| Common Name: | TOUGH GUY POWDERED FLOOR DEGREASER |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 12/10/2009 |
| SDS Format: | No Format Specified |
| Item Number(s): | 5DJC7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
GRAINGER(R*)
FOR THE ONES WHO GET IT DONE
MANUFACTURED FOR:
W.W. GRAINGER, INC.
100 GRAINGER PKWY.
LAKE FOREST, IL 60045-5201
1-847-535-1000
WWW.GRAINGER.COM
| SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: TOUGH GUY POWDERED FLOOR DEGREASER
PRODUCT USE: FLOOR DEGREASER
PRODUCT CODE: 5DJC7
DATE OF ISSUE: 12/10/09
SUPERSEDES:
EMERGENCY TELEPHONE NUMBERS:
FOR MSDS INFORMATION:
TECHNICAL SERVICES: 1-847-535-5400
FOR MEDICAL EMERGENCY: (800) 983-4582 TOLL FREE
FOR TRANSPORTATION EMERGENCY:
CHEMTREC: (800) 424-9300 - ALL CALLS RECORDED
IN THE DISTRICT OF COLUMBIA: (202) 483-7616
PREPARED BY:
COMPLIANCE SERVICES
1420 SEABOARD INDUSTRIAL BLVD.
ATLANTA, GA 30318
| SECTION 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER!
CAUSES EYE AND SKIN BURNS.
NOTE:
MSDS DATA PERTAINS TO THE PRODUCT AS DELIVERED IN THE ORIGINAL SHIPPING
CONTAINER(S). RISK OF ADVERSE EFFECTS ARE LESSENED BY FOLLOWING ALL
PRESCRIBED SAFETY PRECAUTIONS, INCLUDING THE USE OF PROPER PERSONAL
PROTECTIVE EQUIPMENT.
*HAZARD DETERMINATION SYSTEM (HDS):
HEALTH 3
FLAMMABILITY 0
REACTIVITY 0
ACUTE EFFECTS:
ROUTES OF ENTRY: DERMAL CONTACT.
EYES:
CORROSIVE TO EYES. DIRECT CONTACT WITH THE EYES CAN CAUSE IRREVERSIBLE
DAMAGE, INCLUDING BLINDNESS.
SKIN:
SKIN CONTACT MAY PRODUCE BURNS. THE AMOUNT OF TISSUE DAMAGE DEPENDS ON
LENGTH OF CONTACT. SKIN INFLAMMATION IS CHARACTERIZED BY ITCHING, SCALING,
OR REDDENING.
INHALATION:
AVOID BREATHING DUST. INHALATION OF DUST WILL PRODUCE IRRITATION TO
GASTRO-INTESTINAL OR RESPIRATORY TRACT, CHARACTERIZED BY BURNING, SNEEZING
AND COUGHING.
INGESTION:
MAY BE HARMFUL IF SWALLOWED. MAY CAUSE BURNS TO MOUTH, THROAT, AND STOMACH.
CHRONIC EFFECTS:
REPEATED OR PROLONGED EXPOSURE TO THE SUBSTANCE CAN PRODUCE TARGET ORGANS
DAMAGE.
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS:
UPPER RESPIRATORY TRACT, EYES. REPEATED EXPOSURE OF THE EYES TO A LOW LEVEL
OF DUST CAN PRODUCE EYE IRRITATION. REPEATED SKIN EXPOSURE CAN PRODUCE
LOCAL SKIN DESTRUCTION OR DERMATITIS. REPEATED INHALATION OF DUST CAN
PRODUCE VARYING DEGREES OF RESPIRATORY IRRITATION OR LUNG DAMAGE.
CARCINOGENICITY:
INGREDIENTS: NOT LISTED AS CARCINOGEN BY OSHA, NTP OR IARC.
PRODUCT/INGREDIENT NAME: NOT AVAILABLE.
ADDITIONAL INFORMATION: SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
NAME OF HAZARDOUS INGREDIENTS CAS NUMBER % BY WEIGHT
SODIUM METASILICATE; SILICIC ACID (H2-Si-O3) 6834-92-0 70 - 80
DISODIUM SALT; WATER GLASS
SODIUM CARBONATE; SODA ASH; CARBONIC ACID, 497-19-8 5 - 15
DISODIUM SALT
| SECTION 4. FIRST AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
FLUSH AFFECTED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND
SHOES. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING OR
WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. WASH CLOTHING
BEFORE REUSE. GET MEDICAL ATTENTION IMMEDIATELY.
INHALATION:
MOVE EXPOSED PERSON TO FRESH AIR. FLUSH MOUTH AND NASAL PASSAGES WITH WATER
REPEATEDLY. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
IF AFFECTED PERSON IS CONSCIOUS, GIVE PLENTY OF WATER TO DRINK. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION
IMMEDIATELY.
| SECTION 5. FIRE FIGHTING MEASURES | |
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
3
0
0
FLASH POINT: NOT APPLICABLE
FLAMMABLE LIMITS: NOT APPLICABLE
FLAMMABILITY: NOT APPLICABLE
FIRE HAZARD: NO SPECIFIC FIRE OR EXPLOSION HAZARD.
FIRE-FIGHTING PROCEDURES:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
SPILL CLEAN UP:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). MOVE
CONTAINERS FROM SPILL AREA. VACUUM OR SWEEP UP MATERIAL AND PLACE IN A
DESIGNATED, LABELED WASTE CONTAINER. FINISH CLEANING BY SPREADING WATER ON
THE CONTAMINATED SURFACE AND DISPOSE OF ACCORDING TO LOCAL AND REGIONAL
AUTHORITY REQUIREMENTS.
| SECTION 7. HANDLING AND STORAGE | |
HANDLING:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
GET IN EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE DUST. DO NOT INGEST. USE
WITH ADEQUATE VENTILATION. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN
BE HAZARDOUS. DO NOT REUSE CONTAINER. WASH THOROUGHLY AFTER HANDLING.
OBSERVE LABEL PRECAUTIONS.
STORAGE:
CONTAINS MOISTURE-SENSITIVE MATERIAL. STORE IN A DRY PLACE. STORE IN
ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND
WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND
FOOD AND DRINK. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR
USE.
STORE BETWEEN THE FOLLOWING TEMPERATURES:
40 DEG. F - 120 DEG. F (4.4 DEG. C - 49 DEG. C).
KEEP OUT OF THE REACH OF CHILDREN.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRODUCT NAME EXPOSURE LIMITS
SODIUM METASILICATE; SILICIC ACID (H2-Si-O3) ACGIH TLV (UNITED STATES).
DISODIUM SALT; WATER GLASS TWA: 10 MG/M3 8 HOUR(S).
FORM: DUST
OSHA PEL (UNITED STATES).
: 15 MG/M3
FORM: DUST
SODIUM CARBONATE; SODA ASH; CARBONIC ACID, ACGIH (UNITED STATES).
DISODIUM SALT : 15 MG/M3
FORM: DUST
OSHA PEL (UNITED STATES).
TWA: 15 MG/M3 8 HOUR(S).
FORM: TOTAL DUST
PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYES: SPLASH GOGGLES.
RECOMMENDED: FACE SHIELD.
BODY: WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT.
RECOMMENDED:
RUBBER GLOVES. NEOPRENE GLOVES. NITRILE GLOVES.
CHEMICAL-RESISTANT APRON. CHEMICAL RESISTANT BOOTS.
RESPIRATORY:
USE WITH ADEQUATE VENTILATION. IF DUST IS GENERATED AND VENTILATION IS
INADEQUATE, USE RESPIRATOR THAT WILL PROTECT AGAINST DUST/MIST.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SOLID. (POWDER.)
COLOR: ORANGE.
pH: NOT APPLICABLE.
ODOR: PINE
BOILING POINT: NOT APPLICABLE.
VAPOR PRESSURE: NOT APPLICABLE.
SPECIFIC GRAVITY: NOT APPLICABLE.
VAPOR DENSITY: NOT APPLICABLE.
SOLUBILITY:
SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
EVAPORATION RATE: NOT APPLICABLE.
VOC (CONSUMER): 0.67%
| SECTION 10. STABILITY AND REACTIVITY | |
STABILITY AND REACTIVITY: THE PRODUCT IS STABLE.
INCOMPATIBILITY:
SLIGHTLY REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS:
METALS AND ACIDS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON OXIDES (CO, CO2), SULFUR OXIDES (SO2, SO3 ETC.)
| SECTION 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
SODIUM METASILICATE LD50 ORAL RAT 2200 MG/KG
SODIUM CARBONATE LD50 ORAL RAT 2800 MG/KG
| SECTION 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL EFFECTS: NOT AVAILABLE.
AQUATIC ECOTOXICITY:
PRODUCT/INGREDIENT NAME TEST RESULT SPECIES EXPOSURE
SODIUM CARBONATE ACUTE LC50: FISH - BLUEGILL. 96 HOURS
300 MG/L
ACUTE LC50: DAPHNIA 96 HOURS
265 MG/L
| SECTION 13. DISPOSAL CONSIDERATIONS | |
WASTE INFORMATION:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
ENVIRONMENTAL CONTROL REGULATIONS. CONSULT YOUR LOCAL OR REGIONAL
AUTHORITIES FOR ADDITIONAL INFORMATION.
WASTE STREAM:
CODE: (NONE.)
CLASSIFICATION: (NON-HAZARDOUS WASTE)
| SECTION 14. TRANSPORT INFORMATION | |
REGULATORY UN PROPER CLASSES PG* LABEL
INFORMATION NUMBER SHIPPING NAME
DOT NOT NOT A DOT CONTROLLED
CLASSIFICATION APPLICABLE. MATERIAL (UNITED
STATES).
NOTE:
DOT CLASSIFICATION APPLIES TO MOST PACKAGE SIZES. FOR SPECIFIC CONTAINER
SIZE CLASSIFICATIONS OR FOR SIZE EXCEPTIONS, REFER TO THE BILL OF LADING
WITH YOUR SHIPMENT.
PG*: PACKING GROUP
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING:
NO PRODUCTS WERE FOUND.
CLEAN WATER ACT (CWA) 307: NO PRODUCTS WERE FOUND.
CLEAN WATER ACT (CWA) 311: NO PRODUCTS WERE FOUND.
CLEAN AIR ACT (CAA) 112 REGULATED TOXIC SUBSTANCES: NO PRODUCTS WERE FOUND.
ALL COMPONENTS OF THIS PRODUCT ARE LISTED OR EXEMPT FROM LISTING ON TSCA
INVENTORY.
STATE REGULATIONS:
CALIFORNIA PROP 65: NO PRODUCTS WERE FOUND.
| SECTION 16. OTHER INFORMATION | |
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE NAMED SUPPLIER NOR ANY OF ITS SUBSIDIARIES
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
*NOTE:
HAZARD DETERMINATION SYSTEM (HDS) RATINGS ARE BASED ON A 0-4 RATING SCALE,
WITH 0 REPRESENTING MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING
SIGNIFICANT HAZARDS OR RISKS ALTHOUGH THESE RATINGS ARE NOT REQUIRED ON
MSDSS UNDER 29 CFR 1910.1200, THE PREPARER MAY CHOOSE TO PROVIDE THEM. HDS
RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED PROGRAM TO RELAY THE
MEANINGS OF THIS SCALE.