| Common Name: | GREEN ENVY MURIATIC ACID REPLACEMENT |
| Manufacturer: | SUNNYSIDE |
| SDS Revision Date: | 1/28/2009 |
| SDS Format: | No Format Specified |
| Item Number(s): | 5KPY1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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610
MATERIAL SAFETY DATA SHEET
COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200
DATE OF PREP: 01/28/09
| SECTION 1 |  |
SUNNYSIDE CORPORATION
225 CARPENTER AVENUE
WHEELING, ILLINOIS 60090
EMERGENCY TELEPHONE:
(847) 541-5700 - SUNNYSIDE CORPORATION
(800) 424-9300 - CHEM TREC
FOR INFORMATION: (847) 541-5700
PRODUCT CLASS: INORGANIC ACID
TRADE NAME: GREEN ENVY MURIATIC ACID REPLACEMENT
MANUFACTURER'S CODE: 610
NPCA HMIS:
HEALTH 3
FIRE 0
REACTIVITY 1
PRODUCT APPEARANCE AND ODOR:
CLEAR, COLORLESS TO PALE YELLOW LIQUID, PUNGENT ODOR.
| SECTION 2 - HAZARDOUS INGREDIENTS | |
INGREDIENT CAS # PERCENT
HYDROGEN CHLORIDE 7647-01-0
ETHOXYLATED AMINES
UREA 57-13-6
CITRIC ACID 77-92-9
INGREDIENT OCCUPATIONAL EXPOSURE LIMITS VAPOR PRESSURE
ACGIH TLV ACGIH TLV OSHA PEL OSHA PEL
(TWA) (STEL) (TWA) (STEL)
HYDROGEN 5 PPM 5 PPM 5 PPM 5 PPM APPROXIMATELY
CHLORIDE (CEILING) (CEILING) 35 MMHg @
77 DEG. F.
ETHOXYLATED NOT NOT NOT AVAILABLE
AMINES AVAILABLE AVAILABLE
UREA 10 MG/M3 5 MG/M3 NOT APPLICABLE
OSHA NUISANCE
DUST
15 MG/M3
(TOTAL)
CITRIC ACID NOT NOT NOT APPLICABLE
AVAILABLE AVAILABLE
| SECTION 3 - EMERGENCY AND FIRST AID PROCEDURES | |
EYE CONTACT:
IMMEDIATELY FLUSH THE EYES WITH LARGE QUANTITY OF WATER WHILE HOLDING THE
EYELIDS APART, FOR AT LEAST 15 TO 20 MINUTES. SEVERE EYE INJURY CAN OCCUR,
PARTICULARLY IF RINSING IS DELAYED. GET MEDICAL ATTENTION IMMEDIATELY.
APPLY COOL PACKS ON EYES WHILE TRANSPORTING VICTIM TO MEDICAL FACILITY.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH AFFECTED AREA WITH
SOAP AND LARGE AMOUNTS OF WATER FOR AT LEAST 15 TO 20 MINUTES. IN CASE OF
CHEMICAL BURNS, COVER AREA WITH STERILE, DRY DRESSING. KEEP AFFECTED AREA
COOL. GET MEDICAL ATTENTION IMMEDIATELY.
INHALATION:
REMOVE TO FRESH AIR. ADMINISTER OXYGEN AS SOON AS POSSIBLE (6 LITERS PER
MINUTE) IF BREATHING IS DIFFICULT. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IMMEDIATELY CONTACT A PHYSICIAN. KEEP THE VICTIM WARM AND AT
REST.
INGESTION:
DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER OR MILK.
IF VOMITING PERSISTS, ADMINISTER FLUIDS REPEATEDLY. MAINTAIN AIRWAY AND
TREAT FOR SHOCK. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS TO PREVENT
ASPIRATION. GET MEDICAL ATTENTION IMMEDIATELY.
| SECTION 4 - PHYSICAL DATA | |
THE FOLLOWING DATA REPRESENT APPROXIMATE OR TYPICAL VALUES. THEY DO NOT
CONSTITUTE PRODUCT SPECIFICATIONS.
BOILING RANGE: APPROX. 183 DEG. (F) - I.B.P.
VAPOR DENSITY: HEAVIER THAN AIR
EVAPORATION RATE: SLOWER THAN ETHER
% VOLATILE BY VOLUME: 100%
WEIGHT PER GALLON: 9.41 LBS
SOLUBILITY IN WATER: 100 WT. %
pH: <1.0
| SECTION 5 - FIRE AND EXPLOSION DATA | |
FLAMMABILITY CLASSIFICATION: NON-FLAMMABLE
FLASH POINT: NOT APPLICABLE
LOWER EXPLOSIVE LIMIT: NOT APPLICABLE
EXTINGUISHING MEDIA:
USE WATER SPRAY, FOG, FOAM, DRY CHEMICALS, CARBON DIOXIDE OR OTHER AGENTS
AS APPROPRIATE FOR SURROUNDING FIRE.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
REACTS WITH ACTIVE METALS (POTASSIUM, SODIUM, CALCIUM, POWDERED ALUMINUM,
ZINC, MAGNESIUM) TO PRODUCE FLAMMABLE HYDROGEN.
SPECIAL FIRE FIGHTING PROCEDURES:
USE SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE ACID RESISTANT
CLOTHING. WATER SPRAY SHOULD BE USED TO COOL FIRE EXPOSED CONTAINERS AND TO
CONTROL VAPORS.
| SECTION 6 - HEALTH HAZARD DATA | |
THRESHOLD LIMIT VALUE: SEE SECTION 2
EFFECTS OF OVEREXPOSURE:
ACUTE INHALATION:
INHALATION OF FUMES AT LOWER LEVELS MAY CAUSE IRRITATION AND BURNING OF THE
THROAT, COUGHING AND CHOKING. AT HIGHER LEVELS (ABOVE 50 PPM), INFLAMMATION
OF THE NOSE, THROAT OR LARYNX, BRONCHITIS, PNEUMONIA, AND HEADACHE MAY
OCCUR. SEVERE CASES MAY EXHIBIT NECROSIS OF THE WINDPIPE AND BRONCHIAL
EPITHELIUM, DAMAGE TO PULMONARY BLOOD VESSELS AND EMPHYSEMA.
CHRONIC INHALATION:
REPEATED OR PROLONGED OVEREXPOSURE MAY CAUSE EROSION AND DISCOLORATION OF
EXPOSED TEETH, CHRONIC BRONCHITIS AND GASTRITIS.
ACUTE EYE CONTACT:
CONTACT MAY CAUSE SEVERE IRRITATION, CONJUNCTIVITIS, CORNEAL NECROSIS AND
BURNS.
CHRONIC EYE CONTACT:
CONJUNCTIVITIS OR EFFECTS SIMILAR TO THOSE FOR ACUTE EXPOSURE MAY OCCUR.
ACUTE SKIN CONTACT:
CONTACT MAY CAUSE SEVERE IRRITATION, INFLAMMATION, ULCERATION, NECROSIS AND
CHEMICAL BURNS.
CHRONIC SKIN CONTACT:
REPEATED OR PROLONGED CONTACT MAY CAUSE CHRONIC IRRITATION AND DERMATITIS.
PHOTOSENSITIZATION MAY ALSO OCCUR.
ACUTE INGESTION:
INGESTION MAY CAUSE BURNS OF THE MOUTH, THROAT, ESOPHAGUS AND STOMACH WITH
PAIN, NAUSEA, SALIVATION, VOMITING, DIARRHEA, CHILLS, SHOCK AND INTENSE
THIRST. NEPHRITIS, FEVER AND PERFORATION OF THE INTESTINAL TRACT, AND
CIRCULATORY COLLAPSE MAY OCCUR.
CARCINOGENICITY:
THIS PRODUCT IS NOT LISTED AS A CARCINOGEN BY NTP, IARC OR OSHA.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE LUNGS MAY HAVE INCREASED
SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.
| SECTION 7 - REACTIVITY DATA | |
STABILITY: STABLE
CONDITIONS TO AVOID: AVOID CONTACT WITH METALS AND STRONG OXIDIZERS.
INCOMPATIBILITY (MATERIALS TO AVOID): AVOID BASE AND CORROSIVE MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
FLAMMABLE HYDROGEN GAS CAN BE PRODUCED BY REACTION WITH MOST METALS AND MAY
FORM EXPLOSIVE MIXTURES WITH AIR. CHLORINE GAS WILL BE RELEASED BY MIXING
WITH STRONG OXIDIZERS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| SECTION 8 - SPILL OR LEAK PROCEDURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS SPILLED OR RELEASED:
EVACUATE AREA AND DENY ENTRY BY UNAUTHORIZED PERSONNEL. DO NOT BREATHE
VAPORS, STAY UPWIND. FOR LARGE SPILLS, CONTAIN AND PUMP INTO TANKS, WHICH
HAVE BEEN CONSTRUCTED FOR HYDROCHLORIC ACID SERVICE. FULL ACID RESISTANT
SUITS AND SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN DURING
EMERGENCY OPERATIONS. KNOCK DOWN VAPORS WITH WATER SPRAY OR WATER FOG.
WATER USED TO KNOCK DOWN VAPORS MAY BECOME CORROSIVE AND SHOULD BE
CONTAINED PROPERLY FOR LATER DISPOSAL. NEUTRALIZE SPILL WITH SLAKED LIME,
SODIUM BICARBONATE OR CRUSHED LIMESTONE. SINCE NEUTRALIZATION GENERATES
HEAT (EXOTHERMIC REACTION), THE REACTION CAN BE VIOLENT. THE ACID SHOULD BE
DILUTED AND COOLED BEFORE ATTEMPTING TO NEUTRALIZE. SPILLS MUST BE
NEUTRALIZED AND FEDERAL, STATE AND LOCAL REGULATIONS MUST BE CONSULTED
BEFORE FLUSHING TO SEWER. FOR SMALL SPILLS, TAKE UP WITH SAND OR OTHER
ABSORBENT MATERIAL AND REACT WITH DRY ALKALI (SODA ASH OR LIME). PLACE INTO
CONTAINERS FOR LATER DISPOSAL. ADHERE TO FEDERAL, STATE AND LOCAL
REGULATIONS ON REPORTING RELEASES.
WASTE DISPOSAL METHOD:
LANDFILL OR NEUTRALIZE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.
| SECTION 9 - SAFE HANDLING AND USE INFORMATION | |
RESPIRATORY PROTECTION:
USE NIOSH/MSHA APPROVED ACID-GAS RESPIRATOR FOR AREAS WHERE AIRBORNE
EXPOSURE IS EXCESSIVE. DO NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR.
VENTILATION:
PROVIDE GOOD GENERAL ROOM VENTILATION TO KEEP WORKROOM CONCENTRATION BELOW
CURRENT APPLICABLE OSHA SAFETY AND HEALTH REQUIREMENTS (SECTION 2).
USE LOCAL EXHAUST VENTILATION AT POINTS OF VAPOR EMISSION.
PROTECTIVE GLOVES:
WEAR PROTECTIVE GLOVES, SUCH AS RUBBER OR NEOPRENE, TO MINIMIZE SKIN
CONTACT.
EYE PROTECTION:
CHEMICAL SAFETY GOGGLES AND A FULL FACESHIELD TO PREVENT CONTACT.
OTHER PROTECTIVE EQUIPMENT:
EYE WASH FACILITY SHOULD BE IN CLOSE PROXIMITY. USE OF RUBBERIZED
COVERALLS, RUBBER SHOES, AND EMERGENCY SHOWER AVAILABILITY ARE RECOMMENDED.
| SECTION 10 - SPECIAL PRECAUTIONS | |
DEPT. OF LABOR STORAGE CATEGORY: NON-FLAMMABLE LIQUID.
HYGIENIC PRACTICES:
WASH THOROUGHLY AFTER CONTACT. WASH PROTECTIVE CLOTHING PRIOR TO RE-USE.
ADDITIONAL PRECAUTIONS:
DO NOT GET IN EYES OR ON SKIN OR CLOTHING. AVOID BREATHING VAPORS. KEEP
CONTAINERS CLOSED. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. STORE IN COOL,
WELL VENTILATED PLACE, SEPARATE FROM ALL OXIDIZING MATERIALS. KEEP LIGHTS,
FIRE AND SPARKS AWAY FROM CONTAINER OPENINGS.
EMPTY CONTAINER WARNING:
"EMPTY" CONTAINERS CONTAIN HAZARDOUS ACID VAPOR OR LIQUID; NEVER ADD TO,
MIX OR STORE ANY OTHER PRODUCT IN ANY CONTAINER THAT CONTAINS OR HAS
CONTAINED HYDROCHLORIC ACID. MIXING HYDROCHLORIC ACID WITH SOME COMMONLY
AVAILABLE CHEMICALS AND SOME HOUSEHOLD PRODUCTS, SUCH AS BLEACH, CAN CAUSE
A VIOLENT REACTION OR THE EVOLUTION OF POISONOUS OR EXPLOSIVE GASES.
| SECTION 11 - ADDITIONAL INFORMATION | |
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL(S) WHICH ARE SUBJECT TO
THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
TOXIC CHEMICAL CAS # APPROXIMATE % BY WEIGHT
HYDROCHLORIC ACID 7647-01-0 19.81%
SARA TITLE III HAZARD CATEGORIES: IMMEDIATE (ACUTE) HEALTH HAZARD
COMMON NAMES:
HYDROGEN CHLORIDE SOLUTION, HCl, AQUEOUS SOLUTION OF HYDROCHLORIC ACID,
MURIATIC ACID
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS TRACE AMOUNTS OF CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, AND TRACE AMOUNTS OF CHEMICALS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
TRANSPORTATION (U.S. D.O.T. LAND TRANSPORTATION):
U.S. D.O.T. PROPER SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONTAINS HYDROCHLORIC ACID
SOLUTION)
U.S. D.O.T. I.D. NUMBER: UN 3264
U.S. D.O.T. HAZARD CLASS: 8
U.S. D.O.T. PACKING GROUP: PG III
U.S. D.O.T. HAZARDOUS SUBSTANCE: HYDROCHLORIC ACID RQ 5000 LBS.
SHIPPED AS CONSUMER COMMODITY, ORM-D, IN PACKAGES OF 5L OR LESS.
REFER TO 49 CFR FOR POSSIBLE EXCEPTIONS AND EXEMPTIONS.