| Common Name: | AUTORF SSPR 6PK GRAY AUTO FILLER PRIMER, 249279 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 12/15/2008 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4YLA9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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249279 AUTORF SSPR 6PK GRAY AUTO FILLER PRIMER
MATERIAL SAFETY DATA SHEET
24 HOUR ASSISTANCE: 1-847-367-7700
RUST-OLEUM CORP.
WWW.RUSTOLEUM.COM
| SECTION 1 - CHEMICAL PRODUCT / COMPANY INFORMATION |  |
PRODUCT NAME: AUTORF SSPR 6PK GRAY AUTO FILLER PRIMER
IDENTIFICATION NUMBER: 249279
REVISION DATE: 12/15/2008
PRODUCT USE/CLASS: PRIMER/AEROSOLS
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
| SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NUMBER WEIGHT % LESS THAN
LIQUEFIED PETROLEUM GAS 68476-86-8 30.0
MAGNESIUM SILICATE 14807-96-6 15.0
ACETONE 67-64-1 10.0
XYLENE 1330-20-7 10.0
TOLUENE 108-88-3 10.0
TITANIUM DIOXIDE 13463-67-7 10.0
MINERAL SPIRITS 64742-88-7 10.0
ALIPHATIC HYDROCARBON 64742-89-8 10.0
n-BUTYL ACETATE 123-86-4 5.0
AROMATIC PETROLEUM DISTILLATES 64742-94-5 5.0
ETHYLBENZENE 100-41-4 5.0
ZINC PHOSPHATE 7779-90-0 5.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA PEL
TLV-TWA TLV-STEL PEL-TWA CEILING
LIQUEFIED PETROLEUM GAS 1000 PPM N.E. 1000 PPM N.E.
MAGNESIUM SILICATE 10 MG/M3 N.E. 15 MG/M3 N.E.
ACETONE 500 PPM 750 PPM 750 PPM N.E.
XYLENE 100 PPM 150 PPM 100 PPM N.E.
TOLUENE 50 PPM 150 PPM 200 PPM 300 PPM
TITANIUM DIOXIDE 10 MG/M3 N.E. 10 MG/M3 N.E.
MINERAL SPIRITS 100 PPM N.E. 100 PPM N.E.
ALIPHATIC HYDROCARBON 300 PPM N.E. 300 PPM N.E.
n-BUTYL ACETATE 150 PPM 200 PPM 150 PPM N.E.
AROMATIC PETROLEUM DISTILLATES 10 PPM N.E. 10 PPM N.E.
ETHYLBENZENE 100 PPM 125 PPM 100 PPM N.E.
ZINC PHOSPHATE N.E. N.E. N.E. N.E.
| SECTION 3 - HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
CONTAINS AROMATIC DISTILLATE, WHICH MAY CAUSE CANCER. CONTENTS UNDER
PRESSURE. HARMFUL IF INHALED. MAY AFFECT THE BRAIN OR NERVOUS SYSTEM
CAUSING DIZZINESS, HEADACHE OR NAUSEA. HARMFUL IF SWALLOWED. EXTREMELY
FLAMMABLE LIQUID AND VAPOR. VAPORS MAY CAUSE FLASH FIRE OR EXPLOSION.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES EYE IRRITATION.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION. SUBSTANCE MAY
CAUSE SLIGHT SKIN IRRITATION.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND
LUNGS. HARMFUL IF INHALED. HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS
MAY BE HARMFUL IF INHALED. AVOID BREATHING VAPORS OR MISTS.
EFFECTS OF OVEREXPOSURE - INGESTION:
ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND CAUSE DAMAGE.
SUBSTANCE MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
IARC LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B). CONTAINS
TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP 2B-"POSSIBLY
CARCINOGENIC TO HUMANS" BY IARC. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED
DURING BRUSH APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON
DURATION AND LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES
OR SPRAY MIST AND THE ACTUAL CONCENTRATION OF TITANIUM DIOXIDE IN THE
FORMULA.
MAY CAUSE CENTRAL NERVOUS SYSTEM DISORDER (E.G., NARCOSIS INVOLVING A LOSS
OF COORDINATION, WEAKNESS, FATIGUE, MENTAL CONFUSION, AND BLURRED VISION)
AND/OR DAMAGE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH LIVER
ABNORMALITIES, KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS WELL AS
REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC OVEREXPOSURE,
HAVE INCLUDED LIVER, CARDIAC ABNORMALITIES AND NERVOUS SYSTEM DAMAGE.
OVEREXPOSURE TO TOLUENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH
LIVER ABNORMALITIES, KIDNEY, LUNG AND SPLEEN DAMAGE. EFFECTS IN HUMANS HAVE
INCLUDED LIVER AND CARDIAC ABNORMALITIES.
PRIMARY ROUTE(S) OF ENTRY:
SKIN CONTACT, SKIN ABSORPTION, INHALATION, EYE CONTACT
| SECTION 4 - FIRST AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION.
FIRST AID - SKIN CONTACT:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR
PERSISTS.
FIRST AID - INHALATION:
IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ASSISTANCE
IMMEDIATELY.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN
ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT (SETAFLASH): -156 F
LOWER EXPLOSIVE LIMIT: 0.7%
UPPER EXPLOSIVE LIMIT: 32.5%
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
WATER SPRAY MAY BE INEFFECTIVE.
FLASH POINT IS LESS THAN 20 DEG. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR!
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. VAPORS MAY FORM
EXPLOSIVE MIXTURES WITH AIR. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND
FLASH BACK. KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL
EQUIPMENT, SPARKS AND OPEN FLAME. PERFORATION OF THE PRESSURIZED CONTAINER
MAY CAUSE BURSTING OF THE CAN.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE
WITH INERT ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF ACCORDING TO LOCAL,
STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED
CONTAINERS.
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING:
FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED
BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING VAPOR OR MIST.
WASH THOROUGHLY AFTER HANDLING. USE ONLY IN A WELL-VENTILATED AREA.
WASH HANDS BEFORE EATING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. DO NOT STORE ABOVE 120 DEG. F. STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS I
FLAMMABLE LIQUIDS. CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO HEAT OR STORE
ABOVE 120 DEG. F.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR
OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS. USE EXPLOSION-PROOF VENTILATION EQUIPMENT.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE
LIMITS.
PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A
POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL
FOR AN UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING RANGE: -34 - 468 F
VAPOR DENSITY: HEAVIER THAN AIR
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
APPEARANCE: LIQUID
EVAPORATION RATE: FASTER THAN ETHER
SOLUBILITY IN H2O: SLIGHT
FREEZE POINT: N.D.
SPECIFIC GRAVITY: 0.854
VAPOR PRESSURE: N.D.
pH: N.A.
PHYSICAL STATE: LIQUID
(SEE SECTION 16 FOR ABBREVIATION LEGEND)
| SECTION 10 - STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEG. F. AVOID ALL POSSIBLE SOURCES OF
IGNITION.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
PRODUCT LD50: N.D.
PRODUCT LC50: N.D.
CHEMICAL NAME LD50 LC50
LIQUEFIED PETROLEUM GAS N.E. N.E.
MAGNESIUM SILICATE N.E. TCLO:
11 MG/M3 (INHALATION)
ACETONE 5800 MG/KG (RAT) 50100 MG/M3 (RAT, 8 HR)
XYLENE 4300 MG/KG 5000 PPM
(RAT, ORAL) (RAT, INHALATION, 4 HR)
TOLUENE 636 MG/KG 49 G/M3
(ORAL, RAT) (INHALATION, RAT)
TITANIUM DIOXIDE >7500 MG/KG N.E.
(RAT, ORAL)
MINERAL SPIRITS >8 MG/KG >1400 PPM 4 HR
(ORAL, RAT) (INHALATION, RAT)
ALIPHATIC HYDROCARBON >5000 MG/KG N.E.
(RAT, ORAL)
n-BUTYL ACETATE 13100 MG/KG 2000 PPM
(RAT, ORAL) (RAT, INHALATION, 4 HR)
AROMATIC PETROLEUM DISTILLATES 4900 MG/KG N.E.
(RAT, ORAL)
ETHYLBENZENE 3500 MG/KG N.E.
(RAT, ORAL)
ZINC PHOSPHATE N.E. N.E.
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| SECTION 13 - DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER STORM DRAINS OR SEWER SYSTEMS.
| SECTION 14 - TRANSPORTATION INFORMATION | |
DOT PROPER SHIPPING NAME: AEROSOLS
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: 2.1
DOT UN/NA NUMBER: UN1950
PACKING GROUP: N.A.
HAZARD SUBCLASS: N.A.
RESP. GUIDE PAGE: 126
| SECTION 15 - REGULATORY INFORMATION | |
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES"
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD, PRESSURIZED
GAS HAZARD
SARA SECTION 313:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE
SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS NUMBER
XYLENE 1330-20-7
TOLUENE 108-88-3
AROMATIC PETROLEUM DISTILLATES 64742-94-5
ETHYLBENZENE 100-41-4
ZINC PHOSPHATE 7779-90-0
TOXIC SUBSTANCES CONTROL ACT:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT
ARE SUBJECT TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM
THE UNITED STATES:
U.S. STATE REGULATIONS: AS FOLLOWS
NEW JERSEY RIGHT-TO-KNOW:
THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE
COMPONENTS IN THIS PRODUCT.
CHEMICAL NAME CAS NUMBER
ALKYD RESIN PROPRIETARY
PENNSYLVANIA RIGHT-TO-KNOW:
THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT
GREATER THAN 3%.
CHEMICAL NAME CAS NUMBER
ALKYD RESIN PROPRIETARY
CALIFORNIA PROPOSITION 65:
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN BY THE STATE OF CALIFORNIA TO
CAUSE CANCER.
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
CANADIAN WHMIS CLASS:
AB5
D2A
D2B
| SECTION 16 - OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 4
REACTIVITY 0
PERSONAL PROTECTION X
REASON FOR REVISION: REGULATORY UPDATE
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
THE INFORMATION CONTAINED ON THIS MSDS HAS BEEN CHECKED AND SHOULD BE
ACCURATE. HOWEVER, IT IS THE RESPONSIBILITY OF THE USER TO COMPLY WITH
ALL FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS.