| Common Name: | ALKALINE ZINC-MANGANESE DIOXIDE BATTERIES, LR1 |
| Manufacturer: | ZHONGYIN (NINGBO) BATTERY CHINA |
| SDS Revision Date: | (No Date) |
| SDS Format: | No Format Specified |
| Item Number(s): | 5HXH5, 5U076 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PAIRDEER(R*)
MSDS-LR1
MATERIAL SAFETY DATA SHEET
| 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE |  |
COMPANY / UNDERTAKING
PRODUCT NAME: ALKALINE ZINC-MANGANESE DIOXIDE BATTERIES
PRODUCT DESIGNATION: LR1
NOMINAL VOLTAGE: 1.5V
CHEMICAL SYSTEM: ZINC / MANGANESE DIOXIDE
DESIGNED FOR RECHARGE:
YES ( )
NO (X)
COMPANY NAME:
ZHONGYIN NINGBO BATTERY CO., LTD.
128 XINGGUANG ROAD, HI-TECH PARK
NINGBO
CHINA
TEL: +86 574 87491087 / 87493214
FAX: +86 574 87493903
| 2 COMPOSITIONS / INFORMATION ON INGREDIENTS | |
CHEMICAL NATURE: ALKALINE ZINC-MANGANESE DIOXIDE BATTERIES
MATERIALS CAS# APPROXIMATE PERCENT
OF TOTAL WEIGHT (APPROX. %)
MANGANESE DIOXIDE 1313-13-9 34.2
(MnO2)
ZINC (Zn) 7440-66-6 13.5
WATER (H2O) 7732-18-5 9.5
POTASSIUM HYDROXIDE 1310-58-3 4.2
(KOH)
GRAPHITE 7782-42-5 3
BRASS 12597-71-6 2.3
STEEL 7439-89-6 29.5
Ni-PLATING 7440-02-0 0.3
IMPURITY CAS# APPROXIMATE PERCENT
OF TOTAL WEIGHT (APPROX. %)
MERCURY (Hg) 7439-97-6 <0.0001
LEAD (Pb) 7439-92-1 <0.0030
CADMIUM (Cd) 7440-43-9 <0.0003
ARSENIC (As) 7440-38-2 <0.0001
| 3 HAZARDS IDENTIFICATIONS | |
GENERAL ADVICE:
THE COMMON KNOWN RULES FOR HANDLING OF CHEMICALS SHOULD BE OBEYED. THESE
CHEMICALS ARE CONTAINED IN A SEALED STEEL CAN. FOR CONSUMER USE, ADEQUATE
HAZARD WARNINGS ARE PRINTED ON BOTH THE PACKAGE AND THE BATTERY. POTENTIAL
FOR EXPOSURE SHOULD NOT EXIST UNLESS THE BATTERY LEAKS, IS EXPOSED TO HIGH
TEMPERATURES OR IS MECHANICALLY OR ELECTRICALLY ABUSED. CONCENTRATED
POTASSIUM HYDROXIDE CONTAINED IS CAUSTIC. ANTICIPATED POTENTIAL LEAKAGE OF
POTASSIUM HYDROXIDE IS 2-20 ML, DEPENDING ON BATTERY SIZE. DO NOT EAT AND
DRINK BATTERIES. KEEP BATTERIES AWAY FROM SMALL CHILDREN.
PHYSICAL-CHEMICAL HAZARDS:
THIS PREPARATION IS NOT CLASSIFIED AS DANGEROUS ACCORDING TO THE CRITERIA
OF DIRECTIVE 99/45/EEC.
HAZARDS TO MAN:
IF BATTERY LEAKING, EXPOSURE TO CAUSTIC INGREDIENTS MAY OCCUR. THEREFORE,
MAY CAUSE SENSITIZATION BY SKIN CONTRACT.
HAZARDS TO ENVIRONMENT: N.A..
| 4 FIRST-AID MEASURES | |
INHALATION:
IN CASE OF EXCESSIVE INHALATION DUE TO LEAKING BATTERIES REMOVE TO FRESH
AIR. OBTAIN MEDICAL ADVICE.
SKIN CONTACT:
IF EXPOSED TO A LEAKING BATTERY, REMOVE CONTAMINATED CLOTHING. WASH EXPOSED
AREAS WITH PLENTY OF WATER AND SOAP. IF IRRITATION OCCURS, CONSULT A
PHYSICIAN.
EYE CONTACT:
IF A BATTERY IS LEAKING AND MATERIALS CONTACT EYES, FLUSH IMMEDIATELY WITH
RUNNING WATER FOR AT LEAST 15 MINUTES. CONSULT AN OPHTHALMOLOGIST AT ONCE.
INGESTION:
NOT ANTICIPATED DUE TO SIZE OF BATTERIES. CHOKING MAY OCCUR WITH THE
SMALLER SIZE BATTERIES. IF EXPOSED TO A LEAKING BATTERY, RINSE MOUTH AND
SURROUNDING AREAS WITH RUNNING WATER FOR AT LEAST 15 MINUTES. GIVE PLENTY
OF WATER TO DRINK. DO NOT INDUCE VOMITING. OBTAIN MEDICAL ADVICE.
| 5 FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2), FOAM, DRY CHEMICAL POWDER.
EXTINGUISHING MEDIA NOT TO BE USED: NEVER USE A DIRECT WATER JET.
EXPOSURE HAZARDS FROM COMBUSTION PRODUCTS:
IN CASE OF FIRE, CARBON DIOXIDE, CARBON MONOXIDE AND OTHER TOXIC ORGANIC
SUBSTANCES WILL BE GENERATED. DO NOT INHALE FUMES AND SMOKE.
PERSONAL PROTECTIVE EQUIPMENTS:
WEAR FULL PROTECTIVE CLOTHING. USE SELF-CONTAINED BREATHING APPARATUS.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
NOTIFY SAFETY PERSONNEL OF LARGE SPILLS. CAUSTIC POTASSIUM HYDROXIDE MAY BE
RELEASED FROM LEAKING OR RUPTURED BATTERIES. AVOID EYE OR SKIN CONTACT AND
INHALATION OF VAPORS. INCREASE THE VENTILATION. WEAR PROTECTIVE CLOTHING.
KEEP UNPROTECTED PERSONS AWAY.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE AND PENETRATION INTO SEWERAGE SYSTEMS, WATERWAYS, PITS, AND
CELLARS.
METHODS FOR CLEANING UP:
COLLECT SPILLED MATERIAL WITH AN INSERT STANDARD ABSORBENT LIKE SAND OR
SILICA. CARE FOR WELL-VENTILATED CONDITIONS. RECYCLE OR DISPOSE OF THE
MATERIALS IN AN APPROPRIATE WAY.
| 7 HANDLING AND STORAGE | |
GENERAL HANDLING:
OBEY THE COMMON KNOWN RULES AND PRECAUTIONS FOR HANDLING WITH CHEMICALS.
AVOID MECHANICAL AND ELECTRICAL ABUSE. DO NOT SHORT BATTERY OR INSTALL
INCORRECTLY. BATTERIES MAY EXPLODE, PYROLIZE OR VENT IF DISASSEMBLED,
CRUSHED, RECHARGED OR EXPOSED TO HIGH TEMPERATURES. INSTALL BATTERIES
ACCORDING TO EQUIPMENT INSTRUCTIONS. DO NOT MIX BATTERY SYSTEMS, SUCH AS
ALKALINE AND ZINC - CARBON. REPLACE ALL BATTERIES IN EQUIPMENT AT THE SAME
TIME. DO NOT CARRY BATTERIES LOOSE IN POCKET OR BAG. DO NOT REMOVE BATTERY
LABELS.
STORAGE:
STORE PRODUCT IN WELL-FILLED, APPROPRIATE COATED AND TIGHTLY CLOSED
CONTAINERS AVOIDING INFLUENCE OF OXYGEN/AIR, LIGHT AND HUMIDITY. STORAGE AT
ROOM TEMPERATURE.
| 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
EXPOSITION/TECHNICAL MEASURES:
ATMOSPHERIC VAPOR CONCENTRATIONS MUST BE MINIMIZED BY ADEQUATE VENTILATION.
PROTECTION OF HANDS, EYES AND SKIN:
NONE REQUIRED UNDER NORMAL USE CONDITIONS. WHEN HANDLING LEAKING BATTERIES,
USE NEOPRENE, RUBBER OR NITRILE GLOVES AND WEAR SAFETY GLASSES TO PROTECT
HANDS, EYES AND SKIN.
GENERAL SAFETY AND HYGIENE MEASURES: USE ONLY AS DIRECTED.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: STAINLESS STEEL TOP BATTERY
COLOR: CONTENTS DARK AND GRAY IN COLOR
ODOR: N.A.
MELTING POINT: N.A.
BOILING POINT: N.A.
FLASH POINT: N.A.
EXPLOSION LIMIT: NOT AVAILABLE
IGNITION TEMPERATURE: NOT AVAILABLE
VAPOR PRESSURE: NOT AVAILABLE
SPECIFIC GRAVITY: N.A.
SOLUBILITY IN WATER: N.A.
SOLUBILITY IN OTHER SOLVENTS: N.A.
pH VALUE: NOT AVAILABLE
PARTITION COEFFICIENT: NOT AVAILABLE
VISCOSITY: NOT AVAILABLE
| 10 STABILITY AND REACTIVITY | |
THERMAL DECOMPOSITION:
BATTERIES MAY BURST AND RELEASE HAZARDOUS DECOMPOSITION PRODUCTS WHEN
EXPOSED TO FIRE.
SUBSTANCES TO AVOID: STRONG OXIDATION AGENTS.
HAZARDOUS REACTIONS: CONTENTS INCOMPATIBLE WITH STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DEGRADATION MAY PRODUCE HAZARDOUS FUMES OF ZINC AND MANGANESE;
HYDROGEN GAS; CAUSTIC VAPORS OF POTASSIUM HYDROXIDE AND OTHER TOXIC
BY-PRODUCTS.
| 11 TOXICOLOGICAL INFORMATION | |
TOXICITY INFORMATION IS AVAILABLE ON THE BATTERY INGREDIENTS NOTED IN
SECTION 2, BUT IN GENERAL, N.A. TO INTACT BATTERIES.
CHRONIC HEALTH EFFECTS: N.A.
| 12 ECOLOGICAL INFORMATION | |
NOT AVAILABLE
| 13 DISPOSABLE CONSIDERATIONS | |
PRODUCT:
DISPOSE IN ACCORDANCE WITH APPROPRIATE REGULATIONS. IF IN DOUBT, CONTACT
YOUR LOCAL GOVERNMENT OFFICE CONCERNED FOR INFORMATION. DO NOT INCINERATE,
SINCE BATTERIES MAY EXPLODE AT EXCESSIVE TEMPERATURES.
| 14 TRANSPORT INFORMATION | |
ROAD (ADR/RID): NOT REGULATED
AIR (ICAO/IATA): NOT REGULATED
SEA (IMDG): NOT REGULATED
THESE BATTERIES ARE NOT REGULATED BY INTERNATIONAL AGENCIES AS HAZARDOUS
MATERIALS OR DANGEROUS GOODS WHEN SHIPPED. A SHIPPING NAME OF "ALKALINE
BATTERIES - NON-HAZARDOUS" MAY BE USED ON ALL DOMESTIC AND INTERNATIONAL
BILLS OF LADING.
IN GENERAL, ALL BATTERIES IN ALL FORMS OF TRANSPORTATION (GROUND, AIR, OR
OCEAN) MUST BE PACKAGED IN A SAFE AND RESPONSIBLE MANNER. REGULATORY
CONCERNS FROM ALL AGENCIES FOR SAFE PACKAGING REQUIRE THAT BATTERIES BE
PACKAGED IN A MANNER THAT PREVENTS SHORT CIRCUITS AND BE CONTAINED IN
"STRONG OUTER PACKAGING" THAT PREVENTS SPILLAGE OF CONTENTS. ALL ORIGINAL
PACKAGING FOR PAIRDEER ALKALINE BATTERIES HAS BEEN DESIGNED TO BE COMPLIANT
WITH THESE REGULATORY CONCERNS.
| 15 REGULATORY INFORMATION | |
SYMBOL: N/A
EC LABELING: NONE
RISK PHRASES: NONE
SAFETY PHRASES: NONE
LABELING IS NOT REQUIRED BECAUSE ALKALINE BATTERIES ARE CLASSIFIED AS
"ARTICLES" UNDER THE DANGEROUS PREPARATIONS DIRECTIVE AND AS SUCH ARE
EXEMPT FROM THE REQUIREMENTS OF THE DIRECTIVE.
| 16 OTHER INFORMATION | |
THE INFORMATION ON THIS MATERIAL SAFETY DATA SHEET (MSDS) WAS OBTAINED
FROM CURRENT AND REPUTABLE SOURCES. HOWEVER, THE DATA IS PROVIDED
WITHOUT ANY WARRANTY; EXPRESSED OR IMPLIED, REGARDING ITS CORRECTNESS OR
ACCURACY. IT IS THE USER'S RESPONSIBILITY TO ASSUME LIABILITY ON LOSS,
INJURY, DAMAGE, OR EXPENSE RESULTING FROM IMPROPER USE OF THIS PRODUCT. ANY
PREVIOUS MSDS OF THIS PRODUCT MENTIONED ABOVE ARE HEREBY REPLACED WITH THIS
NEW DOCUMENT. WE URGE YOU TO MAKE THIS INFORMATION AVAILABLE AS APPROPRIATE
IN YOUR ORGANIZATION AND TO ANY OTHERS WITH WHOM YOU ARRANGE TO HANDLE THIS
PRODUCT.
VERSION: 2