| Common Name: | COMET DEODORIZING CLEANSER WITH CHLORINOL (PROFESSIONAL LINE) |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 2/18/2010 |
| SDS Format: | No Format Specified |
| Item Number(s): | 19MG93, 3U557, 3WGY4, 9AMJ6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G
THE PROCTER & GAMBLE COMPANY
P&G PROFESSIONAL
FABRIC & HOME CARE INNOVATION CENTER
5299 SPRING GROVE AVENUE
CINCINNATI, OH 45217-1087
MATERIAL SAFETY DATA SHEET
MSDS #: RQ0908940
ISSUE DATE: FEBRUARY 18, 2010
SUPERSEDES: NEW
ISSUE DATE:
| SECTION I - CHEMICAL PRODUCT |  |
IDENTITY: DEODORIZING POWDER CLEANSER FINISHED PRODUCT
BRANDS: COMET DEODORIZING CLEANSER WITH CHLORINOL (PROFESSIONAL LINE)
EMERGENCY TELEPHONE NUMBER:
1-800-332-7787 OR CALL LOCAL POISON CONTROL CENTER
| SECTION II - HAZARDS IDENTIFICATION | |
HEALTH HAZARDS (ACUTE AND CHRONIC):
INGESTION: MILD MUCOUS MEMBRANE IRRITANT.
EYE CONTACT: MILD EYE IRRITANT.
SKIN: MILD SKIN IRRITANT.
INHALATION: MILD RESPIRATORY IRRITANT.
SIGNS AND SYMPTOMS OF EXPOSURE:
INGESTION:
MAY RESULT IN GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND
DIARRHEA.
EYE CONTACT:
DIRECT CONTACT WITH EYE MAY RESULT IN SUPERFICIAL, TEMPORARY IRRITATION
SIMILAR TO THOSE PRODUCED BY OTHER HOUSEHOLD DETERGENTS.
SKIN:
PROLONGED SKIN CONTACT OR DIRECT CONTACT WITH EYE MAY RESULT IN
SUPERFICIAL, TEMPORARY IRRITATION SIMILAR TO THOSE PRODUCED BY OTHER
HOUSEHOLD DETERGENTS.
INHALATION:
UNUSUALLY HIGH EXPOSURES MAY CAUSE COUGHING OR IRRITATION OF NOSE AND
THROAT.
| SECTION III - COMPOSITION AND INGREDIENTS | |
INGREDIENTS/CHEMICAL NAME:
CALCIUM CARBONATE (CAS # 1317-65-3); SODIUM CARBONATE (CAS # 497-19-8);
CALCIUM HYDROXIDE (CAS # 1305-62-0); SODIUM DICHLORO-S-TRIAZINETRIONE
DIHYDRATE (CAS # 2893-78-9), CONFIDENTIAL INGREDIENT (NJTSRN 370001001)
HAZARDOUS INGREDIENTS AS DEFINED BY OSHA, 29 CFR 1910.1200 AND/OR WHMIS
UNDER THE HPA.
CHEMICAL NAME COMMON NAME CAS NO. CONCENTRATION LD50
RANGE
CALCIUM CARBONATE LIMESTONE 1317-65-3 60-100% 6.5 G/KG
(ORAL, RATS)
CALCIUM HYDROXIDE HYDRATED 1305-62-0 1-1.5% N/A
LIME
SILICA, QUARTZ QUARTZ 14808-60-7 0.1-1% 9 G/KG
(NATURALLY
OCCURRING
COMPONENT
OF LIMESTONE)
| SECTION IV - FIRST AID INFORMATION | |
EMERGENCY AND FIRST AID PROCEDURES:
INGESTION: DILUTE WITH FLUIDS AND TREAT SYMPTOMATICALLY.
EYE CONTACT:
FOR ACCIDENTAL EYE CONTACT, HOLD EYE OPEN AND RINSE SLOWLY AND GENTLY WITH
WATER FOR 15-20 MINUTES. REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST
5 MINUTES, THEN CONTINUE RINSING EYE.
SKIN: WASH WITH SOAP AND WATER AND DISCONTINUE USE.
INHALATION:
FOR ACCIDENTAL, HIGH LEVEL INHALATION, REMOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF COUGHING PERSISTS.
OTHER:
PRODUCT PACKAGE HAS CAUTION STATEMENTS ON THE FRONT AND BACK PANEL:
FRONT PANEL: KEEP OUT OF REACH OF CHILDREN.
CAUTION:
MAY CAUSE EYE IRRITATION.
READ BACK PANEL CAREFULLY.
BACK PANEL:
CAUTION:
MAY CAUSE EYE IRRITATION. IN CASE OF CONTACT WITH EYE, FLUSH THOROUGHLY
WITH WATER. IF IRRITATION PERSISTS, SEE A PHYSICIAN. IF SWALLOWED, DRINK
A GLASS OF WATER TO DILUTE. FOR SENSITIVE SKIN OR PROLONGED CONTACT, WEAR
GLOVES.
| SECTION V - FIRE FIGHTING INFORMATION | |
FLASH POINT (METHOD USED): N/A
EXPLOSIVE LIMITS:
LEL: N/A
UEL: N/A
EXTINGUISHING MEDIA: USE CO2, WATER, OR DRY CHEMICAL.
SPECIAL FIRE FIGHTING PROCEDURES: NONE REQUIRED.
UNUSUAL FIRE HAZARDS: NONE KNOWN.
| SECTION VI - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
AVOID DUST FORMATION. USE VENTILATION TO MINIMIZE EXPOSURE TO HIGH LEVELS
OF AIRBORNE DUST. EXPOSURE TO HIGH LEVELS OF AIRBORNE DUST MAY REQUIRE
RESPIRATORY PROTECTION AS APPROVED BY LOCAL REGULATORY AGENCIES
(E.G., NIOSH).
ENVIRONMENTAL PRECAUTIONS:
DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS. PRODUCT CONTAINS BIODEGRADABLE SURFACTANT. SMALL (HOUSEHOLD)
QUANTITIES MAY BE DISPOSED OF VIA SEWER WITH LARGE QUANTITIES OF WATER.
DISCARD EMPTY CONTAINER IN TRASH.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
VACUUM TO REMOVE SPILL AND PLACE IN TRASH CONTAINER FOR DISPOSAL OR FLUSH
WITH WATER. DO NOT DRY SWEEP.
| SECTION VII - HANDLING AND STORAGE | |
PRECAUTIONS TO BE TAKEN IN HANDLING: AVOID DUST FORMATION.
PRECAUTIONS TO BE TAKEN IN STORAGE:
STORE IN COOL DRY PLACE WITH ADEQUATE VENTILATION.
| SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
INGREDIENT EXPOSURE LIMIT TYPE* EXPOSURE LIMIT REGULATORY
AGENCY
CALCIUM CARBONATE PEL (TOTAL DUST) 15 MG/M3 OSHA
(LIMESTONE) PEL (RESPIRABLE DUST) 5 MG/M3 OSHA
(CAS # 1317-65-3)
CALCIUM HYDROXIDE PEL 5 MG/M3 OSHA
(CAS # 1305-62-0) TLV-TWA 5 MG/M3 ACGIH
SILICA, QUARTZ TWA (TOTAL DUST) 0.3 MG/M3 OSHA
(CAS # 1808-60-7) TWA (RESPIRABLE) 0.1 MG/M3 OSHA
TWA ((ALPHA)-QUARTZ, 0.025 MG/M3 ACGIH
RESPIRABLE FRACTION)
ENGINEERING CONTROLS:
USE MECHANICAL VENTILATION (DILUTION AND LOCAL EXHAUST) TO CONTROL
EXPOSURE.
PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
NONE REQUIRED FOR NORMAL USE. AVOID CONTACT WITH EYES. WASH HANDS AFTER
HANDLING SHADES. IF EYE CONTACT OCCURS, RINSE WITH PLENTY OF WATER FOR
20 MINUTES.
INDUSTRIAL SETTING:
IF A SPLASH OF SOLUTION IS LIKELY, CHEMICAL GOGGLES MAY BE NEEDED.
SKIN PROTECTION: NONE REQUIRED FOR NORMAL USE.
INDUSTRIAL SETTING:
MINIMIZE PROLONGED SKIN CONTACT WITH PROTECTIVE GLOVES
(RUBBER OR NEOPRENE).
RESPIRATORY PROTECTION: NONE REQUIRED WITH NORMAL USE.
INDUSTRIAL SETTING:
USE VENTILATION TO MINIMIZE EXPOSURE TO HIGH LEVELS OF AIRBORNE DUST.
EXPOSURE TO HIGH LEVELS OF AIRBORNE DUST MAY REQUIRE RESPIRATORY PROTECTION
AS APPROVED BY LOCAL REGULATORY AGENCIES (E.G., NIOSH).
| SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT DEG. F: N/A
SPECIFIC GRAVITY @ 25 DEG. C (H2O=1): CA. 1
VAPOR PRESSURE (MMHg): N/A
PERCENT VOLATILE BY VOLUME (%): CA. 1
VAPOR DENSITY (AIR=1): N/A
EVAPORATION RATE (nBuOAc=1): N/A
ODOR THRESHOLD: N/A
FREEZING POINT: N/A
COEFFICIENT OF WATER/OIL DISTRIBUTION: N/A
pH (1% SOLUTION): 11.7 - 12.9
SCOOPED DENSITY: N/A
SOLUBILITY IN WATER: MODERATELY
APPEARANCE AND ODOR: GREEN POWDER, CEDAR PINE SCENT.
RESERVE ALKALINITY: N/A
| SECTION X - STABILITY AND REACTIVITY | |
POSSIBLE HAZARDOUS REACTIONS/CONDITIONS: NONE KNOWN
CONDITIONS TO AVOID: NONE.
MATERIALS TO AVOID: AMMONIA AND ACIDS
HAZARDOUS DECOMPOSITION PRODUCTS: CHLORINE GAS
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
OTHER RECOMMENDATIONS: NONE
| SECTION XI - TOXICOLOGICAL INFORMATION | |
CALCIUM CARBONATE, AN INGREDIENT OF THIS PRODUCT, CONTAINS SMALL AMOUNTS OF
CRYSTALLINE SILICA (QUARTZ) AS A NATURALLY OCCURRING IMPURITY. PROLONGED,
EXCESSIVELY HIGH EXPOSURES TO RESPIRABLE CRYSTALLINE SILICA MAY RESULT IN
REDUCED LUNG FUNCTION IN SOME INDIVIDUALS. IARC HAS FOUND SUFFICIENT
EVIDENCE TO CLASSIFY CRYSTALLINE SILICA AS A CARCINOGEN IN ANIMALS, BUT
THERE IS LIMITED EVIDENCE IN HUMANS.
LD50 (RATS ORAL): 9 G/KG
ED50: 0.23 G/KG
PRODUCT AS A WHOLE:
CARCINOGENICITY: NONE KNOWN
SENSITIZATION EFFECTS: NONE KNOWN
REPRODUCTIVE EFFECTS: NONE KNOWN
SYNERGISTIC EFFECTS: NONE KNOWN
| SECTION XII - ECOLOGICAL INFORMATION | |
THE PRODUCT IS INTENDED FOR WIDE DISPERSIVE USE AND IS COMPATIBLE WITH THE
DOWN-THE-DRAIN DISPOSAL ROUTE.
THE PRODUCT IS NOT CONSIDERED HARMFUL TO AQUATIC ORGANISMS NOR TO CAUSE
LONG-TERM ADVERSE EFFECTS IN THE ENVIRONMENT.
| SECTION XIII - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL, STATE/PROVINCIAL
AND LOCAL REGULATIONS. THE PRODUCT WASTE IS NOT CONSIDERED RCRA HAZARDOUS.
INDUSTRIAL SETTING:
INCINERATION IS PREFERRED. DO NOT LANDFILL LIQUIDS. DISCARD EMPTY CONTAINER
IN TRASH.
NON-HOUSEHOLD SETTING (FEDERAL):
PRODUCTS COVERED BY THIS MSDS, IN THEIR ORIGINAL FORM, WHEN DISPOSED AS
WASTE, ARE CONSIDERED NON HAZARDOUS WASTE ACCORDING TO FEDERAL RCRA
REGULATIONS (40 CFR 261). DISPOSAL SHOULD BE IN ACCORDANCE WITH LOCAL,
STATE AND FEDERAL REGULATIONS.
NON-HOUSEHOLD SETTING (CALIFORNIA):
HAZARDOUS, IN ACCORDANCE WITH 22 CCR 66261.20 THROUGH 22 CCR 66261.24.
| SECTION XIV - TRANSPORT INFORMATION | |
GROUND TRANSPORT (US DOT): NOT REGULATED.
AIR TRANSPORT (IATA): NOT REGULATED
MARINE/WATER TRANSPORT (IMDG): NOT REGULATED
| SECTION XV - ADDITIONAL REGULATORY INFORMATION | |
UNITED STATES:
ALL INTENTIONALLY-ADDED COMPONENTS OF THIS PRODUCT ARE LISTED ON THE US
TSCA INVENTORY.
EPA REGISTRATION NUMBER: NOT APPLICABLE
SARA 313/302/304/311/312 CHEMICALS: NONE.
CALIFORNIA:
THIS PRODUCT HAS BEEN EVALUATED AND DOES NOT REQUIRE WARNING LABELING UNDER
CALIFORNIA PROPOSITION 65.
CALIFORNIA REGISTRATION NUMBER: NOT APPLICABLE
STATE RIGHT-TO-KNOW AND CERCLA:
THE FOLLOWING INGREDIENTS PRESENT IN THIS FINISHED PRODUCT ARE LISTED ON
STATE RIGHT-TO-KNOW LISTS OR STATE WORKER EXPOSURE LISTS:
INGREDIENT CAS # CONCENTRATION CERCLA STATE
RANGE RQ IL MA NJ PA RI
CALCIUM CARBONATE 1317-65-3 60 - 100% X X
CALCIUM HYDROXIDE 1305-62-0 1 - 1.5% X X X X
SODIUM DICHOLO-S- 2893-78-9 1 - 1.5% X X X X
TRIAZINETRIONE
DIHYDRATE
CRYSTALLINE 14808-60-7 0.1 - 1% X X X
SILICA, QUARTZ
ALL INGREDIENTS ARE CEPA APPROVED FOR IMPORT TO CANADA BY PROCTER & GAMBLE.
THIS PRODUCT HAS BEEN CLASSIFIED WITH HAZARD CRITERIA OF THE CANADIAN
CONTROL PRODUCTS REGULATION (CPR) AND THIS MSDS CONTAINS ALL INFORMATION
REQUIRED BY THE CANADIAN PRODUCTS REGULATION.
| SECTION XVI - OTHER INFORMATION | |
PERFUMES CONTAINED WITHIN THE PRODUCTS COVERED BY THIS MSDS COMPLY WITH
APPROPRIATE IFRA GUIDANCE.
P&G HAZARD RATING:
HEALTH 1
FLAMMABILITY 0
REACTIVITY 0
4=EXTREME
3=HIGH
2=MODERATE
1=SLIGHT
0=NOT SIGNIFICANT
*N/A. - NOT APPLICABLE
*N/K. - NOT KNOWN
DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND
HEALTH.
THE SUBMISSION OF THIS MSDS MAY BE REQUIRED BY LAW, BUT THIS IS NOT AN
ASSERTION THAT THE SUBSTANCE IS HAZARDOUS WHEN USED IN ACCORDANCE WITH
PROPER SAFETY PRACTICES AND NORMAL HANDLING PROCEDURES. DATA SUPPLIED IS
FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH.
THE INFORMATION CONTAINED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED
BY PROCTER & GAMBLE TO BE DEPENDABLE AND IS ACCURATE TO THE BEST OF THE
COMPANY'S KNOWLEDGE. THE INFORMATION RELATES TO THE SPECIFIC MATERIAL
DESIGNATED HEREIN, AND DOES NOT RELATE TO THE USE IN COMBINATION WITH ANY
OTHER MATERIAL OR ANY OTHER PROCESS. PROCTER & GAMBLE ASSUMED NO
RESPONSIBILITY FOR INJURY TO THE RECIPIENT OR THIRD PERSONS, FOR ANY DAMAGE
TO ANY PROPERTY RESULTING FROM MISUSE OF THE CONTROLLED PRODUCT.