| Common Name: | HEAVY DUTY CITRUS DEGREASER |
| Manufacturer: | ZEP MANUFACTURING |
| SDS Revision Date: | 7/31/2009 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3HUW4, 3HUW5, 5ULH6, 9KW82 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
ZEP PROFESSIONAL
MATERIAL SAFETY DATA SHEET
ZEP INC.
1310 SEABOARD INDUSTRIAL BLVD.
ATLANTA, GA 30318
1-877-793-7776
| SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: HEAVY DUTY CITRUS DEGREASER
PRODUCT USE: INDUSTRIAL SOLVENT DEGREASER
PRODUCT CODE: R077
EMERGENCY TELEPHONE NUMBERS:
FOR MSDS INFORMATION:
COMPLIANCE SERVICES: 1-877-793-7776
FOR MEDICAL EMERGENCY:
(877) 541-2016 TOLL FREE - ALL CALLS RECORDED
FOR TRANSPORTATION EMERGENCY:
CHEMTREC: (800) 424-9300 - ALL CALLS RECORDED
IN THE DISTRICT OF COLUMBIA: (202) 483-7616
PREPARED BY:
COMPLIANCE SERVICES
1420 SEABOARD INDUSTRIAL BLVD.
ATLANTA, GA 30318
DATE OF ISSUE: 07/31/09
SUPERSEDES: 08/11/08
| SECTION 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
CAUTION!
COMBUSTIBLE. CAUSES EYE IRRITATION.
*HAZARD DETERMINATION SYSTEM (HDS):
HEALTH 1
FLAMMABILITY 2
REACTIVITY 0
NOTE:
MSDS DATA PERTAINS TO THE PRODUCT AS DELIVERED IN THE ORIGINAL SHIPPING
CONTAINER(S). RISK OF ADVERSE EFFECTS ARE LESSENED BY FOLLOWING ALL
PRESCRIBED SAFETY PRECAUTIONS, INCLUDING THE USE OF PROPER PERSONAL
PROTECTIVE EQUIPMENT.
ACUTE EFFECTS:
ROUTES OF ENTRY: INHALATION. SKIN CONTACT EYE CONTACT.
EYES:
CAUSES EYE IRRITATION. INFLAMMATION OF THE EYE IS CHARACTERIZED BY
REDNESS, WATERING AND ITCHING.
SKIN:
MAY CAUSE SKIN IRRITATION. MAY CAUSE SKIN SENSITIZATION. MAY CAUSE
ALLERGIC REACTIONS IN CERTAIN INDIVIDUALS. SKIN INFLAMMATION IS
CHARACTERIZED BY ITCHING, SCALING, OR REDDENING.
INHALATION:
AVOID BREATHING VAPORS, SPRAY OR MISTS. OVER-EXPOSURE BY INHALATION MAY
CAUSE RESPIRATORY IRRITATION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED. ASPIRATION HAZARD IF SWALLOWED. CAN ENTER
LUNGS AND CAUSE DAMAGE.
CHRONIC EFFECTS:
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
CARCINOGENICITY:
INGREDIENTS: NOT LISTED AS CARCINOGEN BY OSHA, NTP OR IARC.
PRODUCT/INGREDIENT NAME ACGIH IARC EPA NIOSH NTP OSHA
NONE.
ADDITIONAL INFORMATION: SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
NAME OF HAZARDOUS INGREDIENTS CAS NUMBER % BY WEIGHT
ALKYL (C16-C18) METHYL ESTERS 67784-80-9 60 - 70
D-LIMONENE; ORANGE DISTILLATE; CITRUS 5989-27-5 20 - 30
TERPENE; CYCLOHEXENE, 1-METHYL-4-(1-
METHYLETHENYL)-,(R)-
NONYLPHENOXY POLY(ETHYLENEOXY) ETHANOL - 9016-45-9 1 - 10
NPE; POLY(OXY-1,2-ETHANEDIYL) ALPHA-
(NONYLPHENYL)-OMEGA-HYDROXY
| SECTION 4. FIRST AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE
UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE
TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
WASH AFFECTED AREA WITH SOAP OR MILD DETERGENT AND WATER. REMOVE
CONTAMINATED CLOTHING AND SHOES. CONTINUE TO RINSE FOR AT LEAST 10
MINUTES. WASH CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION
DEVELOPS.
INHALATION:
MOVE EXPOSED PERSON TO FRESH AIR. IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT
DOES NOT ENTER THE LUNGS. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5. FIRE FIGHTING MEASURES | |
FLASH POINT:
CLOSED CUP: 62.7 DEG. C (145 DEG. F) (TAGLIABUE.)
FLAMMABLE LIMITS: NOT DETERMINED.
FLAMMABILITY: COMBUSTIBLE.
FIRE HAZARD:
COMBUSTIBLE LIQUID AND VAPOR. KEEP AWAY FROM HEAT, SPARKS AND FLAME. RAGS,
STEEL WOOL OR OTHER WASTES SOAKED WITH PRODUCT MAY SPONTANEOUSLY CATCH
FIRE IF IMPROPERLY DISCARDED.
FIRE-FIGHTING PROCEDURES:
USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM. FIRE-FIGHTERS SHOULD
WEAR APPROPRIATE PROTECTIVE EQUIPMENT. DO NOT RELEASE RUNOFF FROM FIRE TO
SEWERS OR WATERWAYS.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
1
2
0
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
SPILL CLEAN UP:
ELIMINATE ALL IGNITION SOURCES. PUT ON APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT (SEE SECTION 8). DILUTE WITH WATER AND MOP UP IF WATER-SOLUBLE
OR ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
| SECTION 7. HANDLING AND STORAGE | |
HANDLING:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). STORE
AND USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE.
IMMEDIATELY AFTER USE, PLACE RAGS, STEEL WOOL OR OTHER WASTE IN A SEALED,
WATER-FILLED METAL CONTAINER. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID BREATHING VAPORS, SPRAY OR MISTS. USE ONLY WITH ADEQUATE
VENTILATION. DO NOT INGEST. OBSERVE LABEL PRECAUTIONS. WASH THOROUGHLY
AFTER HANDLING. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE
HAZARDOUS. DO NOT REUSE CONTAINER.
STORAGE:
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT. AVOID ALL POSSIBLE SOURCES OF
IGNITION (SPARK OR FLAME). KEEP CONTAINER IN A COOL, WELL-VENTILATED AREA.
KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. KEEP AWAY
FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS. KEEP OUT OF THE REACH OF
CHILDREN.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRODUCT NAME:
EXPOSURE LIMITS: NO EXPOSURE LIMIT VALUE KNOWN.
PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYES: SAFETY GLASSES.
BODY: FOR PROLONGED OR REPEATED HANDLING, USE GLOVES.
RECOMMENDED: NEOPRENE GLOVES. NITRILE GLOVES. RUBBER GLOVES.
RESPIRATORY:
USE WITH ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS BELOW
THEIR RESPECTIVE OCCUPATIONAL EXPOSURE LIMITS.
SAFETY GLASSES
GLOVES
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID.
pH: NOT APPLICABLE
BOILING POINT: NOT DETERMINED.
SPECIFIC GRAVITY: 0.88
SOLUBILITY: EMULSIFIES IN WATER.
COLOR: CLEAR. ORANGE.
ODOR: CITRUS
VAPOR PRESSURE: 0.04 KPA (0.3 MMHg)
VAPOR DENSITY: >1 (AIR = 1)
EVAPORATION RATE: NOT DETERMINED.
VOC (CONSUMER):
202 (G/L).
1.68 LBS/GAL (23.0%)
| SECTION 10. STABILITY AND REACTIVITY | |
STABILITY AND REACTIVITY: THE PRODUCT IS STABLE.
INCOMPATIBILITY:
COMBUSTIBLE MATERIALS SHOULD BE STORED AWAY FROM EXTREME HEAT AND AWAY
FROM STRONG OXIDIZING AGENTS. INCOMPATIBLE WITH SOME STRONG ACIDS.
REACTIVE WITH ACIDIC CLAY (I.E. CLAY ABSORBENT) REACTIVE OR INCOMPATIBLE
WITH THE FOLLOWING MATERIALS: OXIDIZING MATERIALS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES
| SECTION 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
NONYLPHENOXYPOLY(ETHYLENEOXY) LD50 DERMAL RABBIT 2000 MG/KG
ETHANO LD50 ORAL RAT 3310 MG/KG
| SECTION 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL EFFECTS NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
AQUATIC ECOTOXICITY: NOT AVAILABLE.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
WASTE INFORMATION:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
ENVIRONMENTAL CONTROL REGULATIONS. CONSULT YOUR LOCAL OR REGIONAL
AUTHORITIES FOR ADDITIONAL INFORMATION.
WASTE STREAM:
CLASSIFICATION: (NON-HAZARDOUS WASTE)
| SECTION 14. TRANSPORT INFORMATION | |
REGULATORY UN NUMBER PROPER SHIPPING CLASSES PG* LABEL
INFORMATION NAME
DOT NOT APPLICABLE. NOT A DOT
CLASSIFICATION CONTROLLED
MATERIAL (UNITED
STATES).
IMDG CLASS NOT DETERMINED.
NOTE:
DOT CLASSIFICATION APPLIES TO MOST PACKAGE SIZES. FOR SPECIFIC CONTAINER
SIZE CLASSIFICATIONS OR FOR SIZE EXCEPTIONS, REFER TO THE BILL OF LADING
WITH YOUR SHIPMENT.
PG*: PACKING GROUP
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING:
NO PRODUCTS WERE FOUND.
CLEAN WATER ACT (CWA) 307: NO PRODUCTS WERE FOUND.
CLEAN WATER ACT (CWA) 311: NO PRODUCTS WERE FOUND.
CLEAN AIR ACT (CAA) 112 REGULATED TOXIC SUBSTANCES:
NO PRODUCTS WERE FOUND.
ALL COMPONENTS OF THIS PRODUCT ARE LISTED OR EXEMPT FROM LISTING ON TSCA
INVENTORY.
STATE REGULATIONS:
CALIFORNIA PROP 65: NO PRODUCTS WERE FOUND.
| SECTION 16. OTHER INFORMATION | |
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS
ACCURATE. HOWEVER, NEITHER THE ABOVE NAMED SUPPLIER NOR ANY OF ITS
SUBSIDIARIES ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR
COMPLETENESS OF THE INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED
HEREIN, WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
*NOTE:
HAZARD DETERMINATION SYSTEM (HDS) RATINGS ARE BASED ON A 0-4 RATING SCALE,
WITH 0 REPRESENTING MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING
SIGNIFICANT HAZARDS OR RISKS ALTHOUGH THESE RATINGS ARE NOT REQUIRED ON
MSDSS UNDER 29 CFR 1910.1200, THE PREPARER MAY CHOOSE TO PROVIDE THEM. HDS
RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED PROGRAM TO RELAY THE
MEANINGS OF THIS SCALE.