| Common Name: | SUPREME GOLD 5W30, UNITED HEAT SHIELD 20W-50 HYDRAULIC, RED LITHIUM COMPLEX 9312 |
| Manufacturer: | U.S. OIL |
| SDS Revision Date: | 6/16/2009 |
| SDS Format: | No Format Specified |
| Item Number(s): | 5TXN7, 5TXN8, 5TXN9, 5TXP0, 5TXP1, 5TXP2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
PRODUCT TRADE NAME: SUPREME GOLD 5W30
PRODUCT NO.: 055
REVISION NUMBER: 2099
U.S. OIL CO., INC.
LUBRICANTS DIVISION
425 S. WASHINGTON ST.
COMBINED LOCKS, WI 54113
PHONE: 920-735-8298
EMERGENCY PHONE #: (920)-735-8298
PREPARATION/REVISION DATE: 06/16/09
REVISED FROM (DATE): 04/15/09
NFPA CODE:
HEALTH 1
FIRE 1
REACTIVITY 0
HMIS CODE:
HEALTH 1
FIRE 1
REACTIVITY 0
| SECTION 1 - HAZARDOUS INGREDIENTS |  |
THIS MATERIAL IS NOT KNOWN TO CONTAIN GREATER THAN 0.1% OF ANY CARCINOGEN
REQUIRED TO BE LISTED UNDER THE OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200).
COMPONENT CAS # OSHA PEL ACGIH TLV
HYDROTREATED HEAVY PARAFFINIC 64742-54-7 5 MG/M3 5 MG/M3
DISTILLATE
ZINC DIALKYL DITHIOPHOSPHATE 68649-42-3 N.E. N.E.
1-DODECENE HOMOPOLYMER 151006-63-2 N.E. N.E.
| SECTION 2 - FIRE AND EXPLOSION HAZARDs | |
FLASH POINT: 405 DEG. F
UPPER FLAMMABLE LIMIT: 10% (ESTIMATED VALUE)
LOWER FLAMMABLE LIMIT: 1% (ESTIMATED VALUE)
EXTINGUISHING MEDIA: CO2, DRY CHEMICAL, FOAM, WATER SPRAY, WATER FOG
SPECIAL FIRE FIGHTING PROCEDURES:
WEAR SELF CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE. COOL EXPOSED
CONTAINERS WITH WATER SPRAY. AVOID BREATHING FUMES.
UNUSUAL FIRE & EXPLOSION HAZARDS:
TOXIC FUMES MAY BE EVOLVED ON BURNING OR EXPOSURE TO HEAT. PRESSURE MAY
INCREASE IN OVERHEATED CLOSED CONTAINERS. STORE BELOW 120 DEG. F.
| SECTION 3 - HEALTH HAZARD DATA | |
ACUTE EXPOSURE:
ORAL TOXICITY:
THE LD50 IN RATS IS >5000 MG/KG. BASED ON DATA FROM COMPONENTS OR SIMILAR
MATERIALS.
EYE IRRITATION:
EYE IRRITANT. BASED ON DATA FROM COMPONENTS OR SIMILAR MATERIAL.
SKIN IRRITATION:
NOT EXPECTED TO BE A PRIMARY SKIN IRRITANT. BASED ON DATA FROM COMPONENTS
OR SIMILAR MATERIALS. PROLONGED OR REPEATED SKIN CONTACT AS FROM CLOTHING
WET WITH MATERIAL MAY CAUSE DERMATITIS. SYMPTOMS MAY INCLUDE REDNESS,
EDEMA, DRYING, DEFATTING AND CRACKING OF THE SKIN.
DERMAL TOXICITY:
THE LD50 IN RABBITS IS >2000 MG/KG. BASED ON DATA FROM COMPONENTS OR
SIMILAR MATERIALS.
INHALATION TOXICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR COMPONENTS MAY BE A TOXIC
INHALATION HAZARD.
RESPIRATORY IRRITATION:
IF MATERIAL IS MISTED OR IF VAPORS ARE GENERATED FROM HEATING, EXPOSURE
MAY CAUSE IRRITATION OF MUCOUS MEMBRANES AND THE UPPER RESPIRATORY TRACT
SIMILAR TO THAT OBSERVED WITH MINERAL OIL. BASED ON DATA FROM COMPONENTS
OR SIMILAR MATERIALS. UNDER GOOD INDUSTRIAL HYGIENE PRACTICES WHERE ALL
EXPOSURE LIMITS ARE OBSERVED RESPIRATORY IRRITATION SHOULD NOT BE A
PROBLEM.
DERMAL SENSITIZATION:
NO DATA AVAILABLE TO INDICATE PRODUCT OR COMPONENTS MAY BE A SKIN
SENSITIZER.
INHALATION SENSITIZATION:
NO DATA AVAILABLE TO INDICATE PRODUCT OR COMPONENTS MAY BE A RESPIRATORY
SENSITIZER.
CHRONIC EXPOSURE:
CHRONIC TOXICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR COMPONENTS PRESENT AT GREATER
THAN 1% ARE CHRONIC HEALTH HAZARDS.
CARCINOGENICITY:
NO DATA AVAILABLE TO INDICATE ANY COMPONENTS PRESENT AT GREATER THAN 0.1%
MAY PRESENT A CARCINOGENIC HAZARD.
MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
REPRODUCTIVE TOXICITY:
NO DATA AVAILABLE TO INDICATE EITHER PRODUCT OR COMPONENTS PRESENT AT
GREATER THAN 0.1% THAT MAY CAUSE REPRODUCTIVE TOXICITY.
TERATOGENICITY:
NO DATA AVAILABLE TO INDICATE EITHER PRODUCT OR COMPONENTS CONTAINED AT
GREATER THAN 0.1% MAY CAUSE BIRTH DEFECTS.
REPRODUCTIVE TOXICITY:
NO DATA AVAILABLE TO INDICATE EITHER PRODUCT OR COMPONENTS PRESENT AT
GREATER THAN 0.1% THAT MAY CAUSE REPRODUCTIVE TOXICITY.
ADDITIONAL INFORMATION:
OTHER: NO OTHER HEALTH HAZARDS KNOWN.
EXPOSURE LIMITS:
SEE HAZARDOUS INGREDIENTS SECTION FOR ANY APPLICABLE EXPOSURE LIMITS FOR
COMPONENTS.
| SECTION 3A - EMERGENCY FIRST AID PROCEDURES | |
SKIN:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS.
LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
EYE:
FLUSH WITH WATER AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF EYE
IRRITATION DEVELOPS OR PERSISTS.
INHALATION:
REMOVE EXPOSED PERSON TO FRESH AIR IF ADVERSE EFFECTS ARE OBSERVED.
ORAL:
DO NOT INDUCE VOMITING!
IF CONSCIOUS, GIVE 2 GLASSES OF WATER. GET IMMEDIATE MEDICAL ATTENTION.
ADDITIONAL:
NOTE TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| SECTION 4 - SPECIAL PROTECTION INFORMATION | |
VENTILATION PROCEDURE: USE LOCAL EXHAUST VENTILATION TO CONTROL DUST.
GLOVE PROTECTION: NEOPRENE OR NITRILE GLOVES RECOMMENDED.
EYE PROTECTION: SAFETY GLASSES RECOMMENDED.
RESPIRATORY PROTECTION:
NORMALLY NOT REQUIRED, MASK OR RESPIRATOR FOR MISTS.
CLOTHING RECOMMENDATION:
AS NEEDED TO PREVENT REPEATED OR PROLONGED CONTACT.
| SECTION 5 - PHYSICAL DATA | |
VAPOR PRESSURE: LESS THAN 0.01 MMHg @ 20 DEG. C
pH: ESSENTIALLY NEUTRAL
SPECIFIC GRAVITY: 0.86
LB/GAL: 7.16
WATER SOLUBILITY: INSOLUBLE
PERCENT VOLATILE:
NEGLIGIBLE FROM OPEN CONTAINER IN 4 HOURS @ 38 DEG. C (100 DEG. F)
VAPOR DENSITY: GREATER THAN 1 (AIR = 1)
EVAPORATION RATE:
LESS THAN 0.01 (@ 1 ATM AND 25 DEG. C. n-BUTYL ACETATE = 1)
ODOR: MILD PETROLEUM OIL LIKE
APPEARANCE: AMBER VISCOUS LIQUID
VISCOSITY: 10.0 - 11.0 CST @ 100 DEG. C
POUR POINT: -25 DEG. F
| SECTION 6 - STABILITY | |
STABILITY: STABLE
INCOMPATIBILITY: OXIDIZING AGENTS AND ACIDS.
POLYMERIZATION: WILL NOT OCCUR.
THERMAL DECOMPOSITION:
SMOKE, CARBON MONOXIDE, ALDEHYDES AND OTHER PRODUCTS OF INCOMPLETE
COMBUSTION.
HYDROGEN SULFIDE AND ALKYL MERCAPTANS AND SULFIDES MAY ALSO BE RELEASED,
UNDER COMBUSTION CONDITIONS, OXIDES OF THE FOLLOWING ELEMENTS WILL BE
FORMED: SULFUR, ZINC, AND METHYL METHACRYLATE.
| SECTION 7 - SPILL OR LEAK PROCEDURES | |
SPILL PROCEDURES:
PREVENT ENTRY INTO SEWERS AND WATERWAYS. PICK UP FREE LIQUID FOR RECYCLE
OR DISPOSAL. ABSORB SMALL AMOUNTS AN INERT MATERIAL.
WASTE DISPOSAL:
IF DISPOSED OF, THIS MATERIAL IS BELIEVED TO BE HAZARDOUS WASTE UNDER RCRA
DUE TO TOXICITY. WASTE MANAGEMENT SHOULD BE IN COMPLIANCE WITH FEDERAL,
STATE, AND LOCAL LAWS.
| SECTION 8 - SPECIAL PRECAUTIONS | |
SPECIAL PRECAUTIONS:
KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO NOT HANDLE OR STORE NEAR HIGH
HEAT OR FLAMES. AVOID BREATHING OIL MISTS, WASH SKIN THOROUGHLY WITH SOAP
AND WATER AFTER HANDLING.
| SECTION 9 - TRANSPORTATION AND OSHA LABELING INFORMATION | |
TRANSPORTATION INCIDENT INFORMATION:
FOR FURTHER INFORMATION RELATIVE TO SPILLS RESULTING FROM TRANSPORTATION
INCIDENTS, REFER TO LATEST DEPARTMENT OF TRANSPORTATION EMERGENCY RESPONSE
GUIDEBOOK FOR HAZARDOUS MATERIALS INCIDENTS.
U.S. DOT HAZARDOUS MATERIALS SHIPPING DESCRIPTION: NOT REGULATED.
OSHA REQUIRED LABEL INFORMATION:
IN COMPLIANCE WITH HAZARD AND RIGHT-TO-KNOW REQUIREMENTS, WHERE APPLICABLE
OSHA HAZARD WARNINGS MAY BE FOUND ON THE LABEL, BILL OF LADING OR INVOICE
ACCOMPANYING THIS SHIPMENT.
THE INFORMATION PRESENTED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED
TO BE DEPENDABLE AND IS ACCURATE TO THE BEST OF SELLER'S KNOWLEDGE,
HOWEVER, SELLER MAKES NO WARRANTY WHATSOEVER, EXPRESSED, IMPLIED OR OF
MERCHANTABILITY REGARDING THE ACCURACY OF SUCH DATA OR THE RESULTS TO BE
OBTAINED FROM THE USE THEREOF, SELLER ASSUMES NO RESPONSIBILITY FOR INJURY
TO BUYER OR TO THIRD PERSONS OR FOR ANY DAMAGE TO ANY PROPERTY AND BUYER
ASSUMES ALL SUCH RISKS.
N.A. = NOT APPLICABLE
N.D. = NOT DETERMINE
N.E. = NONE ESTABLISHED
MATERIAL SAFETY DATA SHEET
GROWMARK, INC.
2200 SOUTH AVENUE
COUNCIL BLUFFS, IA 51503
EMERGENCY TELEPHONE NUMBER: 1-(800)-798-6457
UPDATED: JANUARY 27, 2009
| I. PRODUCT IDENTIFICATION | |
OLD CODE: 3029
PRODUCT NAME: UNITED HEAT SHIELD 20W-50 HYDRAULIC
CHEMICAL NAME: LUBRICATING OIL
CHEMICAL FAMILY: PETROLEUM HYDROCARBON
TRADE NAMES: GROWMARK, INC., HYDE, NOURSE, TRACTO, EN-O-CO (ENOCO)
| II. TYPICAL CHEMICAL AND PHYSICAL PROPERTIES | |
VAPOR PRESSURE (MMHg): NIL
VAPOR DENSITY (AIR=1): NIL
SOLUBILITY (IN WATER): NIL
MELTING POINT: NA
SPECIFIC GRAVITY (H2O=1): .86 - .94
BOILING POINT DEG. F (DEG. C): GREATER THAN 680 DEG. F (360 DEG. C)
EVAPORATION RATE: SLOWER THAN n-BUTYL ACETATE
APPEARANCE AND ODOR: AMBER LIQUID, SLIGHT HYDROCARBON ODOR
| III. HAZARDOUS COMPONENTS | |
COMPONENT CAS WT - % ACGIH TLV OSHA PEL STEL
HIGHLY REFINED 64742-65-0 80-95 5 MG/M3 5 MG/M3 10 MG/M3
PETROLEUM OIL
ZINC 25103-54-2 0.10-1.50 NO LIMITS
DIALKYL- ESTABLISHED
DITHIOPHOSPHATE
| IV. FIRE AND EXPLOSION HAZARD DATA | |
FLAMMABILITY CLASS:
NFPA 704=1
NFPA 30=III-B COMBUSTIBLE
FLASH POINT DEG. F (DEG. C):
370 DEG. F (188 DEG. C)
455 DEG. F (235 DEG. C) (COC)
LEL: N/AV
EXTINGUISHING MEDIA:
ACCORDING TO THE NFPA GUIDE, USE WATER FOG. FOAM. DRY CHEMICAL OR CO2. DO
NOT USE A DIRECT STREAM OF WATER. PRODUCT WILL FLOAT AND CAN BE REIGNITED
ON THE SURFACE OF WATER. USE WATER TO COOL CONTAINERS
SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS:
MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE-SPACE
WITHOUT PROPER PROTECTIVE EQUIPMENT INCLUDING A POSITIVE-PRESSURE NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS. USE WATER TO KEEP FIRE
EXPOSED CONTAINERS COOL.
| V. REACTIVITY DATA | |
STABILITY (THERMAL, LIGHT, ETC.): STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
INCOMPATABILITY (MATERIALS TO AVOID): STRONG OXIDIZERS
CONDITIONS TO AVOID: EXTREME HEAT
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE
| VI. HEALTH HAZARD DATA | |
EYE CONTACT:
LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN MINIMALLY
IRRITATING TO THE EYES.
SKIN CONTACT:
BRIEF CONTACT IS NOT IRRITATING. LUBRICATING OILS ARE GENERALLY CONSIDERED
NO MORE THAN MILDLY IRRITATING TO THE SKIN. BECAUSE OF ITS DEFATTING
PROPERTIES, PROLONGED AND REPEATED CONTACT MAY AGGRAVATE AN EXISTING OR
RESULT IN VARIOUS SKIN DISORDERS (DERMATITIS, FOLLICULITIS, ETC.)
INHALATION:
INHALATION OF VAPOR OR OIL MIST (GENERATED AT HIGH TEMPERATURES) MAY
RESULT IN MILD IRRITATION OF THE UPPER RESPIRATORY TRACT, INCLUDING
IRRITATION OF THE NOSE AND THROAT, HEADACHE, NAUSEA AND DROWSINESS.
INGESTION:
NO ADVERSE EFFECTS EXPECTED. IF MORE THAN SEVERAL MOUTHFULS ARE SWALLOWED,
ABDOMINAL DISCOMFORT, NAUSEA AND DIARRHEA MAY OCCUR.
| VII. EMERGENCY AND FIRST AID PROCEDURES | |
EYE CONTACT:
FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. IF IRRITATION
OCCURS, SEEK MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND WIPE OFF EXCESS. WASH WITH PLENTY OF SOAP
AND WATER OR A WATERLESS HAND CLEANER FOLLOWED BY SOAP AND WATER. IF
IRRITATION OCCURS, SEEK MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR. IF BREATHING IS DIFFICULT, PROVIDE RESPIRATORY
SUPPORT, AND SEEK MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. DRINK WATER. IF UNCOMFORTABLE, SEEK MEDICAL
ATTENTION.
| VIII. ENVIRONMENTAL PROTECTION AND ACCIDENTAL RELEASE | |
SPILL OR LEAK PROCEDURE:
STOP SOURCE OF LEAK IF POSSIBLE. DIKE AND CONTAIN SPILL. REMOVE WITH
VACUUM TRUCKS OR PUMP TO STORAGE SALVAGE VESSELS. SOAK UP RESIDUE WITH
ABSORBENT SUCH AS CLAY, SAND, ETC. DISPOSE OF IN ACCORDANCE WITH CURRENT
APPLICABLE LAWS AND REGULATIONS.
| IX. EMPLOYEE PROTECTION | |
EYE / FACE PROTECTION:
CHEMICAL - TYPE GOGGLES OR FACE SHIELD IS RECOMMENDED TO PREVENT EYE
CONTACT.
RESPIRATORY PROTECTION:
NO SPECIAL REQUIREMENTS UNDER ORDINARY CONDITIONS OF USE AND WITH ADEQUATE
VENTILATION. IF CONCENTRATION EXCEEDS OCCUPATIONAL EXPOSURE LIMITS
(SECTION III.) USE A NIOSH APPROVED RESPIRATOR.
PROTECTIVE CLOTHING:
NORMAL INDUSTRIAL EYE PROTECTION, GLOVES, AND OTHER PROTECTIVE CLOTHING AS
REQUIRED TO MINIMIZE CONTACT WITH EYES AND SKIN.
VENTILATION: ADEQUATE TO MEET COMPONENT OCCUPATIONAL EXPOSURE LIMITS.
EXPOSURE LIMIT FOR TOTAL PRODUCT: NONE ESTABLISHED FOR THIS PRODUCT.
| X. TOXICOLOGICAL INFORMATION | |
MEDIAN LETHAL DOSE (LD50 LC50) (SPECIES):
ORAL: BELIEVED TO BE >5 G/KG (RAT); PRACTICALLY NON-TOXIC
INHALATION: N.D.
DERMAL: BELIEVED TO BE >5 G/KG (RABBIT); NO APPRECIABLE EFFECT
IRRITATION INDEX, ESTIMATE OF IRRITATION (SPECIES):
SKIN: BELIEVED TO BE <0.5 / 8.0 (RABBIT); NO APPRECIABLE EFFECT
EYES: BELIEVED TO BE <15 / 110 (RABBIT); NO APPRECIABLE EFFECT
SENSITIZATION: N.D.
OTHER:
THIS PRODUCT AND ITS COMPONENTS ARE NOT CLASSIFIED AS CARCINOGENS BY THE
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) OR OSHA. USED GASOLINE
MOTOR OILS HAVE BEEN SHOWN TO CAUSE SKIN CANCER WHEN REPEATEDLY APPLIED TO
MOUSE SKIN WITHOUT ANY EFFORT TO REMOVE THE MATERIAL BETWEEN APPLICATIONS.
THERE IS NO EVIDENCE OF A CAUSAL RELATIONSHIP BETWEEN SKIN CANCER IN
HUMANS AND EXPOSURE TO USED MOTOR OIL.
| XI. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHODS:
THIS PRODUCT HAS BEEN EVALUATED FOR RCRA CHARACTERISTICS AND DOES NOT MEET
THE CRITERIA OF A HAZARDOUS WASTE IF DISCARDED IN ITS PURCHASED FORM.
UNDER RCRA, IT IS THE RESPONSIBILITY OF THE USER OF THE PRODUCT TO
DETERMINE AT THE TIME OF DISPOSAL, WHETHER THE PRODUCT MEETS RCRA CRITERIA
FOR HAZARDOUS WASTE. THIS IS BECAUSE PRODUCT USES, TRANSFORMATIONS,
MIXTURES, PROCESSES, ETC. MAY RENDER THE RESULTING MATERIALS HAZARDOUS.
REMARKS:
RECYCLE ALL USED OILS. RECYCLING USED OILS MAY PROVIDE EXEMPTIONS RELATED
TO HAZARDOUS WASTE REGULATIONS.
| XII. TRANSPORTATION INFORMATION | |
D.O.T. CLASSIFICATION: NOT HAZARDOUS BY D.O.T. REGULATIONS
D.O.T. PROPER SHIPPING NAME: NOT APPLICABLE
THIS PRODUCT IS CONSIDERED AN OIL UNDER 49 CFR (DOT) PART 130. IF SHIPPED
BY RAIL OR HIGHWAY IN A TANK WITH A CAPACITY OF 3,500 GALLONS OR MORE, IT
IS SUBJECT TO THE REQUIREMENTS OF PART 130.
| XIII. OTHER INFORMATION | |
THE INFORMATION CONTAINED HEREIN IS BASED UPON DATA AVAILABLE TO US AND IS
BELIEVED TO BE ACCURATE. HOWEVER, WE MAKE NO WARRANTY, EXPRESS OR IMPLIED,
REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM
THE USE THEREOF. WE ASSUME NO RESPONSIBILITY FOR INJURY FROM THE USE OF
THE PRODUCT DESCRIBED HEREIN.
INQUIRIES REGARDING MSDS SHOULD BE DIRECTED TO:
GROWMARK, INC.
MANAGER, SAFETY AND INSURANCE SERVICES
1701 TOWANDA AVENUE
BLOOMINGTON, IL 61702
309-557-6000
FILE NAME: UNITED HEAT SHIELD 20W-50 HYDRAULIC OIL MSDS.DOC
PRINTED ON: 01/27/09
MATERIAL SAFETY DATA SHEET
NL GREASE, LLC.
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: RED LITHIUM COMPLEX 9312
COMMON NAME: GREASE, MULTIPURPOSE
CHEMICAL NAME: SOAP-THICKENED OIL LUBRICANT
MSDS: 1149-L98A00
CHEMICAL FORMULA: MIXTURE
CHEMICAL FAMILY: HYDROCARBON
NL GREASE, LLC
115 W. 26TH AVE.
NORTH KANSAS CITY, MISSOURI 64116
TRANSPORTATION EMERGENCY (CHEMTREC): 1-800-424-9300
TECHNICAL INFORMATION: 1-816-421-5222
MSDS INFORMATION: 1-816-421-5522
REV. A (06-27-01)
| SECTION 2 - COMPOSITION AND INFORMATION ON INGREDIENTS | |
INGREDIENTS PERCENTAGES PEL TLV (ACGIH) CAS #
(BY WEIGHT) (OSHA)
OIL, SEVERELY 75-95% N/A 5 MG/M3 TWA (OIL MIST) 64742-52-5
HYDROTREATED
NAPHTHENIC
SOAP PROPRIETARY N/A 2 MG/M3 TWA 7620-77-1
THICKENER
PERFORMANCE PROPRIETARY N/A 15 MG/M3 TWA
ADDITIVES (MOLYBDENUM COMPOUNDS)
(TWA):
TIME WEIGHTED AVERAGE IS THE EMPLOYEE'S AVERAGE AIRBORNE EXPOSURE IN ANY
8-HOUR WORK SHIFT OF A 40-HOUR WORK WEEK WHICH SHALL NOT BE EXCEEDED.
(STEL):
SHORT TERM EXPOSURE LIMIT IS THE EMPLOYEE'S 15-MINUTE TIME WEIGHTED
AVERAGE EXPOSURE WHICH SHALL NOT BE EXCEEDED AT ANY TIME DURING A WORK DAY
UNLESS ANOTHER TIME LIMIT IS SPECIFIED.
| SECTION 3 - HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS:
ROUTES OF ENTRY: (EYE CONTACT, DERMAL, INHALATION, INGESTION.)
ACUTE EFFECTS OF OVER EXPOSURE:
EYES: CONTACT WITH EYES MAY CAUSE IRRITATION.
SKIN: CONTACT WITH SKIN MAY CAUSE IRRITATION.
INHALATION: MAY CAUSE IRRITATION OF THE NOSE AND THROAT.
INGESTION:
MAY CAUSE NAUSEA AND VOMITING. LARGE QUANTITIES MAY EFFECT THE CENTRAL
NERVOUS SYSTEM.
CHRONIC EFFECTS OF OVEREXPOSURE: NO ADVERSE EFFECTS ANTICIPATED.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
EXISTING DERMATITIS AND RESPIRATORY CONDITIONS.
CARCINOGENICITY:
NTP: NO
IARC: NO
OSHA: NO
| SECTION 4 - FIRST AID MEASURES | |
EMERGENCY AND FIRST AID PROCEDURES:
EYE CONTACT:
IF MATERIAL COMES IN CONTACT WITH THE EYES, IMMEDIATELY WASH THE EYES WITH
LARGE AMOUNTS OF WATER FOR FIFTEEN MINUTES, OCCASIONALLY LIFTING THE LOWER
AND UPPER LIDS. GET MEDICAL ATTENTION.
SKIN CONTACT:
IF THE MATERIAL COMES IN CONTACT WITH THE SKIN, WASH THE CONTAMINATED SKIN
WITH SOAP AND WATER PROMPTLY. IF THE MATERIAL PENETRATES THROUGH CLOTHING,
REMOVE THE CLOTHING AND WASH THE SKIN WITH SOAP AND WATER PROMPTLY. IF
IRRITATION PERSISTS AFTER WASHING, GET MEDICAL ATTENTION IMMEDIATELY.
INHALATION:
IF PERSON BREATHES IN LARGE AMOUNTS OF MATERIAL, MOVE THE EXPOSED PERSON
TO FRESH AIR AT ONCE. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL
RESPIRATION. KEEP THE PERSON WARM AND AT REST. GET MEDICAL ATTENTION AS
SOON AS POSSIBLE.
INGESTION:
IF MATERIAL HAS BEEN SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION IMMEDIATELY.
| SECTION 5 - FIRE - FIGHTING MEASURES | |
FLASH POINT: >300 DEG. F (>149 DEG. C)
AUTO IGNITION TEMP: N/A
FLAMMABLE LIMITS IN AIR % BY VOLUME:
LOWER: N/A
UPPER: N/A
EXTINGUISHING MEDIA:
USE WATER SPRAY TO COOL FIRE EXPOSED SURFACES AND TO PROTECT PERSONNEL.
USE FOAM, DRY CHEMICAL OR WATER SPRAY (FOG) TO EXTINGUISH FIRE.
SPECIAL FIRE FIGHTING PROCEDURES:
WHEN FIGHTING FIRES WEAR FULL TURNOUT GEAR AND SELF CONTAINED BREATHING
APPARATUS. WATER MAY CAUSE SPLATTERING. MATERIAL FLOATS ON WATER.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
TOXIC FUMES GASES OR VAPORS MAY EVOLVE ON BURNING.
HAZARD RATINGS:
NFPA 704:
HEALTH 1
FIRE 1
REACTIVITY 0
HMIS:
HEALTH
FIRE
REACTIVITY
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO TAKE IF MATERIAL IS RELEASED OR SPILLED:
PERSONAL PROTECTIVE EQUIPMENT SHOULD BE WORN. VENTILATE AREA IF CONFINED
OR POORLY VENTILATED. CONTAIN WITH DIKES OR ABSORBENT TO PREVENT MIGRATION
TO SEWERS/STREAMS. TAKE UP SMALL SPILL WITH DRY CHEMICAL ABSORBENT; LARGE
SPILLS MAY REQUIRE PUMP OR VACUUM PRIOR TO ABSORBENT. MAY REQUIRE
EXCAVATION OF SEVERELY CONTAMINATED SOIL. AVOID CONTACT WITH SKIN AND
EYES.
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING AND STORING:
STORE IN CLOSED CONTAINER AWAY FROM ALL IGNITION SOURCES. HANDLING
TEMPERATURES SHOULD NOT EXCEED 175 DEG. F (80 DEG. C). WASH THOROUGHLY
AFTER HANDLING. DO NOT STORE AT TEMPERATURES EXCEEDING 113 DEG. F
(45 DEG. C). ODOROUS AND TOXIC FUMES MAY FORM FROM THE DECOMPOSITION OF
THIS PRODUCT IF STORED AT EXCESSIVE TEMPERATURES FOR EXTENDED PERIODS OF
TIME. OPEN CONTAINERS CAREFULLY AND ONLY IN WELL VENTILATED AREAS OR USE
APPROPRIATE RESPIRATORY PROTECTION. STORE IN WELL VENTILATED AREA.
| SECTION 8 - EXPOSURE CONTROL - PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
VENTILATE TO CONTROL MISTS AND VAPORS BELOW EXPOSURE LIMITS.
RESPIRATORY EQUIPMENT:
NORMALLY NOT REQUIRED, IF EXPOSURE LIMITS ARE EXCEEDED USE A NIOSH
APPROVED ORGANIC VAPOR RESPIRATOR. SELF CONTAINED BREATHING APPARATUS IS
RECOMMENDED FOR ENTRY INTO CONFINED SPACES OR OTHER POORLY VENTILATED
AREAS AND FOR LARGE SPILL CLEAN-UP SITES.
EYE PROTECTION:
CHEMICAL GOGGLES OR FACE SHIELD RECOMMENDED TO MINIMIZE EYE CONTACT.
PROTECTIVE CLOTHING:
IMPERVIOUS (NITRITE) GLOVES RECOMMENDED WHEN HANDLING MATERIAL TO MINIMIZE
EXPOSURE. LONG SLEEVE SHIRTS, CHEMICALLY PROTECTIVE APRONS AND CHEMICALLY
PROTECTIVE BOOTS ARE RECOMMENDED FOR CONTACT EXPOSURE OR SPILL CLEAN-UP.
DO NOT WEAR WATCHES, RINGS OR SIMILAR APPAREL THAT COULD ENTRAP THE
MATERIAL NEXT TO THE SKIN.
OTHER (SAFETY SHOWERS, EYE WASH STATIONS, ETC.):
WATER SHOULD BE AVAILABLE FOR FLUSHING AND WASHING WHEN EXPOSURE EXISTS.
LAUNDER SOILED CLOTHES. DISCARD SHOES OR OTHER LEATHER ARTICLES SATURATED
WITH THE MATERIAL.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: SEMI-SOLID GEL, SMOOTH TEXTURE, MAY CONTAIN DYE
ODOR: MILD PETROLEUM ODOR
BOILING POINT: N/D
SPECIFIC GRAVITY (WATER=1): 0.8800-0.9200
VAPOR PRESSURE: <1 MMHg 68 DEG. F
VAPOR DENSITY (AIR=1): N/D
SOLUBLE IN WATER: INSOLUBLE
EVAPORATION RATE (ETHER=1): <1
| SECTION 10 - STABILITY AND REACTIVITY | |
pH: N/D
STABILITY:
STABLE (X)(AT ROOM TEMPERATURE AND PRESSURE.
SEE HANDLING AND STORAGE SECTION)
UNSTABLE ( )
INCOMPATIBILITY:
CONDITIONS TO AVOID: SEE HANDLING AND STORAGE SECTION.
MATERIALS TO AVOID: ACIDS, OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
SMOKE, CARBON MONOXIDE, ALDEHYDES, HYDROGEN SULFIDE AND ALKYL MERCAPTANS
MAY BE RELEASED.
UNDER COMBUSTION CONDITIONS, OXIDES OF THE FOLLOWING ELEMENTS WILL BE
FORMED: NITROGEN, SULFUR, CARBON, MOLYBDENUM, BORON LITHIUM, POTASSIUM.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| SECTION 11 - TOXICOLOGY INFORMATION | |
NOTE:
NL GREASE LLC HAS NOT CONDUCTED SPECIFIC TOXICITY TESTS ON THIS PRODUCT.
| SECTION 12 - ECOLOGICAL INFORMATION | |
NOTE:
NL GREASE LLC HAS NOT CONDUCTED SPECIFIC ECOLOGICAL TESTS ON THIS PRODUCT.
| SECTION 13 - DISPOSAL CONSIDERATION | |
WASTE DISPOSAL PROCEDURES:
PLACE CONTAMINATED MATERIALS IN A DISPOSABLE CONTAINER AND DISPOSE OF IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
| SECTION 14 - TRANSPORTATION | |
DOT PROPER SHIPPING NAME: N/A
DOT HAZARD CLASS: N/A
DOT IDENTIFICATION NUMBER: N/A
DOT EMER. RESPONSE GUIDE NO.: N/A
| SECTION 15 - REGULATORY INFORMATION | |
THIS PRODUCT DOES NOT CONTAIN TOXIC CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF SARA SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY
RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372.
CAS NUMBER CHEMICAL NAME PERCENT BY WEIGHT
SARA SECTION 311-312 HAZARD CATEGORIES (40 CFR 370.2):
FIRE: NO
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE: NO
ACUTE: NO
CHRONIC: NO
| SECTION 16 - OTHER INFORMATION | |
PREPARED BY:
APPROVED BY: DENISE CAMPBELL
TITLE: SR. CHEMIST
DATE: APRIL 24, 2003
SUPERSEDES:
REASON FOR ISSUE: NEW PRODUCT
THE INFORMATION CONTAINED IN THIS MSDS RELATES ONLY TO THE SPECIFIC
MATERIAL IDENTIFIED. IT DOES NOT COVER USE OF THAT MATERIAL IN COMBINATION
WITH ANY OTHER MATERIAL OR IN ANY PARTICULAR PROCESS. IN COMPLIANCE WITH
29 C.F.R. 1910.1200(G), NL GREASE, LLC HAS PREPARED THIS MSDS IN SEGMENTS,
WITH THE INTENT THAT THOSE SEGMENTS BE READ TOGETHER AS A WHOLE WITHOUT
TEXTUAL OMISSIONS OR ALTERATIONS. NL GREASE, LLC BELIEVES THE INFORMATION
CONTAINED HEREIN TO BE ACCURATE, BUT MAKES NO REPRESENTATION, GUARANTEE,
OR WARRANTY, EXPRESS OR IMPLIED, ABOUT THE ACCURACY, RELIABILITY, OR
COMPLETENESS OF THE INFORMATION OR ABOUT THE FITNESS OF CONTENTS HEREIN
FOR EITHER GENERAL OR PARTICULAR PURPOSES. PERSONS REVIEWING THIS MSDS
SHOULD MAKE THEIR OWN DETERMINATION AS TO THE MATERIAL'S SUITABILITY AND
COMPLETENESS FOR USE IN THEIR PARTICULAR APPLICATIONS.