4UTT4, 4UTT5, 4UTT6, 4UTT7, 4UTT8, 4UTT9, 4UTU1, 4UTU2, 4UTU3, 4UTU4, 4UTU5, 4UTU6, 4UTU7, 4UTU8, 4UTU9, 4UTV1, 4UTV2, 4UTV3, 4UTV4, 4UTV5, 4UTV6, 4UTV7, 4UTV8, 4UTV9, 4UTW1, 4UTW2, 4UTW3, 4UTW4, 4UTW5, 4UTW6, 4UTW7, 4UTW8, 4UTW9, 4UTX1, 4UTX2, 4UTX3, 4UTX4, 4UTX5, 4UTX6, 4UTX7, 4UTX8, 4UTX9, 4UTY1, 4UTY2, 4UTY3, 4UTY4, 4UTY5, 4UTY6, 4UTY7, 4UTY8, 4UTY9, 4UTZ1, 4UTZ2, 4UTZ3, 4UTZ4, 4UTZ5, 4UTZ6, 4UTZ7, 4UTZ8, 4UTZ9, 4UUA1, 4UUA2, 4UUA3, 4UUA4, 4UUA5, 4UUA6, 4UUA7, 4UUA8, 4UUA9, 4UUC1, 4UUC2, 4UUC3, 4UUC4, 4UUC5, 4UUC6, 4UUC7, 4UUC8, 4UUC9, 4UUD1, 4UUD2, 4UUD3, 4UUD4, 4UUD5, 4UUD6, 4UUD7, 4UUD8, 4UUD9, 4UUE1, 4UUE2, 4UUE3, 4UUE4, 4UUE5, 4UUE6, 4UUE7, 4UUE8, 4UUE9, 4UUF1, 4UUF2, 4UUF3, 4UUF4, 4UUF5, 4UUF6, 4UUF7, 4UUF8, 4UUF9, 4UUG1, 4UUG2, 4UUG3, 4UUG4, 4UUG5, 4UUG6, 4UUG7, 4UUG8, 4UUG9, 4UUH1, 4UUH2, 4UUH3, 4UUH4, 4UUH5, 4UUH6, 4UUH7, 4UUH8, 4UUH9, 4UUJ1, 4UUJ2, 4UUJ3, 4UUJ4, 4UUJ5, 4UUJ6, 4UUJ7, 4UUJ8, 4UUJ9, 4UUK1, 4UUK2, 4UUK3, 4UUK4, 4UUK5, 4UUK6, 4UUK7, 4UUK8, 4UUK9, 4UUL1, 4UUL2, 4UUL3, 4UUL4, 4UUL5, 4UUL6, 4UUL7, 4UUL8, 4UUL9, 4UUN1, 4UUN2, 4UUN3, 4UUN4, 4UUN5, 4UUN6, 4UUN7, 4UUN8, 4UUN9, 4UUP1, 4UUP2, 4UUP3, 4UUP4, 4UUP5, 4UUP6, 4UUP7, 4UUP8, 4UUP9, 4UUR1, 4UUR2, 4UUR3, 4UUR4, 4UUR5, 4UUR6, 4UUR7, 4UUR8, 4UUR9, 4UUT1, 4UUT2, 4UUT3, 4UUT4, 4UUT5, 4UUT6, 4UUT7, 4UUT8, 4UUT9, 4UUU1, 4UUU2, 4UUU3, 4UUU4, 4UUU5, 4UUU6, 4UUU7, 4UUU8, 4UUU9, 4UUV1, 4UUV2, 4UUV3, 4UUV4, 4UUV5, 4UUV6, 4UUV7, 4UUV8, 4UUV9, 4UUW1, 4UUW2, 4UUW3, 4UUW4, 4UUW5, 4UUW6, 4UUW7, 4UUW8, 4UUW9, 4UUX1, 4UUX2, 4UUX3, 4UUX4, 4UUX5, 4UUX6, 4UUX7, 4UUX8, 4UUX9, 4UUY1, 4UUY2, 4UUY3, 4UUY4, 4UUY5, 4UUY6, 4UUY7, 4UUY8, 4UUY9, 4UUZ1, 4UUZ2, 4UUZ3, 4UUZ4, 4UUZ5, 4UUZ6, 4UUZ7, 4UUZ8, 4UUZ9, 4UVA1, 4UVA2, 4UVA3, 4UVA4, 4UVA5, 4UVA6, 4UVA7, 4UVA8, 4UVA9, 4UVC1, 4UVC2, 4UVC3, 4UVC4, 4UVC5, 4UVC6, 4UVC7, 4UVC8, 4UVC9, 4UVD1, 4UVD2, 4UVD3, 4UVD4, 4UVD5, 4UVD6, 4UVD7, 4UVD8, 4UVD9, 4UVE1, 4UVE2, 4UVE3, 4UVE4, 4UVE5, 4UVE6, 4UVE7, 4UVE8, 4UVE9, 4UVF1, 4UVF2, 4UVF3, 4UVF4, 4UVF5, 4UVF6, 4UVF7, 4UVF8, 4UVF9, 4UVG1, 4UVG2, 4UVG3, 4UVG4, 4UVG5, 4UVG6, 4UVG7, 4UVG8, 4UVG9, 4UVH1, 4UVH2, 4UVH3, 4UVH4, 4UVH5, 4UVH6, 4UVH7, 4UVH8, 4UVH9, 4UVJ1, 4UVJ2, 4UVJ3, 4UVJ4, 4UVJ5, 4UVJ6, 4UVJ7, 4UVJ8, 4UVJ9, 4UVK1, 4UVK2, 4UVK3, 4UVK4, 4UVK5, 4UVK6, 4UVK7, 4UVK8, 4UVK9, 4UVL1, 4UVL2, 4UVL3, 4UVL4, 4UVL5, 4UVL6, 4UVL7, 4UVL8, 4UVL9, 4UVN1, 4UVN2, 4UVN3, 4UVN4, 4UVN5, 4UVN6, 4UVN7, 4UVN8, 4UVN9, 4UVP1, 4UVP2, 4UVP3, 4UVP4, 4UVP5, 4UVP6, 4UVP7, 4UVP8, 4UVP9, 4UVR1, 4UVR2, 4UVR3, 4UVR4, 4UVR5, 4UVR6, 4UVR7, 4UVR8, 4UVR9, 4UVT1, 4UVT2, 4UVT3, 4UVT4, 4UVT5, 4UVT6, 4UVT7, 4UVT8, 4UVT9, 4UVU1, 4UVU2, 4UVU3, 4UVU4, 4UVU5, 4UVU6, 4UVU7, 4UVU8, 4UVU9, 4UVX1, 4UVX2, 4UVX3, 4UVX4, 4UVX5, 4UVX6, 4UVX7, 4UVX8, 4UVX9, 4UVY1, 4UVY2, 4UVY3, 4UVY4, 4UVY5, 4UVY6, 4UVY7, 4UVY8, 4UVY9, 4UVZ1, 4UVZ2, 4UVZ3, 4UVZ4, 4UVZ5, 4UVZ6, 4UVZ7, 4UVZ8, 4UVZ9, 4UWA1, 4UWA2, 4UWA3, 4UWA4, 4UWA5, 4UWA6, 4UWA7, 4UWA8, 4UWA9, 4UWC1, 4UWC2, 4UWC3, 4UWC4, 4UWC5, 4UWC6, 4UWC7, 4UWC8, 4UWC9, 4UWD1, 4UWD2, 4UWD3, 4UWD4, 4UWD5, 4UWD6, 4UWD7, 4UWD8, 4UWD9, 4UWE1, 4UWE2, 4UWE3, 4UWE4, 4UWE5, 4UWE6, 4UWE7, 4UWE8, 4UWE9, 4UWF1, 4UWF2, 4UWF3, 4UWF4, 4UWF5, 4UWF6, 4UWF7, 4UWF8, 4UWF9, 4UWG1, 4UWG2, 4UWG3, 4UWG4, 4UWG5, 4UWG6, 4UWG7, 4UWG8, 4UWG9, 4UWH1, 4UWH2, 4UWH3, 4UWH4, 4UWH5, 4UWH6, 4UWH7, 4UWH8, 4UWH9, 4UWJ1, 4UWJ2, 4UWJ3, 4UWJ4, 4UWJ5, 4UWJ6, 4UWJ7, 4UWJ8, 4UWJ9, 4UWK1, 4UWK2, 4UWK3, 4UWK4, 4UWK5, 4UWK6, 4UWK7, 4UWK8, 4UWK9, 4UWL1, 4UWL2, 4UWL3, 4UWL4, 4UWL5, 4UWL6, 4UWL7, 4UWL8, 4UWL9, 4UWN1, 4UWN2, 4UWN3, 4UWN4, 4UWN5, 4UWN6, 4UWN7, 4UWN8, 4UWN9, 4UWP1, 4UWP2, 4UWP3, 4UWP4, 4UWP5, 4UWP6, 4UWP7, 4UWP8, 4UWP9, 4UWR1, 4UWR2, 4UWR3, 4UWR4, 4UWR5, 4UWR6, 4UWR7, 4UWR8, 4UWR9, 4UWT1, 4UWT2, 4UWT3, 4UWT4, 4UWT5, 4UWT6, 4UWT7, 4UWT8, 4UWT9, 4UWU1, 4UWU2, 4UWU3, 4UWU4, 4UWU5, 4UWU6, 4UWU7, 4UWU8, 4UWU9, 4UWX1, 4UWX2, 4UWX3, 4UWX4, 4UWX5, 4UWX6, 4UWX7, 4UWX8, 4UWX9, 4UWY1, 4UWY2, 4UWY3, 4UWY4, 4UWY5, 4UWY6, 4UWY7, 4UWY8, 4UWY9, 4UWZ1, 4UWZ2, 4UWZ3, 4UWZ4, 4UWZ5, 4UWZ6, 4UWZ7, 4UWZ8, 4UWZ9, 4UXA1, 4UXA2, 4UXA3, 4UXA4, 4UXA5, 4UXA6, 4UXA7, 4UXA8, 4UXA9, 4UXC1, 4UXC2, 4UXC3, 4UXC4, 4UXC5, 4UXC6, 4UXC7, 4UXC8, 4UXC9, 4UXD1, 4UXD2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SANDVIK COROMANT
ORDERING CODE: LIT-MSDS 1
REVEIWED: 05/26/09
SUPERSEDES: 11/22/06
MATERIAL SAFETY DATA SHEET
| SECTION 1 COMPANY AND PRODUCT INFORMATION |  |
COMPANY NAME:
SANDVIK COROMANT COMPANY
1702 NEVINS ROAD
FAIR LAWN, NJ 07410
PRODUCT NAME:
ALL SANDVIK COROMANT CEMENTED TUNGSTEN CARBIDE AND CERMET GRADES
PRODUCT DESCRIPTIONS:
CEMENTED TUNGSTEN CARBIDE PRODUCT WITH COBALT OR COBALT/NICKEL BINDER
UNCOATED OR COATED WITH ANY OF THE FOLLOWING:
ALUMINUM CHROMIUM (Al, Cr), ALUMINUM NITRIDE (AIN), ALUMINUM OXIDE (Al2O3),
ALUMINUM TITANIUM NITRIDE (AlTiN), BORON CARBIDE (B4C), CHROMIUM CARBIDE
(CrC), CHROMIUM NITRIDE (CrN), DIAMOND FILM, MOLYBDENUM CARBIDE (MO2c),
MOLYBDENUM DISULFIDE (MoS2), NIOBIUM CARBIDE (NbC), TANTALUM CARBIDE (TaC),
TITANIUM ALUMINUM NITRIDE (TiALN), TITANIUM BORIDE CARBONITRIDE (TiBCN),
TITANIUM CARBIDE (TiC), TITANIUM CARBO NITRIDE (TiCN), TITANIUM DIBORIDE
(TiB2), TITANIUM NITRIDE (TiN), TITANIUM ZIRCONIUM NITRIDE (TiZrN),
TUNGSTEN CARBIDE/CARBON (WC/W), VANADIUM CARBIDE (Vc), ZIRCONIUM NITRIDE
(ZrN).
DATE PREPARED: 11-22-06
EMERGENCY TELEPHONE: 201-794-5000
NON-EMERGENCY TELEPHONE: 201-794-5000
NON-EMERGENCY FAX: 201-794-5165
NFPA HAZARD RATING:
HEALTH 1
FLAMMABILITY 0
REACTIVITY 0
| SECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS | |
TUNGSTEN CARBIDES / CERMETS:
CHEMICAL NAME CAS # WEIGHT* OSHA ACGIH
PEL-TWA TLV-TWA
ALUMINUM OXIDE 1344-28-1 0 - 2 15 MG/M3 10 MG/M3
TOTAL DUST
5 MG/M3
RESP. FRACTION
BORON 1303-86-2 0 - 2 15 MG/M3 10 MG/M3
(LIMIT AS B2O2) TOTAL DUST
CHROMIUM 7440-47-3 0 - 3 0.5 MG/M3 0.5 MG/M3
CHROMIUM CARBIDE 12012-35-0 0 - 3 0.5 MG/M3 0.5 MG/M3
(LIMIT FOR CHROMIUM
III COMPOUNDS)
COBALT 7440-48-4 0 - 20 0.1 MG/M3 0.02 MG/M3
MOLYBDENUM 7439-98-7 0 - 2 15 MG/M3 10 MG/M3
DISULFIDE (LIMIT TOTAL DUST INH. FRACTION
FOR Mo INSOLUABLE 3 MG/M3
COMPOUNDS) RESP. FRACTION
NICKEL 7440-02-0 0 - 15 1 MG/M3 1.5 MG/M3
NIOBIUM CARBIDE 12011-99-3 0 - 5 NOT NOT
ESTABLISHED ESTABLISHED
TANTALUM CARBIDE 12070-06-3 0 - 15 5 MG/M3 5 MG/M3
(LIMIT AS
TANTULUM DUST)
TITANIUM CARBIDE 12070-08-5 0.2 - 53 15 MG/M3 10 MG/M3
(LIMIT AS TiO2) TOTAL DUST
TUNGSTEN CARBIDE 12070-12-1 10 - 94 NOT 5 MG/M3
(LIMIT AS W) ESTABLISHED
ZIRCONIUM 7440-67-7 0 - 2 5 MG/M3 5 MG/M3
* EXACT PERCENTAGES DEPEND ON GRADE SPECIFICATIONS
DURING NORMAL OPERATION AND USAGE, CEMENTED CARBIDE PRODUCTS DO NOT
PRESENT INHALATION, INGESTION, OR OTHER CHEMICAL HAZARDS. HOWEVER,
OPERATIONS SUCH AS GRINDING, CUTTING, BURNING, AND WELDING OF SUCH PRODUCTS
MAY RELEASE DUSTS, FUMES, OR VAPORS WHICH MAY PRESENT HEALTH HAZARDS, IF
THE EXPOSURE LIMITS DESCRIBED IN SECTION 2 ARE EXCEEDED. THE HEALTH HAZARDS
DESCRIBED BELOW RELATE TO THESE NON-ROUTINE OPERATIONS, AS WELL AS EXPOSURE
TO COMPONENT MATERIALS.
| SECTION 3 HAZARDS IDENTIFICATION | |
WET OR DRY GRINDING OF CEMENTED CARBIDE PRODUCTS WILL PRODUCE DUSTS OF
POTENTIALLY HAZARDOUS INGREDIENTS WHICH CAN BE INHALED, SWALLOWED, OR
COME IN CONTACT WITH THE SKIN OR EYES. DURING WET GRINDING, THE DUST CAN
BE SUSPENDED OR DISSOLVED IN THE COOLANT MIST.
PRIMARY ROUTES OF ENTRY: INHALATION, INGESTION, SKIN CONTACT
ACUTE HEALTH EFFECTS:
DUST FROM GRINDING CAN CAUSE IRRITATION OF THE NOSE, THROAT, LUNGS, EYES,
AND MUCOUS MEMBRANES. SKIN EXPOSURE CAN CAUSE AN ALLERGIC RED RASH
(COBALT ITCH).
CHRONIC HEALTH EFFECTS:
CHRONIC EXPOSURE TO RESPIRABLE DUST CONTAINING COBALT AND TUNGSTEN CARRY
THE POTENTIAL TO CAUSE PERMANENT RESPIRATORY DISEASES, INCLUDING
OCCUPATIONAL ASTHMA, INTERSTITIAL PNEUMONITIS AND FIBROSIS (HARD-METAL
DISEASE), AND EMPHYSEMA. SYMPTOMS INCLUDE PRODUCTIVE COUGH, WHEEZING,
DYSPNEA (UPON EXERTION), PLEURITIC CHEST PAIN, AND WEIGHT LOSS. SKIN
SENSITIZATION IS ALSO NOTED IN A SMALL PERCENTAGE OF CASES. REPORTS OUTSIDE
THE INDUSTRY SUGGEST THAT INGESTION OF SIGNIFICANT AMOUNTS OF COBALT CAN
CAUSE BLOOD, HEART, AND OTHER ORGAN EFFECTS.
CARCINOGENICITY (OSHA, NTP, IARC, ACGIH):
COBALT METAL WITH TUNGSTEN CARBIDE IS LISTED BY IARC AS GROUP 2A - PROBABLY
CARCINOGENIC TO HUMANS. NICKEL IS LISTED BY IARC AS CATEGORY 2B - POSSIBLY
CARCINOGENIC TO HUMANS. COBALT IS LISTED BY ACGIH AS AN ANIMAL CARCINOGEN
(A3). COBALT AND NICKEL ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER. NICKEL IS CONSIDERED REASONABLY ANTICIPATED TO BE A CARCINOGENIC
BY NTP.
| SECTION 4 FIRST AID MEASURES | |
INHALATION:
IF SYMPTOMS OF PULMONARY INVOLVEMENT DEVELOP (COUGHING, WHEEZING, DYSPNEA,
ETC.), REMOVE TO FRESH AIR. IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
SKIN CONTACT:
IF IRRITATION OR RASH OCCURS, THOROUGHLY WASH AFFECTED AREA WITH SOAP AND
WATER. IF IRRITATION OR RASH PERSISTS, SEEK MEDICAL ATTENTION.
EYE CONTACT:
REMOVE CONTACT LENSES AT ONCE. FLUSH EYES WITH WATER FOR AT LEAST FIFTEEN
MINUTES. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION.
INGESTION:
IF SUBSTANTIAL QUANTITIES ARE SWALLOWED, DILUTE WITH LARGE AMOUNT OF WATER.
INDUCE VOMITING AND SEEK MEDICAL ATTENTION.
| SECTION 5 FIRE FIGHTING MEASURES | |
FLASH POINT: NOT APPLICABLE
LOWER EXPLOSIVE LIMIT: NOT APPLICABLE
UPPER EXPLOSIVE LIMIT: NOT APPLICABLE
CEMENTED CARBIDE PRODUCTS ARE NOT A FIRE HAZARD UNDER NORMAL CONDITIONS
OF USE. HOWEVER, DUSTS GENERATED IN GRINDING MAY BE SENSITIVE TO STATIC
DISCHARGE OR IGNITE IF ALLOWED TO ACCUMULATE AND THEN ARE EXPOSED TO AN
IGNITION SOURCE.
EXTINGUISHING MEDIA:
FOR DUST FIRES, SMOTHER WITH DRY SAND, DRY DOLOMITE, ABC TYPE FIRE
EXTINGUISHER, OR FLOOD WITH WATER.
SPECIAL FIRE FIGHTING PROCEDURES:
FOR A DUST FIRE CONFINED TO A SMALL AREA, USE A RESPIRATOR APPROVED FOR
TOXIC DUSTS AND FUMES. FOR A LARGE FIRE INVOLVING THIS MATERIAL, FIRE
FIGHTERS SHOULD USE A SELF-CONTAINED BREATHING APPARATUS. SEE SECTION 3
AND 8 FOR SPECIFIC HAZARD IDENTIFICATION AND EXPOSURE CONTROL MEASURES.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
DUSTS MAY PRESENT A FIRE OR EXPLOSION HAZARD UNDER RARE FAVORING CONDITIONS
OF PARTICLE SIZE, DISPERSION, CONCENTRATION, AND STRONG IGNITION SOURCE.
HOWEVER, THIS IS NOT EXPECTED TO BE A PROBLEM UNDER NORMAL HANDLING
CONDITIONS.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF ALUMINUM, COBALT, TITANIUM, AND TUNGSTEN; CARBON DIOXIDE, AND
CARBON MONOXIDE. SEE SECTION 3 FOR SPECIFIC HAZARD IDENTIFICATION.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
CLEAN UP AREA USING METHODS THAT AVOID DUST GENERATION SUCH AS A HIGH
EFFICIENCY PARTICULATE AIR (HEPA) VACUUM, WET DUST MOP, OR WET CLEAN-UP.
USE AN APPROPRIATE NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
(NIOSH)-APPROVED RESPIRATOR WHENEVER AIRBORNE CONCENTRATIONS OF HAZARDOUS
COMPONENTS EXCEED EXPOSURE LIMITS LISTED IN SECTION 2.
| SECTION 7 HANDLING AND STORAGE | |
UNDER NORMAL OPERATING CONDITIONS, THE USE OF CEMENTED CARBIDE PRODUCTS
DOES NOT REQUIRE SPECIAL SAFETY PRECAUTIONS BEYOND NORMAL SAFETY PROCEDURES
FOR HANDLING AND USING CUTTING TOOLS, SUCH AS SAFETY GLASSES AND GLOVES.
HOWEVER, OPERATIONS SUCH AS GRINDING, CUTTING, BURNING, AND WELDING OF
CEMENTED CARBIDE PRODUCTS MAY GENERATE DUSTS OR FUMES WHICH MAY REQUIRE
SPECIAL HANDLING PROCEDURES. THE PROCEDURES DESCRIBED BELOW RELATE TO THESE
NON-ROUTINE OPERATIONS.
HYGIENIC PRACTICES:
WASH HANDS THOROUGHLY AFTER HANDLING, AND BEFORE EATING OR SMOKING. WASH
EXPOSED SKIN AT THE END OF THE WORK SHIFT. SMOKING AND CONSUMPTION OF FOOD
OR BEVERAGES SHOULD BE RESTRICTED FROM AREAS WHERE HAZARDOUS COMPONENTS MAY
BE PRESENT. DO NOT SHAKE CLOTHING, RAGS, OR OTHER ITEMS TO REMOVE DUST.
DUST SHOULD BE REMOVED BY LAUNDERING OR VACUUMING (WITH APPROPRIATE
FILTERS) THE CLOTHING, RAGS, OR OTHER ITEMS.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
MAINTAIN GOOD HOUSEKEEPING PROCEDURES TO PREVENT DUST ACCUMULATION DURING
GRINDING. AVOID DUST INHALATION AND DIRECT SKIN CONTACT WITH DUST. SEE
SECTION 3 FOR SPECIFIC HEALTH HAZARDS.
OTHER PRECAUTIONS:
CLEAN UP USING METHODS THAT AVOID DUST GENERATION SUCH AS A HEPA VACUUM,
WET DUST MOP, OR WET CLEAN-UP. USE A NIOSH-APPROVED RESPIRATOR WHENEVER
AIRBORNE CONCENTRATIONS OF HAZARDOUS COMPONENTS EXCEED EXPOSURE LIMITS
LISTED IN SECTION 2. SEE SECTION 3 FOR SPECIFIC HEALTH HAZARDS.
NOTE:
PERIODIC MEDICAL MONITORING IS RECOMMENDED FOR INDIVIDUALS REGULARLY
EXPOSED TO DUST OR FUMES, WITH PARTICULAR ATTENTION TO ANY POTENTIAL
SENSITIZATION EFFECTS OF SUCH SUBSTANCES.
| SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION | |
PERSONAL PROTECTION:
ALWAYS WEAR SAFETY GLASSES WITH SIDE SHIELDS WHEN GRINDING OR CUTTING
CEMENTED CARBIDE PRODUCTS. USE A NIOSH-APPROVED RESPIRATOR, WITH THE PROPER
ASSIGNED PROTECTION FACTOR, WHENEVER AIRBORNE CONCENTRATIONS OF HAZARDOUS
COMPONENTS EXCEED EXPOSURE LIMITS LISTED IN SECTION 2. PROTECTIVE GLOVES OR
BARRIER CREAM, AND CLOTHING TO PREVENT SKIN CONTACT WITH DUSTS ARE
RECOMMENDED. SEE SECTION 3 FOR SPECIFIC HEALTH HAZARDS.
VENTILATION:
USE ADEQUATE LOCAL (PREFERABLY) OR GENERAL EXHAUST VENTILATION TO ENSURE
THAT CONCENTRATIONS OF DUSTS OR FUMES DO NOT EXCEED EXPOSURE LIMITS.
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE AND ODOR: DARK GRAY SOLID, ODORLESS
SPECIFIC GRAVITY (H2O=1): NOT APPLICABLE
BOILING POINT: NOT APPLICABLE
PERCENT VOLATILE BY VOLUME: NOT APPLICABLE
VAPOR PRESSURE (MMHg): NOT APPLICABLE
EVAPORATION RATE: NOT APPLICABLE
VAPOR DENSITY (AIR=1): NOT APPLICABLE
SOLUBILITY IN WATER: INSOLUBLE
| SECTION 10 STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS DECOMPOSITION PRODUCTS: NONE
CONDITIONS TO AVOID: NONE KNOWN
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
INCOMPATIBILITY:
STRONG ACIDS. CONTACT OF DUST WITH STRONG OXIDIZERS MAY CAUSE FIRE OR
EXPLOSIONS.
| SECTION 11 TOXICOLOGICAL INFORMATION | |
COBALT:
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) LISTS COBALT METAL
WITH TUNGSTEN CARBIDE AS A GROUP 2A CARCINOGEN (PROBABLY CARCINOGENIC TO
HUMANS). COBALT FUMES OR DUST MAY CAUSE PULMONARY, SKIN, OR EYE IRRITATION.
COBALT MAY BE A SENSITIZING AGENT FOR SKIN AND RESPIRATORY SYSTEM. CHRONIC
EXPOSURE MAY AFFECT THE HEART, PANCREAS, THYROID GLAND, OR BONE MARROW.
RAT ORAL LDLO: 1500 MG/KG
RABBIT ORAL LDLO: 20 MG/KG
RAT INTRAPERITONEAL LDLO: 250 MG/KG
RABBIT INTRATRACHEAL LDLO: 100 MG/KG
RAT INTRAVENOUS LDLO: 100 MG/KG
NICKEL:
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) LISTS METALLIC
NICKEL AND NICKEL COMPOUNDS AS A GROUP 2B CARCINOGEN (POSSIBLY CARCINOGENIC
TO HUMANS). EPIDEMIOLOGICAL STUDIES INDICATE INCREASED INCIDENCE OF CANCER
OF THE NASAL CAVITY, LUNGS, AND POSSIBLY THE LARYNX IN NICKEL REFINERY
WORKERS. NICKEL IS AN EYE, SKIN, AND MUCOUS MEMBRANE IRRITANT AND A
PULMONARY AND SKIN SENSITIZER.
RAT ORAL LDLO: 5 MG/KG
DOG INTRAVENOUS LDLO: 10 MG/KG
GUINEA PIG SUBCUTANEOUS LDLO: 500 MG/KG
RAT INTRATRACHEAL LDLO: 12 MG/KG
MOUSE INTRAVENOUS LDLO: 50 MG/KG
TUNGSTEN CARBIDE, TITANIUM CARBIDE, NIOBIUM CARBIDE, VANADIUM CARBIDE:
TOXICITY HAS NOT BEEN QUANTIFIED. MAY CAUSE PULMONARY AND SKIN
SENSITIZATION AND MUCOUS MEMBRANE IRRITATION IN DUST FORM.
THERE IS INADEQUATE EVIDENCE FOR THE CARCINOGENICITY OF CHROMIUM
(7440-47-3) AND MOST TRIVALENT CHROMIUM COMPOUNDS IN EXPERIMENTAL ANIMALS.
| SECTION 12 ECOLOGICAL INFORMATION | |
AQUATIC TOXICITY:
COBALT:
ALGEA (SELENASTRUM CAPRICONUTUM):
EC10 72H: 0,006 MG/L
EC50 72H: 0,035 MG/L
NOEC 72H: 0,0053 MG/L
COBALT:
DAPHNIA (MAGNA):
EC50 48H: >100 MG/L
FISH (BRACHYDANIO RERIO):
NOEC 96H: >100 MG/L
BACTERIA (ACTIVATED SLUDGE):
EC50: 42 MG/L
TUNGSTEN CARBIDE:
ALGEA (SCENEDESMUS SUBSPICATUS):
EC50 72H: 130 MG/L (GROW RATE)
DAPHNIA (MAGNA):
EC50 48H: >1000 MG/L
FISH (BRACHYDANIO RERIO):
LC0 96H: >1000 MG/L
LC50 96H: >1000 MG/L
BACTERIA (ACTIVATED SLUDGE):
EC20 3H: >1000 MG/L
EC50 3H: >1000 MG/L
| SECTION 13 DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
DISPOSE OF IN ACCORDANCE WITH APPROPRIATE GOVERNMENT REGULATIONS. MAY BE
SOLD AS SCRAP FOR RECLAMATION.
| SECTION 14 TRANSPORTATION INFORMATION | |
DOT PROPER SHIPPING NAME: NOT REGULATED BY THIS MODE OF TRANSPORTATION
IMO PROPER SHIPPING NAME: NOT REGULATED BY THIS MODE OF TRANSPORTATION
IATA PROPER SHIPPING NAME: NOT REGULATED BY THIS MODE OF TRANSPORTATION
AFI PROP. SHIPPING NAME: NOT REGULATED BY THIS MODE OF TRANSPORTATION
| SECTION 15 REGULATORY INFORMATION | |
OSHA:
THIS PRODUCT, UNDER NORMAL CONDITIONS OF USE, IS NOT HAZARDOUS UNDER
THE CRITERIA OF THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD 29 CFR
1910.1200. HOWEVER, DUST GENERATED WHILE GRINDING, CUTTING, BURNING OR
WELDING THIS PRODUCT MAY BE HAZARDOUS AS NOTED IN SECTIONS 2 AND 3.
TSCA: COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY.
SARA:
CHROMIUM AND COBALT ARE SUBJECT TO THE REQUIREMENTS OF SECTION 313 OF
TITLE III OF SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986.
STATE REGULATORY INFORMATION:
THIS PRODUCT MAY CONTAIN COBALT AND/OR NICKEL, WHICH IS LISTED IN
CALIFORNIA PROPOSITION 65 AS A KNOWN CANCER-CAUSING CHEMICAL.
| SECTION 16 OTHER INFORMATION | |
USERS RESPONSIBILITIES:
THIS MATERIAL SAFETY DATA SHEET PROVIDES INFORMATION CONSISTENT WITH
RECOMMENDED APPLICATIONS OF THESE PRODUCTS AND ANTICIPATED NON-ROUTINE
ACTIVITIES INVOLVING THE PRODUCT. IT IS THE USER'S RESPONSIBILITY TO
IDENTIFY AND PROTECT AGAINST HEALTH AND SAFETY HAZARDS PRESENTED BY
MODIFICATION OF CEMENTED CARBIDE PRODUCTS AFTER MANUFACTURE. INDIVIDUALS
HANDLING CEMENTED CARBIDE PRODUCTS SHOULD BE INFORMED OF ALL RELEVANT
HAZARDS AND RECOMMENDED SAFETY PRECAUTIONS, AND SHOULD HAVE ACCESS TO THE
INFORMATION CONTAINED IN THIS MSDS.
DISCLAIMER:
THE INFORMATION CONTAINED HEREIN IS BASED UPON DATA PROVIDED BY
MANUFACTURERS AND SUPPLIERS OF RAW MATERIALS USED IN THE MANUFACTURE OF
CEMENTED CARBIDE PRODUCTS. THE INFORMATION IS OFFERED IN GOOD FAITH AS
ACCURATE AND CORRECT, BUT NO REPRESENTATIONS, GUARANTEES, OR WARRANTIES
OF ANY KIND ARE MADE AS TO ITS ACCURACY OR COMPLETENESS, SUITABILITY FOR
PARTICULAR APPLICATIONS, HAZARDS CONNECTED WITH THE USE OF THE PRODUCT, OR
THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. USER ASSUMES ALL RISK AND
LIABILITY OF ANY USE OR HANDLING OF ANY MATERIAL BEYOND SANDVIK COROMANT'S
CONTROL. VARIATIONS IN METHODS, CONDITIONS, EQUIPMENT USED TO STORE,
HANDLE, OR PROCESS THE MATERIAL, AND HAZARDS CONNECTED WITH THE USE OF
THE PRODUCT ARE SOLELY THE RESPONSIBILITY OF THE USER AND REMAIN AT ITS
SOLE DISCRETION.
WHEN APPLICABLE, THE PRODUCTS DESCRIBED IN THIS MSDS ARE CONSIDERED
TO BE "ARTICLES" WITHIN THE MEANING OF TITLE 29 OF THE CODE OF FEDERAL
REGULATIONS, SECTION 1910.1200 ET SEQ. THIS MSDS IS INTENDED TO BE USED
SOLELY FOR THE PURPOSE OF SATISFYING INFORMATIONAL REQUESTS MADE PURSUANT
TO THAT REQUIREMENT. IT IS NOT INTENDED TO PRE-EMPT, REPLACE, OR EXPAND THE
TERMS CONTAINED IN THE SANDVIK COROMANT CONDITIONS OF SALE. COMPLIANCE WITH
ALL APPLICABLE FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS REMAINS THE
RESPONSIBILITY OF THE USER, AND THE USER HAS THE RESPONSIBILITY TO PROVIDE
A SAFE WORKPLACE, TO EXAMINE ALL ASPECTS OF ITS OPERATION, AND TO DETERMINE
IF OR WHERE PRECAUTIONS, IN ADDITION TO THOSE DESCRIBED HEREIN, ARE
REQUIRED. THIS INFORMATION MAY NOT BE VALID FOR THESE PRODUCTS WHEN
MANUFACTURED WITH ALTERNATE MATERIALS MEETING THE SPECIAL REQUIREMENTS
OF A PARTICULAR USER.
SANDVIK COROMANT MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT
NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A
PARTICULAR PURPOSE.