| Common Name: | AS-150 HAPS FREE TILE RED |
| Manufacturer: | ITW POLYMER TECHNOLOGIES |
| SDS Revision Date: | 2/23/2010 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3VYV8, 3VYX6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ITW POLYMER TECHNOLOGIES
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: AS-150 HAPS FREE TILE RED
MSDS MANUFACTURER NUMBER: AS120R
MANUFACTURER NAME: ITW POLYMER TECHNOLOGIES
ADDRESS:
130 COMMERCE DRIVE
MONTGOMERYVILLE, PA 18936
GENERAL PHONE NUMBER: (215) 855-8450
EMERGENCY PHONE NUMBER: (215) 855-8450
CHEMTREC:
FOR EMERGENCIES IN THE US, CALL CHEMTREC: 800-424-9300
CANUTEC:
IN CANADA, CALL CANUTEC: (613) 996-6666 (CALL COLLECT)
MSDS CREATION DATE: 2/23/2010
MSDS REVISION DATE: 2/23/2010
HMIS:
HEALTH HAZARD 1
FIRE HAZARD 2
REACTIVITY 1
PERSONAL PROTECTION X
* CHRONIC HEALTH EFFECTS
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS# INGREDIENT PERCENT
ALUMINUM OXIDE 1344-28-1 1 - 5 BY WEIGHT
NATURAL WOLLASTONITE 13983-17-0 1 - 5 BY WEIGHT
SILICA, CRYSTALLINE (QUARTZ) 14808-60-7 10 - 30 BY WEIGHT
NEPHELINE SYENITE 37244-96-5 10 - 30 BY WEIGHT
BENZENE, 1-CHLORO-4-(TRIFLUOROMETHYL)- 98-56-6 10 - 30 BY WEIGHT
ORGANICALLY MODIFIED SEPIOLITE NO DATA 10 - 30 BY WEIGHT
SOLVENT NAPHTHA, PETROLEUM, LIGHT 64742-95-6 1 - 5 BY WEIGHT
AROMATIC
TITANIUM DIOXIDE 13463-67-7 0.1 - 1 BY WEIGHT
| SECTION 3 - HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING!
COMBUSTIBLE. IRRITANT.
ROUTE OF EXPOSURE: EYES. SKIN. INHALATION. INGESTION.
POTENTIAL HEALTH EFFECTS:
EYE: MAY CAUSE IRRITATION.
SKIN: MAY CAUSE IRRITATION.
INHALATION:
PROLONGED OR EXCESSIVE INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION.
INGESTION: MAY BE HARMFUL IF SWALLOWED. MAY CAUSE VOMITING.
CHRONIC HEALTH EFFECTS:
PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION.
SIGNS/SYMPTOMS: OVEREXPOSURE MAY CAUSE HEADACHES AND DIZZINESS.
TARGET ORGANS:
EYES. SKIN. RESPIRATORY SYSTEM. DIGESTIVE SYSTEM. CENTRAL NERVOUS SYSTEM.
AGGRAVATION OF PRE-EXISTING CONDITIONS: NONE GENERALLY RECOGNIZED.
| SECTION 4 - FIRST AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 TO 20 MINUTES.
ENSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS WITH
FINGERS. GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH SKIN WITH PLENTY OF SOAP AND WATER FOR 15 TO 20 MINUTES,
WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION OR GIVE OXYGEN BY TRAINED PERSONNEL. SEEK IMMEDIATE MEDICAL
ATTENTION.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL
CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
OTHER FIRST AID:
DUE TO POSSIBLE ASPIRATION INTO THE LUNGS, DO NOT INDUCE VOMITING IF
INGESTED. PROVIDE A GLASS OF WATER TO DILUTE THE MATERIAL IN THE STOMACH.
IF VOMITING OCCURS NATURALLY, HAVE THE PERSON LEAN FORWARD TO REDUCE THE
RISK OF ASPIRATION.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLAMMABLE PROPERTIES: COMBUSTIBLE LIQUID.
FLASH POINT: 105 DEG. F
AUTO IGNITION TEMPERATURE: NOT DETERMINED.
LOWER FLAMMABLE/EXPLOSIVE LIMIT: NOT DETERMINED.
UPPER FLAMMABLE/EXPLOSIVE LIMIT: NOT DETERMINED.
FIRE FIGHTING INSTRUCTIONS:
EVACUATE AREA OF UNPROTECTED PERSONNEL. USE COLD WATER SPRAY TO COOL FIRE
EXPOSED CONTAINERS TO MINIMIZE RISK OF RUPTURE. DO NOT ENTER CONFINED FIRE
SPACE WITHOUT FULL PROTECTIVE GEAR. IF POSSIBLE, CONTAIN FIRE RUN-OFF
WATER.
EXTINGUISHING MEDIA:
USE CARBON DIOXIDE (CO2) OR DRY CHEMICAL WHEN FIGHTING FIRES INVOLVING
THIS MATERIAL.
PROTECTIVE EQUIPMENT:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA), MSHA/NIOSH
(APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
UNUSUAL FIRE HAZARDS:
SEALED CONTAINERS AT ELEVATED TEMPERATURES MAY RUPTURE EXPLOSIVELY AND
SPREAD FIRE DUE TO POLYMERIZATION. HEATING ABOVE 300 DEG F IN THE PRESENCE
OF AIR MAY CAUSE SLOW OXIDATIVE DECOMPOSITION AND ABOVE 500 DEG F MAY
CAUSE POLYMERIZATION.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONNEL PRECAUTIONS:
EVACUATE AREA AND KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING
THE SPILL AREA.
ENVIRONMENTAL PRECAUTIONS:
AVOID RUNOFF INTO STORM SEWERS, DITCHES, AND WATERWAYS.
SPILL CLEANUP MEASURES:
ABSORB SPILL WITH INERT MATERIAL (E,G., DRY SAND OR EARTH), THEN PLACE IN
A CHEMICAL WASTE CONTAINER. PROVIDE VENTILATION. COLLECT SPILL WITH A
NON-SPARKING TOOL. PLACE INTO A SUITABLE CONTAINER FOR DISPOSAL. CLEAN UP
SPILLS IMMEDIATELY OBSERVING PRECAUTIONS IN THE PROTECTIVE EQUIPMENT
SECTION. AFTER REMOVAL, FLUSH SPILL AREA WITH SOAP AND WATER TO REMOVE
TRACE RESIDUE.
FLAMMABLE, ELIMINATE IGNITION SOURCES. VAPORS CAN FORM AN IGNITABLE
MIXTURE WITH AIR. VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION
SOURCES AND FLASH BACK. VENTILATE AREA. USE PROPER PERSONAL PROTECTIVE
EQUIPMENT AS LISTED IN SECTION 8.
OTHER PRECAUTIONS: PUMP OR SHOVEL TO STORAGE/SALVAGE VESSELS.
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING:
USE WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR, AEROSOL OR MIST.
MATERIAL WILL ACCUMULATE STATIC CHARGES WHICH MAY CAUSE AN ELECTRICAL
SPARK (IGNITION SOURCE). USE PROPER GROUNDING PROCEDURES. DO NOT REUSE
CONTAINERS WITHOUT PROPER CLEANING OR RECONDITIONING.
STORAGE:
STORE IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM SOURCES OF HEAT,
COMBUSTIBLE MATERIALS, DIRECT SUNLIGHT, AND INCOMPATIBLE SUBSTANCES. KEEP
CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
SPECIAL HANDLING PROCEDURES:
HAZARDOUS LIQUID OR VAPOR RESIDUE MAY REMAIN IN EMPTIED CONTAINER. DO NOT
REUSE, HEAT, BURN, PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND,
EXPOSE TO SPARKS, FLAME, OR IGNITION SOURCES OF EMPTY CONTAINERS WITHOUT
PROPER COMMERCIAL CLEANING OR RECONDITIONING.
HYGIENE PRACTICES: WASH THOROUGHLY AFTER HANDLING.
| SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE | |
GUIDELINES
ENGINEERING CONTROLS:
USE APPROPRIATE ENGINEERING CONTROL SUCH AS PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. GOOD GENERAL VENTILATION SHOULD
BE SUFFICIENT TO CONTROL AIRBORNE LEVELS. WHERE SUCH SYSTEMS ARE NOT
EFFECTIVE WEAR SUITABLE PERSONAL PROTECTIVE EQUIPMENT, WHICH PERFORMS
SATISFACTORILY AND MEETS OSHA OR OTHER RECOGNIZED STANDARDS. CONSULT WITH
LOCAL PROCEDURES FOR SELECTION, TRAINING, INSPECTION AND MAINTENANCE OF
THE PERSONAL PROTECTIVE EQUIPMENT.
EYE/FACE PROTECTION:
WEAR APPROPRIATE PROTECTIVE GLASSES OR SPLASH GOGGLES AS DESCRIBED BY 29
CFR 1910.133, OSHA EYE AND FACE PROTECTION REGULATION, OR THE EUROPEAN
STANDARD EN 166.
SKIN PROTECTION DESCRIPTION:
WEAR APPROPRIATE PROTECTIVE GLOVES AND OTHER PROTECTIVE APPAREL TO PREVENT
SKIN CONTACT. CONSULT MANUFACTURER'S DATA FOR PERMEABILITY DATA.
RESPIRATORY PROTECTION:
A NIOSH APPROVED AIR-PURIFYING RESPIRATOR WITH AN ORGANIC VAPOR CARTRIDGE
OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE
CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS. PROTECTION PROVIDED
BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN UNCONTROLLED RELEASE,
EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER CIRCUMSTANCES WHERE AIR
PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION.
OTHER PROTECTIVE:
FACILITIES STORING OR UTILIZING THIS MATERIAL SHOULD BE EQUIPPED WITH AN
EYEWASH AND A DELUGE SHOWER SAFETY STATION.
EXPOSURE GUIDELINES:
ALUMINUM OXIDE:
GUIDELINE ACGIH: 10 MG/M3
TLV-TWA: 10 MG/M3
GUIDELINE OSHA: 5 MG/M3
PEL-TWA: 15 MG/M3 TOTAL PARTICULATE/DUST (T)
PEL-TWA: 5 MG/M3 RESPIRABLE FRACTION (R)
SILICA, CRYSTALLINE (QUARTZ):
GUIDELINE ACGIH: 0.025 MG/M3
TLV-TWA: 0.025 MG/M3 RESPIRABLE FRACTION (R)
GUIDELINE OSHA: (10 MG/M3)/((% SiO2) +2)
SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC:
GUIDELINE ACGIH: 0.1 F/CC (FIBEROUS FORM)
TLV-TWA: 0.1 F/CC RESPIRABLE FRACTION (R)
TLV-TWA: 10 MG/M3 INHALABLE FRACTION (I)
TLV-TWA: 3 MG/M3 RESPIRABLE FRACTION (R)
GUIDELINE OSHA: 15 MG/M3
PEL-TWA: 15 MG/M3 TOTAL PARTICULATE/DUST (T)
PEL-TWA: 5 MG/M3 RESPIRABLE FRACTION (R)
TITANIUM DIOXIDE:
GUIDELINE ACGIH: 10 MG/M3
TLV-TWA: 10 MG/M3
NOTES: ONLY ESTABLISHED PEL AND TLV VALUES FOR THE INGREDIENTS ARE LISTED.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE APPEARANCE: LIQUID.
COLOR: GREEN
BOILING POINT: >240 DEG. F
MELTING POINT: NOT DETERMINED.
VAPOR DENSITY: 3.7
VAPOR PRESSURE: 8 MMHg
EVAPORATION RATE: 0.7
pH: NOT DETERMINED.
MOLECULAR FORMULA: MIXTURE
MOLECULAR WEIGHT: MIXTURE
FLASH POINT: 105 DEG. F
AUTO IGNITION TEMPERATURE: NOT DETERMINED.
VOC CONTENT: 0.82 LBS/GAL (98 G/L)
| SECTION 10 - STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
HAZARDOUS POLYMERIZATION: NOT REPORTED.
CONDITIONS TO AVOID:
EXTREME HEAT, SPARKS, AND OPEN FLAME. INCOMPATIBLE MATERIALS, OXIDIZERS
AND OXIDIZING CONDITIONS.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. STRONG ACIDS AND ALKALIS.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
ALUMINUM OXIDE:
RTECS NUMBER: BD1200000
SKIN:
INTRAPERITONEAL. - MOUSE LD50:
>3600 MG/KG (DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE.)
RTECS NUMBER: ZC9750000
SILICA, CRYSTALLINE (QUARTZ):
RTECS NUMBER: VV7330000
CARCINOGENICITY:
IARC:
GROUP 1: CARCINOGENIC TO HUMANS.
NTP: REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
RTECS NUMBER: QP9365000
BENZENE, 1-CHLORO-4-(TRIFLUOROMETHYL)-:
RTECS NUMBER: VV7328000
SKIN:
ORAL - RAT LD50:
13 GM/KG (DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE.)
ORAL - MOUSE LD50:
11500 MG/KG (DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE.)
INHALATION:
INHALATION - RAT LC50:
22 GM/M3 (DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE.)
INHALATION - MOUSE LC50:
20 GM/M3 (DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE.)
INGESTION:
ORAL - RAT LD50:
13 GM/KG (DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE.)
ORAL - MOUSE LD50:
11500 MG/KG (DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE.)
RTECS NUMBER: LK3651000
SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC:
RTECS NUMBER: VW0450000
EYE:
EYE - RABBIT STANDARD DRAIZE TEST.: 100 (MICRO)L/24H (MILD)
SKIN:
ORAL - RAT LD50:
8400 MG/KG (BEHAVIORAL - SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL - TREMOR LUNGS, THORAX, OR RESPIRATION - OTHER CHANGES)
INGESTION:
ORAL - RAT LD50:
8400 MG/KG (BEHAVIORAL - SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL - TREMOR LUNGS, THORAX, OR RESPIRATION - OTHER CHANGES)
TITANIUM DIOXIDE:
RTECS NUMBER: XR2275000
CARCINOGENICITY:
IARC:
GROUP 2B: POSSIBLY CARCINOGENIC TO HUMANS.
NTP: REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICITY: NO ECOTOXICITY DATA WAS FOUND FOR THE PRODUCT.
ENVIRONMENTAL FATE: NO ENVIRONMENTAL INFORMATION FOUND FOR THIS PRODUCT.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL:
CONSULT WITH THE US EPA GUIDELINES LISTED IN 40 CFR PART 261.3 FOR THE
CLASSIFICATIONS OF HAZARDOUS WASTE PRIOR TO DISPOSAL. FURTHERMORE, CONSULT
WITH YOUR STATE AND LOCAL WASTE REQUIREMENTS OR GUIDELINES, IF APPLICABLE,
TO ENSURE COMPLIANCE. ARRANGE DISPOSAL IN ACCORDANCE TO THE EPA AND/OR
STATE AND LOCAL GUIDELINES.
RCRA NUMBER: D001
IMPORTANT DISPOSAL INFORMATION:
DANGER!
RAGS, STEEL WOOL AND WASTE SOAKED WITH THIS PRODUCT MAY SPONTANEOUSLY
CATCH FIRE IF IMPROPERLY DISCARDED OR STORED. TO AVOID A SPONTANEOUS
COMBUSTION FIRE, IMMEDIATELY AFTER USE, PLACE RAGS, STEEL WOOL OR WASTE IN
A SEALED, WATER-FILLED, METAL CONTAINER.
| SECTION 14 - TRANSPORT INFORMATION | |
DOT SHIPPING NAME: PAINT
DOT UN NUMBER: UN1263
DOT HAZARD CLASS: 3
DOT PACKING GROUP: III
| SECTION 15 - REGULATORY INFORMATION | |
ALUMINUM OXIDE:
TSCA INVENTORY STATUS: LISTED
SARA:
EPCRA - 40 CFR PART 372 - (SARA TITLE III) SECTION 313 LISTED CHEMICAL.
NEW JERSEY:
LISTED: NJ HAZARDOUS LIST
SUBSTANCE NUMBER: 2891
MASSACHUSETTS: LISTED
PENNSYLVANIA: LISTED
CANADA DSL: LISTED
SILICA, CRYSTALLINE (QUARTZ):
TSCA INVENTORY STATUS: LISTED
MASSACHUSETTS: LISTED
PENNSYLVANIA: LISTED
CANADA DSL: LISTED
NEPHELINE SYENITE:
CANADA DSL: LISTED
BENZENE, 1-CHLORO-4-(TRIFLUOROMETHYL)-:
TSCA INVENTORY STATUS: LISTED
CANADA DSL: LISTED
SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC:
TSCA INVENTORY STATUS: LISTED
CANADA DSL: LISTED
TITANIUM DIOXIDE:
TSCA INVENTORY STATUS: LISTED
MASSACHUSETTS: LISTED
PENNSYLVANIA: LISTED
CANADA DSL: LISTED
CANADIAN REGULATIONS.:
WHMIS HAZARD CLASS(ES): B2
ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DOMESTIC SUBSTANCES
LIST.
WHMIS PICTOGRAMS:
B - FLAMMABLE AND COMBUSTIBLE MATERIAL
| SECTION 16 - ADDITIONAL INFORMATION | |
HMIS HEALTH HAZARD 1
HMIS FIRE HAZARD 2
HMIS REACTIVITY 1
HMIS PERSONAL PROTECTION X
MSDS CREATION DATE: 2/23/2010
MSDS REVISION DATE: 2/23/2010
MSDS AUTHOR: ACTIO CORPORATION
DISCLAIMER:
THIS HEALTH AND SAFETY INFORMATION IS CORRECT TO THE BEST OF OUR KNOWLEDGE
AND BELIEF AT THE DATE OF ITS PUBLICATION BUT WE CANNOT ACCEPT LIABILITY
FOR ANY LOSS, INJURY OR DAMAGE WHICH MAY RESULT FROM ITS USE. THE
INFORMATION GIVEN IN THE DATA SHEET IS DESIGNED ONLY AS A GUIDANCE FOR
SAFE HANDLING, STORAGE AND THE USE OF THE SUBSTANCE. IT IS NOT A
SPECIFICATION NOR DOES IT GUARANTEE ANY SPECIFIC PROPERTIES. ALL CHEMICALS
SHOULD BE HANDLED ONLY BY COMPETENT PERSONNEL, WITHIN A CONTROLLED
ENVIRONMENT.
COPYRIGHT(C) 1996-2010 ACTIO SOFTWARE CORPORATION. ALL RIGHTS RESERVED.
VERSION: 0.0000